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At least 37 records · Page 2

Detection of Intergranular Corrosion in Cold Plate Face Sheets

Cold plates are critical for cooling electronic systems in the shuttle. As a result of the environmental conditions in which they operate, water can condense between them and a support shelf. In some cases, this water results in intergranular corrosion in the face sheet. If the intergranular corrosion sufficiently penetrates the face sheet, a coolant leak could occur and jeopardize cold plate operation. This paper examines techniques for detecting and characterizing the intergranular corrosion, to enable recertification of cold plates that have been in operation for 15 plus years. Intergranular corrosion was artificially induced in the face sheets of a series of cold plate specimens using an electrochemical process. Some of the cold plate specimens were separated for destructive characterization of the extent of corrosion produced by the electrochemical process and to insure the induced corrosion was intergranular. The rest of the specimens were characterized nondestructively using several techniques. X-ray tomography and ultrasonic techniques provided the best indication of corrosion in these specimens and will be the focus of this paper. An x-ray tomography technique was shown to be the most effective technique for characterizing depth of the intergranular corrosion. From these measurements, corrosion profile maps were developed that were consistent with subsequent destructive evaluations of the specimens. This enabled the assessment of NDE (ondestructive evaluation) standards to evaluate the viability of other NDE techniques. Due to system constraints, a different technique must be used to inspect an entire cold plate. An ultrasonic technique was shown to be very reliable for detection of corrosion in the unbacked regions of the face sheet. The ultrasonic technique was performed in an alcohol bath to avoid additional corrosion during the NDE evaluation. A pulse echo technique that focuses on the RMS value of the signal is shown to be very sensitive to the presence of intergranular corrosion.

Winfree, William P.↗

Identification characteristics of certain lunar relief forms on pictures obtained from spacecraft

This investigation was restricted to the determination of recognitional characteristics of a single type of relief form, dimple craters on the surface of maria. These craters were arbitrarily considered as closed, negative relief forms, circular in plan-view, and symmetric relative to the center. Two techniques were used to determine the shadow configuration in the craters: (1) experimental determination of the shadow edge by illuminating the models of different profile shapes with a parallel light beam; and (2) geometric construction of the shadow edge using a vertical section of the formation in the direction of the solar rays. A morphological map of the surface which includes the following factors can be compiled using the proposed identification technique: crater profile nature, crater diameter, ratio of diameter and depth, sharpness of the lip, and distribution density of the forms.

Kravtsova, V. I.↗

Measurement techniques for trace metals in coal-plant effluents: A brief review

The strong features and limitations of techniques for determining trace elements in aerosols emitted from coal plants are discussed. Techniques reviewed include atomic absorption spectroscopy, charged particle scattering and activation, instrumental neutron activation analysis, gas/liquid chromatography, gas chromatographic/mass spectrometric methods, X-ray fluorescence, and charged-particle-induced X-ray emission. The latter two methods are emphasized. They provide simultaneous, sensitive multielement analyses and lend themselves readily to depth profiling. It is recommended that whenever feasible, two or more complementary techniques should be used for analyzing environmental samples.

Singh, J. J.↗

Rhenium in seawater - Confirmation of generally conservative behavior

A depth profile of the concentration of Re was measured in the Pacific Ocean using a technique developed for the clean chemical separation and the precise measurement of Re by isotope dilution and negative thermal ionization mass spectrometry (ID-NTIMS). We obtain a narrow range for Re from 7.20 +/- 0.03 to 7.38 +/- 0.03 ng/kg for depths between 45 m and 4700 m. This demonstrates that Re is relatively well mixed throughout the water column and confirms the theoretical prediction that the behavior of Re in the oceans is conservative. When examined in detail, both salinity and the concentration of Re increase by approximately 1.5 percent between 400 and 4700 m, a correlation consistent with conservative behavior. However, Re appears to be depleted relative to salinity by 1.0-1.5 percent at 100 m, and enriched by approximately 4 percent at the surface. These observations suggest a minor level of Re scavenging in near surface waters, and an input of Re to the ocean surface. This work demonstrates the utility of geochemical investigations of certain trace elements not previously been amenable to detailed study.

Anbar, A. D.↗

Auger profiling of 'abrupt' LPE Al/x/Ga/1-x/As-GaAs heterojunctions

Auger analysis in conjunction with ion milling was used to study depth profiles of 'abrupt' Al/x/Ga/1-x/As-GaAs heterojunctions grown by liquid-phase epitaxial (LPE) techniques. Results are presented on samples with x = 0.43, 0.60, and 0.85. The interface widths obtained are listed in a table together with the growth conditions and the layer thicknesses. The values for the layer thicknesses are in the range from 125 to 950 A. It is found that for thin layers the interface widths do not differ greatly from the average value of 110A.

Garner, C. M.↗

Looking at Ozone From a New Angle: Shuttle Ozone Limb Sounding Experiment-2 (SOLSE-2)

The ozone layer above Earth is our planet's fragile sunscreen, protecting people, vegetation, and wildlife. NASA has been measuring ozone for more than 20 years by looking down, but SOLSE-2 will show that more information is available by looking at ozone from the side, at Earth's limb or atmospheric boundary. When the ozone layer is compromised, increased ultraviolet (UV) levels from the sun cause health problems ranging from severe sunburns to skin cancer and cataracts. A concerted global effort has been made to reduce or eliminate the production of chemicals that deplete ozone, but the ozone layer is not expected to recover for many decades because these chemicals can remain active in the atmosphere for up to 100 years. We know now that ozone monitoring needs to be focused in the lower stratosphere. The discovery of the ozone hole in 1985 demonstrated that very large changes in ozone were occurring in the lower stratosphere near 20 km, instead of the upper stratosphere as first expected, and where current ozone instruments are focused. Measuring ozone from a tangential perspective that is centered at the limb provides ozone profiles concentrated in the lower stratosphere. The first flight of SOLSE proved that this technique achieves the accuracy and coverage of traditional measurements, and surpasses the altitude resolution and depth of retrieval of conventional techniques. Results from the first flight convinced the science community to design the next generation ozone monitoring satellite based on SOLSE. The Ozone Mapping and Profiling Suite (OMPS) is currently being built for the NPOESS satellite. The primary objective of SOLSE-2 is to confirm the promising results of the first flight over a wider range of viewing conditions and spectral wavelengths. Sometimes a really hard problem can be solved when you look at it from a different angle! While scientists conduct research, protect yourself by observing the UV index and spend less unprotected time outdoors.

McPeters, Richard↗

Local atomic and electronic structure of oxide/GaAs and SiO2/Si interfaces using high-resolution XPS

The chemical structures of thin SiO2 films, thin native oxides of GaAs (20-30 A), and the respective oxide-semiconductor interfaces, have been investigated using high-resolution X-ray photoelectron spectroscopy. Depth profiles of these structures have been obtained using argon ion bombardment and wet chemical etching techniques. The chemical destruction induced by the ion profiling method is shown by direct comparison of these methods for identical samples. Fourier transform data-reduction methods based on linear prediction with maximum entropy constraints are used to analyze the discrete structure in oxides and substrates. This discrete structure is interpreted by means of a structure-induced charge-transfer model.

Grunthaner, F. J.↗

Production of radionuclides in artificial meteorites irradiated isotropically with 600 MeV protons

The understanding of the production of cosmogenic nuclides in small meteorites (R is less than 40 cm) still is not satisfactory. The existing models for the calculation of depth dependent production rates do not distinguish between the different types of nucleons reacting in a meteorite. They rather use general depth dependent particle fluxes to which cross sections have to be adjusted to fit the measured radionuclide concentrations. Some of these models can not even be extended to zero meteorite sizes without logical contradictions. Therefore, a series of three thick target irradiations was started at the 600 MeV proton beam of the CERN isochronuous cyclotron in order to study the interactions of small stony meteorites with galactic protons. The homogeneous 4 pi irradiation technique used provides a realistic meteorite model which allows a direct comparison of the measured depth profiles with those in real meteorites. Moreover, by the simultaneous measurement of thin target production cross sections one can differentiate between the contributions of primary and secondary nucleons over the entire volume of the artificial meteorite.

Michel, R.↗

Evaluation of CALIOP 532-nm Aerosol Optical Depth Over Opaque Water Clouds

With its height-resolved measurements and near global coverage, the CALIOP lidar onboard the CALIPSO satellite offers a new capability for aerosol retrievals in cloudy skies. Validation of these retrievals is difficult, however, as independent, collocated and co-temporal data sets are generally not available. In this paper, we evaluate CALIOP aerosol products above opaque water clouds by applying multiple retrieval techniques to CALIOP Level 1 profile data and comparing the results. This approach allows us to both characterize the accuracy of the CALIOP above-cloud aerosol optical depth (AOD) and develop an error budget that quantifies the relative contributions of different error sources. We focus on two spatial domains: the African dust transport pathway over the tropical North Atlantic and the African smoke transport pathway over the southeastern Atlantic. Six years of CALIOP observations (2007-2012) from the northern hemisphere summer and early fall are analyzed. The analysis is limited to cases where aerosol layers are located above opaque water clouds so that a constrained retrieval technique can be used to directly retrieve 532 nm aerosol optical depth and lidar ratio. For the moderately dense Sahara dust layers detected in the CALIOP data used in this study, the mean/median values of the lidar ratios derived from a constrained opaque water cloud (OWC) technique are 45.1/44.4 +/- 8.8 sr, which are somewhat larger than the value of 40 +/- 20 sr used in the CALIOP Level 2 (L2) data products. Comparisons of CALIOP L2 AOD with the OWC-retrieved AOD reveal that for nighttime conditions the L2 AOD in the dust region is underestimated on average by approx. 26% (0.183 vs. 0.247). Examination of the error sources indicates that errors in the L2 dust AOD are primarily due to using a lidar ratio that is somewhat too small. The mean/median lidar ratio retrieved for smoke is 70.8/70.4 +/- 16.2 sr, which is consistent with the modeled value of 70 +/- 28 sr used in the CALIOP L2 retrieval. Smoke AOD is found to be underestimated, on average, by approx. 39% (0.191 vs. 0.311). The primary cause of AOD differences in the smoke transport region is the tendency of the CALIOP layer detection scheme to prematurely assign layer base altitudes and thus underestimate the geometric thickness of smoke layers.

Liu, Z.↗

Depositional history of core section 74001 - Depth profiles of maturity, FeO, and metal

Samples from every 0.5-cm interval of soil in core section 74001 have been studied by ferromagnetic resonance (FMR) and magnetic techniques. The values of the FMR maturity index show that the 74001 samples are very immature (the index ranges from 0.14 to 0.29 units) and have not seen appreciable, if any, surface exposure since their deposition. In fact, the small amount of fine-grained metal in the 74001 samples is probably not acquired as a result of their exposure to the micrometeoroid flux at the lunar surface. Thus, the black-glass soil of 74001 was deposited very rapidly, probably in a single episode or several closely spaced episodes of lunar fire fountaining. The average concentration of FeO and its standard deviation for all the 74001 samples are 22.5 + or - 0.3 wt.%. Since the FeO concentration is so uniform, no large variations in the major-element chemistry of 74001 are expected, with the possible exception of the volatile elements. The concentration of coarse-grained metal, which is measured magnetically, and its standard deviation are 0.15 + or - 0.01 wt.%. The coarse-grained metal probably precipitated contemporaneously with the silicate and oxide phases in the black-glass droplets.

Morris, R. V.↗

Remote Sensing of Multiple Cloud Layer Heights Using Multi-Angular Measurements

Cloud top height (CTH) affects the radiative properties of clouds. Improved CTH observations will allow for improved parameterizations in large-scale models and accurate information on CTH is also important when studying variations in freezing point and cloud microphysics. NASAs airborne Research Scanning Polarimeter (RSP) is able to measure cloud top height using a novel multi-angular contrast approach. For the determination of CTH, a set of consecutive nadir reflectances is selected and the cross-correlations between this set and co-located sets at other viewing angles are calculated for a range of assumed cloud top heights, yielding a correlation profile. Under the assumption that cloud reflectances are isotropic, local peaks in the correlation profile indicate cloud layers. This technique can be applied to every RSP footprint and we demonstrate that detection of multiple peaks in the correlation profile allow retrieval of heights of multiple cloud layers within single RSP footprints. This paper provides an in-depth description of the architecture and performance of the RSPs CTH retrieval technique using data obtained during the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC(exp. 4)RS) campaign. RSP retrieved cloud heights are evaluated using collocated data from the Cloud Physics Lidar (CPL). The method's accuracy associated with the magnitude of correlation, optical thickness, cloud thickness and cloud height are explored. The technique is applied to measurements at a wavelength of 670 nm and 1880 nm and their combination. The 1880-nm band is virtually insensitive to the lower troposphere due to strong water vapor absorption.

Sinclair, Kenneth↗

Using lunar sounder imagery to distinguish surface from subsurface reflectors in lunar highlands areas

We have developed a method using the Apollo 17 Lunar Sounder imagery data which appears capable of filtering out off-nadir surface noise from highland area profiles, so that subsurface features may now be detected in highland areas as well as mare areas. Previously, this had been impossible because the rough topography in the highland areas created noise in the profiles which could not be distinguished from subsurface echoes. The new method is an image processing procedure involving the computerized selection of pixels which represent intermediate echo intensity values, then manually removing those pixels from the profile. Using this technique, a subsurface feature with a horizontal extent of about 150 km, at a calculated depth of approximately 3 km, has been detected beneath the crater Riccioli in the highlands near Oceanus Procellarum. This result shows that the ALSE data contain much useful information that remains to be extracted and used.

Cooper, Bonnie L.↗

An Alternate Method for Estimating Dynamic Height from XBT Profiles Using Empirical Vertical Modes

A technique is presented that applies modal decomposition to estimate dynamic height (0-450 db) from Expendable BathyThermograph (XBT) temperature profiles. Salinity-Temperature-Depth (STD) data are used to establish empirical relationships between vertically integrated temperature profiles and empirical dynamic height modes. These are then applied to XBT data to estimate dynamic height. A standard error of 0.028 dynamic meters is obtained for the waters of the Gulf of Alaska- an ocean region subject to substantial freshwater buoyancy forcing and with a T-S relationship that has considerable scatter. The residual error is a substantial improvement relative to the conventional T-S correlation technique when applied to this region. Systematic errors between estimated and true dynamic height were evaluated. The 20-year-long time series at Ocean Station P (50 deg N, 145 deg W) indicated weak variations in the error interannually, but not seasonally. There were no evident systematic alongshore variations in the error in the ocean boundary current regime near the perimeter of the Alaska gyre. The results prove satisfactory for the purpose of this work, which is to generate dynamic height from XBT data for coanalysis with satellite altimeter data, given that the altimeter height precision is likewise on the order of 2-3 cm. While the technique has not been applied to other ocean regions where the T-S relation has less scatter, it is suggested that it could provide some improvement over previously applied methods, as well.

Lagerloef, Gary S. E.↗

An investigation of impurity redistribution in diffused layer on /n+/-p silicon solar cells parameters

Recent calculations by Wang et al. (1974) have shown that the short-circuit current for silicon solar cells is sensitive to the impurity distribution in the diffused and base region. In the present work, these theoretical results were verified by experimentally investigating the impurity profile and sheet resistance of the diffused layers of (n+)-p silicon solar cells fabricated by normal diffusion processes and at subsequently various drive-in times. Impurity profiles of the n+ diffused layer, measured by differential Hall and resistivity technique, resemble the erfc distribution. The junction depth is larger as drive-in time increases. Measured short-circuit current is in agreement with calculated ones. Open-circuit voltage is independent of drive-in times, and its calculated values are consistent with capacitance-voltage measurements.

Wang, E. Y.↗

Climatology of Global Precipitation Measurement Mission Precipitation Regimes and Implications for Global Estimates of Vertical Winds

The Global Precipitation Measurement (GPM) mission Validation Network (VN) framework leverages over 118 ground-based polarimetric Doppler radars to validate a large subset of precipitation measurements and retrievals from the GPM Dual-frequency Precipitation Radar (DPR). Recently, GPM DPR reflectivity profiles within the VN have been classified according to their convective regime using unsupervised machine learning techniques. The archetypal regimes are stratiform, convective, mixed stratiform-convective (e.g., transition regions), and “other” (e.g., peripheral regions of light precipitation). Subcategories within these four primary regimes vary according to the characteristic depth of included reflectivity profiles, resulting in 12 main GPM DPR precipitation profile categories. Polarimetry of ground-based Doppler radars in the VN offers additional insights into the types of precipitation, while pairs of radars positioned near each other enable retrieval of vertical winds via dual-Doppler analysis. Geometrically matched to the DPR reflectivity profiles in the GPM VN, these ground-based data and retrievals contribute more detailed characterization of the distinct kinematic and microphysical structures associated with each of the 12 DPR precipitation regimes. DPR reflectivity profiles linked with wind in the VN are restricted to GPM overpasses of proximal radar pairs that allow dual-Doppler analysis. Although a limited subset of DPR profiles in the VN are matched with vertical motion, agreement between the reflectivity structures paired with wind data and those of the greater DPR dataset in the VN suggest that estimates of vertical motion may be inferred in regions without ground-based measurements. We present a climatology of the 12 convective regimes identified within the DPR VN dataset as well as early efforts to estimate the kinematic and microphysical structures of precipitation profiles within the greater GPM DPR dataset by applying machine learning techniques. Precipitation data paired with global estimates of vertical winds from these efforts offer early insight to and support upcoming missions to retrieve convective mass flux, including the Investigation of Convective Updrafts (INCUS) in the Tropics and the global Atmosphere Observing System (AOS).

Precipitation↗

Remote sensing of subsurface water temperature by laser Raman spectroscopy

This paper describes experimental remote sensing of subsurface water temperature using the Raman spectroscopic technique. By the use of a pulsed laser and range gating detection techniques, Raman scattering is analyzed as a function of depth in a radar-like echo mode, and thus subsurface profiles of temperature and transmission are obtained. Experiments are described in which Raman data using polarization spectroscopy has been obtained from a ship as a function of depth in ocean water near Grand Bahama Island. A spectral temperature accuracy of + or - 1 C has been obtained from this data in the first two optical attenuation lengths. Raman data obtained from ocean water using the NASA airborne oceanographic lidar is also presented.

Leonard, D. A.↗

Slant-lidar aerosol extinction measurements and their relation to measured and calculated albedo changes

Lidar and albedo data for a single day on which aerosols increased the surface plus atmospheric albedo above values measured on two surrounding very clean days are presented. The slant-lidar extinction measurement technique used is described along with the equipment and operating procedures. The derivation of optical depths, backscatter-to-extinction ratios, and extinction profiles is addressed, and the use of the lidar-derived optical depths in calculating expected albedo change is considered. Measured and calculated albedo changes are compared, and the results are found to agree within experimental uncertainties.

Russell, P. B.↗

Directed-energy process technology efforts

A summary of directed-energy process technology for solar cells was presented. This technology is defined as directing energy or mass to specific areas on solar cells to produce a desired effect in contrast to exposing a cell to a thermal or mass flow environment. Some of these second generation processing techniques are: ion implantation; microwave-enhanced chemical vapor deposition; rapid thermal processing; and the use of lasers for cutting, assisting in metallization, assisting in deposition, and drive-in of liquid dopants. Advantages of directed energy techniques are: surface heating resulting in the bulk of the cell material being cooler and unchanged; better process control yields; better junction profiles, junction depths, and metal sintering; lower energy consumption during processing and smaller factory space requirements. These advantages should result in higher-efficiency cells at lower costs. The results of the numerous contracted efforts were presented as well as the application potentials of these new technologies.

Alexander, P.↗