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Improved Simulations of Biomass Burning Aerosol Optical Properties and Lifetimes in the NASA GEOS Model during the ORACLES-I Campaign

In order to improve aerosol representation in the NASA Goddard Earth Observing System (GEOS) model, we evaluated simulations of the aerosol properties and transport over the southern African biomass burning source and outflow region using observations made during the first deployment of the ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) field campaign in September 2016. An example case study of September 24 was analyzed in detail, during which aircraft-based in-situ and remote sensing observations showed the presence of a multi-layered smoke plume structure with significant vertical variation in single scattering albedo (SSA). Our baseline GEOS simulations were not able to represent the observed SSA variation, nor the observed organic aerosol-to-black carbon ratio (OA : BC). Analyzing the simulated smoke age suggests that the higher altitude, less absorbing smoke plume was younger (~4 days), while the lower altitude and more absorbing smoke plume was older (~7 days). We hypothesize a chemical or microphysical loss process exists to explain the change in aerosol absorption as the smoke plume ages, and we apply a simple 6-day e-folding loss rate to the model hydrophilic biomass burning OA to mimic this process. Adding this loss process required some adjustment to the model assumed scaling factors of aerosol emissions to conserve the regional aerosol loading and further improve the simulated OA : BC ratio. Accordingly, we have increased our biomass burning emissions of OA by 60 % and biomass burning BC by 15 %. We also utilized the ORACLES airborne observations to better constrain the simulation of aerosol optical properties, adjusting the assumed particle size, hygroscopic growth, and absorption. Our final GEOS model simulation with additional OA loss and updated optics showed a better performance in simulating AOD and SSA compared to independent ground and space-based retrievals for the entire month of September 2016, including the OMI Aerosol Index. In terms of radiative implications of our model adjustments, the final GEOS simulation suggested a decreased atmospheric warming of about 10 % (~2 W m -2 ) over the south-east Atlantic region and above the stratocumulus cloud decks compared to the model baseline simulations. These results improve the representation of the smoke age, transport, and optical properties in Earth system models.

aerosols↗

Identifying Chemical and Optical Smoke Signatures in Suborbital Observations to Improve Model Projections

Biomass Burning (BB) fires are expected to occur more frequently in the future due to climate change, the build‐up of fuels due to fire suppression, and the expansion of the wildland‐urban interface [Schoennagel et al., 2017; Shivdenko & Schepaschenko, 2013; Stevens et al., 2014; Turner et al., 2019; Yue et al., 2015; Tilman et al., 2001]. Accurate knowledge of the abundance, distribution, and optical properties of absorbing aerosols such as BB smoke is essential to understanding regional and global aerosol radiative effects [Boucher et al., 2013]. It is recognized that differing fuel types (e.g., rice straw, ponderosa pine), combustion modes (i.e., flaming, smoldering or both) and temperature/ moisture content produce smoke with differing optical characteristics (e.g., aerosol light scattering and absorption) and component mixing ratios [e.g., BC, OC and inorganic species such as sulfate, potassium, chloride; Streets et al. 2003; Reid et al., 2005a, b; Janhäll et al., 2010; Sayer et al., 2014]. However, climate models often ascribe a fixed set of emission factors [i.e., amount of particulate for a given species released in the atmosphere per unit dry fuel burned; Darmenov and Dasilva, 2013] and optical properties [Hess et al., 1998] to all BB aerosol plumes, inherently limiting accurate representation of the global and regional heterogeneity of BB. The overarching goal of the proposed work is to improve the microphysical and optical representation of different types of Biomass Burning in Chemistry Transport Models. Our strategy is to capitalize on multiple airborne campaigns (e.g., ARCTAS, SEAC4RS, ORACLES, FIREX-AQ), which sampled different types of BB plumes at different aging stages. Models, when improved and combined with satellite, airborne, and ground observations will help address many aerosol science objectives from the NASA Decadal survey [National Academies of Sciences, Engineering, and Medicine. 2018].

Meloe Shenandoah F Kacenelenbogen↗

Impact Assessment of Biomass Burning on Air Quality in Southeast and East Asia During BASE-ASIA

A synergy of numerical simulation, ground-based measurement and satellite observation was applied to evaluate the impact of biomass burning originating from Southeast Asia (SE Asia) within the framework of NASA's 2006 Biomass burning Aerosols in Southeast Asia: Smoke Impact Assessment (BASE-ASIA). Biomass burning emissions in the spring of 2006 peaked in MarcheApril when most intense biomass burning occurred in Myanmar, northern Thailand, Laos, and parts of Vietnam and Cambodia. Model performances were reasonably validated by comparing to both satellite and ground-based observations despite overestimation or underestimation occurring in specific regions due to high uncertainties of biomass burning emission. Chemical tracers of particulate K(+), OC concentrations, and OC/EC ratios showed distinct regional characteristics, suggesting biomass burning and local emission dominated the aerosol chemistry. CMAQ modeled aerosol chemical components were underestimated at most circumstances and the converted AOD values from CMAQ were biased low at about a factor of 2, probably due to the underestimation of biomass emissions. Scenario simulation indicated that the impact of biomass burning to the downwind regions spread over a large area via the Asian spring monsoon, which included Southern China, South China Sea, and Taiwan Strait. Comparison of AERONET aerosol optical properties with simulation at multi-sites clearly demonstrated the biomass burning impact via longrange transport. In the source region, the contribution from biomass burning to AOD was estimated to be over 56%. While in the downwind regions, the contribution was still significant within the range of 26%-62%.

biomass burning↗

Interpreting the Ultraviolet Aerosol Index Observed with the OMI Satellite Instrument to Understand Absorption by Organic Aerosols: Implications for Atmospheric Oxidation and Direct Radiative Effects

Satellite observations of the ultraviolet aerosol index (UVAI) are sensitive to absorption of solar radiation by aerosols; this absorption affects photolysis frequencies and radiative forcing. We develop a global simulation of the UVAI using the 3-D chemical transport model GEOSChem coupled with the Vector Linearized Discrete Ordinate Radiative Transfer model (VLIDORT). The simulation is applied to interpret UVAI observations from the Ozone Monitoring Instrument (OMI) for the year 2007. Simulated and observed values are highly consistent in regions where mineral dust dominates the UVAI, but a large negative bias (-0.32 to -0.97) exists between simulated and observed values in biomass burning regions. We determine effective optical properties for absorbing organic aerosol, known as brown carbon (BrC), and implement them into GEOS-Chem to better represent observed UVAI values over biomass burning regions. The inclusion of absorbing BrC decreases the mean bias between simulated and OMI UVAI values from -0.57 to -0.09 over West Africa in January, from -0.32 to +0.0002 over South Asia in April, from -0.97 to -0.22 over southern Africa in July, and from -0.50 to +0.33 over South America in September. The spectral dependence of absorption after including BrC in the model is broadly consistent with reported observations for biomass burning aerosol, with absorbing Angstrom exponent (AAE) values ranging from 2.9 in the ultraviolet (UV) to 1.3 across the UV-Near IR spectrum. We assess the effect of the additional UV absorption by BrC on atmospheric photochemistry by examining tropospheric hydroxyl radical (OH) concentrations in GEOS-Chem. The inclusion of BrC decreases OH by up to 30% over South America in September, up to 20% over southern Africa in July, and up to 15% over other biomass burning regions. Global annual mean OH concentrations in GEOS-Chem decrease due to the presence of absorbing BrC, increasing the methyl chloroform lifetime from 5.62 to 5.68 years, thus reducing the bias against observed values. We calculate the direct radiative effect (DRE) of BrC using GEOS-Chem coupled with the radiative transfer model RRTMG (GC-RT). Treating organic aerosol as containing more strongly absorbing BrC changes the global annual mean all-sky top of atmosphere (TOA) DRE by +0.03Wm(exp -2) and all-sky surface DRE by -0.08Wm(exp -2). Regional changes of up to +0.3Wm(exp -2) at TOA and down to -1.5Wm(exp -2) at the surface are found over major biomass burning regions.

Air Pollution↗

Airborne lidar observations of smoke haze during SCAR-B 1995

The Smoke, Clouds, Aerosol, and Radiation Brazil(SCAR-B) field campaign was conducted to study the effects that widespread and persistent biomass burning have upon radiative and chemical processes in the atmosphere. The radiative transfer characteristics of the atmosphere are altered by the introduction of particulate and gaseous materials which are the products of the combustion of vegetative material at ground level. These substances are transported and distributed horizontally and vertically by atmospheric dynamical processes which may be perturbed by the heat energy from the fires. As the pollutants disperse, their physical and chemical properties change substantially. A complete description of the effects of smoke requires that the evolution back to the natural situation be fully examined. A most important component of smoke haze investigation is finding its vertical and horizontal distribution in relation to the driving factors of dynamics and the related horizontal transport. In this presentation, we employ data from the Cloud Lidar System(CLS), carried aboard the NASA ER-2 aircraft, to provide a unique view of the particulate or aerosol loading produced by fires, especially with regard to the geometrical distribution of the aerosols in the vertical plane. The lidar has the ability to measure aerosol optical properties in a continuous fashion at quite fine vertical and horizontal resolution. The results from the lidar provide measurements that are largely independent of influences that corrupt passive instruments and thus it can serve to corroborate their results. The extended horizontal and vertical range of lidar results can also augment ground based and airborne in situ measurements which have limited horizontal and vertical scope. We present the results of our analysis of CLS observations taken during the SCAR-B field campaign. Observations of the the aerosol optical thickness from the Aerosol Robotic Network(AERONET) of solar photometers are employed in conjunction with CLS data to derive extinction to backscatter ratio values which are used to convert the lidar backscatter coefficient into extinction coefficient. The extinction coefficient is integrated vertically to find aerosol optical thickness along ER-2 flight tracks. We use images of the CLS derived extinction coefficient to depict its horizontal and vertical distribution. Multispectral photometer optical thickness is used to compute the Angstrom exponent. With these, we examine the hypothesis that the values of extinction to backscatter ratio can be related to the Anstrom coefficient since both of these would be a function of the refractive index and size distribution of the aerosols.

Hart, William D.↗

Biomass in the upwelling areas along the northwest coast of Africa as viewed with ERTS-1

Light penetration in water is affected by plankton, algae, and dissolved and suspended matter. As a consequence, the composition of backscattered light from below the air-sea interface is determined by the nature of the constituents in the water column. In contrast to the absorption spectrum of chemically pure chlorophyll in solution, algae suspensions absorb and scatter light more uniformly throughout the visible part of the electromagnetic spectrum. Because of their spectral absorption and scattering properties plankton concentration can be estimated by measuring the spectral backscattered radiance over water. Experiments using this approach were performed in upwelling regions along the northwest coast of Africa.

Szekielda, K.↗

Modeling Atmospheric Brown Carbon in the GISS ModelE Earth System Model

Brown carbon (BrC) is an absorbing organic aerosol (OA), primarily emitted through biomass burning (BB), which exhibits light absorption unique to both black carbon (BC) and other organic aerosols. Despite many field and laboratory studies seeking to constrain BrC properties, the radiative forcing (RF) of BrC is still highly uncertain. To better understand its climate impact, we introduced BrC to the One-Moment Aerosol (OMA) module of the GISS ModelE Earth system model (ESM). We assessed ModelE sensitivity to primary BrC processed through a novel chemical aging scheme and to secondary BrC formed from biogenic volatile organic compounds (BVOCs). Initial results show that BrC typically contributes a top-of-the-atmosphere (TOA) radiative effect of 0.04 W m −2 . Sensitivity tests indicate that explicitly simulating BrC (separating it from other OAs), including secondary BrC, and simulating chemical bleaching of BrC contribute distinguishable radiative effects and should be accounted for in BrC schemes. This addition of prognostic BrC to ModelE allows greater physical and chemical complexity in OA representation with no apparent trade-off in model performance, as the evaluation of ModelE aerosol optical depth against Aerosol Robotic Network (AERONET) and Moderate Resolution Imaging Spectroradiometer (MODIS) retrieval data, with and without the BrC scheme, reveals similar skill in both cases. Thus, BrC should be explicitly simulated to allow more physically based chemical composition, which is crucial for more detailed OA studies like comparisons to in situ measurement campaigns. We include a summary of best practices for BrC representation within ModelE at the end of this paper.

brown carbon aerosols↗

Aerosol Retrievals Using Channel 1 and 2 AVHRR Data

The effect of tropospheric aerosols on global climate via the direct and indirect radiative forcings is one of the largest remaining uncertainties in climate change studies. Current assessments of the direct aerosol radiative effect mainly focus on sulfate aerosols. It has become clear, however, that other aerosol types like soil dust and smoke from biomass burning are also likely to be important climate forcing factors. The magnitude and even the sign of the climate forcing caused by these aerosol types is still unknown. General circulation models (GCMs) can be used to estimate the climatic effect of the direct radiative forcing by tropospheric and stratospheric aerosols. Aerosol optical properties are already parameterized in the Goddard Institute for Space Studies GCM. Once the global distribution of aerosol properties (optical thickness, size distribution, and chemical composition) is available, the calculation of the direct aerosol forcing is rather straighfforward. However, estimates of the indirect aerosol effect require additional knowledge of the physics and chemistry of aerosol-cloud interactions which are still poorly understood. One of the main objectives of the Global Aerosol Climatology Project, established in 1998 as a joint initiative of NASA's Radiation Science Program and GEWEX, is to infer the global distribution of aerosols, their properties, and their seasonal and interannual variations for the full period of available satellite data. This will be accomplished primarily through a systematic application of multichannel aerosol retrieval algorithms to existing satellite data and advanced 3-dimensional aerosol chemistry/transport models. In this paper we outline the methodology of analyzing channel 1 and 2 AVHRR radiance data over the oceans and describe preliminary retrieval results.

Mishchenko, Michael I.↗

Columnar Aerosol Types and Compositions Over Peninsular Southeast Asia Based on Long-Term AERONET Data

Aerosol chemical components such as black carbon (BC) and brown carbon (BrC) regulate aerosol optical properties, which in turn drive the atmospheric radiative forcing estimations due to aerosols. In this study, we used the long-term measurements from AERONET (Aerosol Robotic Network) to better understand the aerosol types and composition with respect to their seasonal and spatial variabilities in peninsular Southeast Asia (PSEA, here defined as Vietnam, Cambodia, Thailand, Laos, and Myanmar). Two methods (i.e., aerosol type cluster and aerosol component retrieval) were applied to determine the aerosol type and chemical composition during the biomass-burning (BB) season. AERONET sites in northern PSEA showed a higher AOD (aerosol optical depth) compared to that of southern PSEA. Differences in land use pattern, geographic location, and weather regime caused much of the aerosol variability over PSEA. Lower single-scattering albedo (SSA) and higher fine-mode fraction (FMF) values were observed in February and March, suggesting the predominance of BB type aerosols with finer and stronger absorbing particles during the dry season. However, we also found that the peak BB month (i.e., March) in northern PSEA may not coincide with the lowest SSA once dust particles have mixed with the other aerosols. Furthermore, we investigated two severe BB events in March of 2014 and 2015, revealing a significant BrC fraction during BB event days. On high AOD days, although the BC fraction was high, the BrC fraction remained low due to lack of aerosol aging. This study highlights the dominance of carbonaceous aerosols in the PSEA atmosphere during the BB season, while also revealing that transported dust particles and BrC aerosol aging may introduce uncertainties into the aerosol radiative forcing calculation.

Sheng-Hsiang Wang↗

Synergy of Satellite-Surface Observations for Studying the Properties of Absorbing Aerosols in Asia

Through interaction with clouds and alteration of the Earth's radiation budget, atmospheric aerosols significantly influence our weather and climate. Monsoon rainfalls, for example, sustain the livelihood of more than half of the world's population. Thus, understanding the mechanism that drives the water cycle and freshwater distribution is high-lighted as one of the major near-term goals in NASA's Earth Science Enterprise Strategy. Every cloud droplet/ice-crystal that serves as an essential element in portraying water cycle and distributing freshwater contains atmospheric aerosols at its core. In addition, the spatial and temporal variability of atmospheric aerosol properties is complex due to their dynamic nature. In fact, the predictability of the tropical climate system is much reduced during the boreal spring, which is associated with the peak season of biomass burning activities and regional/long-range transport of dust aerosols. Therefore, to accurately assess the impact of absorbing aerosols on regional-to-global climate requires not only modeling efforts but also continuous observations from satellites, aircraft, networks of ground-based instruments and dedicated field experiments. Since 1997 NASA has been successfully launching a series of satellites the Earth Observing System - to intensively study, and gain a better understanding of, the Earth as an integrated system. Through participation in many satellite remote-sensing/retrieval and validation projects over the years, we have gradually developed and refined the SMART (Surface-sensing Measurements for Atmospheric Radiative Transfer) and COMMIT (Chemical, Optical & Microphysical Measurements of In-situ Troposphere) mobile observatories, a suite of surface remote sensing and in-situ instruments that proved to be vital in providing high temporal measurements, which complement the satellite observations. In this talk, we will present SMART-COMMIT which has played key roles, serving as network or supersite, in major international research projects such as the Joint Aerosol Monsoon Experiment (JAM EX), a core element of the Asian Monsoon Years (AMY, 2008-2012). SMART-COMMIT deployments during 2008 AMY/JAMEX were conducted in northwestern China to characterize the properties of dust-laden aerosols and in the vicinity of Beijing for mega-city aerosols. In 2009, SMART-COMMIT also participated in the JAMEX/RAJO-MEGHA (Radiation, Aerosol Joint Observations-Monsoon Experiment in the Gangetic-Himalayan Area; Sanskrit for Dust-Cloud) to study the aerosol properties, solar absorption and the associated atmospheric warming, and the climatic impact of elevated aerosols during the pre-monsoon season in South Asia. We will show results from these field experiments, as well as discuss a new initiative of 7-SEAS (7 South East Asian Studies) to study the interaction of anthropogenic aerosols with regional meteorology, particularly with clouds.

Tsay, Si-Chee↗

Surface-Satellite Measurements for Atmospheric Radiative Transfer (SMART)and Chemical, Optical and Microphysical Measurements of In-Situ Troposphere (COMMIT) Research Activities

The GSFC SMART consists of a suite of remote sensing instruments, including many commercially available radiometers, spectrometer, interferometer, and three in-house developed inskuments: micro-pulse lidar (MPL), scanning microwave radiometer (SMiR), and sun-sky-surface photometer (S(sup 3)). SMART cover the spectral range from UV to microwave, and passive to active remote sensing. This is to enrich the EOS-like research activities (i.e., EOS validation, innovative investigations, and long-term local environmental observations). During past years, SMART has been deployed in many NASA supported field campaigns to collocate with satellite nadir overpass for intercomparisons, and for initializing model simulations. Built on the successful experience of SMART, we are currently developing a new ground-based in-situ sampling package, COMMIT, including measurements of trace gases (CO, SO2, NOx, and O3,) concentrations, fine/coarse particle sizers and chemical composition, single- and three-wavelength nephelometers, and surface meteorological probes. COMMIT is built for seeking a relationship between surface in-situ measurements and boundary layer characteristics. This is to enrich EOS-like research on removing boundary layer signal from the entire column from space observation - to deduce the stable (less variability) free-troposphere observations. The COMMIT will try its best to link the chemical, microphysical, and optical properties of the boundary layer with radiation. The next major activities for SMART-COMMIT are scheduled for 2004-2006 in BASE-ASIA and EAST-AIRE. The expected close collaboration of BASE-ASIA with various research projects in Asia (i.e., ABC in South Asia, led by Ramanathan et al.; EAST-AIRE in East Asia, led by Li et al.; and APEX in Northeast Asia, led by Nakajima et al.) will definitely provide a better understanding of the impact of the biomass burning and air pollutants on regional-to-global climate, hydrological and carbon cycles, and tropospheric chemistry in Asia.

Tsay, Si-Chee↗

Modeling and Assimilating Ocean Color Radiances

Radiances are the source of information from ocean color sensors to produce estimates of biological and geochemical constituents. They potentially provide information on various other aspects of global biological and chemical systems, and there is considerable work involved in deriving new information from these signals. Each derived product, however, contains errors that are derived from the application of the radiances, above and beyond the radiance errors. A global biogeochemical model with an explicit spectral radiative transfer model is used to investigate the potential of assimilating radiances. The results indicate gaps in our understanding of radiative processes in the oceans and their relationships with biogeochemical variables. Most important, detritus optical properties are not well characterized and produce important effects of the simulated radiances. Specifically, there does not appear to be a relationship between detrital biomass and its optical properties, as there is for chlorophyll. Approximations are necessary to get beyond this problem. In this reprt we will discuss the challenges in modeling and assimilation water-leaving radiances and the prospects for improving our understanding of biogeochemical process by utilizing these signals.

Gregg, Watson↗

Biomass-Burning Aerosols in South East-Asia: Smoke Impact Assessment (BASE-ASIA)

Biomass burning has been a regular practice for land clearing and land conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the unique climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Significant global sources of greenhouse gases (e.g., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3Br), and atmospheric aerosols are produced by biomass burning processes. These gases influence the Earth- atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play an important role in determining cloud lifetime and precipitation, hence, altering the earth s radiation and water budget. Analyses from satellite measurements reveal the reflected solar (emitted thermal) radiation from clouds due to smoke aerosols can be reduced (enhanced) by 100 (20) Watts per square meter over the month of March 2000. In addition, the reduction in cloud spectral reflectance is large enough to lead to significant errors in satellite retrievals of cloud properties (e.g., optical thickness and effective radius). The fresh water distribution in this region is highly dependent on monsoon rainfall; in fact, the predictability of the tropical climate system is much reduced during the boreal spring. Therefore, to accurately assess the impact of smoke aerosols in this region requires continuous observations from satellites, aircraft, ground-based networks and dedicated field experiments. BASE-ASIA initiative has been proposed and will be discussed.

Tsay, S.-C.↗

A Strategy to Assess Aerosol Direct Radiative Forcing of Climate Using Satellite Radiation Measurements

Atmospheric aerosols have a complex internal chemical composition and optical properties. Therefore it is difficult to model their impact on redistribution and absorption of solar radiation, and the consequent impact on atmospheric dynamics and climate. The use in climate models of isolated aerosol parameters retrieved from satellite data (e.g. optical thickness) may result in inconsistent calculations, if the model assumptions differ from these of the satellite retrieval schemes. Here we suggest a strategy to assess the direct impact of aerosol on the radiation budget at the top and bottom of the atmosphere using satellite and ground based measurements of the spectral solar radiation scattered by the aerosol. This method ensures consistent use of the satellite data and increases its accuracy. For Kaufman and Tanre: Strategy for aerosol direct forcing anthropogenic aerosol in the fine mode (e.g. biomass burning smoke and urban pollution) consistent use of satellite derived optical thickness can yield the aerosol impact on the spectral solar flux with accuracy an order of magnitude better than the optical thickness itself. For example, a simulated monthly average smoke optical thickness of 0.5 at 0.55 microns (forcing of 40-50 W/sq m) derived with an error of 20%, while the forcing can be measured directly with an error of only 0-2 W/sq m. Another example, the effect of large dust particles on reflection of solar flux can be derived three times better than retrievals of optical thickness. Since aerosol impacts not only the top of the atmosphere but also the surface irradiation, a combination of satellite and ground based measurements of the spectral flux, can be the most direct mechanism to evaluate the aerosol effect on climate and assimilate it in climate models. The strategy is applied to measurements from SCAR-B and the Tarfox experiments. In SCAR-B aircraft spectral data are used to derive the 24 hour radiative forcing of smoke at the top of the atmosphere of (Delta)F(sub 24hr)/(Delta)tau = - 25 +/- 5 W/sq m. Ground based data give forcing at the surface of (Delta)F(sub 24hr)/(Delta)taur = -80 +/- 5 W/sq m. In TARFOX a mixture of maritime and regional pollution aerosol resulted in a varied forcing at the top of the atmosphere, (Delta)F(sub 24hr)/(Delta)tau, between -26 W/sq 2 and -50 W/sq m depending on mixture of coarse and accumulation modes, for Angstrom exponents of 1.0 and 0.2 respectively.

Kaufman, Yoram J.↗

Health and Safety Effects of Airborne Soil Dust in the Americas and Beyond

Risks associated with dust hazards are often underappreciated, a gap between the knowledge pool and public awareness that can be costly for impacted communities. This study reviews the emission sources and chemical, physical, and biological characteristics of airborne soil particles (dust) and their effects on human and environmental health and safety in the Pan-American region. American dust originates from both local sources (western United States, northern Mexico, Peru, Bolivia, Chile, and Argentina) and long-range transport from Africa and Asia. Dust properties, as well as the trends and interactions with criteria air pollutants, are summarized. Human exposure to dust is associated with adverse health effects, including asthma, allergies, fungal infections, and premature death. In the Americas, a well-documented and striking effect of soil dust is its association with Coccidioidomycosis, commonly known as Valley fever, an infection caused by inhalation of soil-dwelling fungi unique to this region. Besides human health, dust affects environmental health through nutrients that increase phytoplankton biomass, contaminants that diminish water supply and affect food (crops/fruits/vegetables and ready-to-eat meat), spread crop and marine pathogens, cause Valley fever among domestic and wild animals, transport heavy metals, radionuclides and microplastics, and reduce solar and wind power generation. Dust is also a safety hazard to road transportation and aviation, in the southwestern US where blowing dust is one of the deadliest weather hazards. To mitigate the harmful effects, coordinated regional and international efforts are needed to enhance dust observations and prediction capabilities, soil conservation measures, and Valley fever and other disease surveillance.

health↗

Exoplanet Biosignatures: A Review of Remotely Detectable Signs of Life

In the coming years and decades, advanced space- and ground-based observatories will allow an unprecedented opportunity to probe the atmospheres and surfaces of potentially habitable exoplanets for signatures of life. Life on Earth, through its gaseous products and reflectance and scattering properties, has left its fingerprint on the spectrum of our planet. Aided by the universality of the laws of physics and chemistry, we turn to Earth's biosphere, both in the present and through geologic time, for analog signatures that will aid in the search for life elsewhere. Considering the insights gained from modern and ancient Earth, and the broader array of hypothetical exoplanet possibilities, we have compiled a comprehensive overview of our current understanding of potential exoplanet biosignatures, including gaseous, surface, and temporal biosignatures. We additionally survey biogenic spectral features that are well known in the specialist literature but have not yet been robustly vetted in the context of exoplanet biosignatures. We briefly review advances in assessing biosignature plausibility, including novel methods for determining chemical disequilibrium from remotely obtainable data and assessment tools for determining the minimum biomass required to maintain short-lived biogenic gases as atmospheric signatures. We focus particularly on advances made since the seminal review by Des Marais et al. The purpose of this work is not to propose new biosignature strategies, a goal left to companion articles in this series, but to review the current literature, draw meaningful connections between seemingly disparate areas, and clear the way for a path forward.

biosignatures↗

Tidal Marsh Outwelling of Dissolved Organic Matter and Resulting Temporal Variability in Coastal Water Optical and Biogeochemical Properties

Coastal wetlands are highly dynamic environments at the land-ocean interface where human activities, short-term physical forcings and intense episodic events result in high biological and chemical variability. Long being recognized as among the most productive ecosystems in the world, tidally-influenced coastal marshes are hot spots of biogeochemical transformation and exchange. High temporal resolution observations that we performed in several marsh-estuarine systems of the Chesapeake Bay revealed significant variability in water optical and biogeochemical characteristics at hourly time scales, associated with tidally-driven hydrology. Water in the tidal creek draining each marsh was sampled every hour during several semi-diurnal tidal cycles using ISCO automated samplers. Measurements showed that water leaving the marsh during ebbing tide was consistently enriched in dissolved organic carbon (DOC), frequently by more than a factor of two, compared to water entering the marsh during flooding tide. Estimates of DOC fluxes showed a net DOC export from the marsh to the estuary during seasons of both low and high biomass of marsh vegetation. Chlorophyll amounts were typically lower in the water draining the marsh, compared to that entering the marsh during flooding tide, suggesting that marshes act as transformers of particulate to dissolved organic matter. Moreover, detailed optical and compositional analyses demonstrated that marshes are important sources of optically and chemically distinctive, relatively complex, high molecular weight, aromatic-rich and highly colored dissolved organic compounds. Compared to adjacent estuarine waters, marsh-exported colored dissolved organic matter (CDOM) was characterized by considerably stronger absorption (more than a factor of three in some cases), larger DOC-specific absorption, lower exponential spectral slope, larger fluorescence signal, lower fluorescence per unit absorbance, and higher fluorescence at visible wavelengths. Observed patterns in water optical and biogeochemical variables were very consistent among different marsh systems and throughout the year, despite continued tidal exchange, implying rapid transformation of marsh DOM in the estuary through both photochemical and microbial processes. These findings illustrate the importance of tidal marsh ecosystems as sources, sinks and/or transformers of biologically important nutrients, carbon and colored dissolved organic compounds, and their influence on short-term biological, optical and biogeochemical variability in coastal waters.

Tzortziou, Maria↗

Recent advances in radar remote sensing of forest

On a global scale, forests represent most of the terrestrial standing biomass (80 to 90 percent). Thus, natural and anthropogenic change in forest covers can have major impacts not only on local ecosystems but also on global hydrologic, climatic, and biogeochemical cycles that involve exchange of energy, water, carbon, and other elements between the earth and atmosphere. Quantitative information on the state and dynamics of forest ecosystems and their interactions with the global cycles appear necessary to understand how the earth works as a natural system. The information required includes the lateral and vertical distribution of forest cover, the estimates of standing biomass (woody and foliar volume), the phenological and environmental variations and disturbances (clearcutting, fires, flood), and the longer term variations following deforestation (regeneration, successional stages). To this end, seasonal, annual, and decadal information is necessary in order to separate the long term effects in the global ecosystem from short term seasonal and interannual variations. Optical remote sensing has been used until now to study the forest cover at local, regional, and global scales. Radar remote sensing, which provides recent SAR data from space on a regular basis, represents an unique means of consistently monitoring different time scales, at all latitudes and in any atmospheric conditions. Also, SAR data have shown the potential to detect several forest parameters that cannot be inferred from optical data. The differences--and complementarity--lie in the penetration capabilities of SAR data and their sensitivity to dielectric and geometric properties of the canopy volume, whereas optical data are sensitive to the chemical composition of the external foliar layer of the vegetation canopy.

Letoan, Thuy↗