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All sourcesNASA NTRSDOE OSTI
NASA NTRS2009

Origin and Evolution of Organic Matter Preserved in Stardust Cometary Aerogel Tracks

The STARDUST spacecraft captured dust samples from Comet 81P/Wild 2 at a relative velocity of 6.1 km/s in a low density silica aerogel and returned them to the Earth. One of the main of the scientific goals established for the mission was to determine whether comets contained complex organic materials and, contingently, the nature and abundance of this material. [1] Although contamination concerns due to carbonaceous impurities intrinsic to the flight aerogel remain, it is generally accepted that at least a fraction of the captured dust particles contain an indigenous organic component. [2] However, understanding the nature and abundance of this material is complicated by nature of the collection process. The rapid dissipation of particle s kinetic energy during its impact and deceleration cause both the particle and surrounding aerogel to experience an intense thermal pulse of upwards of 2000K for a period up to several hundred nanoseconds [3]. During this period thermal alteration and or destruction of organic species present in the impacting particle are likely to occur. We have used the technique of ultrafast two-step laser mass spectrometry (ultra L2MS) [4] to investigate how the nature and distribution of aromatic and conjugated organic species varies between and within aerogel cometary tracks and their associated terminal particles.

McKay, D.S.↗
NASA NTRS2017

PHYS: Division of Physical Chemistry 258 - Properties and Origins of Cometary and Asteroidal Organic Matter Delivered to the Early Earth

Comets and asteroids may have contributed much of the Earth's water and organic matter. The Earth accretes approximately 4x10(exp 7) Kg of dust and meteorites from these sources every year. The least altered meteorites contain complex assemblages of organic compounds and abundant hydrated minerals. These carbonaceous chondrite meteorites probably derive from asteroids that underwent hydrothermal processing within the first few million years after their accretion. Meteorite organics show isotopic and chemical signatures of low-T ion-molecule and grain-surface chemistry and photolysis of icy grains that occurred in cold molecular clouds and the outer protoplanetary disk. These signatures have been overprinted by aqueously mediated chemistry in asteroid parent bodies, forming amino acids and other prebiotic molecules. Comets are much richer in organic matter but it is less well characterized. Comet dust collected in the stratosphere shows larger H and N isotopic anomalies than most meteorites, suggesting better preservation of primordial organics. Rosetta studies of comet 67P coma dust find complex organic matter that may be related to the macromolecular material that dominates the organic inventory of primitive meteorites. The exogenous organic material accreting on Earth throughout its history is made up of thousands of molecular species formed in diverse processes ranging from circumstellar outflows to chemistry at near absolute zero in dark cloud cores and the formative environment within minor planets. NASA and JAXA are currently flying sample return missions to primitive, potentially organic-rich asteroids. The OSIRIS-REx and Hayabusa2 missions will map their target asteroids, Bennu and Ryugu, in detail and return regolith samples to Earth. Laboratory analyses of these pristine asteroid samples will provide unprecedented views of asteroidal organic matter relatively free of terrestrial contamination within well determined geological context. Studies of extraterrestrial materials and returned samples are essential to understand the origins of Solar System organic material and the roles of comets and asteroids to providing the starting materials for the emergence of life.

Messenger, Scott↗
NASA NTRS2011

Organic Compounds in Stardust

The successful return of the STARDUST spacecraft provides a unique opportunity to investigate the nature and distribution of organic matter in cometary dust particles collected from Comet 81P/Wild-2. Analysis of individual cometary impact tracks in silica aerogel using the technique of two-step laser mass spectrometry (L2MS) demonstrates the presence of complex aromatic organic matter. While concerns remain as to the organic purity of the aerogel collection medium and the thermal effects associated with hypervelocity capture, the majority of the observed organic species appear indigenous to the impacting particles and are hence of cometary origin. While the aromatic fraction of the total organic matter present is believed to be small, it is notable in that it appears to be N-rich. Spectral analysis in combination with instrumental detection sensitivities suggest that N is incorporated predominantly in the form of aromatic nitriles (R-C N). While organic species in the STARDUST samples do share some similarities with those present in the matrices of carbonaceous chondrites, the closest match is found with stratospherically collected interplanetary dust particles. These findings are consistent with the notion that a fraction of interplanetary dust is of cometary origin. The presence of complex organic N-containing species in comets has astrobiological implications since comets are likely to have contributed to the prebiotic chemical inventory of both the Earth and Mars.

McKay, David S.↗
NASA NTRS2010

The Search for Interstellar Sulfide Grains

The lifecycle of sulfur in the galaxy is poorly understood. Fe-sulfide grains are abundant in early solar system materials (e.g. meteorites and comets) and S is highly depleted from the gas phase in cold, dense molecular cloud environments. In stark contrast, sulfur is essentially undepleted from the gas phase in the diffuse interstellar medium, indicating that little sulfur is incorporated into solid grains in this environment. It is widely believed that sulfur is not a component of interstellar dust grains. This is a rather puzzling observation unless Fe-sulfides are not produced in significant quantities in stellar outflows, or their lifetime in the ISM is very short due to rapid destruction. Fe sulfide grains are ubiquitous in cometary samples where they are the dominant host of sulfur. The Fe-sulfides (primarily pyrrhotite; Fe(1-x)S) are common, both as discrete 0.5-10 micron-sized grains and as fine (5-10 nm) nanophase inclusions within amorphous silicate grains. Cometary dust particles contain high abundances of well-preserved presolar silicates and organic matter and we have suggested that they should contain presolar sulfides as well. This hypothesis is supported by the observation of abundant Fe-sulfides grains in dust around pre- and post-main sequence stars inferred from astronomical spectra showing a broad 23 micron IR feature due to FeS. Fe-sulfide grains also occur as inclusions in bona fide circumstellar amorphous silicate grains and as inclusions within deuterium-rich organic matter in cometary dust samples. Our irradiation experiments show that FeS is far more resistant to radiation damage than silicates. Consequently, we expect that Fe sulfide stardust should be as abundant as silicate stardust in solar system materials.

Keller, Lindsay P.↗
NASA NTRS2003

Workshop on Cometary Dust in Astrophysics

The paper include contribution of each Lunar and Planetary Institute. Contents include the following: Mass flux in the ancient Earth-Moon system and benign implications for the origin of life on Earth. In-situ analysis of complex organic matter in cometary dust by ion microprobe. Pristine presolar silicon carbide. Infrared spectra of melilite solid solution. Comet observations with SIRTF. Ice and carbon chemistry in comets. The nature in interstellar dust. Modeling the infrared emission from protoplanetary dust disks.

Source record↗
NASA NTRS2015

Measurement and Modeling of Electromagnetic Scattering by Particles and Particle Groups

Small particles forming clouds of interstellar and circumstellar dust, regolith surfaces of many solar system bodies, and cometary atmospheres have a strong and often controlling effect on many ambient physical and chemical processes. Similarly, aerosol and cloud particles exert a strong influence on the regional and global climates of the Earth, other planets of the solar system, and exoplanets. Therefore, detailed and accurate knowledge of physical and chemical characteristics of such particles has the utmost scientific importance.

Interstellar matter↗
NASA NTRS1989

Organic chemistry of cometary dust as derived from PUMA 1 data

Onboard the Halley Fly-By spacecrafts Vega 1, Vega 2, and Giotto were the dust impact mass spectrometers PUMA 1, PUMA 2, and PIA respectively. PUMA 1 was the most sensitive instrument among them. From its data the occurrence of masslines greater than 60 Daltons could be shown to be statistically significant. An analysis of these masslines lead to a scenario, which could explain the masslines as fragment ions from larger molecules which characterize the chemical nature of cometary organic matter as: (1) highly unsaturated hydrocarbons; (2) some of them containing oxygen; (3) less containing nitrogen; and (4) a few containing oxygen and nitrogen as heteroatoms. From the properties of the spectrometer, also some physical parameters of the dust particles could be inferred, such as their density and structure.

Kissel, J.↗
NASA NTRS1992

Experimental studies of the far-infrared spectra of cosmic-type ices

Work performed during the period is reported. The abstract of a paper presented at the Second International Workshop on the Nature of Cometary Organic Matter is included. Far infrared spectra of amorphous and crystalline water ice before and after proton irradiation is presented. Also, a study of clathrate hydrates was conducted in which a methanol (CH3OH) clathrate hydrate was prepared and its far-infrared spectrum investigated. This paper is also included.

Hudson, Reggie L.↗
NASA NTRS2017

Cometary Dust: The Diversity of Primitive Matter

The connections between comet dust and primitive chondrites from asteroids has strengthened considerably over the past decade. Understanding the importance of the connections between Stardust samples and chondrites requires geochemistry lingo as well as a perspective of other cometary dust samples besides Stardust. We present the principal findings of an extensive review prepared for by us for the June 2016 "Cometary Science After Rosetta" meeting at The Royal Society, London.

asteroids↗
NASA NTRS2018

Water-Rock Interactions in Outer Solar System Bodies: Evidence from the Coordinated Analysis of Interplanetary Dust

NASA has an ongoing program of collecting interplanetary dust particles (IDPs) in the stratosphere using high altitude research aircraft. The collected IDPs are derived from asteroids and comets and here we report studies of a subset of hydrated IDPs rich in carbonaceous matter that are proposed to have a cometary origin. Our studies are aimed at understanding the evolution of oxygen reservoirs in the Solar System and their interaction with cometary minerals and organic matter. The small size (<20 μm) and fragility of these IDPs present a number of analytical challenges. We have pioneered techniques for performing chemical, mineralogical, isotopic, and spectroscopic measurements on the same sample in a carefully coordinated sequence. Coordinated analyses of nanogram-size samples is made possible by several delicate sample preparation techniques. To avoid organic contamination, we embed IDPs in elemental sulfur and use ultramicrotomy to partly section the particles (the first few micrometers). Multiple thin sections (50-70 nm thick) are placed on different substrates depending on the analysis technique. We use a JEOL 2500SE scanning, transmission electron microscope (STEM) to determine the mineralogy, microstructure, and elemental compositions of constituent minerals in the thin sections through a combination of high resolution imaging, electron diffraction, quantitative energy-dispersive x-ray mapping, and electron energy-loss spectroscopy. Following the STEM analyses, we use a NanoSIMS 50L for high spatial resolution isotopic measurements of H, C, N, and O to search for presolar grains and to understand the origin of the indigenous organic matter. The isotopic analyses are performed on the same sections analyzed in the STEM in order to correlate isotopic properties with the elemental and mineralogical data. We reserve other thin sections for non-destructive analyses utilizing synchrotron-based techniques including Fourier-transform infrared (FTIR) micro-spectroscopy and X-ray absorption near-edge structure (XANES) analyses, especially for functional group analysis of organic matter in the particles. The remainder of the IDP is extracted from the sulfur bead that was used for microtomy and is pressed into Au foil for quantitative analysis (including light elements) using a JEOL 8530F field emission electron probe microanalyzer (EPMA). After the EPMA measurements, high precision oxygen isotopic analyses are obtained using Cameca IMS1270/1290 instruments at UCLA. The hydrated IDPs in this study are dominated by saponitic clays, with minor magnetite, carbonate and abundant organic matter. The remarkable oxygen isotopic compositions, high carbon contents, and the abundance of isotopically anomalous organic matter, together suggest that the high carbon, hydrated IDPs are derived from primitive sources not yet represented in meteorite collections such as outer main belt P- and D-type asteroids or comets.

Keller, Lindsay P.↗
NASA NTRS1983

Radio science and the International Halley Watch

The radio observations planned for the perihelion passage of Halley's comet in 1986 within the framework of the International Halley Watch (IHW) are reviewed. The roles of radar astronomy, continuum radio astronomy, and spectral-line radio astronomy in investigating the size and surface characteristics of the cometary nucleus, the nature and kinematics of the parent molecules sublimating into the coma, the properties of the coma particulate matter, and the cometary plasma are examined. Problems related to the inaccuracy of comet position data and lacks of background-source information, simultaneous submillimeter observations, and Southern-Hemisphere radio observing time are discussed; and the observatories participating in the IHW network are listed in tables with their instrument parameters.

Irvine, W. M.↗
NASA NTRS2012

Observations of Carbon Isotopic Fractionation in Interstellar Formaldehyde

Primitive Solar System materials (e.g. chondrites. IDPs, the Stardust sample) show large variations in isotopic composition of the major volatiles (H, C, N, and O ) even within samples, witnessing to various degrees of processing in the protosolar nebula. For ex~ ample. the very pronounced D enhancements observed in IDPs [I] . are only generated in the cold. dense component of the interstellar medium (ISM), or protoplanetary disks, through ion-molecule reactions in the presence of interstellar dust. If this isotopic anomaly has an interstellar origin, this leaves open the possibility for preservation of other isotopic signatures throughout the form ation of the Solar System. The most common form of carbon in the ISM is CO molecules, and there are two potential sources of C-13 fractionation in this reservoir: low temperature chemistry and selective photodissociation. While gas-phase chemistry in cold interstellar clouds preferentially incorporates C-13 into CO [2], the effect of self-shielding in the presence of UV radiation instead leads to a relative enhancement of the more abundant isotopologue, 12CO. Solar System organic material exhibit rather small fluctuations in delta C-13 as compared to delta N-15 and delta D [3][1], the reason for which is still unclear. However, the fact that both C-13 depleted and enhanced material exists could indicate an interstellar origin where the two fractionation processes have both played a part. Formaldehyde (H2CO) is observed in the gas-phase in a wide range of interstellar environments, as well as in cometary comae. It is proposed as an important reactant in the formation of more complex organic molecules in the heated environments around young stars, and formaldehyde polymers have been suggested as the common origin of chondritic insoluable organic matter (IOM) and cometary refractory organic solids [4]. The relatively high gas-phase abundance of H2CO observed in molecular clouds (10(exp- 9) - 10(exp- 8) relative to H2) makes it feasible to observe its less common isotopologues. As a step in our investigation of C-13 fractionation patterns in the ISM, we here present comparisons between observations of the C-13 fraction in formaldehyde, and chemical fractionation models.

Wirstrom, E. S.↗
NASA NTRS2024

Chemical and Physical Properties of Cometary Dust

Cometary dust particles are best preserved remnants of the matter present at the onset of the formation of the Solar System. In Space missions, telescopic observations and laboratory analyses advanced the knowledge on the properties of cometary dust. the only samples certified with a cometary origin were returned by the Stardust space mission from comet 81P/Wild2. The “chondritic porous” (here called “chondritic anhydrous”) interplanetary dust particles (CA-IDPs) and micrometeorites (CP-MMs), and the ultracarbonaceous Antarctic MMs (UCAMMs) also show strong evidence for a cometary origin. The elemental composition of cometary dust is generally consistent with the chondritic (CI) composition, with the notable exception of elevated contents in carbon and nitrogen compared with CI. The organic matter of cometary dust is mixed with minor amounts of crystalline (at least 25% of the minerals) and amorphous mineral phases. The most abundant crystalline minerals are ferromagnesian silicates (olivine and low-Ca pyroxenes), but High-Ca pyroxenes, refractory minerals and Low Ni Fe sulfides are also present. The crystalline olivine and low-Ca pyroxene compositions can vary from their Mg-rich end-member (forsterite and enstatite) to relatively Fe-rich compositions. Refractory minerals as well as secondary minerals likeLIME (low-iron, Mn-enriched) olivines, unusual Fe sulfides or mineral aggregates of specific compositions like Kosmochloric high-Ca pyroxene and FeO-rich olivine - KOOL grains) are also found. The presence of carbonates in cometary dust is still debated, but a phyllosilicate-like phase was observed in a UCAMM. The abundance of pyroxene to olivine (in numbers) is larger than in primitive meteorites (e.g. the Px/Ol ratio is usually larger than 1). GEMS phases (glass with embedded metals and sulfides) are abundant in cometary dust, although not systematically found. Some of the organic matter present in cometary dust particle resembles the insoluble organic matter (IOM) present in primitive meteorites, but amorphous carbon and exotic (e.g. N-rich) organic phases are also present. The hydrogen isotopic composition of cometary dust particles (in the organic matter) is usually rich in deuterium, tracing a formation at very low temperatures, either in the protosolar cloud or in the outer regions of the protoplanetary disk. The presolar dust concentration in cometary dust can reach about 1%, which is the most elevated value observed in extraterrestrial samples. The size distribution of cometary dust in comet trails is well represented by a power-law distribution (differential size distribution) with a mean power index N typically ranging from -3 to -4. Polarimetric and light scattering studies of cometary dust suggest mixtures of porous agglomerates of sub-micrometer minerals with organic matter, which is compatible with the in situ analyses of 67P/Churyumov-Gerasimenko by MIDAS (Rosetta) and with the studies of it Stardust samples, CA-IDPs, CP-MMs and UCAMMs. Cometary dust particles have low tensile strength, and low density.

C. Engrand↗
NASA NTRS1981

Could life have evolved in cometary nuclei

The suggestion by Hoyle and Wickramasinghe (1978) that life might have originated in cometary nuclei rather than directly on the earth is discussed. Factors in the cometary environment including the conditions at perihelion passage leading to the ablation of cometary ices, ice temperatures, the absence of an atmosphere and discrete liquid and solid surfaces, weak cometary structure incapable of supporting a liquid core, and radiation are presented as arguments against biopoesis in comets. It is concluded that although the contribution of cometary and meteoritic matter was significant in shaping the earth environment, the view that life on earth originally arose in comets is untenable, and the proposition that the process of interplanetary infection still occurs is unlikely in view of the high specificity of host-parasite relationships.

Bar-Nun, A.↗
NASA NTRS2000

Search for Extraterrestrial Origin of Atmospheric Trace Molecules Radio Sub-MM Observations During The Leonids

HCN is a minor constituent of the Earth atmosphere, with a typical volume mixing ratio around 10(exp -10) HCN per air molecule. At present, the main source of HCN in the lower atmosphere is expected to be biomass burning. The atmospheric HCN has been observed since 1981, first in the infrared, then at microwave radio frequencies. Globally, above 30 km, HCN measurements are in excess of model predictions based on standard photochemistry and biomass burning as the only HCN source. This excess has been explained by: 1) ion-catalyzed reactions in the entire stratosphere, involving CH.3CN as a precursor and/or 2) a high altitude source as a result of chemical production from the methyl radical CH3, or from injection or production by meteors. HCN is a minor constituent of cometary ices. HCN polymers or copolymers have been suggested as constituents of cometary refractory organic matter, and would thus be present in the incoming meteoroids, if these polymers survived their stay in interplanetary space after ejection. HCN may also be created from the CN radical decomposition product of organic carbon, after reaction with hydrogen-bearing molecules. To test the hypothesis of HCN input by meteoroids or the formation in the upper atmosphere from meteoric ablation products, we decided to monitor the HCN submillimeter lines around a major shower: the Leonids.

Depois, D.↗
NASA NTRS2012

Nitrogen Isotopic Composition of Organic Matter in a Pristine Collection IDP

Anhydrous chondritic porous interplanetary dust particles (CP IDPs) are probable cometary materials that show primitive characteristics, such as unequilibrated mineralogy, fragile structure, and abundant presolar grains and organic matter [1-3]. CP IDPs are richer in aliphatic species and N-bearing aromatic hydrocarbons than meteoritic organics and commonly exhibit highly anomalous H and N isotopic compositions [4,5]. Cometary organic matter is of interest in part because it has escaped the hydrothermal processing experienced by meteorites. However, IDPs are collected using silicon oil that must be removed with strong organic solvents such as hexane. This procedure is likely to have removed some fraction of soluble organic phases in IDPs. We recently reported the first stratospheric collection of IDPs without the use of silicone oil [6]. Here we present initial studies of the carbonaceous material in an IDP from this collection.

Messenger, S.↗
NASA NTRS1993

Mass and spatial distribution of carbonaceous component in Comet Halley

Cometary grains containing large amounts of carbon and/or organic matter were discovered by in situ measurements of cometary dust composition during VEGA and GIOTTO fly-by missions. In accordance with the classification for the data of PUMA-1 and PUMA-2 mass-spectrometers on board the VEGA spacecraft, particles with a ratio of C to any rock-forming element (Mg, Si, Fe, Ca etc.) greater than 10, were categorized as CHON. There are 464 such particles in PUMA-1 data and 51 in PUMA-2 data. Application of cluster analysis to these grains revealed several distinct compositional classes, namely: (H,C,N,O), (H,C,N), (H,C), (H,C,O), (C,N), (C,O), (C,N,O), and (C). Similar classes were identified among particles analyzed by PIA. Also, about a third of all particles fell into groups (H) and (O) characterized by abundances of these elements beyond chemically reasonable limits.

Fomenkova, M.↗
NASA NTRS1978

The primitive solar accretion disk and the formation of the planets

The author develops the idea that the formation of the solar system was triggered by the explosion of a supernova near a compressed interstellar cloud, which was further compressed by the supernova ejecta until it went over the threshold for gravitational collapse. During the collapse it is expected that the cloud would fragment into much smaller pieces. The principle source of friction in the collapsing nebula is taken to be turbulent viscosity, the required stirring having been supplied possibly by meridional circulation currents. The theory can be shown to account for how a great deal of condensed matter in the form of cometary bodies could be put into elliptical orbits extending toward 100,000 AU, the region of the Oort reservoir.

Cameron, A. G. W.↗