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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
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NASA NTRS1982

A model study of Fuego volcanic aerosol dispersion in the lower stratosphere

A zonally averaged time-dependent primitive equation model is used to simulate the dispersion of both a carbon 14 injection and the volcanic aerosol from the 1974 Fuego eruption. It is noted that both injections occurred at low latitudes to midlatitudes in the Northern Hemisphere. The eddy flux terms, which account for the major portion of the transport in the lower stratosphere of this model, are specified in a manner similar to that of Harwood and Pyle (1975). Comparisons with data underline the ability of the model to simulate the vertical character of the tracer while maintaining reasonable meridional transport times. For the aerosol study, the simulated 1/e decay time at 37 deg N and for the 16- to 21-km altitude region is 9 months, whereas lidar measurements at the same latitude give a decay time of 8 months. The simulated vertical width at half-maximum for the aerosol tracer at 37 deg N and 19 deg N and for 6 months after the event possesses values of 5.0 km and 3.6 km, respectively, whereas the observed lidar values are 4.4 km and 3.0 km, respectively. The tracer transport to the Southern Hemisphere also is in qualitative agreement with the limited data that are available.

Remsberg, E. E.↗
NASA NTRS1984

Radioactivities in returned lunar materials and in meteorites

Carbon 14 terrestial ages were determined with low level minicomputers and accelerator mass spectrometry on 1 Yamato and 18 Allan Hills and nearby sited meteorites. Techniques for an accelerator mass spectrometer which make C(14) measurements on small samples were developed. Also Be(10) concentrations were measured in Byrd core and Allan Hills ice samples.

Fireman, E. L.↗
NASA NTRS1996

Permeation of protons, potassium ions, and small polar molecules through phospholipid bilayers as a function of membrane thickness

Two mechanisms have been proposed to account for solute permeation of lipid bilayers. Partitioning into the hydrophobic phase of the bilayer, followed by diffusion, is accepted by many for the permeation of water and other small neutral solutes, but transient pores have also been proposed to account for both water and ionic solute permeation. These two mechanisms make distinctively different predictions about the permeability coefficient as a function of bilayer thickness. Whereas the solubility-diffusion mechanism predicts only a modest variation related to bilayer thickness, the pore model predicts an exponential relationship. To test these models, we measured the permeability of phospholipid bilayers to protons, potassium ions, water, urea, and glycerol. Bilayers were prepared as liposomes, and thickness was varied systematically by using unsaturated lipids with chain lengths ranging from 14 to 24 carbon atoms. The permeability coefficient of water and neutral polar solutes displayed a modest dependence on bilayer thickness, with an approximately linear fivefold decrease as the carbon number varied from 14 to 24 atoms. In contrast, the permeability to protons and potassium ions decreased sharply by two orders of magnitude between 14 and 18 carbon atoms, and leveled off, when the chain length was further extended to 24 carbon atoms. The results for water and the neutral permeating solutes are best explained by the solubility-diffusion mechanism. The results for protons and potassium ions in shorter-chain lipids are consistent with the transient pore model, but better fit the theoretical line predicted by the solubility-diffusion model at longer chain lengths.

NASA Program Exobiology↗
NASA NTRS2024

Evaluation of CMIP6 Model Simulations of PM 2.5 and its Components Over China

Earth system models (ESMs) participating in the latest Coupled Model Intercomparison Project Phase 6 (CMIP6) simulate various components of fine particulate matter (PM 2.5 ) as major climate forcers. Yet the model performance for PM 2.5 components remains little evaluated due in part to a lack of observational data. Here, we evaluate near-surface concentrations of PM 2.5 and its five main components over China as simulated by 14 CMIP6 models, including organic carbon (OC; available in 14 models), black carbon (BC; 14 models), sulfate (14 models), nitrate (4 models), and ammonium (5 models). For this purpose, we collect observational data between 2000 and 2014 from a satellite-based dataset for total PM2.5 and from 2469 measurement records in the literature for PM 2.5 components. Seven models output total PM 2.5 concentrations, and they all underestimate the observed total PM 2.5 over eastern China, with GFDL-ESM4 (−1.5 %) and MPI-ESM-1-2-HAM (−1.1 %) exhibiting the smallest biases averaged over the whole country. The other seven models, for which we recalculate total PM 2.5 from the available component output, underestimate the total PM 2.5 concentrations partly because of the missing model representations of nitrate and ammonium. Concentrations of the five individual components are underestimated in almost all models, except that sulfate is overestimated in MPI-ESM-1-2-HAM by 12.6 % and in MRI-ESM2-0 by 24.5 %. The underestimation is the largest for OC (by −71.2 % to −37.8 % across the 14 models) and the smallest for BC (−47.9 % to −12.1 %). The multi-model mean (MMM) reproduces the observed spatial pattern for OC (R = 0.51), sulfate (R = 0.57), nitrate (R = 0.70) and ammonium (R = 0.74) fairly well, yet the agreement is poorer for BC (R = 0.39). The varying performances of ESMs on total PM 2.5 and its components have important implications for the modeled magnitude and spatial pattern of aerosol radiative forcing.

CMIP6↗
NASA NTRS1972

Carbon chemistry of Apollo 14 size-fractionated fines.

Experiments have been conducted on several Apollo 12 and 14 samples that confirm the identification of CH4 and C2H6 in lunar fines and breccias. In particular, data for various size fractions of sample 14240,5 are reported which show that the concentrations of these species are dependent on particle size. Results strongly support proposals that solar wind activity is a source of CH4 in lunar samples.

Holland, P. T.↗
NASA NTRS1976

Viking on Mars - A preliminary survey

Selection of landing site, observations of Martian topography from orbit, a log of entry into the Martian atmosphere and landing operations, and soil experiments executed at the landing site are recounted. Several photographs overviewing Martian terrain from orbit (1600 to 1900 km up) are shown. Soil sampling and analysis experiments and experiments designed to detect biotic activity (pyrolysis, labeled release of 14-carbon-tagged CO2, gas exchange and vapor chromatography, pyrolytic release) are described and some preliminary results reported. Results on surface geology and chemical composition of the Martian atmosphere are cited.

Young, R. S.↗
NASA NTRS1972

Survey of lunar carbon compounds. II - The carbon chemistry of Apollo 11, 12, 14, and 15 samples.

The methane and carbide concentrations of a number of Apollo 11, 12, 14, and 15 samples of fines and breccias have been examined by the deuterated acid dissolution method. Location studies indicate that these carbon compounds are concentrated in the outer surfaces of the fines particles of 48-152 micron diameter; for larger particles a volume-related component may contribute. In individual samples the methane and carbide concentrations correlate with parameters indicative of lunar surface exposure. The data provide further evidence that solar wind implantation is the major source of the methane in the fines and that the carbide originates from both solar wind implantation and meteorite impacts.

Cadogan, P. H.↗
NASA NTRS1972

Study of carbon compounds in Apollo 12 and 14 lunar samples.

The results of gas-chromatography and high-resolution mass spectroscopy studies of gases released on deuterium fluoride dissolution of Apollo 12 and 14 lunar samples are reported. The results confirm previous observations that CH4 and C2H6 are released as well as CD4, C2D4, C2D6, and higher deuterated hydrocarbons. The yields correlate with the total carbon content of the samples, and the CH4 and C2H6 released may be regarded as indigenous, while the deuterated products result from hydrolysis of carbide material. The results provide the first experimental confirmation of the hypothesis that the CH4 derives from solar wind interactions.

Holland, P. T.↗
NASA NTRS1972

Compounds of carbon and other volatile elements in Apollo 14 and 15 samples.

DF dissolution and pyrolysis showed that the indigenous methane and ethane contents in Apollo 14 and 15 lunar samples correlated with the amounts of solar wind gases and the deutero-carbon reaction gases. Pyrolysis evolved mainly CO and N2 and lower amounts of CO2. Other compounds detected and quantitated by these techniques were DCN, HCN, CS2, D2S, and PD3.

Holland, P. T.↗
NASA NTRSDate not supplied

Formation of Complex Organic Molecules (COMs) from Polycyclic Aromatic Hydrocarbons (PAHs): Top-Down Synthesis of organics in planetary systems

Complex, organic molecules have been found in many solar system objects (i.e., dust, comets, meteorites, moons, etc.); however, their origins and formation remain a mystery. Two chemical evolutionary pathways have been proposed to explain the organic inventory of our solar system. The first pathway, the top-down approach, suggests an interstellar (ISM) heritage whereby the organic material found in the solar system formed from the erosion and functionalization of large pre-solar carbon-bearing species (mainly large Polycyclic Aromatic Hydrocarbons or PAHs). The second pathway suggests that the origin of the Solar System prebiotic matter is the result of bottom-up synthesis from small reactive molecules (e.g., formaldehyde – H2CO, acetylene – H2C2, and similar species). In this second scenario, it is supposed that very few, if any, pre-solar large molecules could have survived due to the proto - solar nebula radiation environment. Polycyclic Aromatic Hydrocarbons or PAHs comprise ~20-30% of all available carbon in the Universe. The PAHs found within our Solar System tend to be smaller than those suspected to be in the ISM, comprised of only 14 to 18 carbon atoms in size whereas ISM PAHs are typically 50 to 100 carbon atoms. The disparity in PAH sizes between the ISM and Solar System environments is not understood, but may point to conversion of large ISM PAHs to Solar System Organics. This presentation details recent experiments regarding the stability of large PAHs to the various types of radiation found within a proto - solar disk and the production of smaller, complex, molecules from the degradation of the larger PAHs. The presentation will highlight differences and similarities in degradation products based on experimental conditions (e.g., radiation type) and discuss future work with a new experimental setup known as ICEE (Institute for Carbon Evolution Experiments).

molecukes↗
NASA NTRS1986

Carbon and nitrogen in B2 to A2 main-sequence stars

Carbon abundances are derived from the C II resonance doublet at 1335 A in 108 main-sequence stars between 9000 and 21000 K from IUE archival data. Only alpha Leo and psi sq 2 Aqr are strongly carbon deficient (factors 14 and 50, resp.). The N I lines at 1493 and 1495 A were measured in 28 sharp-lined stars below 16500 K. Nitrogen anomalies are found in 5 stars, but seem uncorrelated to the C abundances. Four mechanisms for the depletion of carbon are discussed, but none is satisfactory.

Hardorp, Johannes↗