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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Self-diffusion of carbon and oxygen in dolomite.

Self-diffusion of carbon and oxygen in dolomite was measured by isotopic exchange with CO2 at 645-785 C at 120-935 bars pressure. Several runs were also made with calcite under comparable experimental conditions. The principal findings of this study are that (1) the self-diffusion coefficients of both carbon and oxygen in dolomite are approximately 100 times larger than the values in calcite over the temperature range investigated and (2) oxygen self-diffusion in calcite is accelerated by high CO2 pressure.

Anderson, T. F.↗
NASA NTRS1974

Stratigraphic Subdivision of the Transvaal Dolomite from ERTS imagery

ERTS imagery has revealed the presence of broad stratigraphic subdivisions in the previously undifferentiated Transvaal Dolomite of the western Tranvaal, Republic of South Africa. While detailed field mapping in areas of good outcrop, as well as borehole logging has recently led to the recognition of a stratigraphy in the Transvaal Dolomite of the central Transvaal, poor outcrop in the western Transvaal has to date prevented this. The ERTS-imagery, however, clearly reveals the presence of six, and in the far west seven, distinct stratigraphic zones extending along strike for a distance of at least 200 km. The investigation clearly demonstrates the potential applications of ERTS-imagery in geological studies, even in a country where the geology is supposedly well known.

Grootenboer, J.↗
NASA NTRS1987

Paleobiology of distinctive benthic microfossils from the upper Proterozoic Limestone-Dolomite "Series," central East Greenland

Populations of Polybessurus bipartitus Fairchild ex Green et al., a large morphologically distinctive microfossil, occur in silicified carbonates of the Upper Proterozoic (700-800 Ma) Limestone-Dolomite "Series," central East Greenland. Large populations of well-preserved individuals permit reconstruction of P. bipartitus as a coccoidal unicell that "jetted" upward from the sediment by the highly unidirectional secretion of extracellular mucopolysaccharide envelopes. Reproduction by baeocyte formation is inferred on the basis of clustered envelope stalks produced by small cells. Sedimentological evidence indicates that P. bipartitus formed surficial crusts locally within a shallow peritidal carbonate platform. Among living microorganisms a close morphological, reproductive, and behavioral counterpart to Polybessurus is provided by populations of an as yet underscribed cyanobacterium found in coastal Bahamian environments similar to those in which the Proterozoic fossils occur. In general morphology and "jetting" behavior, this population resembles species of the genus Cyanostylon, Geitler (1925), but reproduces via baeocyte formation. Polybessurus is but one of the more than two dozen taxa in the richly fossiliferous biota of the Limestone-Dolomite "Series." This distinctive population, along with co-occurring filamentous cyanobacteria and other microfossils, contributes to an increasingly refined picture of ecological heterogeneity in late Proterozoic oceans.

NASA Discipline Exobiology↗
DOE OSTI2021

Autogenous formation and smart behaviors of nitrite- and nitrate-intercalated layered double hydroxides (LDHs) in Portland cement-metakaolin-dolomite blends

In this work, the influence of sodium nitrite (NaNO{sub 2}) and sodium nitrate (NaNO{sub 3}) corrosion inhibitors on the composition, structure, and chloride binding behaviors of layered double hydroxides (LDHs) formed in ternary ordinary Portland cement-metakaolin-dolomite (OPC-MK-DM) systems is studied. The results show that the nitrite and nitrate anions are preferably intercalated in the CaAl LDHs (AFm phases), but not in the MgAl LDHs (hydrotalcite-type phases) due to its limited formation in these ternary cementitious systems cured at ambient temperature. The autogenously formed nitrate- and nitrite-AFm phases are decomposed upon chloride exposure accompanied by Friedel's salts formation, potentially releasing corrosion inhibitive ions to the pore solution in a progressive manner. The NaNO{sub 2} and NaNO{sub 3} incorporation in ternary OPC-MK-DM binders marginally lowers chloride binding capacity but reduces its penetration resistance mainly due to pore coarsening. Nevertheless, a strong linear correlation can be established between the water-soluble and total chloride contents in ternary OPC-MK-DM systems, regardless of OPC replacement level and corrosion inhibitor incorporation.

36 MATERIALS SCIENCE↗
NASA NTRS1996

Study of the Reed Dolomite Aided by Remotely Sensed Imagery, Central White-Inyo Range, Easternmost California

Remote-sensing methods are of great value in assessing the stratigraphy and geologic structure of inaccessible terrains, especially where lithologic contrasts are marked. In this report, we show that such techniques can be successfully applied to a massive carbonate unit, the Reed Dolomite, exposed in the Wacuoba Mountain, Blanco Mountain, and Mount Barcroft quadrangles of east-central California.

Remote-sensing stratigraphy geology lithologic con↗
NASA NTRS1988

Distribution and diagenesis of microfossils from the lower Proterozoic Duck Creek Dolomite, Western Australia

Two distinct generations of microfossils occur in silicified carbonates from a previously undescribed locality of the Lower Proterozoic Duck Creek Dolomite, Western Australia. The earlier generation occurs in discrete organic-rich clasts and clots characterized by microquartz anhedra; it contains a variety of filamentous and coccoidal fossils in varying states of preservation. Second generation microfossils consist almost exclusively of well-preserved Gunflintia minuta filaments that drape clasts or appear to float in clear chalcedony. These filaments appear to represent an ecologically distinct assemblage that colonized a substrate containing the partially degraded remains of the first generation community. The two assemblages differ significantly in taxonomic frequency distribution from previously described Duck Creek florules. Taken together, Duck Creek microfossils exhibit a range of assemblage variability comparable to that found in other Lower Proterozoic iron formations and ferruginous carbonates. With increasing severity of post-mortem alteration, Duck Creek microfossils appear to converge morphologically on assemblages of simple microstructures described from early Archean cherts. Two new species are described: Oscillatoriopsis majuscula and O. cuboides; the former is among the largest septate filamentous fossils described from any Proterozoic formation.

NASA Discipline Number 52-30↗
NASA NTRS1989

Microfossils from silicified stromatolitic carbonates of the Upper Proterozoic Limestone-Dolomite 'Series', central East Greenland

Silicified flake conglomerates and in situ stratiform stromatolites of the Upper Proterozoic (c. 700-800 Ma) Limestone-Dolomite 'Series', central East Greenland, contain well preserved microfossils. Five stratigraphic horizons within the 1200 m succession contain microbial mat assemblages, providing a broad palaeontological representation of late Proterozoic peritidal mat communities. Comparison of assemblages demonstrates that the taxonomy and diversity of mat builder, dweller, and allochthonous populations all vary considerably within and among horizons. The primary mat builder in most assemblages is Siphonophycus inornatum, a sheath-forming prokaryote of probable but not unequivocally established cyanobacterial affinities. An unusual low diversity unit in Bed 17 is dominated by a different builder, Tenuofilum septatum, while a thin cryptalgal horizon in Bed 18 is built almost exclusively by Siphonophycus kestron. Although variable taphonomic histories contribute to observed assemblage variation, most differences within and among horizons appear to reflect the differential success or failure of individual microbial populations in colonizing different tidal flat microenvironments. Twenty-two taxa are recognized, of which two are described as new: Myxococcoides stragulescens n.sp. and Scissilisphaera gradata n. sp.

NASA Discipline Number 52-30↗
DOE OSTI2020

The Impact of Ethylenediaminetetraacetic Acid (EDTA) on the Sorption of Nd(III), Th{sup (IV)}, and U(VI) onto Dolomite in WIPP-Relevant Brines, GWB and ERDA-6 - 20356

Storage of legacy, transuranic waste at the Waste Isolation Pilot Plant (WIPP) requires accurate risk models for performance assessments. These models must predict the long-term fate and transport of contaminants in the WIPP and surrounding environment. Laboratory support is necessary for the development of an accurate model through better understanding of contaminant behavior in the WIPP. The WIPP is a deep geologic repository that is characterized by high ionic strength due to evaporite deposits in the Salado formation (porewaters up to 7.4 M). High concentrations of sodium chloride (NaCl), calcium chloride (CaCl{sub 2}), and magnesium chloride (MgCl{sub 2}) are particularly of concern due to their potential impact on solubility and ultimately transport of contaminants of concern. Additionally, ligands capable of forming strong complexes with metals are found in significant concentrations in the WIPP environment due to their disposal from waste processing and formation during degradation of repository components (e.g. cellulose degradation by calcium hydroxide in cement). Consequently, there is a need to investigate the fate and transport of contaminants in the WIPP environment with a focus on the effects of high ionic strength and strongly coordinating ligands. Contaminants of high concern include the actinides (U(VI), Pu(IV), and Am(III)). Laboratory support of the WIPP modeling efforts was provided by this research. A series of batch experiments were utilized to study the impact of ionic strength, contaminant concentration, and the presence of ethylenediaminetetraacetic acid (EDTA) on the sorption of Nd(III), Th(IV), and U(VI) onto dolomite, a carbonate mineral found within the Culebra formation. The Culebra formation is the most transmissive layer above the WIPP, making transport of contaminants the most likely route in previous risk assessments. Two brines specifically designed to imitate conditions within the WIPP environment were used in these experiments. The U.S. Energy Research and Development Administration Well 6 (ERDA-6, 95%) brine simulates a low Mg environment, while the generic weep brine (GWB, 95%) simulates the WIPP environment with a high Mg concentration. Mg is added to the repository in the form of MgO as an engineered barrier and is naturally present in some formations. It is expected to scavenge carbonate from solutions decreasing formation of the highly soluble and competitive uranium-carbonate complexes. EDTA is used during manipulations of nuclear materials due to its ability to form strong, stable complexes with the actinides and may be found in high concentrations (up to 0.08 mM) within the WIPP as waste canisters degrade. Further, it may provide additional avenues for unwanted transport of contaminants. Nd(III) and Th(IV) were used as stable analogues of Am(III) and Pu(IV), respectively, to represent the most common oxidation states of actinides in the WIPP environment in addition to U(VI). The potential for colloid formation was also investigated with low and high concentrations of contaminants (10 and 1000 μg/L) using three size-dependent particle separation steps. The results of this research provide a better understanding of potential behavior of actinides in the presence of EDTA and within WIPP-relevant brines. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Dolomites in hydrated fine-grained Antarctic micrometeorites: Effective tools for analyzing secondary processes

We report detailed transmission electron microscope (TEM) observations of carbonates from one hydrated fine-grained Antarctic micrometeorite (H-FgMM). These carbonates show the occurrence of complex chemical variations and microstructures that provide important evidence regarding the formation and evolution of rarely analyzed H-FgMMs. The chemical variations were identified at both micrometer and nanometer scales, indicating that these carbonates formed under localized fluid conditions that suggest a variable chemical microenvironment. Individual carbonates grew from isolated reservoirs of fluid. Moreover, these carbonates contain manganese amounts almost twice as high as those measured in CM chondrites but similar to those identified in CI chondrites. Their particular compositions indicate reducing and progressively evolving conditions in the fluid from which these carbonates precipitated, probably due to water consumption during phyllosilicates formation. In addition to the compositional variability, microstructural features are pervasive in these carbonates, similar to those described in heavily shocked meteorites indicating that these carbonates were probably modified during shock processes after their formation. Since carbonates are highly susceptible to shock metamorphism, we suggest that it is essential to investigate their structure in detail before interpreting the isotopic measurements related to the time of their formation. Additionally, associated with carbonates, ubiquitous phosphates were identified in the micrometeorite analyzed. Future studies of these mineral associations will provide us further insight into the formation and evolution of asteroids, especially since they were both identified in the surface materials of Ryugu and Bennu.

58 GEOSCIENCES↗
NASA NTRS1976

A Gunflint-type microbiota from the Duck Creek dolomite, Western Australia

Two-billion-year-old black chert lenses from the Duck Creek formation, northwestern Western Australia, contain abundant organically preserved microorganisms which are morphologically similar to fossils of approximately the same age from the Gunflint formation, Ontario. Entities include a relatively small (5-15 micron) coccoid taxon morphologically comparable to Huroniospora Barghoorn, a larger coccoid form comparable to an apparently planktonic alga from the Gunflint, Gunflintia Barghoorn, and Eoastrion Barghoorn (Metallogenium Perfil'ev). Gunflint-type assemblages had a wide geographic distribution in middle Precambrian times, and these assemblages may eventually prove useful as biostratigraphic indices.

Knoll, A. H.↗
DOE OSTI2025

lllinois Storage Corridor CarbonSAFE Phase III: Pre-drilling Site Assessment: Prairie State Generating Company

The Illinois Storage Corridor project will drill a stratigraphic test well as part of the Illinois Storage Corridor CarbonSAFE Phase 3 project near the Prairie State Generating Company coal-fired power plant near Marissa, Illinois. The pre-drilling site evaluation has considered the primary target reservoirs, the Potosi Dolomite and St. Peter Sandstone, and primary seal, the Maquoketa Group. Data to be collected from the well include core, fluid samples, in situ well tests, geophysical logs intended to provide information on lithologic, geomechanical, and geophysical characteristics to determine the feasibility for the geologic sequestration of 50 million metric tons or more of injected carbon dioxide. The planned drilling site has been evaluated using available subsurface geologic data and analyses from the Illinois Basin. These data provide lithologic and structural information, shallow groundwater resource distribution, location of known nearby wellbores, and regional drilling characteristics. The data were used to generate geologic structure and isopach maps for the target reservoir and caprock strata and for prognosing the tops of major lithologic units to aid drilling and coring procedures. The regional analyses indicate that no known structural features are expected to negatively impact the target storage reservoir or caprock. No protected and sensitive areas, groundwater resources, or existing resource development are expected to be impacted by the proposed well drilling activities. The well is planned to be drilled to a total depth of approximately 5,600 feet (1,707 m) and terminate in the Precambrian. Cores (up to 5 intervals) will be collected from the Maquoketa Group, confining units above the St. Peter Sandstone, St. Peter Sandstone, confining units of the Potosi Dolomite and the Potosi Dolomite. Water samples will be attempted to be collected from the St. Peter Sandstone and Potosi Dolomite. Potential impact on drilling progress is a lost circulation zone in the Potosi Dolomite, which has been demonstrated to have intermittent cavernous porosity from karstification elsewhere in the Illinois Basin. This document also presents a preliminary coring and sampling program, proposed logging suite, and well testing program, all of which will be reviewed during drilling.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS1993

Carbonate compositions in CM and CI chondrites, and implications for aqueous alteration

Carbonate minerals in fourteen CM chondrites and two CI chondrites have been analyzed by electron microprobe to provide a better understanding of the aqueous processes that affected carbonaceous chondrite parent bodies. Calcites in CM chondrites and dolomites and magnesites in CI chondrites display the compositions expected of stable phases formed at low temperatures. Dolomites in CM chondrites, identified here for the first time in five members of the group, have small amounts of excess Ca which may reflect metastable growth. The distribution of Fe between dolomite and coexisting serpentine differs in the two chondrite groups. If the distributions reflect an approach to chemical equilibrium, then the difference implies higher alteration temperatures for the CI group than the CM group in agreement with the results of previously published oxygen isotope thermometry and mineral solubility modeling of the alteration process. Dolomite Fe contents are relatively uniform in the two chondrite groups. Dolomite Mn contents, by contrast, vary widely. The variations may reflect transport-controlled coprecipitation of Mn resulting from a heterogeneous distribution of the element in the anhydrous precursor material. If this interpretation is correct, then the altering fluids were essentially immobile white hydration reactions proceeded on the meteorite parent bodies. The near closed-system character of the alteration process, long known from bulk chemical analyses of the meteorites, is a direct consequence of the limited mobility of dissolved species.

Johnson, Craig A.↗
NASA NTRS1992

Geological evidence for a 2.6-Ga strewn field of impact spherules in the Hamersley Basin of Western Australia

Sand-sized spherules up to 1.7 mm across with spherulitic, vesicular, and other crystalline textures that consist mainly of K-feldspar help define a unique horizon in the well-preserved 2.6-Ga Wittenoom Formation in the Hamersley Basin of Western Australia. This layer is informally known as the spherule marker bed. In the northeastern part of the Hamersley Basin, similar spherules again occur at only one horizon, but here they are a minor constituent of a dolomitic debris-flow deposit known as the dolomixtite layer. The dolomixtite layer occurs in the Carawine Dolomite, which is stratigraphically equivalent to the Wittenoom Formation. Moreover, paleocurrent data from closely associated carbonate and volcaniclastic turbidites indicate the spherule marker bed was deposited in deeper-water paleoenvironments than the dolomixtite layer. Therefore, the dolomixtite layer is believed to be a proximal equivalent of the spherule marker bed. The layers that host the spherules are interpreted to be the deposits of a major sediment gravity flow that exhumed and redeposited most of the spherules after shallow burial, although the flow is not believed to have been a direct result of the proposed impact. The most likely site for the proposed impact would have been in the early Precambrian ocean close to the northeastern edge of the Pilbara Craton. Another thin horizon in the overlying Brockman Iron Formation contains spherules that again consist largely of K-feldspar and have internal textures strikingly similar to those of the Wittenoom Formation and Carawine Dolomite. The close resemblance of these spherules to those of the Wittenoom Formation and Carawine Dolomite suggests they also originated as impact melt droplets, even though they are admixed with volcaniclastic detritus. The stratigraphic separation between the two suggests that a second major impact occurred near the Hamersley Basin after a time interval of about 75 m.y. elapsed. This suggests the record of impacts in early Precambrian strata is richer than is generally appreciated.

Simonson, Bruce M.↗