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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Mars in situ propellants: Carbon monoxide and oxygen ignition experiments

Carbon monoxide and oxygen were tested in a standard spark-torch igniter to identify the ignition characteristics of this potential Mars in situ propellant combination. The ignition profiles were determined as functions of mixture ratio, amount of hydrogen added to the carbon monoxide, and oxygen inlet temperature. The experiments indicated that the carbon monoxide and oxygen combination must have small amounts of hydrogen present to initiate reaction. Once the reaction was started, the combustion continued without the presence of hydrogen. A mixture ratio range was identified where ignition occurred, and this range varied with the oxygen inlet temperature.

Linne, Diane L.↗
NASA NTRS1990

Mars in situ propellants - Carbon monoxide and oxygen ignition experiments

Carbon monoxide and oxygen were tested in a standard spark-torch igniter to identify the ignition characteristics of this potential Mars in situ propellant combination. The ignition profiles were determined as functions of mixture ratio, amount of hydrogen added to the carbon monoxide, and oxygen inlet temperature. The experiments indicated that the carbon monoxide and oxygen combination must have small amounts of hydrogen present to initiate reaction. Once the reaction was started, the combustion continued without the presence of hydrogen. A mixture ratio range was identified where ignition occurred, and this range varied with the oxygen inlet temperature.

Linne, Diane L.↗
NASA NTRS1974

Shock-tube study of carbon monoxide dissociation kinetics

Carbon monoxide dissociation-rate data were obtained over the temperature range 5600-12,000 K. The experiments were conducted with undiluted CO to emphasize rate constants applicable to molecular gas systems. Data were obtained as time-resolved pressure measurements on the end wall of a shock tube and, in some cases, as emission histories of the C2 Swan system (0-0 band) behind incident shock waves. Results confirm the presence of C2 as an intermediate species in CO decomposition.

Hanson, R. K.↗
NASA NTRS1981

Analysis of GASP carbon monoxide data

Atmospheric carbon monoxide in the upper troposphere and lower stratosphere for the period March 1977 through October 1978 was analyzed. The CO data are summarized and the distribution and variations in space and time of this gas are presented. The data show that the CO mixing ratios are higher in the troposphere than those in the stratosphere. In the Northern Hemisphere the highest value of CO mixing ratio occurs in spring, although more data are needed to verify these findings. Correlation coefficients among CO, O3, air temperature (T) and winds were calculated for different regions under different seasons. It was found that the CO correlates negatively with O3 above 20 degrees latitude and positively below that latitude. Case studies using the data of CO, O3, and T measured simultaneously were performed. Discussions and suggestions are made. Ozone data on seasonal basis is also summarized.

Wu, M. F.↗
NASA NTRS1973

A large carbon monoxide cloud in Orion

Carbon monoxide line emission was observed at a wavelength of 2.6 mm in an area of L1630, a diffuse dark nebula forming a bridge between NGC 2024 and the reflection nebula NGC 2068. The absence of a 21-cm counterpart to this region of high visual extinction suggests that L1630 is predominantly molecular hydrogen. The molecular hydrogen mass, estimated from the carbon monoxide observations, is found to comprise a significant fraction of the total mass of stars and gas within the boundaries of I Ori association.

Tucker, K. D.↗
NASA NTRS1976

Venus - Microwave detection of carbon monoxide

The 115-gigahertz microwave line of carbon monoxide has been detected in the spectrum of Venus. The measurement proves that the carbon monoxide mixing ratio increases above an altitude of 85 kilometers in the Venus stratosphere and provides quantitative information on carbon monoxide in the altitude region from 80 to 110 kilometers. This altitude region is well above that which has been previously sensed.

Kakar, R. K.↗
NASA NTRS1979

Circumpolar measurements of ozone, particles, and carbon monoxide from a commercial airliner

Trace constituent data are presented from the unique flight of an airliner around the world over both poles. Relatively high resolution and simultaneous measurements of ozone, carbon monoxide, light-scattering particles, condensation nuclei, and meteorological parameters were obtained. The mutual variations of the data in the polar stratospheres, and in the tropical upper troposphere, are discussed in their meteorological setting. The data from the Arctic lower stratosphere are consistent with a tropospheric source of condensation nuclei, but not of carbon monoxide. Carbon monoxide mixing ratios in the Antarctic stratosphere averaged 44 ppbv. In the tropical troposphere they averaged 66 ppbv over the Pacific versus 89 ppbv over Africa. A local area of higher concentration (115 ppbv) was encountered over tropical Africa; its possible relation to carbon monoxide production by vegetation and deep convection is discussed. Evidence was found in the tropical upper troposphere of distinct boundaries between air masses of different temperature, ozone content, and particle content.

Pratt, R.↗
NASA NTRS1972

A review of carbon monoxide sources, sinks, and concentrations in the earth's atmosphere

Carbon monoxide is a toxic pollutant which is continually introduced into the earth's atmosphere in significant quantities. There are apparently some mechanisms operating which destroy most of the CO in the atmosphere, i.e., a carbon monoxide sink. These mechanisms have not as yet been established in a quantitative sense. This report discusses the various possible removal mechanisms which warrant serious consideration. Particular emphasis is given to chemical reactions (especially that with OH), soil bacteria and other biological action, and transport effects. The sources of carbon monoxide, both natural and anthropogenic, are reviewed and it is noted that there is quite possibly a significant undefined natural source. Atmospheric CO concentrations are discussed and their implications on carbon monoxide lifetime, sinks and sources are considered.

Bortner, M. H.↗
NASA NTRS1971

Carbon monoxide gas dynamic laser

Carbon monoxide gas dynamic laser oscillation generation, observing maximum power and vibrational exchange among single diatomic species states

Watt, W. S.↗
NASA NTRS1973

Carbon monoxide detector

A sensitive carbon monoxide detector, developed specifically for spacecraft use, is described. An instrument range of 0 to 60 ppm CO in air was devised. The fuel cell type detector is used as a highly sensitive electrolysis cell for electrochemically detecting gases. The concept of an electrochemical CO detector is discussed and the CO oxidation behavior in phosphoric and sulfuric acid electrolytes is reported.

Holleck, G. L.↗
NASA NTRS1982

Measurements of the global distribution of carbon monoxide in the troposphere

Carbon monoxide and methane grab samples were obtained simultaneously with ozone, aerosol, nitric oxide and DACOM CO measurements. Eighty grab samples were collected at various altitudes up to 19,000 ft. along a north-south flight path from Wallops Flight Center, VA to 11 N. CO and CH were analyzed by flame ionization gas chromatography with cryogenic preconcentration. The relationship between CO and O3 concentrated is examined. A comparative analysis between trends in aerosol and CO concentration is performed.

Hinton, R. R.↗
NASA NTRS1986

Carbon monoxide in cometary ice

Carbon monoxide has been positively identified by means of ultraviolet fluorescence in the Fourth Positive System in two comets, West (1976 VI) and Bradfield (1979 X). In both cases, the spatial distribution of the emission is consistent with the CO being a 'parent' molecule, present in the cometary ice, rather than a dissociation product of a polyatomic species such as CO2 or HCOH. However, the abundance of CO relative to that of H2O is more than an order of magnitude smaller for comet Bradfield than for comet West. Further data on CO are expected with the use of more sensitive ultraviolet instruments such as the ASTRO spectrographs which will observe P/Halley in March 1986.

Feldman, P. D.↗
NASA NTRS2014

Room Temperature Carbon Nanotube Based Sensor for Carbon Monoxide Detection

Sulfonated single-walled carbon nanotubes have been used in an integrated electrode structure forthe detection of carbon monoxide. The sensor responds to 0.5 ppm of CO in air at room temperature. All eightsensors with this material in a 32-sensor array showed good repeatability and reproducibility, with response andrecovery times of about 10 s. Pristine nanotubes generally do not respond to carbon monoxide and the resultshere confirm sulfonated nanotubes to be a potential candidate for the construction of an electronic nose thatrequires at least a few materials for the selective detection of CO.

Nanomaterial functionalization↗
NASA NTRS2003

Iron catalyst chemistry in modeling a high-pressure carbon monoxide nanotube reactor

The high-pressure carbon monoxide (HiPco) technique for producing single-wall carbon nanotubes (SWNTs) is analyzed with the use of a chemical reaction model coupled with flow properties calculated along streamlines, calculated by the FLUENT code for pure carbon monoxide. Cold iron pentacarbonyl, diluted in CO at about 30 atmospheres, is injected into a conical mixing zone, where hot CO is also introduced via three jets at 30 degrees with respect to the axis. Hot CO decomposes the Fe(CO)5 to release atomic Fe. Then iron nucleates and forms clusters that catalyze the formation of SWNTs by a disproportionation reaction (Boudouard) of CO on Fe-containing clusters. Alternative nucleation rates are estimated from the theory of hard sphere collision dynamics with an activation energy barrier. The rate coefficient for carbon nanotube growth is estimated from activation energies in the literature. The calculated growth was found be about an order of magnitude greater than measured, regardless of the nucleation rate. A study of cluster formation in an incubation zone prior to injection into the reactor shows that direct dimer formation from Fe atoms is not as important as formation via an exchange reaction of Fe with CO in FeCO.

Evaluation Studies↗
NASA NTRS1977

Atmospheric analyzer, carbon monoxide monitor and toluene diisocyanate monitor

The purpose of the atmospheric analyzer and the carbon monoxide and toluene diisocyanate monitors is to analyze the atmospheric volatiles and to monitor carbon monoxide and toluene diisocyanate levels in the cabin atmosphere of Skylab. The carbon monoxide monitor was used on Skylab 2, 3, and 4 to detect any carbon monoxide levels above 25 ppm. Air samples were taken once each week. The toluene diisocyanate monitor was used only on Skylab 2. The loss of a micrometeoroid shield following the launch of Skylab 1 resulted in overheating of the interior walls of the Orbital Workshop. A potential hazard existed from outgassing of an isocyanate derivative resulting from heat-decomposition of the rigid polyurethane wall insulation. The toluene diisocyanate monitor was used to detect any polymer decomposition. The atmospheric analyzer was used on Skylab 4 because of a suspected leak in the Skylab cabin. An air sample was taken at the beginning, middle, and the end of the mission.

Shannon, A. V.↗