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Results for “CHEMILUMINESCENCE”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Absolute rate constant for the O plus NO chemiluminescence in the near infrared

Infrared chemiluminescence from the process O + NO (+M) NO2 + hv (+M) has been studied between 1.3 and 4.1 micrometer. The wavelength dependence of the continuum between 1.3 and 3.3 micrometer is in fair agreement with previous studies and the measured radiative rate constant at 1.51 micrometer establishes the NO-O glow in this spectral range as a secondary emission standard. Comparison with previous studies of the visible region of the glow implies that the overall radiative rate constant lies in the range (9.4 to 11.2) x 10 to the minus 17 power cu cm sec/1. In the region 3.3 to 4.1 micrometer, the previously observed broad band, peaking at 3.7 micrometer, shows a complex kinetic dependence on O and M.

Golde, M. F.↗
NASA NTRS1973

Feasibility study for rocket ozone measurements in the 50 to 80 km region using a chemiluminescent technique

A study has been conducted to determine the feasibility of increasing sensitivity for ozone detection. The detection technique employed is the chemiluminescent reaction of ozone with a rhodamine-B impregnated disk. Previously achieved sensitivities are required to be increased by a factor of about 20 to permit measurements at altitudes of 80 km. Sensitivity was increased by using a more sensitive photomultiplier tube, by increasing the gas velocity past the disk, by different disk preparation techniques, and by using reflective coatings in the disk chamber and on the uncoated side of the glass disk. Reflective coatings provided the largest sensitivity increase. The sum of all these changes was a sensitivity increased by an estimated factor of 70, more than sufficient to permit measurement of ambient ozone concentrations at altitudes of 80 km.

Goodman, P.↗
NASA NTRS1975

Interference of oxygen, carbon dioxide, and water vapor on the analysis for oxides of nitrogen by chemiluminescence

The interference of small concentrations (less than 4 percent by volume) of oxygen, carbon dioxide, and water vapor on the analysis for oxides of nitrogen by chemiluminescence was measured. The sample gas consisted primarily of nitrogen, with less than 100 parts per million concentration of nitric oxide, and with small concentrations of oxygen, carbon dioxide, and water vapor added. Results obtained under these conditions indicate that although oxygen does not measurably affect the analysis for nitric oxide, the presence of carbon dioxide and water vapor causes the indicated nitric oxide concentration to be too low. An interference factor - defined as the percentage change in indicated nitric oxide concentration (relative to the true nitric oxide concentration) divided by the percent interfering gas present - was determined for carbon dioxide to be -0.60 + or - 0.04 and for water vapor to be -2.1 + or - 0.3.

Maahs, H. G.↗
NASA NTRS1976

Chemiluminescent prediction of service life

Technique can be used to predict polymer degradation under actual expected-use conditions, without imposing artificial conditions. Smooth or linear correlations are obtained between chemiluminescence and physical properties of purified polymer gums.

Hassell, J. A.↗
NASA NTRS1975

Analytical Applications of Bioluminescence and Chemiluminescence

Bioluminescence and chemiluminescence studies were used to measure the amount of adenosine triphosphate and therefore the amount of energy available. Firefly luciferase - luciferin enzyme system was emphasized. Photometer designs are also considered.

Chappelle, E. W.↗