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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

Rationale and Methods for Archival Sampling and Analysis of Atmospheric Trace Chemical Contaminants On Board Mir and Recommendations for the International Space Station

Collection and analysis of spacecraft cabin air samples are necessary to assess the cabin air quality with respect to crew health. Both toxicology and engineering disciplines work together to achieve an acceptably clean cabin atmosphere. Toxicology is concerned with limiting the risk to crew health from chemical sources, setting exposure limits, and analyzing air samples to determine how well these limits are met. Engineering provides the means for minimizing the contribution of the various contaminant generating sources by providing active contamination control equipment on board spacecraft and adhering to a rigorous material selection and control program during the design and construction of the spacecraft. A review of the rationale and objectives for sampling spacecraft cabin atmospheres is provided. The presently-available sampling equipment and methods are reviewed along with the analytical chemistry methods employed to determine trace contaminant concentrations. These methods are compared and assessed with respect to actual cabin air quality monitoring needs. Recommendations are presented with respect to the basic sampling program necessary to ensure an acceptably clean spacecraft cabin atmosphere. Also, rationale and recommendations for expanding the scope of the basic monitoring program are discussed.

Perry, J. L.↗
NASA NTRS1998

Precision Cleaning and Verification Processes Used at Marshall Space Flight Center for Critical Hardware Applications

Marshall Space Flight Center (MSFC) of the National Aeronautics and Space Administration performs many research and development programs that require hardware and assemblies to be cleaned to levels that are compatible with fuels and oxidizers (liquid oxygen, solid propellants, etc.). Also, MSFC is responsible for developing large telescope satellites which require a variety of optical systems to be cleaned. A precision cleaning shop is operated within MSFC by the Fabrication Services Division of the Materials & Processes Laboratory. Verification of cleanliness is performed for all precision cleaned articles in the Environmental and Analytical Chemistry Branch. Since the Montreal Protocol was instituted, MSFC had to find substitutes for many materials that have been in use for many years, including cleaning agents and organic solvents. As MSFC is a research center, there is a great variety of hardware that is processed in the Precision Cleaning Shop. This entails the use of many different chemicals and solvents, depending on the nature and configuration of the hardware and softgoods being cleaned. A review of the manufacturing cleaning and verification processes, cleaning materials and solvents used at MSFC and changes that resulted from the Montreal Protocol will be presented.

Caruso, Salvadore V.↗
NASA NTRS1999

Precision Cleaning and Verification Processes Used at Marshall Space Flight Center for Critical Hardware Applications

Marshall Space Flight Center (MSFC) of the National Aeronautics and Space Administration (NASA) performs many research and development programs that require hardware and assemblies to be cleaned to levels that are compatible with fuels and oxidizers (liquid oxygen, solid propellants, etc.). Also, the Center is responsible for developing large telescope satellites which requires a variety of optical systems to be cleaned. A precision cleaning shop is operated with-in MSFC by the Fabrication Services Division of the Materials & Processes Division. Verification of cleanliness is performed for all precision cleaned articles in the Analytical Chemistry Branch. Since the Montreal Protocol was instituted, MSFC had to find substitutes for many materials that has been in use for many years, including cleaning agents and organic solvents. As MSFC is a research Center, there is a great variety of hardware that is processed in the Precision Cleaning Shop. This entails the use of many different chemicals and solvents, depending on the nature and configuration of the hardware and softgoods being cleaned. A review of the manufacturing cleaning and verification processes, cleaning materials and solvents used at MSFC and changes that resulted from the Montreal Protocol will be presented.

Caruso, Salvadore V.↗
NASA NTRS2004

A Review of Monitoring Technologies for Trace Air Contaminants in the International Space Station

NASA issued a Request For Information (RFI) to identify technologies that might be available to monitor a list of air pollutants in the ISS atmosphere. After NASA received responses to the RFI, an expert panel was assembled to hear presentations from 9 technology proponents. The goal of the panel was to identify technologies that might be suitable for replacement of the current Volatile Organics Analyzer (VOA) within several years. The panelists consisted of 8 experts in analytical chemistry without any links to NASA and 7 people with specific expertise because of their roles in NASA programs. Each technology was scored using a tool that enabled rating of many specific aspects of the technology on a 4-point system. The maturity of the technologies ranged from well-tested instrument packages that had been designed for space applications and were nearly ready for flight to technologies that were untested and speculative in nature. All but one technology involved the use of gas chromatography for separation, and there were various detectors proposed including several mass spectrometers and ion mobility spectrometers. In general there was a tradeoff between large systems with considerable capability to address the target list and smaller systems that had much more limited capability.

James, John T.↗
NASA NTRS2009

Development of a Test Protocol for Spacecraft Post-Fire Atmospheric Cleanup and Monitoring

Detecting and extinguishing fires, along with post-fire atmospheric cleaning and monitoring, are vital components of a spacecraft fire response system. Preliminary efforts focused on the technology evaluation of these systems under realistic conditions are described in this paper. While the primary objective of testing is to determine a smoke mitigation filter s performance, supplemental evaluations measuring the smoke-filled chamber handheld commercial off-the-shelf (COTS) atmospheric monitoring devices (combustion product monitors) are also conducted. The test chamber consists of a 1.4 cubic meter (50 cu. ft.) volume containing a smoke generator. The fuel used to generate the smoke is a mixture of polymers in quantities representative of materials involved in a circuit board fire as a typical spacecraft fire. Two fire conditions were examined: no flame and flame. No flame events are produced by pyrolyzing the fuel mixture in a quartz tube furnace with forced ventilation to produce a white, lingering-type smoke. Flame events ignite the smoke at the outlet of the tube furnace producing combustion characterized by a less opaque smoke with black soot. Electrochemical sensor measurements showed carbon monoxide is a major indicator of each fire. Acid gas measurements were recorded, but cross interferents are currently uncharacterized. Electrochemical sensor measurements and sample acquisition techniques from photoacoustic sensors are being improved. Overall, this research shows fire characterization using traditional analytical chemistry techniques is required to verify measurements recorded using COTS atmospheric monitoring devices.

Zuniga, David↗
NASA NTRS2010

Surface-Enhanced X-Ray Fluorescence

Surface-enhanced x-ray fluorescence (SEn-XRF) spectroscopy is a form of surface- enhanced spectroscopy that was conceived as a means of obtaining greater sensitivity in x-ray fluorescence (XRF) spectroscopy. As such, SEn-XRF spectroscopy joins the ranks of such other, longer-wavelength surface-enhanced spectroscopies as those based on surface-enhanced Raman scattering (SERS), surface-enhanced resonance Raman scattering (SERRS), and surfaceenhanced infrared Raman absorption (SEIRA), which have been described in previous NASA Tech Briefs articles. XRF spectroscopy has been used in analytical chemistry for determining the elemental compositions of small samples. XRF spectroscopy is rapid and quantitative and has been applied to a variety of metal and mineralogical samples. The main drawback of XRF spectroscopy as practiced heretofore is that sensitivity has not been as high as required for some applications. In SEn-XRF as in the other surface-enhanced spectroscopies, one exploits several interacting near-field phenomena, occurring on nanotextured surfaces, that give rise to local concentrations of incident far-field illumination. In this case, the far-field illumination comes from an x-ray source. Depending on the chemical composition and the geometry of a given nanotextured surface, these phenomena could include the lightning-rod effect (concentration of electric fields at the sharpest points on needlelike surface features), surface plasmon resonances, and grazing incidence geometric effects. In the far field, the observable effect of these phenomena is an increase in the intensity of the spectrum of interest - in this case, the x-ray fluorescence spectrum of chemical elements of interest that may be present within a surface layer at distances no more than a few nanometers from the surface.

Anderson, Mark↗
NASA NTRS2012

Timescale Correlation between Marine Atmospheric Exposure and Accelerated Corrosion Testing - Part 2

Evaluation of metals to predict service life of metal-based structures in corrosive environments has long relied on atmospheric exposure test sites. Traditional accelerated corrosion testing relies on mimicking the exposure conditions, often incorporating salt spray and ultraviolet (UV) radiation, and exposing the metal to continuous or cyclic conditions similar to those of the corrosive environment. Their reliability to correlate to atmospheric exposure test results is often a concern when determining the timescale to which the accelerated tests can be related. Accelerated corrosion testing has yet to be universally accepted as a useful tool in predicting the long-term service life of a metal, despite its ability to rapidly induce corrosion. Although visual and mass loss methods of evaluating corrosion are the standard, and their use is crucial, a method that correlates timescales from accelerated testing to atmospheric exposure would be very valuable. This paper presents work that began with the characterization of the atmospheric environment at the Kennedy Space Center (KSC) Beachside Corrosion Test Site. The chemical changes that occur on low carbon steel, during atmospheric and accelerated corrosion conditions, were investigated using surface chemistry analytical methods. The corrosion rates and behaviors of panels subjected to long-term and accelerated corrosion conditions, involving neutral salt fog and alternating seawater spray, were compared to identify possible timescale correlations between accelerated and long-term corrosion performance. The results, as well as preliminary findings on the correlation investigation, are presented.

Montgomery, Eliza L.↗
NASA NTRS2000

Planetary protection technologies at the Jet Propulsion Laboratory

This paper presents a summary of the planetary protection technology development efforts currently being conducted at the Jet Propulsion Laboratory (JPL). This is a multidisciplinary effort involving JPL and NASA expertise in microbiology, material science, and analytical chemistry, in conjunction with outside, industrial academic collaborators.

planetary↗
NASA NTRSDate not supplied

The Spacecraft Water Impurity Monitor, a Framework for the Next Generation Complete Water Analysis System for Crewed Vehicles Beyond the ISS

The Spacecraft Water Impurity Monitor (SWIM) is a joint collaboration to develop an instrument platform that will perform in-flight measurements and deliver a more complete picture of water quality to decision makers. Eventually, missions to the moon, Mars, and beyond will be equipped with analytical capabilities equaling those found in terrestrial labs. Based on what we know about current and future spacecraft environments, SWIM will seek to provide enhanced analytical capability that enables NASA to confidently send astronauts on distant missions without the possibility of returned water samples. This paper discusses the challenges presented by exploration requirements and the research and development progress toward the goal of a total water analysis system. For organic analysis, one of the analysis technologies that the SWIM team have been developing is a liquid-injection gas chromatograph mass spectrometer system; these systems are the workhorses of analytical chemistry laboratories world-wide. For inorganic analysis, the team is exploring a number of technologies ranging from traditional liquid chromatography technologies (e.g. ion chromatography, capillary electrophoresis) to flight-heritage technology such as ion-specific electrodes.

water monitoring↗
NASA NTRSDate not supplied

Progress on the Organic and Inorganic Modules of the Spacecraft Water Impurity Monitor, a Next Generation Complete Water Analysis System for Crewed Vehicles

The Spacecraft Water Impurity Monitor (SWIM) is a joint collaboration to develop an instrument platform that will perform in-flight measurements and deliver a more complete picture of water quality to decision makers. For exploration missions, returned water samples will not be an option, so spacecraft and habitats will need to be equipped with advanced water monitoring capabilities. Eventually, missions to the moon, Mars, and beyond should be equipped with analytical capabilities roughly analogous to those found in terrestrial labs. Based on what we know about current and future spacecraft environments, SWIM will seek to provide enhanced analytical capability that enables NASA to confidently send astronauts on distant missions without the possibility of returned water samples. The SWIM architecture can be broken down in an Organic Water Module (OWM) and an Inorganic Water Module (IWM), independent of each other but can be flown together if desired; an integrated system may share some commonality, e.g., single sample injection, sampling consumables, waste, etc. Each of these main modules can be broken down further into separation (if required) and detection modules. And, each separation module can be paired with one or more detection module depending on mission, spacecraft, customer needs, and size/mass/power constraints. This paper discusses the research and development progress toward the goal of a total water analysis system. For OWM, one of the analysis technologies that the SWIM team have been developing is a liquid-injection gas chromatograph mass spectrometer system; these systems are the workhorses of analytical chemistry laboratories world-wide. For IWM, the team is exploring a number of technologies ranging from traditional liquid chromatography technologies (e.g. ion chromatography, capillary electrophoresis) to flight-heritage technology such as ion-specific electrodes.

Stuart J Pensinger↗
NASA NTRSDate not supplied

Progress on the Organic and Inorganic Modules of the Spacecraft Water Impurity Monitor, a Next Generation Complete Water Analysis System for Crewed Vehicles

The Spacecraft Water Impurity Monitor (SWIM) is a joint collaboration to develop an instrument platform that will perform in-flight measurements and deliver a more complete picture of water quality to decision makers. For exploration missions, returned water samples will not be an option, so spacecraft and habitats will need to be equipped with advanced water monitoring capabilities. Eventually, missions to the moon, Mars, and beyond should be equipped with analytical capabilities roughly analogous to those found in terrestrial labs. Based on what we know about current and future spacecraft environments, SWIM will seek to provide enhanced analytical capability that enables NASA to confidently send astronauts on distant missions without the possibility of returned water samples. The SWIM architecture can be broken down in an Organic Water Module (OWM) and an Inorganic Water Module (IWM), independent of each other but can be flown together if desired; an integrated system may share some commonality, e.g., single sample injection, sampling consumables, waste, etc. Each of these main modules can be broken down further into separation (if required) and detection modules. And, each separation module can be paired with one or more detection module depending on mission, spacecraft, customer needs, and size/mass/power constraints. This paper discusses the research and development progress toward the goal of a total water analysis system. For OWM, one of the analysis technologies that the SWIM team have been developing is a liquid-injection gas chromatograph mass spectrometer system; these systems are the workhorses of analytical chemistry laboratories world-wide. For IWM, the team is exploring a number of technologies ranging from traditional liquid chromatography technologies (e.g. ion chromatography, capillary electrophoresis) to flight-heritage technology such as ion-specific electrodes.

Stuart J. Pensinger↗
NASA NTRS2023

Progress on the Organic and Inorganic Modules of the Spacecraft Water Impurity Monitor, a Next Generation Complete Water Analysis System for Crewed Vehicles

The Spacecraft Water Impurity Monitor (SWIM) is a joint collaboration to develop an instrument platform that will perform in-flight measurements and deliver a more complete picture of water quality to decision makers. For exploration missions, returned water samples will not be an option, so spacecraft and habitats will need to be equipped with advanced water monitoring capabilities. Eventually, missions to the moon, Mars, and beyond should be equipped with analytical capabilities roughly analogous to those found in terrestrial labs. Based on what we know about current and future spacecraft environments, SWIM will seek to provide enhanced analytical capability that enables NASA to confidently send astronauts on distant missions without the possibility of returned water samples. The SWIM architecture can be broken down in an Organic Water Module (OWM) and an Inorganic Water Module (IWM), independent of each other but can be flown together if desired; an integrated system may share some commonality, e.g., single sample injection, sampling consumables, waste, etc. Each of these main modules can be broken down further into separation (if required) and detection modules. And, each separation module can be paired with one or more detection module depending on mission, spacecraft, customer needs, and size/mass/power constraints. This paper discusses the research and development progress toward the goal of a total water analysis system. For OWM, one of the analysis technologies that the SWIM team have been developing is a liquid-injection gas chromatograph mass spectrometer system; these systems are the workhorses of analytical chemistry laboratories world-wide. For IWM, the team is exploring a number of technologies ranging from traditional liquid chromatography technologies (e.g. ion chromatography, capillary electrophoresis) to flight-heritage technology such as ion-specific electrodes.

Stuart J Pensinger↗
NASA NTRS2023

Progress on the Organic and Inorganic Modules of the Spacecraft Water Impurity Monitor, a Next Generation Complete Water Analysis System for Crewed Vehicles

The Spacecraft Water Impurity Monitor (SWIM) is a joint collaboration to develop an instrument platform that will perform in-flight measurements and deliver a more complete picture of water quality to decision makers. For exploration missions, returned water samples will not be an option, so spacecraft and habitats will need to be equipped with advanced water monitoring capabilities. Eventually, missions to the moon, Mars, and beyond should be equipped with analytical capabilities roughly analogous to those found in terrestrial labs. Based on what we know about current and future spacecraft environments, SWIM will seek to provide enhanced analytical capability that enables NASA to confidently send astronauts on distant missions without the possibility of returned water samples. The SWIM architecture can be broken down in an Organic Water Module (OWM) and an Inorganic Water Module (IWM), independent of each other but can be flown together if desired; an integrated system may share some commonality, e.g., single sample injection, sampling consumables, waste, etc. Each of these main modules can be broken down further into separation (if required) and detection modules. And, each separation module can be paired with one or more detection module depending on mission, spacecraft, customer needs, and size/mass/power constraints. This paper discusses the research and development progress toward the goal of a total water analysis system. For OWM, one of the analysis technologies that the SWIM team have been developing is a liquid-injection gas chromatograph mass spectrometer system; these systems are the workhorses of analytical chemistry laboratories world-wide. For IWM, the team is exploring a number of technologies ranging from traditional liquid chromatography technologies (e.g. ion chromatography, capillary electrophoresis) to flight-heritage technology such as ion-specific electrodes.

Stuart Pensinger↗