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NASA NTRSDate not supplied

Developments of Bosch Process Architectures for ISRU Terrestrial Applications

To effectively realize NASA’s goals of a sustainable presence on the Moon and be-yond, In-Situ Resource Utilization (ISRU) must be leveraged. To reduce launch mass for space missions, commodities such as oxygen and carbon can be produced in-situ. Oxygen can be used for life support and as a propellant, and carbon can be used for battery production, filtration, additive manufacturing, and steel casting. Carbon is a required reactant in the carbothermal reduction process, a leading candidate for oxygen production on the lunar surface. To pro-duce these consumables, the Carbon Utilization Technology for Lunar and Atmospheric Systems (CUTLAS) project is developing architectures that leverage the Bosch process. The Bosch process re-acts CO 2 and H 2 to produce carbon powder and water, which can then be electrolyzed, leaving O 2 and recycled H 2 . This process is also applicable to carbon dioxide emissions on Earth.

Carbon capture↗

NASA NTRS2023

AI-3000K Infrared Line List for Hot CO 2

AI-3000K is a semi-empirical IR line list constructed for hot CO 2 spectra analysis and simulation up to 3000 – 4000 K. Compared to previously published Ames-1000K and UCL-4000, it represents a major upgrade, utilizing a new algorithm for optimization and including the latest improvements in potential energy surface (PES), dipole moment surface (DMS), and room temperature IR line list (Ames-2021 296K). To maximize the success of introducing experimental based accurate line positions, a new PES (X01d) was refined with respect to >800 selected CDSD2019 [Tashkun et al. JQSRT (2019) 228, 124] energy levels in the range of 0 – 24,000 cm -1 , with σ rms = 0.5 – 0.7 cm -1 . Most differences between the X01d PES based levels and CDSD2019 energies are within ± 2 cm -1 . A new DMS is fitted from extrapolated CCSD(T)/aug-cc-pV(T,Q,5)Z dipole calculations, with σ rms = 5.1 × 10 -6 au for 11,155 geometries up to 40,000 cm -1 , denoted Ames-2021–40K. Compared to the best available Ames-2021 DMS and room temperature IR line list [Huang et al J. Phys. Chem. A (2022) 126, 5940], the relative intensity differences are expected to be ∼ 1 ‰. The line position accuracy of ''X01d + Ames-2021–40K'' IR line list is significantly improved by adopting CDSD2019 energy levels up to 24,000 cm -1 (J ≤ 150). The Einstein A21 coefficients for E' < 15,000 cm -1 transitions are replaced by more accurate values from the Ames-2021 296K IR line list. In short, the AI-3000K is the X01d PES and Ames-2021–40K DMS based line list enhanced with the A 21 of Ames-2021 296K line list and CDSD energy levels. It provides continuous coverage from 0 to 20,000 cm -1 for the four most abundant isotopologues: 12 C 16 O 2 (626), 13 C 16 O 2 (636), 16 O 12 C 18 O (628), and 16 O 12 C 17 O (627). The impacts of isotopologue and E'/E'' cutoffs have been examined. Intensity convergence (not accuracy) of AI-3000K line list is quantitatively estimated in 1 cm -1 bins. It is better than 99% in the whole range of 0 – 20,000 (or 10,000) cm -1 at 1000 K (or 2000 K), or better than 90% in the whole range of 0 – 15,000 (or 9000) cm -1 at 2000 K (or 3000 K), respectively. Convergence beyond 3000 K will require a new PES and DMS for E' > 40,000 cm -1 . The AI-3000K and HITEMP based IR simulations are compared to high resolution shock tube experiments for CO 2 -Ar mixture up to 2000 K. With line position accuracy comparable to that of HITEMP, AI-3000K IR line list yields better agreements at more frequencies. Potential sources of discrepancies with experiment are discussed.

AI-3000K↗

NASA NTRS2018

Updated Benefits for Humanity from the International Space Station

Final document is attached. In 2018, the International Space Station (ISS) [Figure 1] partnership completed a revision for the third edition of the International Space Station Benefits for Humanity, a compilation of case studies of benefits being realized from ISS activities in the areas of human health, Earth observations and disaster response, innovative technology, global education, and economic development of space. The revision included new assessments of economic value and scientific value with more detail than the second edition. The third edition contains updated statistics on the impacts of the benefits as well as new benefits that have developed since the previous publication. This presentation will summarize the updates on behalf of the ISS Program Science Forum, which consists of senior science representatives across the ISS international partnership. An independent consultant determined the economic valuation (EV) of ISS research benefits case studies and the third edition contains the results. The process involved a preliminary assessment of economic, social, and innovation factors. A more detailed assessment followed, which included factors such as addressable market, market penetration, revenue generation, ability to leverage across other applications or customer groups, quality of life improvements, health benefits, environmental benefits, cultural and community cohesion, inspiration, new knowledge, novel approaches, creation of a unique market niche, and research leadership. Because of the unique microgravity environment of the ISS laboratory, the multidisciplinary and international nature of the research, and the significance of the investment in its development, analyzing ISS scientific impacts is an exceptional challenge. As a result, the ISS partnership determined the scientific valuation (SV) of ISS research using a combination of citation analyses, bibliometrics, and narratives of important ISS utilization results. Approximately 2,100 ISS results publications comprised of scientific journal articles, conference proceedings, and gray literature, representing over 5,000 authors and co-authors on Earth were used in this evaluation to enable the communication of impacts of ISS research on various science and technology fields across many countries. The publication also updates and expands the previously described benefits of research results in the areas of space commerce, technology development, human health, environmental change and disaster response, and education activities. Distinct benefits return to Earth from the only orbiting multidisciplinary laboratory of its kind. The ISS is a stepping-stone for future space exploration while also providing findings that develop low Earth orbit as a place for sustained human activity and improve life on our planet.

research↗

NASA NTRS2018

Updated Benefits for Humanity, Third Edition (B4H3), from the International Space Station (ISS)

In 2018, the International Space Station (ISS) [Figure 1] partnership completed a revision for the third edition of the International Space Station Benefits for Humanity, a compilation of case studies of benefits being realized from ISS activities in the areas of human health, Earth observations and disaster response, innovative technology, global education, and economic development of space. The revision included new assessments of economic value and scientific value with more detail than the second edition. The third edition contains updated statistics on the impacts of the benefits as well as new benefits that have developed since the previous publication. This presentation will summarize the updates on behalf of the ISS Program Science Forum, which consists of senior science representatives across the ISS international partnership. An independent consultant determined the economic valuation (EV) of ISS research benefits case studies and the third edition contains the results. The process involved a preliminary assessment of economic, social, and innovation factors. A more detailed assessment followed, which included factors such as addressable market, market penetration, revenue generation, ability to leverage across other applications or customer groups, quality of life improvements, health benefits, environmental benefits, cultural and community cohesion, inspiration, new knowledge, novel approaches, creation of a unique market niche, and research leadership. Because of the unique microgravity environment of the ISS laboratory, the multidisciplinary and international nature of the research, and the significance of the investment in its development, analyzing ISS scientific impacts is an exceptional challenge. As a result, the ISS partnership determined the scientific valuation (SV) of ISS research using a combination of citation analyses, bibliometrics, and narratives of important ISS utilization results. Approximately 2,100 ISS results publications comprised of scientific journal articles, conference proceedings, and gray literature, representing over 5,000 authors and co-authors on Earth were used in this evaluation to enable the communication of impacts of ISS research on various science and technology fields across many countries. The publication also updates and expands the previously described benefits of research results in the areas of space commerce, technology development, human health, environmental change and disaster response, and education activities. Distinct benefits return to Earth from the only orbiting multidisciplinary laboratory of its kind. The ISS is a stepping-stone for future space exploration while also providing findings that develop low Earth orbit as a place for sustained human activity and improve life on our planet.

ISS↗

NASA NTRSDate not supplied

Advanced Electric Propulsion System (AEPS) Enabling a Sustainable Return to the Lunar Surface through NASA Gateway

NASA continues to evolve a human exploration approach for beyond low-Earth orbit. The center of this approach is NASA’s Gateway that is envisioned to provide a maneuverable outpost in lunar orbit to extend human presence in deep space and expand on NASA exploration goals. The Gateway represents the initial step in NASA’s architecture for human cislunar operations, lunar surface access and missions to Mars. NASA announced at the May 2020 NASA Advisory Council’s Human Explorations and Operations Committee a new plan that calls for launching the first two elements of Gateway as a co-manifested mission in the late 2023 timeframe [2]. Launching the Power and Propulsion Element (PPE) and the Habitation and Logistics Outpost (HALO) together reduces mission risk, utilizes the PPE high-powered Electric Propulsion (EP) system to transport both elements to the lunar orbit, and reduces overall cost. NASA and Maxar Technologies have a commercial partnership to develop and demonstration a high-powered Solar Electric Propulsion (SEP) spacecraft [3, 4]. The PPE is baselined to include three 12.5-kW Advanced Electric Propulsion Systems (AEPS) and four 6-kW Hall thrusters, currently under development by Maxar, for a total beginning of life propulsion power of over 48-kW [5]. High-power solar electric propulsion is one of the key technologies that has been prioritized because of its significant exploration benefits, specifically, for missions beyond low Earth orbit. Spacecraft size and mass are currently dominated by onboard chemical propulsion systems and propellants that may constitute more than 50 percent of spacecraft mass. This impact can be substantially reduced through the utilization of SEP, due to its higher specific impulse and lower propellant load required to meet the equivalent mission delta-V. Studies performed for NASA’s HEOMD and Science Mission Directorate (SMD) have demonstrated that 40-kW-class SEP provides the necessary capabilities that would enable near term and future architectures, and science missions [6]. Accordingly, NASA has been developing a 12 kW Hall thruster electric propulsion thruster that can serve as the building block for a 40-kW-class SEP capability. The AEPS development, led by the NASA Glenn Research Center (GRC) and the Jet Propulsion Laboratory (JPL), began with the maturation of the high-power Hall thruster. The technology development work has transitioned to AR via a competitive procurement selection for the AEPS contract in May 2016. Management of the AEPS contract is being led by NASA GRC with funding from NASA’s Science Technology Mission Directorate (STMD) under the Technology Demonstration Missions (TDM) program. NASA continues to support the AEPS development leveraging in-house expertise, plasma modeling capability, and world-class test facilities.

AEPS↗

NASA NTRS2023

Regenerable Liquid Desiccants for High Efficiency Humidity Control in Microgravity

The NASA X-Hab project aims to design, manufacture, test, and prove functionality of an air humidity control subsystem to dehumidify and re-humidify air from a space cabin. The method of regulating cabin air humidity utilizes vortex phase separation, which uses an ionic liquid (IL) desiccant for air-water phase separation. This subsystem is intended to be integrated with a CO 2 removal system requiring de-humidified air to operate efficiently. The air humidity control subsystem is composed of a cold-desiccant or cold-side Vortex Phase Separator (VPS) that dehumidifies the cabin air. The dehumidified air exits the cold-side (CS) VPS chamber to flow into the CO 2 removal module, and the cold, water-laden liquid desiccant flows to a regenerative heat exchanger. From the heat exchanger the liquid desiccant continues to the heater. After heating, the desiccant flows into a hot-desiccant or hot-side (HS) VPS as the dehumidified air from CO 2 removal module enters through the HS VPS air inlet. The rehumidified air exits the HS VPS into the space cabin. One pump installed at the liquid exit of the CS VPS and one pump installed at the liquid exit of the HS VPS transport the fluid through the system. To evaluate the system’s efficiency and effectiveness, the temperature, pressure, flow rate and relative humidity are read, recorded, and analyzed at critical points along the module.

Gerardo Castro↗

NASA NTRS2011

Optimized Li-Ion Electrolytes Containing Triphenyl Phosphate as a Flame-Retardant Additive

A number of future NASA missions involving the exploration of the Moon and Mars will be human-rated and thus require high-specific-energy rechargeable batteries that possess enhanced safety characteristics. Given that Li-ion technology is the most viable rechargeable energy storage device for near-term applications, effort has been devoted to improving the safety characteristics of this system. There is also a strong desire to develop Li-ion batteries with improved safety characteristics for terrestrial applications, most notably for hybrid electric vehicle (HEV) and plug-in hybrid electric vehicle (PHEV) automotive applications. Therefore, extensive effort has been devoted recently to developing non-flammable electrolytes to reduce the flammability of the cells/battery. A number of electrolyte formulations have been developed, including systems that (1) incorporate greater concentrations of the flame-retardant additive (FRA); (2) use di-2,2,2-trifluoroethyl carbonate (DTFEC) as a co-solvent; (3) use 2,2,2- trifluoroethyl methyl carbonate (TFEMC); (4) use mono-fluoroethylene carbonate (FEC) as a co-solvent and/or a replacement for ethylene carbonate in the electrolyte mixture; and (5) utilize vinylene carbonate as a "SEI promoting" electrolyte additive, to build on the favorable results previously obtained. To extend the family of electrolytes developed under previous work, a number of additional electrolyte formulations containing FRAs, most notably triphenyl phosphate (TPP), were investigated and demonstrated in experimental MCMB (mesocarbon micro beads) carbon- LiNi(0.8)Co(0.2)O2 cells. The use of higher concentrations of the FRA is known to reduce the flammability of the electrolyte solution, thus, a concentration range was investigated (i.e., 5 to 20 percent by volume). The desired concentration of the FRA is the highest amount tolerable without adversely affecting the performance in terms of reversibility, ability to operate over a wide temperature range, and the discharge rate capability. The use of fluorinated carbonates, much in the same manner as the incorporation of fluorinated ester-based solvents, was employed to reduce the inherent flammability of mixtures. Thus, electrolyte formulations that embody both approaches are anticipated to have much lower flammability, resulting in enhanced safety.

Smart, Marshall C.↗

NASA NTRSDate not supplied

CO2-Based Manufacturing System for Recombinant Protein Production

Space biomanufacturing is a potential In Situ Resource Utilization (ISRU) strategy to provide critical consumables and products while minimizing the launched mass for long-duration, deep space missions. On Earth, the primary biological conversion of CO 2 to biomass is through photosynthesis, and sugars from photosynthetic organisms are used as feedstocks for microbial biomanufacturing. The efficiency of non-biological reduction of CO 2 to organic molecules, such as acetate or ethanol, has greatly increased in recent years. We are designing a biomanufacturing system to rely on electrochemical CO 2 conversion products for carbon substrates to support microbial growth and production of recombinant proteins. The preliminary design includes a gas-permeable membrane bioreactor with dry salts that are rehydrated and mixed with the carbon source to support growth of bacteria or yeast. The system architecture has a partially automated bioprocessing system to concentrate biomass and purify recombinant protein. This system is designed to operate semi-autonomously with minimal crew intervention. The specific use-case scenario is to produce a thermal stable carbonic anhydrase to increase the efficiency of a proposed liquid amine CO 2 removal subsystem of an environmental control and life-support system (ECLSS) on Mars.

Biomanufacturing↗

NASA NTRSDate not supplied

Development of a Space Compatible Biomanufacturing System

Recombinant↗

NASA NTRS2022

VESIcal: A Critical Approach to Volatile Solubility Modelling Using the Open-Source Engine Vesical

Accurate models of H(2)O and CO(2) solubility in silicate melts are vital for understanding volcanic plumbing systems. These models are used to estimate the depths of magma storage regions from melt inclusion volatile contents, investigate the role of volatile exsolution as a driver of volcanic eruptions, and track the degassing path followed by a magma ascending to the surface. However, despite the large increase in the number of experimental constraints over the last two decades, many recent studies still utilize an earlier generation of models which were calibrated on experimental datasets with restricted compositional ranges. This may be because many of the available tools for more recent models require large numbers of input parameters to be hand-typed (e.g., temperature, concentrations of H(2)O, CO(2), and 8–14 oxides), making them difficult to implement on large datasets. Here, we use a new open-source Python3 tool, VESIcal, to critically evaluate the behaviors and sensitivities of different solubility models for a range of melt compositions. Using literature datasets of andesitic-dacitic experimental products and melt inclusions as case studies, we illustrate the importance of evaluating the calibration dataset of each model. Finally, we highlight the limitations of particular data presentation methods, such as isobar diagrams, and provide suggestions for alternatives, and best practices regarding the presentation and archiving of data. This review will aid the selection of the most applicable solubility model for different melt compositions, and identifies areas where additional experimental constraints on volatile solubility are required.

magma↗

NASA NTRS2018

NASA's Space Launch System and Deep-Space Opportunities for SmallSats

Designed to provide the significant capability required for human deep-space exploration, NASA's Space Launch System (SLS) also provides a unique opportunity for lower-cost deepspace science in the form of small-satellite secondary payloads. This opportunity will be leveraged beginning with the rocket's first flight; a launch of the SLS's Block 1 configuration, capable of delivering >26 metric tons (t) to Trans-Lunar Injection (TLI), which will see the Orion crew vehicle travel around the Moon and return to Earth. On that flight, SLS will also deploy 13 6U CubeSat-class payloads to multiple destinations including deep space. These secondary payloads will include not only NASA research, but also spacecraft from international partners, industry and academia. The payloads represent a variety of disciplines including, but not limited to, studies of the Moon, Earth, Sun, and asteroids, along with technology demonstrations that could pave the way for even more ambitious smallsat missions in the future. As the SLS Program is making significant progress toward that first launch, preparations are already under way for future missions, which will see the booster evolve to its more-capable Block 1 B configuration, able to deliver 40 metric tons to TLI. That configuration will have the capability to carry large payloads co-manifested with the Orion spacecraft, or to utilize an 8.4- meter (m) fairing to carry payloads several times larger than are currently possible. SLS will evolve to its full Block 2 configuration, with a TLI capability of >45 metric tons. Both the Block lB and Block 2 versions of SLS will be able to carry larger secondary payloads than the Block 1 configuration, creating even more opportunities for affordable scientific exploration of deep space. This lecture will provide a status of the SLS development and outline the progress being made toward flying smallsats on the first flight of SLS, and discuss future opportunities for smallsats on subsequent flights.

Bookout, Paul S.↗

NASA NTRS2018

NASA's Space Launch System and Deep Space Opportunities for Smallsats

Designed to provide the significant capability required for human deep-space exploration, the National Aeronautics and Space Administration's Space Launch System (SLS) also provides an exceptional opportunity for lower-cost deep-space science in the form of small-satellite (smallsat) secondary payloads. This opportunity will be leveraged beginning with the rocket's first flight; a launch of the SLS's Block 1 configuration, capable of delivering greater than 26 metric tons (t) to Trans-Lunar Injection (TLI), which will see the Orion crew vehicle travel around the Moon and return to Earth. On that flight, SLS will also deploy 13 6U-class CubeSat secondary payloads to multiple destinations including deep space. Preparations are already under way for future vehicle configurations, with the more capable Block 1B, able to deliver 40 metric tons to TLI. That configuration will have the capability to carry large payloads co-manifested with the Orion spacecraft, or to utilize an 8.4-meter (m) fairing to carry payloads several times larger than are currently possible. SLS will evolve to its full Block 2 configuration, with a TLI capability of greater than 45 metric tons. This paper will provide a status of the SLS development and outline the progress being made toward flying smallsats on SLS, and discuss future opportunities for smallsats.

Bookout, Paul S.↗

NASA NTRSDate not supplied

Integrated Bosch Process System Models for In-Situ Oxygen and Carbon Production

In-Situ Resource Utilization (ISRU) technology is a vital component to NASA’s mission of a sustainable presence on the Moon and Mars. Local resources can be leveraged to reduce resupply frequency and mass. Elements of the Bosch process, combined with the carbothermal reduction process, can produce oxygen on the lunar surface with minimal consumables. The Bosch process can also produce oxygen on the Martian surface by using the CO 2 -rich environment. Between both systems, adsorption pump, solar thermal energy, carbon formation reactor, and water recovery subsystems are modeled and integrated to create a functional model in MATLAB software. The model is used to simulate performance of the system and reduce mass, power, and volume requirements. This integrated system model provides a tool to scale ISRU technologies for oxygen and carbon production. The MATLAB model is created by developing a system of independent subsystem models that are solved for their quasi-steady state values which can be integrated with respect to time to determine the change in current states. A flexible time stepping method is used to ensure a high level of accuracy during periods of rapid change while still making use of a simple explicit integration method. The flexible time step is calculated for each independent subsystem and the minimum value from those is used as the overall time step. A flexible time step is calculated by dividing a resolution value, or the maximum change per time step, by the variables current rate of change. The maximum value from all points in space is used for subsystem models that contain multiple values. The process is done for every variable that is being monitored in each subsystem and the global minimum is used as that iteration’s timestep. Several assumptions used in the MATLAB model for fluid flow dynamics, such as 1-D gas flow through the sorption pump, are supported by modeling in Ansys Fluent software. The Lunar oxygen production system is outlined in Fig. 1. The carbothermal reduction subsystem uses solar energy to heat a mixture of lunar regolith and carbon powder to produce carbon monoxide. To begin, the carbon monoxide feeds to the modified Bosch subsystem along with hydrogen gas. The reactants then enter the carbon formation reactor where water and carbon powder are produced. Solar thermal energy is used to add energy to the reactor, but waste heat from the carbothermal process is another potential heat source. The water is collected and electrolyzed to produce hydrogen which reenters the Bosch subsystem, and the oxygen is stored for downstream use. The carbon powder is collected and feeds back into the carbothermal subsystem. The Martian oxygen production system uses the full Bosch process and is outlined in Fig 2. A CO 2 adsorption pump thermally cycles to scrub and pressurize CO 2 from the environment. Along with an initial supply of hydrogen, the reactants enter the Reverse Water Gas Shift Reactor (RWGSR) which produces carbon monoxide and water. Carbon monoxide and unreacted hydrogen enter the carbon formation reactor to produce water and carbon powder. The water is collected from both reactors and electrolyzed to reintroduce hydrogen and store oxygen for propellant production or life support. Carbon is removed from the carbon formation reactor and stored. The adsorption pump utilizes rapid cycle temperature swings within a stack of zeolite coated surfaces. The subsystem model solves 1-D quasi-steady conservation laws of the quasi-steady form, shown in Eq. 1, for the gas stream and heat exchange liquid to predict performance parameters such as breakthrough capacity and optimum cycle time. The source term S is used to capture interactions between the fluid flows and the sorbent. A quasi-steady-state scheme is used where no time derivatives appear in the governing equations, except for those in the source terms. This results in an autonomous system, where ∂F/∂x = ƒ(F). The fluxes F are provided at the inlet, and an explicit method is used to solve for the spatial distribution of F. The heat and mass flows to the sorbent are then extracted from the source terms. These flows are numerically integrated to produce a 1-D solution for the system’s state as a function of both time and space. The body of the adsorption pump is separated into two semi-independent models: the heat exchanger fluid flow and gas flow through the zeolite coated surfaces. Both models are solved using the above-described method to find a 1-D solution as a function of space and interact only once a timestep is taken. The interaction point is the sorbent through which all heat transfer between the two models must occur. Sorbent mass adsorption is calculated using the Lagergren model, shown in Eq. 2, where the transfer coefficient, λ D , is found by solving a system of nondimensionalized equations derived by using the heat and mass transfer analogy for transport phenomena. Using Grade 544 Type 13X zeolite as the sorbent material, the equilibrium concentration, θ eq , is calculated using the k-site Langmuir isotherm and fit parameters. Additionally, the enthalpy of adsorption used in the model is computed by interpolation of available data [1]. The subsystem model was validated using the Rapid Cycle Temperature Swing Adsorption (RC-TSA) pump. The solar thermal energy subsystem focuses on a solar concentrator concept with a heat exchanger to heat the reactants before entering the carbon formation reactor. The subsystem model assumes a fixed solar flux and reflector efficiency to calculate the reactant temperature given the incoming temperature, pressure, and exchanger geometry. The receiver is a custom manufactured series of copper blocks with serpentine channels to increase its surface area and the residence time of the reactants to heat up to 550 °C. The subsystem model was validated using a heat exchanger developed at NASA Glenn Research Center (GRC). The solar thermal energy subsystem focuses on a solar concentrator concept with a heat exchanger to heat the reactants before entering the carbon formation reactor. The subsystem model assumes a fixed solar flux and reflector efficiency to calculate the reactant temperature given the incoming temperature, pressure, and exchanger geometry. The receiver is a custom manufactured series of copper blocks with serpentine channels to increase its surface area and the residence time of the reactants to heat up to 550 °C. The subsystem model was validated using a heat exchanger developed at NASA Glenn Research Center (GRC).

In situ Resource Utilization↗

NASA NTRS1997

Characteristics of Non-Premixed Turbulent Flames in Microgravity

The overall objectives of this research are: (1) to obtain and analyze experimental data on flame images, and the spatial and temporal distributions of temperature, radiation, velocity and gas-phase species in microgravity turbulent gas-jet diffusion flames; and (2) to utilize these data to validate and refine the existing predictive capabilities. Work on this project commenced in June 1996. The first investigations on turbulent gas-jet diffusion flames in microgravity were initiated by Bahadori and co-workers in 1991. These studies have shown that significant differences exist in the transition processes in normal-gravity and microgravity flames, and that the turbulent flames in microgravity behave very differently as compared to their buoyancy-dominated normal-gravity counterparts. For example, in the transition regime while the visible flame height, for given fuel and nozzle size, in normal gravity decreases, the height of the microgravity flame increases. In the fully developed turbulent regime, the normal-gravity flame height is independent of injection velocity, whereas the microgravity flame height continues to increase, although at a lower rate than in the laminar and transitional regimes. Other differences between the normal-gravity and microgravity flames arise in the jet shear-layer instability characteristics, extent of the transitional regime and blow-off limit characteristics.

Hegde, Uday↗

NASA NTRS1997

A Chemical Approach to Carbon Dioxide Utilization on Mars

We describe several novel proposals for CO2 reduction through chemical, photochemical, and photoelectrochemical means. The approach involves coupled catalytic cycles to simultaneously produce oxygen and carbon monoxide. Efficient metal catalysts and photocatalysts are to be used for both halfreactions: (1) the reduction of CO2 to CO; and (2) the evolution of O2. Photolytic reduction of CO2 to CO and oxygen can occur under mild conditions using a series of recently synthesized trinuclear nickel catalysts. Nickel cluster catalysts hold great promise because of the proven ability of nickel cluster materials to catalyze the reduction of CO2 to CO.

Hepp, Aloysius F.↗

NASA NTRS1993

Pollutant emissions from and within a model gas turbine combustor at elevated pressures and temperatures

Conventional and advanced gas turbine engines are coming under increased scrutiny regarding pollutant emissions. This, in turn, has created a need to obtain in-situ experimental data at practical conditions, as well as exhaust data, and to obtain the data in combustors that reflect modern designs. The in-situ data are needed to (1) assess the effects of design modifications on pollutant formation, and (2) develop a detailed data base on combustor performance for the development and verification of computer modeling. This paper reports on a novel high pressure, high temperature facility designed to acquire such data under controlled conditions and with access (optical and extractive) for in-situ measurements. To evaluate the utility of the facility, a model gas turbine combustor was selected which features practical hardware design, two rows of jets (primary and dilution) with four jets in each row, and advanced wall cooling techniques with laser drilled effusive holes. The dome is equipped with a flat-vaned swirler with vane angles of 60 degrees. Data are obtained at combustor pressures ranging from 2 to 10 atmospheres of pressure, levels of air preheat to 427 C, combustor reference velocities from 10.0 to 20.0 m/s, and an overall equivalence ratio of 0.3. Exit plane and in-situ measurements are presented for HC, O2, CO2, CO, and NO(x). The exit plane emissions of NO(x) correspond to levels reported from practical combustors and the in-situ data demonstrate the utility and potential for detailed flow field measurements.

Drennan, S. A.↗

NASA NTRS2018

Payload Utilization in NASA's Space Launch System

With Space Policy Directive 1, the United States administration has directed the National Aeronautics and Space Administration’s (NASA’s) Human Exploration & Operations Mission Directorate (HEOMD) to return to the Moon with missions and infrastructure designed to support a sustained presence in cislunar space, with robotic and human lunar surface operations. NASA’s new deep space exploration system — the super heavy-lift Space Launch System (SLS), the Orion crew spacecraft and revamped launch facilities at Kennedy Space Center (KSC) — will enable NASA and its commercial and international partners to meet this goal for human exploration of deep space. SLS is the most capable launch vehicle for these efforts, as well as for sending robotic missions deep into the solar system, or even to interstellar space. The vehicle will be available in crew and cargo configurations in progressively more powerful block variants. The initial Block 1 lift capability of at least 26 metric tons (t) to trans-lunar injection (TLI) will be followed by a more powerful Block 1B with the power to loft more than 37 t to TLI. The ultimate Block 2 variant will lift more than 45 t to TLI. For payload accommodation, the Block 1 vehicle can utilize a 5 meter (m) fairing in its cargo configuration with the crew version also able to provide berths for 6U and 12U CubeSats as secondary payloads. The Block 1B crew vehicle will provide as much volume as the space shuttle payload bay in a Universal Stage Adapter (USA) for co-manifested payloads (CPLs). Block 1B cargo vehicles will offer 8.4 m-diameter fairings in 19.1 m and possibly longer lengths, with enough volume to accommodate lunar-orbiting habitat modules and other elements of NASA’s Gateway science outpost. For Mars-class payloads, larger fairings for the Block 2 cargo launcher are under consideration. For missions beyond the Earth-Moon system, SLS offers greater characteristic energy (C3) than any other launch vehicle, enabling shorter transit times or heavier payloads with more robust science packages for missions to the outer solar system. Indeed, the unmatched combination of thrust, payload volume and departure energy that SLS provides opens new opportunities for human and robotic exploration of deep space. This paper will provide an overview of the various vehicle block configurations, their capabilities and payload accommodations for sending primary, co-manifested and secondary payloads to deep space

Creech, Stephen D.↗

NASA NTRSDate not supplied

Evaluation of Low-Energy Hydrogen Separation Method Using Metal-Organic Frameworks (MOFs) for Closed-Loop ECLSS Air Revitalization (CLEAR)

The State-of-the-Art (SOA) air revitalization architecture onboard the International Space Station (ISS) recovered approximately 50% of the oxygen (O 2 ) from metabolic carbon dioxide (CO 2 ) via the Sabatier process from 2011 to 2017. O 2 recovery is currently constrained by the limited availability of reactant hydrogen (H 2 ) preventing complete conversion of CO 2 to H 2 O. Increasing O 2 recovery within Closed-Loop ECLSS is essential to reducing resupply mass for long-duration manned missions; specifically focusing on water (H 2 O) which supplies H 2 for Sabatier via water electrolysis. Past ground test endeavors at Marshall Space Flight Center (MSFC) have attempted to recover H 2 from Sabatier-produced CH 4 using technologies such as carbon vapor deposition (CVD) and plasma pyrolysis. The byproducts of these technologies can act as a catalyst poison or reactor deadload to the Sabatier reactor. Hydrogen separation techniques must be utilized to maintain the Sabatier catalyst during gas recycling and must be scalable, non-energy intensive, and safe to operate in a habitation setting. Research indicated that metal-organic frameworks (MOFs) could meet these criteria and were tested for their capability to capture the various carbon-based gaseous products of CVD and plasma pyrolysis such as acetylene (C 2 H 2 ), ethylene (C 2 H 4 ), ethane (C 2 H 6 ), and carbon monoxide (CO) which would purify the hydrogen gas stream passing through the MOF. A sub-scale adsorption column was developed by Marshall Space Flight Center to test three MOF candidates against a synthetic gas mixture comprised of process-relevant carbonous gases and hydrogen to evaluate the separation capability of the MOFs. The results of the hydrogen separation capability, isothermal desorption capability, and demonstrated cyclic reuse of the MOF are presented in this paper.

Kagen Crawford↗