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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Analysis of Ultra-Pure Gases by Ion Mobility Spectrometry

Work has continued with the evaluation of the Ion Mobility Spectrometer (IMS) for the analysis of gases having low parts-per-billion (10(exp -9)) water concentration. A modified PCP, inc. MMS-160 Mobility Mass Spectrometer System was used for the analysis of ultra-pure argon and nitrogen. The MMS-160 system permits the mass-identification of unique reactant and product ions observed in the reduced-water host gases. When the water is removed to low ppb levels, higher energy reactant ions are observed. In nitrogen, distinct odd- and even-numbered nitrogen cluster ion mobility peaks are observed, as well as adduct ion peaks from the trace contaminants in the gas. Argon also produces a cluster ion mobility peak and adduct ion peaks from trace components in the gas. Levels of contaminants in these ultra-pure gases can be determined from the ion mobility spectra. A calibrated source was used to provide variable known quantities of water to the pure gas supply of the IMS.

Stimac, Robert M.↗

An IR Investigation of Solid Amorphous Ethanol-Spectra, Properties, and Phase Changes

Mid- and far-infrared spectra of condensed ethanol (CH3CH2OH) at 10-160 K are presented, with a special focus on amorphous ethanol, the form of greatest astrochemical interest, and with special attention given to changes at 155-160 K. Infrared spectra of amorphous and crystalline forms are shown. The refractive index at 670 nm of amorphous ethanol at 16 K is reported, along with three IR band strengths and a density. A comparison is made to recent work on the isoelectronic compound ethanethiol (CH3CH2SH), and several astrochemical applications are suggested for future study.

Hudson, Reggie L.↗

Parametric performance characteristics and treatment of temperature coefficients of silicon solar cells for space application

The electrical performance characteristics of 2 and 10 ohms-cm N/P-type silicon solar cells were measured at simulated solar intensities of 5, 50, 100, 140, 250, 400, 550, 700, and 850 mW/sq cm. At each intensity, the temperature was varied in increments of 20 deg between extremes of +160 and -160 C. Short-circuit current, open-circuit voltage, and maximum power are presented in graphical format. Also described are three methods for predicting solar cell electrical performance as a function of temperature and intensity. Two of the methods are suitable for use at extreme temperature-intensity conditions. These methods were used sucessfully to predict the performance of the transducer on board the Mariner Mars 1971 spacecraft.

Patterson, R. E.↗

Plasma-sprayed, self-lubricating coatings for use from cryogenic temperatures to 870 deg C (1600 deg F)

A plasma-sprayed coating is described with good lubricating properties over a wide temperature range. The coating, designated NASA LUBE PS101, contains silver, nichrome, calcium fluoride, and an oxidation protective glass. Oscillating tests were conducted of self-aligning, plain cylindrical bearings, in which the bore was lined with 0.025 cm (0.010 in.) thick coatings of PS101; these were conducted at a radial load of 3.5 x 10 to the 7th power N/sq m (5000 psi) in nitrogen gas at -107 C (-160 F), in vacuum at room temperature, and in air from room temperature to 870 C (1600 F). Friction coefficients were less than 0.25 in all cases and wear rates were low. The coating is not brittle, and it has adequate oxidation resistance in air to at least 870 C.

Sliney, H. E.↗

Determination of nitric oxide concentrations from sunrise E-region electron density measurements

Midlatitude sunrise electron density profiles have been analyzed in order to determine nitric oxide concentrations in the range 100-160 km. In general, the determinations are restricted to heights for which the ionization of nitric oxide by direct solar Lyman-alpha radiation is the main contribution to the growth of the E region. The concentrations obtained are larger, by factors of approximately 3 to 4, than those obtained from the midlatitude airglow measurements of other workers. Concentrations have been obtained from one sunset measurement and these are significantly lower than the sunrise values. The results also give a clear indication of increasing nitric oxide concentrations above 120 km with increasing solar activity.

Monro, P. E.↗

Solid state thermal control for spacecraft

The steady-state heat-pumping capabilities of thermoelectric devices are examined for spacecraft in earth orbit, using a simple model. Thermoelectric parameters for a standard Bi2Te, alloy are fitted with fourth-order polynomials in temperature. Parameters are used which are the average for the temperature difference across the p-n couple. Internal spacecraft temperatures are varied from 270 to 330 K, and absorbed incident radiation fluxes are varied from zero to 700 W per sq m. It is found that heat rejection can be optimized with respect to thermoelectric device and radiator fin geometries, as well as with respect to input electrical power and that these devices are most useful on the surfaces with highest incident radiant power. Maximum heat fluxes which can be pumped out of the spacecraft are on the order of 50-160 W per sq m for the various thermal environments examined. Input electrical powers corresponding to these maximum heat fluxes range from about 50-300 W per sq m. However, efficiency is greatly improved by operation at lower input-power levels.

Harpster, J. W. C.↗

The duration of volcanism in Mare Serenitatis

The crystallization ages of a suite of Apollo 17 basalts from four different stations have been measured using the Ar-39 to Ar-40 stepwise heating technique. The rocks analyzed include all principal petrographic types found at Apollo 17 landing site. A correlation between the ages and the petrographic type exists; plagioclase-poikilitic ilmenite basalts are youngest and olivine porphyritic ilmenite basalts are the oldest. The duration of volcanism in Mare Serenitatis is about 200 million years, the same as observed for Mare Imbrium, and less than observed for Mare Tranquillitatis, 400 million years. A relationship between duration of volcanism and gravity anomalies is noted. The cosmic ray exposure ages (in millions of years) for various locations range as: station 4, 58-315; station 5, 85-440; station 6, 110; station 8, 90-160.

Schaeffer, O. A.↗

The ATS-6 power system: Hardware implementation and orbital performance

The Applications Technology Satellite-6 power system, a shunt-boost configuration, uses partial shunt regulation of the solar array and a boost regulator for control of battery power. Regulation is provided for three different operating modes: shunt, charge, and boost. This configuration achieves the highest efficiency of power transfer from the solar array to the loads. The excellent dynamic regulation and low output impedance of the power system virtually eliminated the problem of subsystem interactions on the power bus due to conducted interference from load current fluctuations. The performance of the power system continues to be excellent. The solar array degradation (18.5 percent) was less than the specified 20 percent in two years in spite of extreme cycling from -160 C to 60 C. A unique battery cycling regime of discharges varying from 5 percent to 60 percent daily is being encountered. During the second year, noneclipse discharges have occurred twice a day to depths of 35 percent and 45 percent. Battery performance was good with only a small decrease in end-of-discharge voltage. A recent test to evaluate capacity gave 12.4 AH (83% of the nominal capacity of 15 AH) after over 1400 battery discharge cycles. A small increase in the end-of-charge voltage has recently occurred necessitating a change in the charge regime to achieve full charge conditions.

Lavigna, T. A.↗

The ATS-6 power system - Hardware implementation and orbital performance

The Applications Technology Satellite-6 has performed more than 20 communications, technological and scientific experiments in 2 years of highly successful operation. Contributing substantially to this success has been the flexibility of the power system that allows multiple operation of experiments. The power system, a shunt-boost configuration, uses partial shunt regulation of the solar array and a boost regulator for control of battery power. Regulation is provided for three different operating modes: shunt, charge, and boost. This configuration achieves the highest efficiency of power transfer from the solar array to the loads. The solar array degradation (18.5 percent) has been less than the predicted 20 percent in spite of extreme cycling from -160 C to 60 C. A unique battery cycling regime of discharges varying from 5 percent to 60 percent daily is being encountered. During the second year, noneclipse discharges have occurred twice a day to depths of 35 percent and 45 percent. Battery performance has been good with only a small decrease in end-of-discharge voltage.

Lavigna, T. A.↗

Wide temperature range fiber optic cable: Cable design study

Factors considered in the design and fabrication of a single fiber optic cable intended for spacecraft applications in an environment of temperature extremes from -160 C to 125 C include: abrasion resistance, low temperature flexibility, small size, low weight, and overall temperature stability. Specific requirements were identified for fiber core and overall diameters, fiber loss and NA, and cable tensile load. The single fiber cable will be fabricated by using a chemical vapor step index fiber of .125 mm coated to .3 mm with RTV silicone and then extruded with a jacket of Teflon PFA to a diameter of .5 mm. Six yarns of 1420 denier unimpregnated Kevlar 49 with a helical lay of 1.3 inches will surround the jacketed fiber under an extrusion of PFA. The finished cable diameter will measure 1.8 mm, and the weight of one kilometer length will be approximately 4350grams.

Speed, E. U.↗

Surface photovoltage in exciton absorption range in CdS

The high resolution, intrinsic spectra of surface photovoltage are reported for semiconducting n-type CdS single crystals. At reduced temperatures (120-160 K) the spectra exhibit three sharp maxima due to A, B and C free exciton transitions. Energy positions of these lines and valence band parameters (spin-orbit and crystal field splittings) estimated from surface photovoltage are in good agreement with values obtained by other methods. The excitonic transitions are very sensitive to surface treatment, i.e. polishing, etching, background illumination and surface doping. The mechanism of direct interaction of free excitons with surface states is proposed to explain exciton lines in surface photovoltage.

Morawski, A.↗

HPLC for quality control of polyimides

High Pressure Liquid Chromatography (HPLC) as a quality control tool for polyimide resins and prepregs are presented. A data base to help establish accept/reject criteria for these materials was developed. This work is intended to supplement, not replace, standard quality control tests normally conducted on incoming resins and prepregs. To help achieve these objectives, the HPLC separation of LARC-160 polyimide precursor resin was characterized. Room temperature resin aging effects were studied. Graphite reinforced composites made from fresh and aged resin were fabricated and tested to determine if changes observed by HPLC were significant.

Young, P. R.↗

Infrared Astronomical Satellite /IRAS/ and Shuttle Infrared Telescope Facility /SIRTF/ - Implications of scientific objectives on focal plane sensitivity requirements

The full potential of infrared astronomy can be realized only through observations made with space-based telescopes cooled to cryogenic temperatures. The paper outlines the scientific mission, system description, and focal plane requirements for two cryogenic telescopes: the Infrared Astronomical Satellite (IRAS) and the Shuttle Infrared Telescope Facility (SIRTF). IRAS, a 60-cm superfluid-helium-cooled telescope system, will perform a one-year 8-120-micron IR sky survey; it will provide results of high reliability and sensitivity, produce the first complete survey data for the 30-120-micron region, and fill in missing portions (spectrally and spatially) of previous surveys short of 30 microns; its focal plane assembly is being designed to approach background-limited performance with an array of 62 discrete detectors. The SIRTF design will allow detailed follow-up studies in the 1-1000-micron range with a 116-160-cm observatory-class instrument. The Shuttle sortie capability introduces the unique SIRTF concept of an easily refurbishable or replaceable focal plane instrument complement in an orbiting cryogenic telescope.

Mccreight, C. R.↗

HEAO observations of X-ray bursts from MXB1730-335

The March 18, 1978 burst activity of the rapid burster MXB 1730-335 was studied by examining 58 minutes of quick-look data for the A2 and A4 experiments on HEAO 1. Very large, moderately sized, and small bursts are characterized. Type II bursts were found to show a spectral softening during burst decay. The existence of flux was sought in the 85-160 keV energy range, and it was found that the large type II bursts contain less than 5% of their total X-ray energy in this range. The implications of the lack of a hard X-ray flux with respect to accretion instability models of X-ray bursts are considered.

Hoffman, J. A.↗

Far-infrared observations of optical emission-line stars - Evidence for extensive cool dust clouds

Far-infrared observations (40-160 microns) of eight optical emission-line stars are presented. Six of these stars, LkH-alpha 198, T Tau, LkH-alpha 101, V380 Ori, R Mon, and MWC 1080, show substantially more far-infrared emission than would be expected on the basis of a blackbody extrapolation of their 10-20-micron fluxes. Additionally, in three cases, the far-infrared emission is shown to be spatially extended (greater than 40 arcsec). A simple model of the thermal emission from cool circumstellar dust (30-70 K) shows that these stars are surrounded by material left over from the star formation process; this result confirms the extreme youth of these stars. MWC 349 was detected at a level consistent with the expected free-free flux from its surrounding H II region, and RY Tau was not detected in the far-infrared; there is little circumstellar dust with temperatures of 20-100 K in these objects.

Harvey, P. M.↗

High Temperature Resin Matrix Composites for Aerospace Structures

Accomplishments and the outlook for graphite-polyimide composite structures are briefly outlined. Laminates, skin-stiffened and honeycomb sandwich panels, chopped fiber moldings, and structural components were fabricated with Celion/LARC-160 and Celion/PMR-15 composite materials. Interlaminar shear and flexure strength data obtained on as-fabricated specimens and specimens that were exposed for 125 hours at 589 K indicate that epoxy sized and polyimide sized Celion graphite fibers exhibit essentially the same behavior in a PMR-15 matrix composite. Analyses and tests of graphite-polyimide compression and shear panels indicate that utilization in moderately loaded applications offers the potential for achieving a 30 to 50 percent reduction in structural mass compared to conventional aluminum panels. Data on effects of moisture, temperature, thermal cycling, and shuttle fluids on mechanical properties indicate that both LARC-160 and PMR-15 are suitable matrix materials for a graphite-polyimide aft body flap. No technical road blocks to building a graphite-polyimide composite aft body flap are identified.

Davis, J. G., Jr.↗

Tackifier for addition polyimides

A modification to the addition polyimide, LaRC-160, was prepared to improve tack and drape and increase prepeg out-time. The essentially solventless, high viscosity laminating resin is synthesized from low cost liquid monomers. The modified version takes advantage of a reactive, liquid plasticizer which is used in place of solvent and helps solve a major problem of maintaining good prepeg tack and drape, or the ability of the prepeg to adhere to adjacent plies and conform to a desired shape during the lay up process. This alternate solventless approach allows both longer life of the polymer prepeg and the processing of low void laminates. This approach appears to be applicable to all addition polyimide systems.

Butler, J. M.↗