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All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

Porosity and Variations in Microgravity Aerogel Nano-Structures: New Laser Speckle Characterization Methods - 2

The transition from sol to gel is a process that is critical to the properties of engineered nanomaterials, but one with few available techniques for observing the dynamic processes occurring during the evolution of the gel network. Specifically, the observation of various cluster aggregation models, such as diffusion-limited and reaction-limited cluster growth can be quite difficult. This can be rather important as the actual aggregation model can dramatically influence the mechanical properties of gels, and is significantly affected by the presence of convective flows, or their absence in microgravity. We have developed two new non-intrusive optical methods for observing the aggregation processes within gels in real time. These make use of the dynamic behavior of laser speckle patterns produced when an intense laser source is passed through a gelling sol. The first method is a simplified time-correlation measurement, where the speckle pattern is observed using a CCD camera and information on the movement of the scattering objects is readily apparent. This approach is extremely sensitive to minute variations in the flow field as the observed speckle pattern is a diffraction-based image, and is therefore sensitive to motions within the sol on the order of the wavelength of the probing light. Additionally, this method has proven useful in determining a precise time for the gel-point, an event often difficult to measure. Monitoring the evolution of contrast within the speckle field is another method that has proven useful for studying aeration. In this case, speckle contrast is dependent upon the size (correlation length) and number of scattering centers, increasing with increasing size, and decreasing with increasing numbers. The dynamic behavior of cluster growth in gels causes both of these to change simultaneously with time, the exact rate of which is determined by the specific aggregation model involved. Actual growth processes can now be observed, and the effects of varying gravity fields on the growth processes qualitatively described. Results on preliminary ground-based measurements have been obtained.

Hunt, A. J.↗
NASA NTRS1996

The concept of a facility for cosmic dust research on the International Space Station

A proposal for the development of a permanently operating facility for the experimental investigation of cosmic dust-related phenomena onboard the International Space Station (ISS) is presented. Potential applications for this facility are the convection-free nucleation of dust grains, studies of coagulation and aggregation phenomena in a microgravity environment, investigations of heat transport through, and dust emissions from, high-porosity cometary analogs, and experiments on the interaction of very fluffy dust grains with electromagnetic radiation and with low pressure gas flows. Possible extensions of such a facility are towards aerosol science and colloidal plasma research.

Blum, Juergen↗
NASA NTRS2006

Multistage Electrophoretic Separators

A multistage electrophoresis apparatus has been invented for use in the separation of cells, protein molecules, and other particles and solutes in concentrated aqueous solutions and suspensions. The design exploits free electrophoresis but overcomes the deficiencies of prior free-electrophoretic separators by incorporating a combination of published advances in mathematical modeling of convection, sedimentation, electro-osmotic flow, and the sedimentation and aggregation of droplets. In comparison with other electrophoretic separators, these apparatuses are easier to use and are better suited to separation in relatively large quantities characterized in the art as preparative (in contradistinction to smaller quantities characterized in the art as analytical). In a multistage electrophoretic separator according to the invention, an applied vertical steady electric field draws the electrically charged particles of interest from within a cuvette to within a collection cavity that has been moved into position of the cuvette. There are multiple collection cavities arranged in a circle; each is aligned with the cuvette for a prescribed short time. The multistage, short-migration-path character of the invention solves, possibly for the first time, the fluid-instability problems associated with free electrophoresis. The figure shows a prototype multistage electrophoretic separator that includes four sample stations and five collection stages per sample. At each sample station, an aqueous solution or suspension containing charged species to be separated is loaded into a cuvette, which is machined into a top plate. The apparatus includes a lower plate, into which 20 collection cavities have been milled. Each cavity is filled with an electrophoresis buffer solution. For the collection of an electrophoretic fraction, the lower plate is rotated to move a designated collection cavity into alignment with the opening of the cuvette. An electric field is then applied between a non-gassing electrode in the collection cavity and an electrolyte compartment, which is separated from the cuvette by a semipermeable membrane. The electrolyte is refreshed by circulation by use of a peristaltic pump. In subsequent steps, the lower plate is rotated to collect other electrophoretic fractions. Later, the collected fractions are removed from the collection cavities through ports that have threaded plugs. The base of the apparatus contains power supplies and a computer interface. The design includes provisions for monitoring and feedback control of cavity position, electric field, and temperature. The operation of the apparatus can easily be automated, as demonstrated by use of software that has already been written for this purpose.

Thomas, Nathan↗
NASA NTRS2001

A TRMM-Calibrated Infrared Technique for Convective and Stratiform Rainfall: Analysis and Validation

A satellite infrared technique with passive microwave calibration has been developed for estimating convective and stratiform. rainfall. The Convective-Stratiform Technique, calibrated by coincident, physically retrieved rain rates from the TRMM Microwave Imager (TMI), has been applied to 30 min interval GOES infrared data and aggregated over seasonal and yearly periods over northern South America. The diurnal cycle of rainfall, as well as the division between convective and stratiform rainfall is presented. For the period Jan-April 1999, analysis revealed significant effects of local circulations (river breeze, land/sea breeze, mountain/valley) on both the total rainfall and it's diurnal cycle. Results compared well (a one-hour lag) with the diurnal cycle derived from TOGA radar-estimated rainfall in Rondonia. The satellite estimates revealed that the convective rain constituted 24% of the rain area while accounting for 67% of the rain volume. Estimates of the diurnal cycle (both total rainfall and convective/stratiform) for an area encompassing the Amazon Basin (3 x 10(exp 6) square km) were in phase with those from the TRMM Precipitation Radar, despite the latter's limited sampling. Results will be presented comparing the yearly (2000) diurnal cycle for large regions (including the Amazon Basin), and an intercomparison of January-March estimates for three years, 1999-2001. We hope to demonstrate the utility of using the TRMM PR observations as verification for infrared estimates of the diurnal cycle, and as verification of the apportionment of rainfall into convective and stratiform components.

Negri, Andrew↗
NASA NTRS2001

A TRMM-Calibrated Infrared Technique for Convective and Stratiform Rainfall: Analysis and Validation

A satellite infrared technique with passive microwave calibration has been developed for estimating convective and stratiform rainfall. The Convective-Stratiform Technique, calibrated by coincident, physically retrieved rain rates from the TRMM Microwave Imager (TMI), has been applied to 30 min interval GOES infrared data and aggregated over seasonal and yearly periods over northern South America. The diurnal cycle of rainfall, as well as the division between convective and stratiform rainfall is presented. For the period Jan-April 1999, analysis revealed significant effects of local circulations (river breeze, land/sea breeze, mountain/valley) on both the total rainfall and it's diurnal cycle. Results compared well (a one-hour lag) with the diurnal cycle derived from TOGA radar-estimated rainfall in Rondonia. The satellite estimates revealed that the convective rain constituted 24% of the rain area while accounting for 67% of the rain volume. Estimates of the diurnal cycle (both total rainfall and convective/stratiform) for an area encompassing the Amazon Basin (3 x 10(exp 6) sq km) were in phase with those from the TRMM Precipitation Radar, despite the latter's limited sampling. Results will be presented comparing the yearly (2000) diurnal cycle for large regions (including the Amazon Basin), and an intercomparison of January-March estimates for three years, (1999-2001). We hope to demonstrate the utility of using the TRMM PR observations as verification for infrared estimates of the diurnal cycle, and as verification of the apportionment of rainfall into convective and stratiform components.

Negri, Andrew↗
NASA NTRS1999

The Effect of Surface Induced Flows on Bubble and Particle Aggregation

Almost 20 years have elapsed since a phenomenon called "radial specific coalescence" was identified. During studies of electrolytic oxygen evolution from the back side of a vertically oriented, transparent tin oxide electrode in alkaline electrolyte, one of the authors (Sides) observed that large "collector" bubbles appeared to attract smaller bubbles. The bubbles moved parallel to the surface of the electrode, while the electric field was normal to the electrode surface. The phenomenon was reported but not explained. More recently self ordering of latex particles was observed during electrophoretic deposition at low DC voltages likewise on a transparent tin oxide electrode. As in the bubble work, the field was normal to the electrode while the particles moved parallel to it. Fluid convection caused by surface induced flows (SIF) can explain these two apparently different experimental observations: the aggregation of particles on an electrode during electrophoretic deposition, and a radial bubble coalescence pattern on an electrode during electrolytic gas evolution. An externally imposed driving force (the gradient of electrical potential or temperature), interacting with the surface of particles or bubbles very near a planar conducting surface, drives the convection of fluid that causes particles and bubbles to approach each other on the electrode.

Guelcher, Scott A.↗
NASA NTRS1997

The Aggregate Description of Semi-Arid Vegetation with Precipitation-Generated Soil Moisture Heterogeneity

Meteorological measurements in the Walnut Gulch catchment in Arizona were used to synthesize a distributed, hourly-average time series of data across a 26.9 by 12.5 km area with a grid resolution of 480 m for a continuous 18-month period which included two seasons of monsoonal rainfall. Coupled surface-atmosphere model runs established the acceptability (for modelling purposes) of assuming uniformity in all meteorological variables other than rainfall. Rainfall was interpolated onto the grid from an array of 82 recording rain gauges. These meteorological data were used as forcing variables for an equivalent array of stand-alone Biosphere-Atmosphere Transfer Scheme (BATS) models to describe the evolution of soil moisture and surface energy fluxes in response to the prevalent, heterogeneous pattern of convective precipitation. The calculated area-average behaviour was compared with that given by a single aggregate BATS simulation forced with area-average meteorological data. Heterogeneous rainfall gives rise to significant but partly compensating differences in the transpiration and the intercepted rainfall components of total evaporation during rain storms. However, the calculated area-average surface energy fluxes given by the two simulations in rain-free conditions with strong heterogeneity in soil moisture were always close to identical, a result which is independent of whether default or site-specific vegetation and soil parameters were used. Because the spatial variability in soil moisture throughout the catchment has the same order of magnitude as the amount of rain failing in a typical convective storm (commonly 10% of the vegetation's root zone saturation) in a semi-arid environment, non-linearitv in the relationship between transpiration and the soil moisture available to the vegetation has limited influence on area-average surface fluxes.

White, Cary B.↗
NASA NTRS2013

Can Solution Supersaturation Affect Protein Crystal Quality?

The formation of large protein crystals of "high quality" is considered a characteristic manifestation of microgravity. The physical processes that predict the formation of large, high quality protein crystals in the microgravity environment of space are considered rooted in the existence of a "depletion zone" in the vicinity of crystal. Namely, it is considered reasonable that crystal quality suffers in earth-grown crystals as a result of the incorporation of large aggregates, micro-crystals and/or large molecular weight "impurities", processes which are aided by density driven convective flow or mixing at the crystal-liquid interface. Sedimentation and density driven convection produce unfavorable solution conditions in the vicinity of the crystal surface, which promotes rapid crystal growth to the detriment of crystal size and quality. In this effort, we shall further present the hypothesis that the solution supersaturatoin at the crystal surface determines the growth mechanism, or mode, by which protein crystals grow. It is further hypothesized that protein crystal quality is affected by the mechanism or mode of crystal growth. Hence the formation of a depletion zone in microgravity environment is beneficial due to inhibition of impurity incorporatoin as well as preventing a kinetic roughening transition. It should be noted that for many proteins the magnitude of neither protein crystal growth rates nor solution supersaturation are predictors of a kinetic roughening transition. That is, the kinetic roughening transition supersaturation must be dtermined for each individual protein.

Gorti, Sridhar↗
NASA NTRS2003

Effects of Convective Transport of Solute and Impurities on Defect-Causing Kinetics Instabilities in Protein Crystallization

Insight into the crystallization processes of biological macromolecules into crystals or aggregates can provide valuable guidelines in many fundamental and applied fields. Such insight will prompt new means to regulate protein phase transitions in-vivo, e.g., polymerization of hemoglobin S in the red cells, crystallization of crystallins in the eye lens, etc. Understanding of protein crystal nucleation will help achieve narrow crystallite size distributions, needed for sustained release of pharmaceutical protein preparations such as insulin or interferon. Traditionally, protein crystallization studies have been related to the pursuit of crystal perfection needed to improve the structure details provided by x-ray, electron or neutron diffraction methods. Crystallization trials for the purposes of structural biology carried out in space have posed an intriguing question related to the inconsistency of the effects of the microgravity growth on the quality of the crystals.

Vekilov, Peter G.↗
NASA NTRS2007

Observed Enhancement of Reflectivity and Electric Field in Long-Lived Florida Anvils

A study of two long-lived Florida anvils showed that reflectivity >20 dBZ increased in area, thickness and sometimes magnitude at mid-level well downstream of the convective cores. In these same regions electric fields maintained strengths >10 kV m1 for many tens of minutes and became quite uniform over tens of kilometers. Millimetric aggregates persisted at 9 to 10 km for extended times and distances. Aggregation of ice particles enhanced by strong electric fields might have contributed to reflectivity growth in the early anvil, but is unlikely to explain observations further out in the anvil. The enhanced reflectivity and existence of small, medium and large ice particles far out into the anvil suggest that an updraft was acting, perhaps in weak convective cells formed by instability generated from the evaporation and melting of falling ice particles. We conclude that charge separation must have occurred in these anvils, perhaps at the melting level but also at higher altitudes, in order to maintain fields >10 kV m 1 at 9 to 10 km for extended periods of time over large distances. We speculate that charge separation occurred as a result of ice-ice particle collisions (without supercooled water being present) via either a non-inductive or perhaps even an inductive mechanism, given the observed broad ice particle spectra, the strong pre-existing electric fields and the many tens of minutes available for particle interactions. The observations, particularly in the early anvil, show that the charge structure in these anvils was quite complex.

Dye, James E.↗
NASA NTRS2001

TRMM Precipitation Radar and Microwave Imager Observations of Convective and Stratiform Rain and Their Theoretical Implications

Theoretical models of radiative transfer are developed to simulate the 85 GHz brightness temperature, T85, observed by the Tropical Rainfall Measuring Mission (TRMM) Microwave Imager (TMI) radiometer as a function of rain rate. These simulations are performed separately over regions of convective and stratiform rain. For the purpose of constructing vertical profiles of hydrometeors in these regions, guidance is taken from TRMM Precipitation Radar (PR) observations, and from recent investigations of LDR and Z(sub DR) measurements made by land-based polarimetric radars. We find that for a given rain rate, the extinction in 85 GHz due to hydrometeors above the freezing level is relatively weak in convective regions compared to that in stratiform regions. The hydrometeor profile above the freezing level responsible for this weak extinction in convective regions is inferred, from LDR and Z(sub DR) observations and theoretical considerations, to contain two layers: 1) a layer of two km thickness with mixed phase particles, liquid drops and graupel, directly above the freezing level, and 2) a layer of graupel extending from the top of the mixed-phase layer to the cloud top. Strong extinction in the stratiform regions is inferred to result from slowly-falling, low-density ice aggregates (snow) above the freezing level. These theoretical results are consistent with T85 measured by TMI and the rain rate deduced from PR for convective and stratiform rain regions. On the basis of this study we infer that the accuracy of the rain rate sensed by TMI depends critically on the specification of the convective or stratiform nature of the rain.

Prabhakara, C.↗
NASA NTRS2015

An Internal Thermal Environment Model of an Aluminized Solid Rocket Motor with Experimental Validation

Due to the severity of the internal solid rocket motor (SRM) environment, very few direct measurements of that environment exist; therefore, the appearance of such data provides a unique opportunity to assess current thermal/fluid modeling capabilities. As part of a previous study of SRM internal insulation performance, the internal thermal environment of a laboratory-scale SRM featuring aluminized propellant was characterized with two types of custom heat-flux calorimeters: one that measured the total heat flux to a graphite slab within the SRM chamber and another that measured the thermal radiation flux. Therefore, in the current study, a thermal/fluid model of this lab-scale SRM was constructed using ANSYS Fluent to predict not only the flow field structure within the SRM and the convective heat transfer to the interior walls, but also the resulting dispersion of alumina droplets and the radiative heat transfer to the interior walls. The dispersion of alumina droplets within the SRM chamber was determined by employing the Lagrangian discrete phase model that was fully coupled to the Eulerian gas-phase flow. The P1-approximation was engaged to model the radiative heat transfer through the SRM chamber where the radiative contributions of the gas phase were ignored and the aggregate radiative properties of the alumina dispersion were computed from the radiative properties of its individual constituent droplets, which were sourced from literature. The convective and radiative heat fluxes computed from the thermal/fluid model were then compared with those measured in the lab-scale SRM test firings and the modeling approach evaluated.

Martin, Heath T.↗
NASA NTRS2007

Observed Enhancement of Reflectivity and Electric Field in Long-Lived Florida Anvils

A study of two long-lived Florida anvils showed that reflectivity greater than 20 dBZ increased in area, thickness and sometimes magnitude at mid-level well downstream of the convective cores. In these same regions electric fields maintained strengths greater than 10 kV m(sup -1) for many tens of minutes and became quite uniform over tens of kilometers. Millimetric aggregates persisted at 9 to 10 km for extended times and distances. Aggregation of ice particles enhanced by strong electric fields might have contributed to reflectivity growth in the early anvil, but is unlikely to explain observations further out in the anvil. The enhanced reflectivity and existence of small, medium and large ice particles far out into the anvil suggest that an updraft was acting, perhaps in weak convective cells formed by instability generated from the evaporation and melting of falling ice particles. We conclude that charge separation must have occurred in these anvils, perhaps at the melting level but also at higher altitudes, in order to maintain fields greater than 10 kV m(sup -1) at 9 to 10 km for extended periods of time over large distances. We speculate that charge separation occurred as a result of ice-ice particle collisions (without supercooled water being present) via either a noninductive or perhaps even an inductive mechanism, given the observed broad ice particle spectra, the strong pre-existing electric fields and the many tens of minutes available for particle interactions. The observations, particularly in the early anvil, show that the charge structure in these anvils was quite complex.

Dye, James E.↗
NASA NTRS1990

Chaotic, subduction-like downflows in a spherical model of convection in the earth's mantle

Model calculations are described for a compressible fluid in a three-dimensional spherical shell with 80 percent of the surface heat flow generated within the model mantle. The numerical solutions are strongly chaotic, with surface planforms dominated by long curvilinear downflows reminiscent of the descending slabs in the earth's mantle. The results suggest that descending slabs play an important part in driving mantle convection, and that their chaotic evolution may influence the spatial and temporal behavior of plates and thus the dispersal and aggregation of continents.

Glatzmaier, Gary A.↗
NASA NTRS2004

Magnetic Control of Convection during Protein Crystallization

An important component in biotechnology, particularly in the area of protein engineering and rational drug design is the knowledge of the precise three-dimensional molecular structure of proteins. The quality of structural information obtained from X-ray diffraction methods is directly dependent on the degree of perfection of the protein crystals. As a consequence, the growth of high quality macromolecular Crystals for diffraction analyses has been the central focus for bio-chemists, biologists, and bioengineers. Macromolecular crystals are obtained from solutions that contain the crystallizing species in equilibrium with higher aggregates, ions, precipitants, other possible phases of the protein, foreign particles, the walls of container, and a likely host of other impurities. By changing transport modes in general, i.e., reduction of convection and Sedimentation as is achieved in "microgravity", we have been able to dramatically affect the movement and distribution of macromolecules in the fluid, and thus their transport, f o d o n of crystal nuclei, and adsorption to the crystal surface. While a limited number of high quality crystals from space flights have been obtained, as the recent National Research Council (NRC) review of the NASA microgravity crystallization program pointed out, the scientific approach and research in crystallization of proteins has been mainly empirical yielding inconclusive results. We postulate that we can reduce convection in ground-based experiments and we can understand the different aspects of convection control through the use of strong magnetic fields and field gradients. We postulate that limited convection in a magnetic field will provide the environment for the growth of high quality crystals. The approach exploits the variation of fluid magnetic susceptibility with counteracts on for this purpose and the convective damping is realized by appropriately positioning the crystal growth cell so that the magnetic susceptibility force counteract terrestrial gravity. The genera1 objective is to test the hypothesis of convective control using a strong magnetic field and magnetic field gradient and to understand the nature of the various forces that come into play. Specifically we aim to delineate causative factors and to quantify them through experiments, analysis and numerical modeling. The paper will report on the experimental results using paramagentic salts and solutions in magnetic fields and compare them to analyticalpr~ctions.

Ramachandran, N.↗
NASA NTRS2003

Using Strong Magnetic Fields to Control Solutal Convection

An important component in biotechnology, particularly in the area of protein engineering and rational drug design is the knowledge of the precise three-dimensional molecular structure of proteins. The quality of structural information obtained from X-ray diffraction methods is directly dependent on the degree of perfection of the protein crystals. As a consequence, the growth of high quality macromolecular crystals for diffraction analyses has been the central focus for biochemists, biologists, and bioengineers. Macromolecular crystals are obtained from solutions that contain the crystallizing species in equilibrium with higher aggregates, ions, precipitants, other possible phases of the protein, foreign particles, the walls of the container, and a likely host of other impurities. By changing transport modes in general, i.e., reduction of convection and sedimentation, as is achieved in microgravity , we have been able to dramatically affect the movement and distribution of macromolecules in the fluid, and thus their transport, formation of crystal nuclei, and adsorption to the crystal surface. While a limited number of high quality crystals from space flights have been obtained, as the recent National Research Council (NRC) review of the NASA microgravity crystallization program pointed out, the scientific approach and research in crystallization of proteins has been mainly empirical yielding inconclusive results. We postulate that we can reduce convection in ground-based experiments and we can understand the different aspects of convection control through the use of strong magnetic fields and field gradients. We postulate that limited convection in a magnetic field will provide the environment for the growth of high quality crystals. The approach exploits the variation of fluid magnetic susceptibility with concentration for this purpose and the convective damping is realized by appropriately positioning the crystal growth cell so that the magnetic susceptibility force counteracts terrestrial gravity. The general objective is to test the hypothesis of convective control using a strong magnetic field and magnetic field gradient and to understand the nature of the various forces that come into play. Specifically we aim to delineate causative factors and to quantify them through experiments, analysis and numerical modeling. The paper will report on the experimental results using paramagnetic salts and solutions in magnetic fields and compare them to analytical predictions.

Ramachandran, N.↗
NASA NTRS2002

Countering Solutal Buoyant Convection with High Magnetic Fields

An important component in biotechnology, particularly in the area of protein engineering and rational drug design is the knowledge of the precise three-dimensional molecular structure of proteins. The quality of structural information obtained from X-ray diffraction methods is directly dependent on the degree of perfection of the protein crystals. As a consequence, the growth of high quality macromolecular crystals for diffraction analyses has been the central focus for biochemist, biologists, and bioengineers. Macromolecular crystals are obtained from solutions that contain the crystallizing species in equilibrium with higher aggregates, ions, precipitant, other possible phases of the protein, foreign particles, the walls of the container, and a likely host of other impurities. By changing transport modes in general, i.e., reduction of convection and sedimentation, as is achieved in microgravity, we have been able to dramatically effect the movement and distribution of macromolecules in the fluid, and thus their transport, formation of crystal nuclei, and adsorption to the crystal surface. While a limited number of high quality crystals from space flights have been obtained, as the recent National Research Council (NRC) review of the NASA microgravity crystallization program pointed out, the scientific approach and research in crystallization of proteins has been mainly empirical yielding inconclusive results. We postulate that we can reduce convection in ground-based experiments and we can understand the different aspects of convection control through the use of strong magnetic fields and field gradients. We postulate that limited convection in a magnetic field will provide the environment for the growth of high quality crystals. The approach exploits the variation of fluid magnetic susceptibility with concentration for this purpose and the convective damping is realized by appropriately positioning the crystal growth cell so that the magnetic susceptibility force counteracts terrestrial gravity. The general objective is to test the hypothesis of convective control using a strong magnetic field and magnetic field gradient and to understand the nature of the various forces that come into play. Specifically we aim to delineate causative factors and to quantify them through experiments, analysis and numerical modeling. The paper will report on the current status of the investigation and discuss results from the experimental and modeling efforts.

Ramachandran, N.↗
NASA NTRS1985

A calculation of the Rosseland mean opacity of dust grains in primordial solar system nebulae

The Rosseland mean opacity owing to grains was calculated as a function of temperature and density for nebulae having solar elemental abundances. The values of the mean opacity were evaluated with a generalized formulation allowing for anisotropic scattering. The values of the mean opacity do not depend sensitively on the choice of the particle size distribution function, provided that there are few particles having sizes in excess of several tens of microns. The results indicate that thermal convection in primordial nebulae occurs over broader ranges of altitudes at low temperatures than at high temperatures, and for size distributions for which extensive aggregation has not yet occurred.

Pollack, J. B.↗