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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Rhenium-osmium-isotope constraints on the age of iron meteorites

Rhenium and osmium concentrations and the osmium isotopic compositions of iron meteorites were determined by negative thermal ionization mass spectrometry. Data for the IIA iron meteorites define an isochron with an uncertainty of approximately +/-31 million years for meteorites about 4500 million years old. Although an absolute rhenium-osmium closure age for this iron group cannot be as precisely constrained because of uncertainty in the decay constant of Re-187, an age of 4460 million years ago is the minimum permitted by combined uncertainties. These age constraints imply that the parent body of the IIAB magmatic irons melted and subsequently cooled within 100 million years after the formation of the oldest portions of chondrites. Other iron meteorites plot above the IIA isochron, indicating that the planetary bodies represented by these iron groups may have cooled significantly later than the parent body of the IIA irons.

Horan, M. F.↗

Uncertainty Analysis of the NASA Glenn 8- by 6-Foot Supersonic Wind Tunnel 2019 Characterization Test 14-Foot, 5.8 Percent Test Section Porosity

This paper presents methods and results of a measurement uncertainty analysis that was performed for the 8- by 6-foot Supersonic Wind Tunnel located at the NASA Glenn Research Center. The uncertainty analysis is based on data collected during a characterization test following major structural modifications to the facility and upgrades to the facility’s data and control systems. The statistical methods and engineering judgments used to estimate elemental uncertainties are described in this report. The Monte Carlo method of propagating uncertainty was selected to determine the uncertainty of calculated variables of interest. A description of the Monte Carlo method as applied for this analysis is provided. The primary variable of interest (VOI) for this facility is free stream Mach number. In addition to determining the uncertainty in Mach number, the uncertainty in free stream values of static pressure, total pressure, dynamic pressure, total temperature, static temperature, Reynolds number, and air speed were also calculated. Uncertainty results are presented as random (unpredictable variation in repeated measurements), systematic (potential offset between observed and true value), and total (random and systematic combined) uncertainty for Mach number. Systematic uncertainty results are presented for the other VOIs. Individual uncertainty sources are presented both dimensionally and as percent contributions to uncertainty in all VOIs, to aid in the identification of primary uncertainty sources.

Uncertainty Analysis↗

Theoretical study of transition-metal ions bound to benzene

Theoretical binding energies are reported for all first-row and selected second-row transition metal ions (M+) bound to benzene. The calculations employ basis sets of at least double-zeta plus polarization quality and account for electron correlation using the modified coupled-pair functional method. While the bending is predominantly electrostatic, the binding energies are significantly increased by electron correlation, because the donation from the metal d orbitals to the benzene pi* orbitals is not well described at the self-consistent-field level. The uncertainties in the computed binding energies are estimated to be about 5 kcal/mol. Although the calculated and experimental binding energies generally agree to within their combined uncertainties, it is likely that the true binding energies lie in the lower portion of the experimental range. This is supported by the very good agreement between the theoretical and recent experimental binding energies for AgC6H6(+).

Bauschlicher, Charles W., Jr.↗

Uncertainty quantification of a deep learning fuel property prediction model

Deep learning models are being widely used in the field of combustion. Given the black-box nature of typical neural network based models, uncertainty quantification (UQ) is critical to ensure the reliability of predictions as well as the training datasets, and for a principled quantification of noise and its various sources. Deep learning surrogate models for predicting properties of chemical compounds and mixtures have been recently shown to be promising for enabling data-driven fuel design and optimization, with the ultimate goal of improving efficiency and lowering emissions from combustion engines. In this study, UQ is performed for a multi-task deep learning model that simultaneously predicts the research octane number (RON), Motor Octane Number (MON), and Yield Sooting Index (YSI) of pure components and multicomponent blends. The deep learning model is comprised of three smaller networks: Extractor 1, Extractor 2, and Predictor, and a mixing operator. The molecular fingerprints of individual components are encoded via Extractor 1 and Extractor 2, the mixing operator generates fingerprints for mixtures/blends based on linear mixing operation, and the predictor maps the fingerprint to the target properties. Two different classes of UQ methods, Monte Carlo ensemble methods and Bayesian neural networks (BNNs), are employed for quantifying the epistemic uncertainty. Combinations of Bernoulli and Gaussian distributions with DropConnect and DropOut techniques are explored as ensemble methods. All the DropConnect, DropOut and Bayesian layers are applied to the predictor network. Aleatoric uncertainty is modeled by assuming that each data point has an independent uncertainty associated with it. The results of the UQ study are further analyzed to compare the performance of BNN and ensemble methods. Although this study is confined to UQ of fuel property prediction, the methodologies are applicable to other deep learning frameworks that are being widely used in the combustion community.

33 ADVANCED PROPULSION SYSTEMS↗

A demonstration of a transportable radio interferometric surveying system with 3-cm accuracy on a 307-m base line

A precision geodetic measurement system (Aries, for Astronomical Radio Interferometric Earth Surveying) based on the technique of very long base line interferometry has been designed and implemented through the use of a 9-m transportable antenna and the NASA 64-m antenna of the Deep Space Communications Complex at Goldstone, California. A series of experiments designed to demonstrate the inherent accuracy of a transportable interferometer was performed on a 307-m base line during the period from December 1973 to June 1974. This short base line was chosen in order to obtain a comparison with a conventional survey with a few-centimeter accuracy and to minimize Aries errors due to transmission media effects, source locations, and earth orientation parameters. The base-line vector derived from a weighted average of the measurements, representing approximately 24 h of data, possessed a formal uncertainty of about 3 cm in all components. This average interferometry base-line vector was in good agreement with the conventional survey vector within the statistical range allowed by the combined uncertainties (3-4 cm) of the two techniques.

Ong, K. M.↗

Advanced probabilistic methods for quantifying the effects of various uncertainties in structural response

The effects of actual variations, also called uncertainties, in geometry and material properties on the structural response of a space shuttle main engine turbopump blade are evaluated. A normal distribution was assumed to represent the uncertainties statistically. Uncertainties were assumed to be totally random, partially correlated, and fully correlated. The magnitude of these uncertainties were represented in terms of mean and variance. Blade responses, recorded in terms of displacements, natural frequencies, and maximum stress, was evaluated and plotted in the form of probabilistic distributions under combined uncertainties. These distributions provide an estimate of the range of magnitudes of the response and probability of occurrence of a given response. Most importantly, these distributions provide the information needed to estimate quantitatively the risk in a structural design.

Nagpal, Vinod K.↗

Validation of UARS Microwave Limb Sounder ClO Measurements

Validation of stratospheric ClO measurements by the Microwave Limb Sounder (MLS) on the Upper Atmosphere Research Satellite (UARS) is described. Credibility of the measurements is established by (1) the consistency of the measured ClO spectral emission line with the retrieved ClO profiles and (2) comparisons of ClO from MLS with that from correlative measurements by balloon-based, ground-based, and aircraft-based instruments. Values of "noise" (random), "scaling" (multiplicative), and "bias" (additive) uncertainties are determined for the Version 3 data, in the first version public release of the known artifacts in these data are identified. Comparisons with correlative measurements indicate agreement to within the combined uncertainties expected for MLS and the other measurements being compared. It is concluded that MLS Version 3 ClO data, with proper consideration of the uncertainties and "quality" parameters produced with these data, can be used for scientific analyses at retrieval surfaces between 46 and 1 hPa (approximately 20-50 km in height). Future work is planned to correct known problems in the data and improve their quality.

Waters, J. W.↗

Uncertainty Analysis of the NASA Glenn 8x6 Supersonic Wind Tunnel

This paper presents methods and results of a detailed measurement uncertainty analysis that was performed for the 8- by 6-foot Supersonic Wind Tunnel located at the NASA Glenn Research Center. The statistical methods and engineering judgments used to estimate elemental uncertainties are described. The Monte Carlo method of propagating uncertainty was selected to determine the uncertainty of calculated variables of interest. A detailed description of the Monte Carlo method as applied for this analysis is provided. Detailed uncertainty results for the uncertainty in average free stream Mach number as well as other variables of interest are provided. All results are presented as random (variation in observed values about a true value), systematic (potential offset between observed and true value), and total (random and systematic combined) uncertainty. The largest sources contributing to uncertainty are determined and potential improvement opportunities for the facility are investigated.

Error↗

From Resilient and Ready to Used and Useful: Managing Temporal and Locational Uncertainty in Electrification, DER Adoption, and Climate Adaptation

Grid planning decisions involve weighing risks against benefits. The best decisions will facilitate development of electrical infrastructure that minimizes risk and maximizes benefits. With the rapidly evolving energy landscape, today's planner must discern new loads and demand cycles; embrace the operational complexity of climate risk; revise settled standards; and anticipate and manage the system impacts of distributed energy resource (DER) adoption. Only by managing the combined uncertainty of these dynamic processes can a planner hope to make effective decisions. Our analysis focuses on the management of temporal and locational uncertainty, and particularly on the risks presented to customers by the mismanagement of the factors that are the sources of these uncertainties.

climate↗

The Stability of Powered Flight around Asteroids with Application to Vesta

The reliability of low-thrust trajectories between science orbits around large asteroids must be evaluated subject to the unavoidable uncertainties of orbit determination, asteroid physical parameters, momentum de-saturation maneuvers, and transfer maneuver execution error. This paper presents a computationally inexpensive way to extend the concept or orbital stability to trajectories undergoing continuously powered low-thrust flight. Trajectories that are stable using this measure are shown to be stable under the combined uncertainties expected during operations. The measure is general and relatively simple to implement. The method was applied to maneuvers planed around the asteroid Vesta in support of NASA's Dawn Discovery mission.

Dawn↗

Ar-Ar Age of Shergottite Dhofar 378: Formation or Early Shock Event?

The Ar-39-Ar40 data for 16 stepwise temperature extractions of mixed mesostasis plus plagioclase show the following major characteristics. Changes in the K/Ca ratio and in the differential rate of Ar-39 release with extraction temperature suggest three distinct, but overlapping Ar diffusion domains: <13%, 13-45%, and >45% cumulative Ar-39 release:. The youngest Ar-Ar age, approx.162-165 Myr is observed at approx.28-40% Ar-39 release, which we attribute primarily to the mesostasis. Extractions releasing >45% Ar-39, probably from plagioclase, suggest older Ar-Ar ages and indicate release of trapped martian Ar-40. An isochron plot for 8 extractions, releasing 3-45% of the Ar-39 and corrected for 36Arcos using directly measured 36Arcos, gives an Ar-Ar age of 143+/-4 Myr (where the +/- ignores the uncertainty in applying a correction for Ar-36cos). Applying a correction assuming only one-half of the measured Ar-36cos gives an age of 159+/-2 Myr. Correcting for cos-Ar-36 using the minimum measured Ar-36/Ar-37 ratio gives a minimum possible age of 138+/-5 Myr. All of these ages are within combined uncertainties of the Sm-Nd age of 157+/-24 Myr [4]. The trapped Ar-40/Ar-36 ratio obtained from the isochron is largely defined by the highest [K] data.

Park, J.↗

The New Sun-Sky-Lunar Cimel CE318-T Multiband Photometer - A Comprehensive Performance Evaluation

This paper presents the new photometer CE318-T, able to perform daytime and night-time photometric measurements using the sun and the moon as light source. Therefore,this new device permits a complete cycle of diurnal aerosol and water vapour measurements valuable to enhance atmospheric monitoring to be extracted. In this study wehave found significantly higher precision of triplets when comparing the CE318-T master instrument and the Cimel AErosol RObotic NET work (AERONET) master (CE318-AERONET) triplets as a result of the new CE318-T tracking system. Regarding the instrument calibration, two new methodologies to transfer the calibration from a reference instrument using only daytime measurements (Sun Ratio and Sun-Moon gain factor techniques) are presented and discussed. These methods allow the reduction of the previous complexities inherent to nocturnal calibration. A quantitative estimation of CE318-T AOD uncertainty by means of error propagation theory during daytime revealed AOD uncertainties (u(sup D)(sub AOD)) for Langley-calibrated instruments similar to the expected values for other reference instruments (0.002-0.009). We have also found u(sup D)(sub AOD) values similar to the values reported in sun photometry for field instruments (approximately 0.015). In the case of the night-time period, the CE318-T-estimated standard combined uncertainty (u(sup N)(sub AOD)) is dependent not only on the calibration technique but also on illumination conditions and the instrumental noise. These values range from 0.011-0.018 for Lunar Langley-calibrated instruments to 0.012-0.021 for instruments calibrated using the Sun Ratio technique. In the case of moon-calibrated instruments using the Sun-Moon gain factor method and sun calibrated using the Langley technique, we found u(sup N)(sub AOD) ranging from 0.016 to 0.017 (up to 0.019 in 440 nm channel), not dependent on any lunar irradiance model. A subsequent performance evaluation including CE318-T and collocated measurements from independent reference instruments has served to assess the CE318-T performance as well as to confirm its estimated uncertainty. Daytime AOD evaluation, performed at Izana station from March to June 2014, encompassed measurements from a reference CE318-T, a CE318-AERONET master instrument, a Precision Filter Radiometer (PFR) and a Precision Spectroradiometer (PSR) prototype, reporting low AOD discrepancies between the four instruments (up to 0.006). The nocturnal AOD evaluation was performed using CE318-T- and starphotometer-collocated measurements and also by means of a day/night coherence transition test using the CE318-T master instrument and the CE318 daytime data from the CE318-AERONET master instrument. Results showed low discrepancies with the star photometer at 870 and 500 nm channels(less tna or equal to 0.013) and differences with AERONET daytime data (1 h after and before sunset and sunrise) in agreement with the estimated u(sup N)(sub AOD) values at all illumination conditions in the case of channels within the visible spectral range, and only for high moon's illumination conditions in the case of near infrared channels. Perceptible water vapour (PWV) validation showed a good agreement between CE318-T and Global Navigation Satellite System (GNSS) PWV values for all illumination conditions, within the expected precision for sun photometry. Finally, two case studies have been included to highlight the ability of the new CE318-T to capture the diurnal cycle of aerosols and water vapour as well as short-term atmospheric variations, critical for climate studies.

Barreto, Africa↗

Cosmological dependence of sterile neutrino dark matter with self-interacting neutrinos

Unexplored interactions of neutrinos could be the key to understanding the nature of the dark matter (DM). In particular, active neutrinos with new self-interactions can produce keV-mass sterile neutrinos that account for the whole of the DM through the Dodelson-Widrow mechanism for a large range of active-sterile mixing values. This production typically occurs before Big-Bang Nucleosynthesis (BBN) in a yet uncharted era of the Universe. We assess how the mixing range for keV-mass sterile neutrino DM is affected by the uncertainty in the early Universe pre-BBN cosmology. This is particularly relevant for identifying the viable parameter space of sterile neutrino searches allowed by all astrophysical limits, as well as for cosmology, since the detection of a sterile neutrino could constitute the first observation of a particle providing information about the pre-BBN epoch. Here, we find that the combined uncertainties in the early Universe cosmology and neutrino interactions significantly expand the allowed parameter space for sterile neutrinos that can constitute the whole of the DM.

79 ASTRONOMY AND ASTROPHYSICS↗

Uncertainty Analysis via Failure Domain Characterization: Unrestricted Requirement Functions

This paper proposes an uncertainty analysis framework based on the characterization of the uncertain parameter space. This characterization enables the identification of worst-case uncertainty combinations and the approximation of the failure and safe domains with a high level of accuracy. Because these approximations are comprised of subsets of readily computable probability, they enable the calculation of arbitrarily tight upper and lower bounds to the failure probability. The methods developed herein, which are based on nonlinear constrained optimization, are applicable to requirement functions whose functional dependency on the uncertainty is arbitrary and whose explicit form may even be unknown. Some of the most prominent features of the methodology are the substantial desensitization of the calculations from the assumed uncertainty model (i.e., the probability distribution describing the uncertainty) as well as the accommodation for changes in such a model with a practically insignificant amount of computational effort.

Crespo, Luis G.↗

Uncertainty Analysis via Failure Domain Characterization: Polynomial Requirement Functions

This paper proposes an uncertainty analysis framework based on the characterization of the uncertain parameter space. This characterization enables the identification of worst-case uncertainty combinations and the approximation of the failure and safe domains with a high level of accuracy. Because these approximations are comprised of subsets of readily computable probability, they enable the calculation of arbitrarily tight upper and lower bounds to the failure probability. A Bernstein expansion approach is used to size hyper-rectangular subsets while a sum of squares programming approach is used to size quasi-ellipsoidal subsets. These methods are applicable to requirement functions whose functional dependency on the uncertainty is a known polynomial. Some of the most prominent features of the methodology are the substantial desensitization of the calculations from the uncertainty model assumed (i.e., the probability distribution describing the uncertainty) as well as the accommodation for changes in such a model with a practically insignificant amount of computational effort.

Crespo, Luis G.↗

Ab initio quantum scattering calculations and a new potential energy surface for the HCl( X 1Σ+)–O2(X3Σg−) system: Collision-induced line shape parameters for O2-perturbed R(0) 0–0 line in H35Cl

The remote sensing of abundance and properties of HCl—the main atmospheric reservoir of Cl atoms that directly participate in ozone depletion—is important for monitoring the partitioning of chlorine between “ozone-depleting” and “reservoir” species. Such remote studies require knowledge of the shapes of molecular resonances of HCl, which are perturbed by collisions with the molecules of the surrounding air. In this work, we report the first fully quantum calculations of collisional perturbations of the shape of a pure rotational line in H35Cl perturbed by an air-relevant molecule [as the first model system we choose the R(0) line in HCl perturbed by O2]. The calculations are performed on our new highly accurate HCl(X1Σ+)–O2(X3Σg−) potential energy surface. In addition to pressure broadening and shift, we also determine their speed dependencies and the complex Dicke parameter. This gives important input to the community discussion on the physical meaning of the complex Dicke parameter and its relevance for atmospheric spectra (previously, the complex Dicke parameter for such systems was mainly determined from phenomenological fits to experimental spectra and the physical meaning of its value in that context is questionable). We also calculate the temperature dependence of the line shape parameters and obtain agreement with the available experimental data. We estimate the total combined uncertainties of our calculations at 2% relative root-mean-square error in the simulated line shape at 296 K. This result constitutes an important step toward computational population of spectroscopic databases with accurate ab initio line shape parameters for molecular systems of terrestrial atmospheric importance.

Chemistry↗

Design of Quasi-Integral Experiments at the Flexible Neutron Source at the University of Tennessee

Nuclear reaction data libraries make use of experimental data that are differential in reaction and neutron energy for evaluation and data that are integral in reaction and energy for validation. In many cases, integral measurements can provide lower experimental uncertainties than differential measurements, but the impact of individual reactions and energies cannot generally be determined from the single experimental observable. “Quasi-integral” or “quasi-differential” measurements, which are integral in one characteristic (energy or reaction) and differential in the other, can often provide a middle ground of lower experimental uncertainties combined with some ability to unpack the impact of individual reactions or energies. Furthermore, the Flexible Neutron Source (FNS) at the University of Tennessee, Knoxville, is a new experimental facility that can perform integral and quasi-integral measurements by removing components of the integral configuration to determine the impact of specific reactions. Possible flux-averaged cross-section measurements, flux perturbation measurements, and neutron downscattering measurements are simulated here to show the value of the FNS to evaluation and validation of nuclear data.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗