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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Research on catalysts for long-life closed-cycle CO2 laser oaperation

Long-life, closed-cycle operation of pulsed CO2 lasers requires catalytic CO-O2 recombination both to remove O2, which is formed by discharge-induced CO2 decomposition, and to regenerate CO2. Platinum metal on a tin-oxide substrate (Pt/SnO2) has been found to be an effective catalyst for such recombination in the desired temperature range of 25 to 100 C. This paper presents a description of ongoing research at NASA-Langley on Pt/SnO2 catalyzed CO-O2 recombination. Included are studies with rare-isotope gases since rare-isotope CO2 is desirable as a laser gas for enhanced atmospheric transmission. Results presented include: (1) the effects of various catalyst pretreatment techniques on catalyst efficiency; (2) development of a technique, verified in a 30-hour test, to prevent isotopic scrambling when C(O-18) and (O-18)2 are reacted in the presence of a common-isotope Pt/Sn(O-16)2 catalyst; and (3) development of a mathematical model of a laser discharge prior to catalyst introduction.

Sidney, Barry D.↗

Advanced Sine Wave Modulation of Continuous Wave Laser System for Atmospheric CO2 Differential Absorption Measurements

NASA Langley Research Center in collaboration with ITT Exelis have been experimenting with Continuous Wave (CW) laser absorption spectrometer (LAS) as a means of performing atmospheric CO2 column measurements from space to support the Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) mission.Because range resolving Intensity Modulated (IM) CW lidar techniques presented here rely on matched filter correlations, autocorrelation properties without side lobes or other artifacts are highly desirable since the autocorrelation function is critical for the measurements of lidar return powers, laser path lengths, and CO2 column amounts. In this paper modulation techniques are investigated that improve autocorrelation properties. The modulation techniques investigated in this paper include sine waves modulated by maximum length (ML) sequences in various hardware configurations. A CW lidar system using sine waves modulated by ML pseudo random noise codes is described, which uses a time shifting approach to separate channels and make multiple, simultaneous online/offline differential absorption measurements. Unlike the pure ML sequence, this technique is useful in hardware that is band pass filtered as the IM sine wave carrier shifts the main power band. Both amplitude and Phase Shift Keying (PSK) modulated IM carriers are investigated that exibit perfect autocorrelation properties down to one cycle per code bit. In addition, a method is presented to bandwidth limit the ML sequence based on a Gaussian filter implemented in terms of Jacobi theta functions that does not seriously degrade the resolution or introduce side lobes as a means of reducing aliasing and IM carrier bandwidth.

Campbell, Joel F.↗

CO2 Capacity Sorbent Analysis Using Volumetric Measurement Approach

In support of air revitalization system sorbent selection for future space missions, Ames Research Center (ARC) has performed CO2 capacity tests on various solid sorbents to complement structural strength tests conducted at Marshall Space Flight Center (MSFC). The materials of interest are: Grace Davison Grade 544 13X, Honeywell UOP APG III, LiLSX VSA-10, BASF 13X, and Grace Davison Grade 522 5A. CO2 capacity was for all sorbent materials using a Micromeritics ASAP 2020 Physisorption Volumetric Analysis machine to produce 0C, 10C, 25C, 50C, and 75C isotherms. These data are to be used for modeling data and to provide a basis for continued sorbent research. The volumetric analysis method proved to be effective in generating consistent and repeatable data for the 13X sorbents, but the method needs to be refined to tailor to different sorbents.

Air Revitalization↗

HgCdTe photomixers for CO2 laser radar systems

The Santa Barbara Research Center has developed a variety of high speed HgCdTe photodetectors for use in CO2 laser radar systems. These detectors have outstanding performance and can be made available in production quantities. Many of them have been employed in a variety of systems applications over the past ten years. In this paper, we briefly describe the detector technology, summarize the state-of-the-art, and indicate some practical applications.

Bratt, Peter R.↗

CO2 Capacity Sorbent Analysis Using Volumetric Measurement Approach

In support of air revitalization system sorbent selection for future space missions, Ames Research Center (ARC) has performed CO2 capacity tests on various solid sorbents to complement structural strength tests conducted at Marshall Space Flight Center (MSFC). The materials of interest are: Grace Davison Grade 544 13X, Honeywell UOP APG III, LiLSX VSA-10, BASF 13X, and Grace Davison Grade 522 5A. CO2 capacity was for all sorbent materials using a Micromeritics ASAP 2020 Physisorption Volumetric Analysis machine to produce 0 C, 10 C, 25 C, 50 C, and 75 C isotherms. These data are to be used for modeling data and to provide a basis for continued sorbent research. The volumetric analysis method proved to be effective in generating consistent and repeatable data for the 13X sorbents, but the method needs to be refined to tailor to different sorbents.

Huang, Roger↗

CO2 Capacity Sorbent Analysis using Volumetric Measurement Approach

In support of air revitalization system sorbent selection for future space missions, Ames Research Center (ARC) has performed CO2 capacity tests on various sorbents to complement structural strength tests from Marshall Space Flight Center (MSFC). The materials of interest are: Grace Davison Grade 544 13x, Honeywell UOP APG III, VSA-10, BASF 13x, and Grace Davison Grade 522 5A. Each sorbents CO2 capacity was measured using a Micromeritics ASAP 2020 Physisorption Volumetric Analysis machine to produce 0C, 10C, 25C, 50C, and 75C isotherms. These datasets were then extrapolated using Langmuir 3-Site and Toth isotherm models to compare with previously measured capacity data from MSFC using a thermogravimetric analysis approach. The modeling and extrapolation from ARC data correlated well with data measured at MSFC.

Air Revitalization↗

Pseudorandom Noise Code-Based Technique for Thin Cloud Discrimination with CO2 and O2 Absorption Measurements

NASA Langley Research Center is working on a continuous wave (CW) laser based remote sensing scheme for the detection of CO2 and O2 from space based platforms suitable for ACTIVE SENSING OF CO2 EMISSIONS OVER NIGHTS, DAYS, AND SEASONS (ASCENDS) mission. ASCENDS is a future space-based mission to determine the global distribution of sources and sinks of atmospheric carbon dioxide (CO2). A unique, multi-frequency, intensity modulated CW (IMCW) laser absorption spectrometer (LAS) operating at 1.57 micron for CO2 sensing has been developed. Effective aerosol and cloud discrimination techniques are being investigated in order to determine concentration values with accuracies less than 0.3%. In this paper, we discuss the demonstration of a pseudo noise (PN) code based technique for cloud and aerosol discrimination applications. The possibility of using maximum length (ML)-sequences for range and absorption measurements is investigated. A simple model for accomplishing this objective is formulated, Proof-of-concept experiments carried out using SONAR based LIDAR simulator that was built using simple audio hardware provided promising results for extension into optical wavelengths.

Campbell, Joel F.↗

Development of a Pulsed 2-micron Laser Transmitter for CO2 Sensing from Space

NASA Langley Research Center (LaRC), in collaboration with NASA Jet Propulsion Laboratory (JPL), is engaged in the development and demonstration of a highly efficient, versatile, 2-micron pulsed laser that can be used in a pulsed Differential Absorption Lidar (DIAL)/Integrated Path Differential Absorption (IPDA) instrument to make precise, high-resolution CO2 measurements to investigate sources, sinks, and fluxes of CO2. This laser transmitter will feature performance characteristics needed for an ASCENDS system that will be capable of delivering the CO2 measurement precision required by the Earth Science Decadal Survey (DS).

Singh, Upendra N.↗

A Novel Method for Breath Capture Inside a Space Suit

Any non-robotic mission to the Mars surface will need to rely on various life support technologies. The large metabolic generation rate and low tolerance to elevated levels of carbon dioxide (CO2) in the Mars atmosphere make CO2 removal one of the preeminent tasks in this domain. In addition, these same features provide a strong impetus for using regenerable CO2 removal technologies. In the past, many of these regenerable technologies have relied on the low partial pressure CO2 surrounding the vehicle to provide an ultimate sink for removing this gas contaminant, however any Mars mission will have to overcome the presence of the Mars atmosphere. This paper describes the investigation of methods to capture the exhaled CO2 from a suited crewmember before it becomes diluted with the high volumetric air flow present within the space suit. Typical expired air contains CO2 partial pressures in the range of 20-35 mm Hg. This research investigated methods to capture this high partial pressure CO2 prior to its dilution with the low partial pressure CO2 ventilation flow. Specifically the research looked at potential designs for a collection cup for use inside the space suit helmet. This collection cup should not be considered the same as a breathing mask typical of that worn by firefighters, etc. Instead, the collection cup is a non-contact device that makes use of detailed analyses of the ventilation flow environment within the helmet. The research used a detailed Computational Fluid Dynamic (CFD) code called Fluent to provide modeling of the various gas species (CO2, water vapor, O2) as they pass through a helmet. This same model was used to numerically evaluate several different collection cup designs for this same CO2 segregation effort.

Paul, Heather↗

Extraction processes for the production of aluminum, titanium, iron, magnesium, and oxygen and nonterrestrial sources

The suitability of existing terrestrial extractive metallurgical processes for the production of Al, Ti, Fe, Mg, and O2 from nonterrestrial resources is examined from both thermodynamic and kinetic points of view. Carbochlorination of lunar anorthite concentrate in conjunction with Alcoa electrolysis process for Al; carbochlorination of lunar ilmenite concentrate followed by Ca reduction of TiO2; and subsequent reduction of Fe2O3 by H2 for Ti and Fe, respectively, are suggested. Silicothermic reduction of olivine concentrate was found to be attractive for the extraction of Mg becaue of the technological knowhow of the process. Aluminothermic reduction of olivine is the other possible alternative for the production of magnesium. The large quantities of carbon monoxide generated in the metal extraction processes can be used to recover carbon and oxygen by a combination of the following methods: (1) simple disproportionation of CO,(2) methanation of CO and electrolysis of H2O, and (3) solid-state electrolysis of gas mixtures containing CO, CO2, and H2O. The research needed for the adoption of earth-based extraction processes for lunar and asteroidal minerals is outlined.

D Bhogeswara Rao↗

Detection of Abiotic Methane in Terrestrial Continental Hydrothermal Systems: Implications for Methane on Mars

The recent detection of methane in the Martian atmosphere and the possibility that its origin could be attributed to biological activity, have highlighted the importance of understanding the mechanisms of methane formation and its usefulness as a biomarker. Much debate has centered on the source of the methane in hydrothermal fluids, whether it is formed biologically by microorganisms, diagenetically through the decomposition of sedimentary organic matter, or inorganically via reduction of CO2 at high temperatures. Ongoing research has now shown that much of the methane present in sea-floor hydrothermal systems is probably formed through inorganic CO2 reduction processes at very high temperatures (greater than 400 C). Experimental results have indicated that methane might form inorganically at temperatures lower still, however these results remain controversial. Currently, methane in continental hydrothermal systems is thought to be formed mainly through the breakdown of sedimentary organic matter and carbon isotope equilibrium between CO2 and CH4 is thought to be rarely present if at all. Based on isotopic measurements of CO2 and CH4 in two continental hydrothermal systems, we suggest that carbon isotope equilibration exists at temperatures as low as 155 C. This would indicate that methane is forming through abiotic CO2 reduction at lower temperatures than previously thought and could bolster arguments for an abiotic origin of the methane detected in the martian atmosphere.

Socki, Richard A.↗

Mars: A Planet with a Dynamic Climate System

Mars is a well-observed planet. Since the 1960s orbiters, landers, rovers, and earth-based telescopic observations show that its climate system is dynamic. Its dynamic nature, largely the result of atmosphere-surface interactions, is most obvious in the seasonal cycles of dust, water, and carbon dioxide that define the planet's climate system. These cycles are linked through the global circulation and MGS, Odyssey, Phoenix, MER, Mars Express, MRO, and now MSL have continuously observed them at Mars for the past 16 years. Their observations show that while the seasonal cycles are largely annually repeatable, there are interannual variations. Planet-encircling dust storms, for example, are quasi-triennial and originate over a broader range of seasons and locations than previously thought. Water moves from pole-to-pole each year in a largely, but not precisely, repeatable pattern that suggests but does not demand non-polar surface reservoirs. And the seasonal CO2 polar caps grow and retreat in a very predictable way with only minor deviations from year-to-year in spite of significant differences in atmospheric dust content. These behaviors suggest a complicated but robust coupled system in which these cycles interact to produce the greatest interannual variability in the dust cycle and least variability in the CO2 cycle. The nature of these interactions is the subject of ongoing research, but clouds, both water ice and CO2 ice, now appear to play a bigger role than believed at the end of the 20th century. There may also be some long-term trends in these cycles as there is evidence from imaging data, for example, that the south polar residual cap may not be stable on decadal to centennial time scales. On even longer time scales, the discovery of as much as 5 mb global equivalent of buried CO2 ice near the south pole, the detection of vast quantities of subsurface water ice at very shallow depths in midlatitudes of both hemispheres, and the presence of remnant glacial features at almost all latitudes, strongly suggests the possibility of significant climate change associated with orbital variations. Some of the major questions these data raise concern how closed the seasonal cycles are and which reservoirs are gaining or loosing, the cause of the large interannual variability of the dust cycle and how it couples to the water and CO2 cycles, and the mechanisms for the origin of past glacial activity and the emplacement and removal of subsurface ice. While many of these questions can be addressed with continued research based on existing data, new observations focused on atmosphere surface-interactions would provide valuable constraints on how dust, water, and CO2 move between the surface and atmosphere.

CO2 cycles↗

A New Method for Breath Capture Inside a Space Suit Helmet

This project investigates methods to capture an astronaut's exhaled carbon dioxide (CO2) before it becomes diluted with the high volumetric oxygen flow present within a space suit. Typical expired breath contains CO2 partial pressures (pCO2) in the range of 20-35 mm Hg. This research investigates methods to capture the concentrated CO2 gas stream prior to its dilution with the low pCO2 ventilation flow. Specifically this research is looking at potential designs for a collection cup for use inside the space suit helmet. The collection cup concept is not the same as a breathing mask typical of that worn by firefighters and pilots. It is well known that most members of the astronaut corps view a mask as a serious deficiency in any space suit helmet design. Instead, the collection cup is a non-contact device that will be designed using a detailed Computational Fluid Dynamic (CFD) analysis of the ventilation flow environment within the helmet. The CFD code, Fluent, provides modeling of the various gas species (CO2, water vapor, and oxygen (O2)) as they pass through a helmet. This same model will be used to numerically evaluate several different collection cup designs for this same CO2 segregation effort. A new test rig will be built to test the results of the CFD analyses and validate the collection cup designs. This paper outlines the initial results and future plans of this work.

Filburn, Tom↗

Acute effects of a large bolide impact simulated by a global atmospheric circulation model

The goal is to use a global three-dimensional atmospheric circulation model developed for studies of atmospheric effects of nuclear war to examine the time evolution of atmospheric effects from a large bolide impact. The model allows for dust and NOx injection, atmospheric transport by winds, removal by precipitation, radiative transfer effects, stratospheric ozone chemistry, and nitric acid formation and deposition on a simulated Earth having realistic geography. Researchers assume a modest 2 km-diameter impactor of the type that could have formed the 32 km-diameter impact structure found near Manson, Iowa and dated at roughly 66 Ma. Such an impact would have created on the order of 5 x 10 to the 10th power metric tons of atmospheric dust (about 0.01 g cm(-2) if spread globally) and 1 x 10 to the 37th power molecules of NO, or two orders of magnitude more stratospheric NO than might be produced in a large nuclear war. Researchers ignore potential injections of CO2 and wildfire smoke, and assume the direct heating of the atmosphere by impact ejecta on a regional scale is not large compared to absorption of solar energy by dust. Researchers assume an impact site at 45 N in the interior of present day North America.

Thompson, Starley L.↗

Tracking the Martian CO2 Polar Ice Caps in Infrared Images

Researchers at NASA s Jet Propulsion Laboratory have developed a method for automatically tracking the polar caps on Mars as they advance and recede each year (see figure). The seasonal Mars polar caps are composed mainly of CO2 ice and are therefore cold enough to stand out clearly in infrared data collected by the Thermal Emission Imaging System (THEMIS) onboard the Mars Odyssey spacecraft. The Bimodal Image Temperature (BIT) histogram analysis algorithm analyzes raw, uncalibrated data to identify images that contain both "cold" ("polar cap") and "warm" ("not polar cap") pixels. The algorithm dynamically identifies the temperature that separates these two regions. This flexibility is critical, because in the absence of any calibration, the threshold temperature can vary significantly from image to image. Using the identified threshold, the algorithm classifies each pixel in the image as "polar cap" or "not polar cap," then identifies the image row that contains the spatial transition from "polar cap" to "not polar cap." While this method is useful for analyzing data that has already been returned by THEMIS, it has even more significance with respect to data that has not yet been collected. Instead of seeking the polar cap only in specific, targeted images, the simplicity and efficiency of this method makes it feasible for direct, onboard use. That is, THEMIS could continuously monitor its observations for any detections of the polar-cap edge, producing detections over a wide range of spatial and temporal conditions. This effort can greatly contribute to our understanding of long-term climatic change on Mars.

Wagstaff, Kiri L.↗