Reactive CO2 capture: A path forward for process integration in carbon management
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Key elements of this report include coal-to-hydrogen production in the context of the U.S. hydrogen market; the state of various hydrogen production technologies; present and forecasted demand for hydrogen in energy, transportation, and industrial sectors; an overview of environmental, economic, and infrastructure challenges to greater coal-to-hydrogen production; and information on the U.S. Department of Energy (DOE) programs and priorities for coal-to-hydrogen research and development.
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Most of the warming is caused by CO 2 . CO 2 stays in the atmosphere. Reduction of greenhouse gas emissions is the most effective way to reduce greenhouse gas concentrations in the atmosphere.
This is the user guide for the tool described here: Development of technologies that convert carbon dioxide (CO 2 ) into products is part of the U.S. Department of Energy's Office of Fossil Energy and Carbon Management Carbon Conversion Program portfolio. One such technology under development converts CO 2 to value-added products via electrochemical reduction, where catalysts are used on the cathode to promote CO 2 conversion across the electrochemical catalyst (ECC) cell. Broadly, the ECC is integrated with balance of plant (BOP) equipment (e.g., compressors, pumps, heat exchangers, purification units) in system configurations to produce the desired product. To guide research and development (R&D) toward advancements that may make such conversion technologies economically competitive, researchers may use sensitivity analyses related to the ECC system cost and performance, including that of the cathodic and anodic catalysts. This tool is intended to inform developers and Program in assessing proposed R&D on ECC systems early in the development process. Results will guide researchers on where efforts would be best directed. The tool may be accessed here: https://www.netl.doe.gov/energy-analysis/details?id=55293cb1-6881-4181-a2b0-d00b711ce74b.
This presentation was given on October 25, 2021 to the Fossil Energy and Carbon Management Carbon Use Welcome Session for algae-based projects. It described the LCA tools available under the NETL CO2 Utilization Guidance Toolkit.
An overview of the Fossil Energy and Carbon Management mission for carbon management was given, along with information on the role the Research and Innovation Center plays in understanding aspect of research needed to accelerate geologic carbon storage nationwide.
Contents include the following: 1) Southeastern Regional Carbon Sequestration Partnership (SECARB)–Southern States Energy Board's 48th Annual Meeting, August 8, 2008; 2) Southern States Energy Board Carbon Management Program SSEB Associate Members Meeting, August 21, 2009; 3) Carbon Capture and Sequestration (CCS) Demonstration Project, August 21, 2009; 4) Clean Energy in the Southern Region, August 27, 2010; 5) Carbon Management–Southern Leadership of a Regional Partnership, October 17, 2011; 6) Southeastern Regional Carbon Sequestration Partnership "Knowledge Sharing", August 10, 2012; 7) Southeastern Regional Carbon Sequestration Partnership; 8) Site Visit by Southern Legislative Group, July 30, 2013; 9) SECARB Awards Anthropogenic Test, March 4, 2014; 10) Southern Company/MHI Ltd. 500 TPD CCS Demonstration; 11) SECARB Anthropogenic Test Project Assessment, March 4-5, 2014; 12) Advanced Monitoring Technologies SECARB Phase III CO 2 Storage Citronell, Alabama, March 4, 2014; 13) Geomechanics at Cranfield, March 5, 2014; 14) Gulf Coast Carbon Center Near-Surface Update, March 4-5, 2014; 15) Monitoring Design Best Practices, March 5, 2014; 16) Special Projects–Carbon Management Program, 2015; 17) Special Projects, November 2-3, 2016; 18) Carbon Management Program Carbon Capture & Storage Projects, September 24, 2017; 19) Remarks Before the 58th Annual Meeting of the Executive Committee, September 16, 2018; 20) Annual Business Session, September 24, 2019; and 21) Recent Activities & 2019-2020 Elections Insights, February 7, 2020.
Abstract Forests provide multiple benefits that include sequestering carbon, supporting biodiversity, and providing wood products. Managing temperate forests to achieve these benefits sustainably is challenging given the legacy of past human impacts, the complexity of forest development, and increasing but unpredictable disturbances. These intricacies prompted debate about the most effective management of temperate forests to achieve climate mitigation while sustaining forest productivity, regeneration, and diversity. Most research focused on management impacts under relatively stable environmental conditions, whereas forests are facing increasingly frequent and more severe climatic and biotic disturbances. Here, we used a regionally calibrated forest growth model to simulate the effects of forest management on carbon, biodiversity, and wood production under prevalent natural disturbances in the northeastern US. We developed scenarios combining forest management and disturbance regimes based on assumptions of species-specific tree regeneration and mortality rates. We compared passive management with no cutting that prioritizes maintaining existing forest trees with two common regional harvest practices: exploitative timber harvest that prioritizes short-term wood production and regenerative timber harvest that prioritizes regenerating biodiverse native forest tree seedlings. In the absence of natural disturbance, no cutting provides 41% higher forest carbon storage and 50% higher tree structural diversity after 100 years than exploitative or regenerative practices. The presence of drought, windstorm, pest, and disease disturbances altered these outcomes. Regenerative forest management provides 25% higher forest carbon storage and 26% higher tree structural diversity after 100 years than no cutting. Our results demonstrate that wood products and their carbon storage and fossil emission avoidance are important for determining the total climate benefits of forest management under natural disturbances. Our findings highlight that natural disturbance regimes should be considered when selecting management to promote multiple forest benefits, suggesting the need for tailored as opposed to one-size-fits-all policies to sustainably manage temperate forests worldwide.
Fossil fuel-based power plants generate 80% of the electricity in the United States and provide a reliable generation source for both base and peak power demands. These plants are expected to adapt to changes in environmental policies that will require carbon management with carbon capture and storage (CCS) representing a possible solution. Current solvent-based CCS has a detrimental impact on a power plant's performance due to large heat loads required for carbon capture solvent regeneration. This parasitic load restricts the power plant's output and operation flexibility. Therefore, this study evaluates the feasibility of using thermal storage technologies for natural gas combined cycle (NGCC) power plants coupled with CCS to minimize the impact of solvent regeneration and enable the plant to operate at peak power output. Thermal storage can minimize the impact of CCS on the power plant by providing the heat load required for solvent regeneration during times of peak demand which will allow the plant to operate unrestricted and at full power. In total, fifteen unique thermal storage configurations were evaluated from three thermal storage categories: Brayton cycle heat pump, vapor compression heat pump, and heat recovery steam generator steam extraction for storage. The viability of these systems was determined by evaluating each configuration on thousands of real-world Locational Marginal Pricing (LMP) profiles from the New York Independent System Operator and California Independent System Operator electricity markets using a techno-economic analysis. Afterwards, results were compared to the performance of a base power plant (NGCC with CCS and no thermal storage) to determine the impact of thermal storage on power plant economics. Overall, six of the thermal storage configurations performed better than base CCS enabled power plant on between 11.5% and 38.7% of the LMP signals evaluated. The best performing configuration was a vapor compression heat pump that used flue gas as the working fluid and had both hot and cold thermal storage units. This configuration performed better than the base CCS power plant on 38.7% of the LMP profiles. The results of this study show thermal storage can mitigate the economic impact of carbon capture solvent regeneration on NGCC power plants. Discussion focuses on the impact of electricity pricing on the optimal thermal storage system, the advantages and disadvantages of the systems evaluated, and identifies limitations with the study.
This is the final scientific / technical report for Front End Engineering Design (FEED) study “Retrofittable Advanced Combined Cycle Integration for Flexible Decarbonized Generation” funded by the US Department of Energy (DOE), Office of Fossil Energy and Carbon Management (FECM), Carbon Capture R&D Program under award DE-FE0032131. The prime recipient is General Electric Company working through its Gas Power division (GEGP) with subrecipients Southern Company and Linde Engineering plus subcontractor Kiewit. Southern Company’s Plant Barry, a 2x1 7F.04 CCGT, is the host site. GEGP led the overall integration of the carbon capture system (CCS) with the existing natural gas combined cycle (NGCC) facility. Linde provided the detailed process engineering and equipment costing for the carbon capture island. Kiewit focused on plant layout, constructability, and installation. With the FEED study finished, the engineering is approximately 50% complete towards the detailed design package needed to proceed to procure, install, build, commission, and operate the integrated NGCC+CCS facility. This FEED study focuses on retrofitting a 95% CO 2 capture system with attention on plant integration. The study was particularly challenging due to unique and substantial cost impacts related to global sourcing challenges associated with COVID. Additional incentives, regulatory support, and dispatch certainty are needed to move forward with implementing CCS at this or other sites in the US. This FEED study highlights the value of integrating NGCC+CCS and is a template for future CCS retrofit studies.
This report summarizes results of CMCSCFCB—Critical Minerals in Coaly Strata of the Cherokee-Forest City Basin, a multiyear and multidisciplinary study funded through DE-FOA-0002364 as part of the Department of Energy Office of Fossil Energy and Carbon Management (FECM) Carbon Ore, Rare Earth and Critical Minerals (CORE-CM) Initiative for U.S. Basins. Our working group of state and tribal agencies collected data and made interpretations included herein. It also surveyed the regional potential for critical mineral/material production.
Project update presentation for the U.S. Department of Energy Fossil Energy and Carbon Management and National Energy Technology Lab Carbon Management Research Project Annual Review Meeting 2023
Project update presentation for the 2024 U.S. Department of Energy Fossil Energy and Carbon Management and National Energy Technology Lab Carbon Management Research Project Annual Review Meeting
Project update presentation for the 2025 U.S. Department of Energy Fossil Energy and Carbon Management and National Energy Technology Lab Carbon Management Research Project Annual Review Meeting
Microbes drive our complex biosphere by regulating the global ecosystem through cycling elements and energy. Humankind has barely begun leveraging this biotransformation capacity to impact global economies and ecologies. Advances in genetic engineering, molecular analysis, metabolic flux modeling, microbial consortia/biome mapping and engineering, cell-free bioproduction, artificial intelligence/machine learning and the ever expanding -omics frontiers have set the stage for paradigm changes to how humankind produces, uses, transforms, and recycles carbon and energy through microbes. Harnessing this enormous potential could drive a global bioeconomy and manage carbon at a planetary level but requires understanding and application at a grand scale across a broad range of science and engineering disciplines. The penultimate manifestation of these advances is the “bio-refinery”, which is often referenced, but is a long way from being fully developed as a global carbon management platform. Broadening the feed stocks, processing operations, and product portfolio to a sequential cascade optimizing the conversion as a whole instead of limited outputs could greatly advance deployment and stability of a bioeconomy.
https://events.usea.org/events/midwest-regional-carbon-conversionutilization-procurement-grant-workshop As the U.S. economy moves toward clean energy and a lower carbon future, the U.S. Department of Energy (DOE) is seeking to partner with states, communities, and industries to support the procurement and development of carbon conversion products. These efforts have been enabled by provisions included in the Bipartisan Infrastructure Law (BIL). As part of the BIL, supporting the Administration’s goal to achieve a carbon-free power sector by 2035 and putting the United States on a path to a net-zero economy by 2050, a new initiative was established within DOE’s Office of Fossil Energy and Carbon Management through its Carbon Conversion/Utilization Program. The new initiative will establish a demonstration grant program to issue grants to eligible entities to procure commercial and industrial products derived from the conversion of anthropogenic carbon oxides and demonstrate a significant net reduction in life cycle greenhouse gas emissions compared to incumbent technologies, processes, and products. DOE-FECM will establish a demonstration grant program within the Carbon Conversion/Utilization Program to support eligible applicants that procure those commercial and industrial products derived from anthropogenic carbon oxides. Therefore, the Carbon Conversion/Utilization Program, with the assistance of the United States Energy Association (USEA), will conduct a series of workshops (both virtual and in-person) with relevant stakeholders, e.g., product manufacturers, eligible entities, or their representative national organizations (e.g., United States Conference of Mayors, etc.) to solicit input and ideas on challenges and opportunities for a potential grant program.
Hydrogen is a zero-carbon energy carrier with potential to decarbonize industrial and transportation sectors, but its life-cycle greenhouse gas (GHG) emissions depend on its energy supply chain and carbon management measures (e.g., carbon capture and storage). Global support for clean hydrogen production and use has recently intensified. In the United States, Congress passed several laws that incentivize the production and use of renewable and low-carbon hydrogen, such as the Bipartisan Infrastructure Law (BIL) in 2021 and the Inflation Reduction Act (IRA) in 2022, which provides tax credits of up to $3/kg depending on the carbon intensity of the produced hydrogen. A comprehensive life-cycle accounting of GHG emissions associated with hydrogen production is needed to determine the carbon intensity of hydrogen throughout its value chain. In the United States, Argonne’s R&D GREET ® (Greenhouse Gases, Regulated emissions, and Energy use in Technologies) model has been widely used for hydrogen carbon intensity calculations. This paper describes the major hydrogen technology pathways considered in the United States and provides data sources and carbon intensity results for each of the hydrogen production and delivery pathways using consistent system boundaries and most recent technology performance and supply chain data.