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Near-infrared mapping spectrometer for investigation of Jupiter and its satellites

In the late 1980s, the investigation of the Jupiter system will be continued with the aid of the Galileo spacecraft, which is to be placed in orbit around the planet. The Near-Infrared Mapping Spectrometer (NIMS) is one of several instruments which will be employed in connection with the study of Jupiter and its satellites. The NIMS combines spectroscopic and imaging capabilities. It represents, therefore, a new concept in remote sensing planetary experiments. Information provided by NIMS will be supplemented by results obtained with the aid of the Galileo Solid State Imager (SSI). In the SSI, very high spatial resolution is obtained, but limited spectral information is available. One of the goals of the Galileo mission is related to the investigation of the chemical composition and physical state of Jupiter's satellites, taking into account Io, Europa, Ganymede, and Callisto. Another primary aim involves the study of the Jovian atmosphere, giving attention to chemical composition, atmospheric structure, clouds, energy balance, and atmospheric motions.

Aptaker, I. M.↗

Infrared observations of planetary atmospheres

Infrared data was obtained on planetary atmospheres which provides critical information on atmospheric structure, composition, and cloud properties in support of planetary missions such as Voyager and Galileo. Mapping of Jupiter and Saturn in thermal and reflected solar radiation is a high-priority monitoring and exploratory activity. Some of these images of Jupiter are shown. Radiation at 17.8 micrometer probes the upper tropospheric temperature structure where spatial structure bears a strong resemblance to visible and near-infrared reflected sunlight such as at 2.0 micrometer. At 7.8 micrometer, stratospheric temperatures appear to have a three-banded structure, enhancements near the magnetic poles and occasional transient features such as the equatorial filament near the right limb. Clouds or hazes are observed high in the stratosphere looking at wavelengths such as 2.2 micrometer, where gaseous opacity is very strong. Other maps examine cloud properties from thermal radiation not strongly influenced by gaseous opacity and the distribution of condensable gases, such as ammonia. Millimeter and submillimeter filtered radiometric observations were made of Jupiter, Uranus and Neptune via collaborative work. Radiometric observations of Uranus and Neptune at 21 and 32 micrometer were acquired and analyzed as well as grating array spectra in the ranges of 8 to 14 micrometer, 16 to 23 micrometer, and 18 to 32 micrometer. These showed evidence for C2H2 in the stratosphere of Uranus and C2H4 in the stratosphere of Neptune.

Orton, G. S.↗

Atmospheric Hydroperoxides in West Antarctica: Links to Stratospheric Ozone and Atmospheric Oxidation Capacity

The troposphere above the West Antarctic Ice Sheet (WAIS) was sampled for hydroperoxides at 21 locations during 2-month-long summer traverses from 2000 to 2002, as part of US ITASE (International Transantarctic Scientific Expedition). First time quantitative measurements using an HPLC method showed that methylhydroperoxide (MHP) is the only important organic hydroperoxide occurring in the Antarctic troposphere, and that it is found at levels ten times those previously predicted by photochemical models. During three field seasons, means and standard deviations for hydrogen peroxide (H2O2) were 321+/-158 pptv, 650+/-176 pptv and 330+/-147 pptv. While MHP was detected, but not quantified in December 2000, levels in summer 2001 and 2002 were 317+128 pptv and 304+/-172.2 pptv. Results from firn air experiments and diurnal variability of the two species showed that atmospheric H2O2 is significantly impacted by a physical snow pack source between 76 and 90degS, whereas MHP is not. We show strong evidence of a positive feedback between stratospheric ozone and H2O2 at the surface. Between November-27 and December-12 in 2001, when ozone column densities dropped below 220 DU (means in 2000 and 2001 were 318 DU and 334 DU, respectively), H2O2 was 1.7 times that observed in the same period in 2000 and 2002, while MHP was only 80% of the levels encountered in 2002. Photochemical box model runs suggest that NO and OH levels on WAIS are closer to coastal values, while Antarctic Plateau levels are higher, confirming that region to be a highly oxidizing environment. The modeled sensitivity of H2O2 and particularly MHP to NO offers the potential to use atmospheric hydroperoxides to constrain the NO background and thus estimate the past oxidation capacity of the remote atmosphere. Index Terms: 0365 Atmospheric Composition and Structure: Troposphere: composition and chemistry; 0322 Atmospheric Composition and Structure: Constituent sources and sinks; 1610 Global Change: Atmosphere (03 15,0325); 0736 Cryosphere: Snow (1827, 1863); 0724 Cryosphere: Ice Cores (4932) Keywords: hydrogen peroxide, methylhydroperoxide, Antarctica, air-snow exchange, stratospheric ozone, atmospheric oxidation capacity

Frey, Markus M.↗

New Particle Formation in Anthropogenic Plumes Advecting from Asia Observed During TRACE-P

The characteristics and sources of what are believed to be newly formed 3 to 4 nm particles in anthropogenic plumes advecting from Asian are reported. Airborne measurements were made from March to April 2001 as part of the NASA TRACE-P experiment at latitudes ranging from North of the Philippines to Northern Japan (20 to 45 deg. N). In the more polluted plumes, high concentrations of 3 to 4 nm diameter particles (less than 100/qu cm) were observed both within and along the upper outer edges of plumes that were identified by enhanced carbon monoxide and fine particulate sulfate concentrations. The results from two research flights are investigated in detail. Three to four-nm particle concentrations are generally correlated with gas phase sulfuric acid and found in regions of low surface areas relative to the immediate surroundings or where there are steep transitions to lower surface areas. Sulfuric acid and surface area concentrations in the most polluted plume reached 6 x l0(exp 7) and 750 micro sq m/qu cm, respectively, in regions of particle formation. In contrast to these anthropogenic plumes, few 3 to 4 nm particles were observed in the clean background and few were detected within a volcanic plume where the studies highest H2SO4 concentrations (less than lO(exp 8)/qu cm) were recorded. Enhanced SO2 concentrations in the range of approximately 2 to 7 ppb, in conjunction with other unidentified, possibly coemitted species, appear to be the driving factor for nucleation. (0345, 4801); 0322 Atmospheric Composition and Structure: Constituent sources and sinks; 0345 Atmospheric Composition and Structure: Pollution-urban and regional (0305); 4801 Oceanography: Biological and Chemical: Aerosols (0305).

Weber, R. J.↗

Jupiter's atmospheric composition and cloud structure deduced from absorption bands in reflected sunlight

The spectrum of sunlight reflected by Jupiter is analyzed by comparing observations of Woodman (1979) with multiple-scattering computations. The analysis yields information on the vertical cloud structure at several latitudes and on the abundance of CH4 and NH3 in the atmosphere of Jupiter. The abundances of CH4 and NH3 suggest that all ices and rocks are overabundant on Jupiter by a factor of 2 or more, providing an important constraint on models for the formation of Jupiter from the primitive solar nebula. The pressure level of the clouds, the gaseous NH3 abundance, the mean temperature profile, and the Clausius-Clapeyron relation suggest that these clouds are predominantly ammonia crystals with the cloud bottom at 600-700 mb. A diffuse distribution of aerosols exists between 150 and 500 mb, and the spectral variation of albedo reflects a changing bulk absorption coefficient of the material composing the aerosols and is diagnostic of the aerosol composition.

Sato, M.↗

Hubble/WFC3 Spectroscopy of the Transiting Exoplanets WASP-19b and WASP-17b

Measurements of transiting exoplanets that target extremes in parameter space offer the best chance to disentangle the structure and composition of the atmospheres of hot Jupiters. WASP-19b is one of the hottest exoplanets discovered to date, while WASP-17b has a much lower equilibrium temperature but has one of the largest atmospheric radii of known transiting planets. We discuss results from HST/WFC3 grism 1.1-1.7 micron spectroscopy of these planets during transit. We compare our integrated-light transit depths to previous IR transit photometry, and derive the 1.4-micron water absorption spectrum. We discuss implications for the atmospheric composition and structure of these hot Jupiters, and outline future observations that will further expand on these results.

Mandell, A.↗

Models of Pluto's upper atmosphere

Best guesses as to the thermal structure and composition of Pluto's atmosphere have led to speculations of substantial loss rates of methane from the planet over cosmogonic time scales. Results from recent stellar occultation measurements, and using a Parker-type hydrodynamic calculation, show that the loss rates may actually be lower by as much as a factor of about 5, depending upon the efficiency of heating of the atmosphere via the absorption of solar EUV and upon the true atmospheric composition, if the thermal structure of the upper atmosphere is properly taken into account. The loss rate may even be less (by another factor of about 10) if there is minimal heating of the upper atmosphere.

Mcnutt, Ralph L., Jr.↗

Ar Atmosphere: Implications for Structure and Composition of Mercury's Crust

We examine the possibilities of sustaining an argon atmosphere by diffusion from the upper 10 km of crust, and alternatively by effusion from a molten or previously molten area at great depth . Ar-40 in the atmospheres of the planets is a measure of potassium abundance in the interiors since Ar-40 is a product of radiogenic decay of K-40 by electron capture with the subsequent emission of a 1.46 eV gamma-ray. Although the Ar-40 in the earth's atmosphere is expected to have accumulated since the late bombardment, Ar-40 in surface-bounded exospheres is eroded quickly by photoionization and electron impact ionization. Thus, the argon content in the exospheres of the Moon, Mercury and probably Europa is representative of current effusion rather than accumulation over the lifetime of the body. Argon content will be a function of K content, temperature, grain size distribution, connected pore volume and possible seismic activity. Although Mercury and the Moon differ in many details, we can train the solutions to diffusion equations to predict the average lunar atmosphere. Then these parameters can be varied for Hermean conditions. Assuming a lunar crustal potassium abundance of 300 ppm, the observed argon atmosphere requires equilibrium between the argon production in the upper 9 Km of the moon (1.135 x 10(exp -3) cm(exp -3) s(exp -1)) and its loss. Hodges et al. conclude that this loss rate and the observed time variability requires argon release through seismic activity, tapping a deep argon source. An important observation is that the extreme surface of the Moon is enhanced in argon rather than depleted, as one would expect from outgassing of radiogenic argon. Manka and Michel concluded that ion implantation explains the surface enhancement of Ar-40. About half of the argon ions produced in the lunar atmosphere would return to the surface, where they would become embedded in the rocks. Similarly, at Mercury we expect the surface rocks to be enhanced in Ar-40 wherever the magnetosphere has been open over time. Thus the measurement of surface composition will reveal the long-term effects of solar wind-magnetosphere interaction. Additional information is contained in the original extended abstract.

Killen, R. M.↗

Interpretation of Voyager UVS observations of occultations by the atmosphere of Neptune

We propose to continue our investigation of the upper atmosphere of Neptune based primarily on the solar occultation measurements made by the Voyager Ultraviolet Spectrometer (UVS). The ultimate goal of this research is to understand the structure and composition of Neptune's upper atmosphere as encoded in the data base obtained by the UVS during the Voyager 2 encounter with Neptune. The UVS occultations provide information essential to studies of atmospheric composition and structure, energy balance, photochemistry, global transport, ionospheric structure, and airglow production mechanisms. In conjunction with other research in progress at the University of Arizona and by our colleagues at other institutions, we not only analyze and interpret individual measurements or observations by the UVS, but also construct models of the upper atmosphere which are consistent with all available data obtained by the UVS. We derive constraints from measurements of the atmospheric emissions and we combine these with constraints derived from the occultation measurements. Principal sources for the atmospheric emissions include dayglow, resonance scattering and, at long wavelengths, the reflected solar spectrum. On the dark side of the planet, a weak H Ly alpha emission is due to resonance scattering of the sky background and perhaps another source. Thus a wide range of physical processes are at work, and each provides its own constraints on the atmosphere.

Sandel, Bill R.↗

The planet Saturn (1970)

The present-day knowledge on Saturn and its environment are described for designers of spacecraft which are to encounter and investigate the planet. The discussion includes physical properties of the planet, gravitational field, magnetic and electric fields, electromagnetic radiation, satellites and meteoroids, the ring system, charged particles, atmospheric composition and structure, and clouds and atmospheric motions. The environmental factors which have pertinence to spacecraft design criteria are also discussed.

Source record↗

Composition and structure of the Venus atmosphere - Results from Pioneer Venus

The composition of the Venusian atmosphere was studied using a mass spectrometer on the Pioneer Venus sounder probe. The single-focusing magnetic-sector spectrometer scanned the mass range from hydrogen through mercury with a dynamic range of six decades. Data taken by the mass spectrometer were compared with those of a gas chromatograph, resulting in slight discrepancies due to the use of a sputter ion pump acting as a sink for entry of rare gases through the inlet leak. A surprisingly large concentration of primordial Ar-36 and Ar-38 was discovered in a ratio of 5 to 1. It was concluded that the large excess of primordial argon was a valid result and that the mixing of HCl in the lower Venusian atmosphere was less than a few parts per million. Arguments against the sun as the source for excess primordial gases on Venus were presented. Concentrations of other elements such as Ne, Kr, He, S, and O were discussed. Although the mass peaks in the spectrum were real, it was not clear whether all of the chemical reactions (i.e., COS production) actually occurred in the atmosphere. Until further analysis can be made, it will be uncertain how the inlet system, which is at atmospheric temperature, affected the results.

Hoffman, J. H.↗

Composition and structure of Mars' upper atmosphere - Results from the neutral mass spectrometers on Viking 1 and 2

The upper atmospheric mass spectrometers flown on Viking 1 and 2 are described, and results obtained for the composition and structure of Mars' upper atmosphere are summarized. Carbon dioxide is the major constituent of the atmosphere at all heights below 180 km. The thermal structure of the upper atmosphere is complex and variable with average temperatures below 200 K for both Viking 1 and 2. The atmosphere is mixed to heights in excess of 120 km. The isotopic composition of carbon and oxygen in the Martian atmosphere is similar to that in the terrestrial atmosphere: N-15 is enriched in Mars' atmosphere by a factor of 1.62 + or - 0.16.

Nier, A. O.↗

The effect of gravity waves on the global mean temperature and composition structure of the upper atmosphere

Formulas are presented that parameterize the heating rate and coefficient of turbulent heat conduction produced by saturated internal gravity waves (IGW) in the upper atmosphere. Estimates of these values are made using observational data. The parameterization of IGW influences are introduced into a one-dimensional model of global mean thermal and composition balances of the upper atmosphere. Computations are performed for different values of IGW energy fluxes entering into the upper atmosphere from below. It is shown that realistic vertical profiles of the global mean temperature can be obtained using different values of IGW energy flux into the upper atmosphere. Increasing the IGW intensity leads not only to an increase of the heating rate due to wave enery dissipation, but also to an increase of the heating rate due to wave energy dissipation, but also to an increase in the coefficient of turbulent heat conduction and cooling rate produced by turbulence generated by the wave. So, near an altitude of 100 km the main part of solar heating is compensated by infrared cooling on one hand, and the main part of wave dissipation heating is compensated by turbulent cooling on the other hand. These quasi-balances generally hold for different values of IGW intensity.

Gavrilov, Nikolai M.↗

An investigation of the structure and composition of the solar atmosphere using X-ray and EUV spectra obtained with the OV1-17 and OSO-4 and OSO-5 satellites

Studies of the structure and composition of the solar corona were undertaken, using a number of satellite observations of the coronal X-ray spectrum. A systematic technique was developed to carry out the required analysis, and the analytical techniques available to calculate the coronal spectrum have been developed and improved. A review of other analyses of solar coronal structure is also included.

Walker, A. B. C., Jr.↗

Network for the detection of stratospheric change (NDSC)

The notion of a ground-based long-term measuring network specifically designed to provide the earliest possible detection of changes in the composition and structure of the stratosphere and to understand the causes of those changes is examined. The network's short-term goals are: to study the temporal and spatial variability of atmospheric composition and structure; to provide the basis for ground truth and complementary measurements for satellite systems such as the NASA Upper Atmosphere Research Satellite; and to critically test multidimensional stratospheric models and provide the broad data base required for improved model development. Priorities, instrumentation, station considerations, and site requirements are also discussed.

Kurylo, Michael J.↗