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At least 37 records · Page 2

The 27-28 October 1986 FIRE IFO cirrus case study - In situ observations of radiation and dynamic properties of a cirrus cloud layer

Observations are presented of cirrus cloud radiative, microphysical, and dynamic properties, their variability, and apparent scale sizes, as observed from NCAR Sabreliner on October 28, 1986. Broadband mass-absorption coefficients were deduced as a function of depth into the cirrus cloud and found to vary with particle dimension. Broadband volume absorption coefficients were deduced. By employing a diffusivity factor of 1.49 this agreement was maximized. Calculated infrared heating rates were typical of thin cirrus layers. The cloud top cooling and cloud base warming were observed to become more accentuated for the denser portions of cloud. The broadband emittances due to the cloud aerosol were found to approach 0.5 to 0.6. The cirrus clouds were observed to exhibit significant horizontal variability and a significant amount of scatter was evident when attempting to relate the broadband infrared and shortwave radiative properties. It is suggested that these radiative properties, which are modulated by the cloud elements, have their scales determined by the eddies detected in the analysis of wind components.

Smith, William L., Jr.

The Quantum Phase-Dynamical Properties of the Squeezed Vacuum State Intensity-Couple Interacting with the Atom

The Phase-dynamical properties of the squeezed vacuum state intensity-couple interacting with the two-level atom in an ideal cavity are studied using the Hermitian phase operator formalism. Exact general expressions for the phase distribution and the associated expectation value and variance of the phase operator have been derived. we have also obtained the analytic results of the phase variance for two special cases-weakly and strongly squeezed vacuum. The results calculated numerically show that squeezing has a significant effect on the phase properties of squeezed vacuum.

Fan, An-Fu

Dynamic properties of aircraft tires

A research program has investigated the use of the von Schlippe string-type tire model for predicting the dynamic behavior of aircraft tires. The transfer-function method was used for theory evaluation. A more flexible two-constant modification to the string theory tire model is presented. Experiments were conducted on four types of scale model aircraft tires. Two types were of conventional bias construction, one type was an isotropic toroid, and one type was of unbelted radial construction. The conventional string theory and model gave predictions that were in good agreement with experimental data for bias constructed tires. The two-constant modification to string theory provided better agreement between predictions and experiment for the unconventional tires. The results indicate that the string theory tire model using static and slow-rolling tire properties predicts dynamic aircraft tire properties that have the same trends as the measured dynamic properties and, in most cases, provides good quantitative agreement.

Clark, S. K.

The atmospheric structure and dynamical properties of Neptune derived from ground-based and IUE spectrophotometry

A wide range of recent full-disk spectral observations is used to constrain the atmospheric structure and dynamical properties of Neptune; analytical determinations are made of the abundances of such spectrally active gas species as the deep-atmosphere CH4 molar fraction and the mean ortho/para hydrogen ratio in the visible atmosphere, as well as stratospheric and tropospheric aerosol properties. Compared to Uranus, the greater abundance and shorter lifetimes of Neptunian particulates in the stratospheric region irradiated by the solar UV flux indicate that such radiation is the darkening agent of stratospheric aerosols on both planets.

Baines, Kevin H.

High power thyristors with 5 kV blocking voltage. Volume 1: Development of high-voltage-thyristors (4.5 kV) with good dynamic properties

Using neutron irradiated silicon with considerably lower spread in resistivity as compared to conventionally doped silicon it was possible to produce power thyristors with breakdown voltages between 3.5 kV and 5.5 kV. The thyristor pellets have a diameter of 50 mm. Maximum average on-state currents of 600 to 800 A can be reached with these elements. The dynamic properties of the thryistors could be improved to allow standard applications up to maximum repetitive voltages of 4.5 kV.

Lock, K.

Joint Theoretical and Experimental Study of the Electronic, Magnetic, and Lattice Phonon Dynamics Properties of Ca x Fe y O z Compounds Applied to CO 2 Capture

Unleashing energy innovation ensures a resilient and reliable energy supply. There is a critical need for the development of new carbon dioxide (CO 2 ) captors that have improved energy efficiency accompanied by lower capital and operational costs to ensure abundant, affordable, and secure energy. Among solid materials, CaO is a good CO 2 sorbent for capture technology due to its wide availability and low cost. However, CaO also suffers from some disadvantages, such as high calcination temperature, decreasing capability due to sintering, attrition, and reaction with SO x and NO x . In this study, we employed an ab initio thermodynamic approach and experimental measurements to improve its CO 2 capture performance during the cycles. To do so, we explored the electronic, magnetic, and lattice dynamic properties of a series of calcium ferrites (Ca x Fe y O z ) and applied them for CO 2 capture. Our results showed that all of them can thermodynamically react with CO 2 to form CaCO 3 and iron oxides. Compared to pure CaO capturing CO 2 , CaFe 3 O 4 , CaFe 2 O 4 , and Ca 2 Fe 2 O 5 could shift the CO 2 regeneration temperature to a lower range. The experimental measurements showed that CaFeO 2 is a good CO 2 captor with or without the presence of an O 2 presence. The calculated thermodynamic properties of Ca x Fe y O z capturing the CO 2 reactions can be used to find their operational temperature ranges for different CO 2 capture technologies.

CO2 capture

Geodetic and dynamical properties of planets

Data concerning planetary dynamics and geodesy are severely limited because, at present, only one planetary system in the universe can be studied. It is, therefore, impossible to base the study of planets on a significant statistical sample. The gravity fields of the planets are discussed, giving attention to the various space missions involved in the collection of the relevant data. Other subjects considered include planetary shape and topography, planetary rotations, and planetary interiors. The basic problem in finding an acceptable model for the planetary interior is to specify the chemical composition with depth and then to find a physically realistic equation for the material.

Anderson, J. D.

Analytical investigations employing dynamic mechanical properties

Dynamic mechanical spectroscopy has emerged as an effective laboratory method for analytical investigations of polymers. These methods were applied in investigating the property changes of silicone poppets implanted in artificial heart valves, and for exploring the cause of hardening of certain solid propellants. As a research activity, the property-structure relations which lead to the ability to superimpose dynamic data for epoxy resins were investigated.

Cuddihy, E. F.

Geodetic and dynamical properties of planets

The study of planetary dynamics and geodesy is a difficult subject. This is so, not simply because of the complexity of the interactions between several scientific disciplines, including geophysics, geology, geochemistry, seismology, celestial mechanics, radar astronomy, and meteoritics, but perhaps more fundamentally, because of a lack of data. Although it is true that the space age has brought about important new observational techniques, which are responsible in large part for the rapid developments in planetary science over the past decade, and although we should expect to see significant progress in the field over the next few years, it is still a sad fact that data will be severely limited for an indefinite period of time in the future. The basic problem is that we can observe and study, at present, only one planetary system in the universe. This system, our solar system, contains only four major planets, five terrestrial planets, where we are inclined to include the moon but exclude Pluto, and a fairly limited collection of debris, presumably left over from some inadequately understood formation process. Thus it is impossible to base the study of planets on a significant statistical sample.

J. D.. Anderson

Mass Mitigation in Structural Designs Via Dynamic Properties

The efforts reported here are focused on mitigating unnecessary mass in aerospace hardware. The approach to remove this undesired mass from the design is to leverage both the dynamic strength of materials and the frequency dependency of strain. Analytically predicted dynamic responses of structures are often applied as static loads in stress analyses that ultimately dictate the weight of a structural design. Assuming a dynamic response is a static load and then comparing resulting stress predictions to a static strength property is a long-standing engineering practice. Doing so is known to be, or is assumed to be, conservative. However, little indication of the order of magnitude of embedded conservatism has been identified. NASA/MSFC efforts in 2011, 2019, 2020, and now in 2021 have begun to qualitatively show the order of magnitude of that conservatism. A quick turnaround engineering method is pursued to leverage the subject facets of physics for the purpose of decreasing the weight of flight hardware. Tests performed using simple beams and significant observations are described.

conservative design loads

Equilibrium and Dynamics Properties of Poly(oxyethylene) Melts and Related Poly(alkylethers) from Simulations and Ab Initio Calculations

Molecular dynamics simulations of POE melts have been performed utilizing a potential force field parameterized to reproduce conformer energies and rotational energy barriers in dimethoxyethane as determined from ab initio electronic structure calculations. Chain conformations and dimensions of POE from the simulations were found to be in good agreement with predictions of a rotational isomeric state (RIS) model based upon the ab initio conformational. energies. The melt chains were found to be somewhat extended relative to chains at theta conditions. This effect will be discussed in light of neutron scattering experiments which indicate that POE chains are extended in the melt relative to theta solutions. The conformational characteristics of POE chains will also be compared with those of other poly (alkylethers), namely poly(oxymethylene), poly(oxytrimethylene) and poly(oxytetramethylene). Local conformational dynamics were found to be more rapid than in polymethylene. Calculated C-H vector correlation times were found to be in reasonable agreement with experimental values from C-13 NMR spin-lattice relaxation times. The influence of ionic salts on local conformations and dynamics will also be discussed.

Smith, Grant D.

Fluid-Dynamic Properties of Some Simple Sharp- and Blunt-Nosed Shapes at Mach Numbers from 16 to 24 in Helium Flow

The fluid-dynamic characteristics of flat plates, 5 deg and 10 deg wedges, and 5 deg and 10 deg cones have been investigated at Mach numbers from 16.3 to 23.9 in helium flow. The flat-plate results are for a leading-edge Reynolds number range of 584 to 19,500 and show that the induced pressure distribution is essentially linear with the hypersonic viscous interaction parameter bar X within the scope of this investigation. It is also shown that the rate at which the induced pressure varies with bar X is a linear function of the leading-edge Reynolds number. The wedge and cone results show that as the flow-deflection angle increases, the induced-pressure effects decrease and the measured pressures approach those predicted by inviscid shock theory.

Henderson, Arthur, Jr.

Tailoring additive manufacturing to optimize dynamic properties in 316L stainless steel

With the advent of additive manufacturing, manipulation of typical microstructural elements such as grain size, texture, and defect densities is now possible at a faster time scale. While the processing–structure–property relationship in additive manufactured metals has been well studied over the past decade, little work has been done in understanding how this process affects the dynamic behavior of materials. We postulate that additive manufacturing can be used to alter the material microstructure and used to enhance its dynamic strength. In this work, 316L stainless steel (SS) was manufactured via selected laser melting and its microstructure was altered through changing build parameters like laser power, speed, and hatch spacing systematically. These samples were then subjected to spall recovery experiments to measure the spall strength and quantify the amount of damage as a function of build parameters. By mapping the spall strength as a function of build parameters, this work demonstrated that indeed additive manufacturing can be used to tailor the spall strength of 316L SS. This work also determined the optimum build parameters (laser power=195W; scanning speed=1083mm/s; hatch spacing=0.09mm; layer thickness=0.02mm) to obtain the highest spall strength and the least amount of total damage in 316L SS. Microstructural characterization of the pre- and post-mortem samples revealed that increased grain average misorientation and textural index were the main driving force behind this higher spall strength. This work aims to enhance microstructural engineering techniques to design materials with greater resistance to dynamic shock loading.

36 MATERIALS SCIENCE

Measurement of interstage fluid-annulus dynamical properties

The work described in this paper is part of an Electric Power Research Institute sponsored effort to improve rotor vibrational performance on power plant feed water pumps. A major objective of this effort is to reduce vibration levels by devising inter-stage sealing configurations with optimized damping capacity, realizing that the typical multi-stage centrifugal pump has several ore inter-stage fluid annuli than it has journal bearings. Also, the fluid annuli are distributed between the journal bearings where vibration levels are highest and can therefore be 'exercised' more as dampers than can the bearings. Described in this paper is a test apparatus which has been built to experimentally determine fluid-annulus dynamical coefficients for various configurations of inter-stage sealing geometry.

Adams, M. L.

Monitoring Depolymerization in Mesopores Using Dynamic Properties of Polymeric Melt Accessed via Dielectric Spectroscopy

Traditional design principles for heterogeneous catalysis guide the use of catalytic particles with mesosized (∼2–50 nm) pores to increase the number of surface-active sites by way of an increased surface area. However, the entry of long-chain polymers into such pores may be significantly limited by the size and entanglement of polymers in the melt state, thereby decreasing the number of accessible sites. Assessment of catalyst performance from traditional reactor-based studies averages over intrapore reaction events as well as reactions on the surface of a particle, resulting in an inability to distinguish between differences in site accessibility and activity. Techniques that assess the intrapore performance can inform the design of future heterogeneous catalysts for polymer upcycling. In this work, we demonstrate the use of broadband dielectric spectroscopy to monitor depolymerization of a polymer melt within mesopores via changes in the segmental relaxation time scale of amorphous polymer chains. In particular, we highlight the use of an anodic aluminum oxide (AAO) membrane as a readily available model for catalyst pores with a well-characterized pore morphology. The decrease in the segmental relaxation (α-relaxation) time of the melt with increasing chain scission emerges as a measure of the extent of polymer deconstruction inside mesopores. To demonstrate the utility of this technique, we demonstrate the decomposition of two commercial poly(propylene carbonate) polymers with different decomposition rates within mesopores. As the polymers depolymerize, their segmental relaxation time decreases as the molecular weight decreases (as predicted by the Fox–Flory equation). The BDS-measured change in segmental relaxation time mirrors the expected trend based on change in molecular weight measured by size exclusion chromatography.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH