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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Phase noise limited frequency shift impulsive Raman spectroscopy

We introduce a method to enable optical amplification of a coherent Raman spectroscopy signal, which we call radio frequency (RF) Doppler Raman spectroscopy. In this article, we consider the perturbation of a probe pulse in a sample due to an excited Raman vibrational coherence as a generalized Doppler shift, which connects a time-varying optical path length (the product of the propagation length and refractive index, OPL = n ℓ) with an optical frequency shift. Amplification of a Raman signal outside of the focused interaction is enabled by converting the Doppler frequency shift experienced by a laser probe pulse into a periodic timing jitter. This transit time perturbation is detected through the phase of a RF electronic signal measured at a harmonic of the probe pulse train with a method adapted from precision metrology techniques used to measure laser pulse train timing jitter. Measurement of a timing jitter allows access to much lower noise floors than other coherent Raman techniques, and by exploiting the new capability to scale the signal of a coherent Raman spectroscopic signal, this method opens the potential to detect very weak Raman signals that are currently not observable due to limits of illumination intensity imposed by laser damage to the specimen and noise.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Structural tunability and origin of two-level systems in amorphous silicon

Amorphous silicon films prepared by electron-beam evaporation have systematically and substantially greater atomic density for higher thickness, higher growth temperature, and slower deposition rate, reaching the density of crystalline Si when films of thickness greater than ~300 nm are grown at 425 °C and at <1 Å/s. Here, a combination of spectroscopic techniques provide insight into atomic disorder, local strains, dangling bonds, and nanovoids. Electron diffraction shows that the short-range order of the amorphous silicon is similar at all growth temperatures, but fluctuation electron microscopy shows that films grown above room temperature show a form of medium-range order not previously observed in amorphous silicon. Atomic disorder and local strain obtained from Raman spectroscopy are reduced with increasing growth temperature and show a nonmonotonic dependence on thickness. Dangling bond density decreases with increasing growth temperature and is only mildly dependent on thickness. Positron annihilation Doppler broadening spectroscopy and electron energy loss spectroscopy show that nanovoids, and not density variations within the network, are responsible for reduced atomic density. Specific heat and mechanical loss measurements, which quantify the density of tunneling two-level systems, in combination with the structural data, suggest that two-level systems in amorphous silicon films are associated with nanovoids and their surroundings, which are in essence loosely bonded regions where atoms are less constrained.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Using convolutional neural networks to detect edge localized modes in DIII-D from Doppler backscattering measurements

In H-mode tokamak plasmas, the plasma is sometimes ejected beyond the edge transport barrier. These events are known as edge localized modes (ELMs). ELMs cause a loss of energy and damage the vessel walls. Understanding the physics of ELMs, and by extension, how to detect and mitigate them, is an important challenge. In this paper, we focus on two diagnostic methods—deuterium-alpha (D α ) spectroscopy and Doppler backscattering (DBS). The former detects ELMs by measuring Balmer alpha emission, while the latter uses microwave radiation to probe the plasma. DBS has the advantages of having a higher temporal resolution and robustness to damage. These advantages of DBS diagnostic may be beneficial for future operational tokamaks, and thus, data processing techniques for DBS should be developed in preparation. In sight of this, we explore the training of neural networks to detect ELMs from DBS data, using D α data as the ground truth. With shots found in the DIII-D database, the model is trained to classify each time step based on the occurrence of an ELM event. The results are promising. When tested on shots similar to those used for training, the model is capable of consistently achieving a high f1-score of 0.93. Furthermore, this score is a performance metric for imbalanced datasets that ranges between 0 and 1. We evaluate the performance of our neural network on a variety of ELMs in different high confinement regimes (grassy ELM, RMP mitigated, and wide-pedestal), finding broad applicability. Beyond ELMs, our work demonstrates the wider feasibility of applying neural networks to data from DBS diagnostic.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Ion thermal transport in the H-mode edge transport barrier on DIII-D

The power balance ion heat flux in the pedestal region on DIII-D increases and becomes increasingly anomalous (above conventional neoclassical) in experiments with higher temperature and lower density pedestals where the ion collisionality ($v^*_i$) is lowered toward values expected on ITER. Direct measurements of the main-ion temperature are shown to be essential on DIII-D when calculating the ion heat flux due to differences between the temperature of $D^+$ and the more commonly measured $C^{6+}$ impurity ions approaching the separatrix. Neoclassical transport calculations from NEO and non-linear gyrokinetic calculations using CGYRO are consistent with these observations and show that while neoclassical transport plays an important role, the turbulent ion heat flux due to ion scale electrostatic turbulence is significant and can contribute similar or larger ion heat fluxes at lower collisionality. Beam emission spectroscopy and Doppler backscattering measurements in the steep gradient region of the H-mode pedestal reveal increased broadband, long-wavelength ion scale fluctuations for the low $v^*_i$ discharges at the radius where the non-linear CGYRO simulations were run. Taken together, increased fluctuations, power balance calculations, and gyrokinetic simulations show that the above neoclassical ion heat fluxes, including the increases at lower $v^*_i$, are likely due to weakly suppressed ion scale electrostatic turbulence. These new results are based on world first inferred ion and electron heat fluxes in the pedestal region of deuterium plasmas using direct measurements of the deuterium temperature for power balance across ion collisionalities covering an order of magnitude from high $v^*_i$ values of 1.3 down to ITER relevant $v^*_i$ ~0.1.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Experimental characterization of a section of a spherically imploding plasma liner formed by merging hypersonic plasma jets

In this work, we report experimental results on merging of hypersonic plasma jets, which is the fundamental building block for forming spherically imploding plasma liners as a potential standoff compression driver for magneto-inertial fusion. Jets are formed and launched by contoured-gap coaxial plasma guns mounted at the six vertices and the center of a hexagon covering approximately one-tenth of the surface area of a 9-ft-diameter spherical chamber. First, from experiments with two and three merging jets of four different species (N, Ar, Kr, and Xe), we show that (1) density spatial non-uniformities can be large (with electron-density jumps ranging from 2.9 for N to 6.6 for Xe) when shocks form upon jet merging, but smaller (density jumps <2) when shocks do not form; (2) jet impurities (20% Ti in these experiments) can increase the level of density spatial non-uniformity by increasing the collisionality of jet merging, leading to shock formation rather than potentially more desirable shockless jet merging; and (3) the liner Mach number can remain high (≳10), as required for plasma liners to be an effective compression driver. Secondly, from experiments with six and seven merging jets using Ar, we present results with improved jet-to-jet mass balance of <2% across jets, including (1) evidence of substantially increased balance in the jet merging and symmetry of the liner structure and (2) potentially favorable changes in the jet-merging morphology with the addition of the seventh jet. Ultimately, for both experiments, we present comparisons between experimental and synthetic data from three-dimensional hydrodynamic codes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Flow Z-pinch plasma production on the FuZE experiment

The Fusion Z Pinch Experiment (FuZE) investigates sheared-flow stabilization of classic m = 0 and m = 1 instabilities in Z pinches with an embedded axial flow. FuZE consists of a 100 cm coaxial plasma accelerator, where neutral gas is ionized and accelerated in a pulsed electrical discharge, followed by a 50 cm assembly region, where pinches are formed. Maintaining the pinch requires continuous plasma injection provided by a deflagration mode in the coaxial accelerator. Two discharge modes, with and without deflagration, are investigated on FuZE. Pinch formation is observed with deflagration only. Plasma velocities in the assembly region are found to match the E × B velocity estimated in the accelerator based on a 1D circuit model, indicating that a 1D MHD approximation may offer a valid description of the plasma in the accelerator channel. The velocity of magnetic field propagation is found to agree with the snowplow model based on momentum conservation, and the lifetime of the pinch is shown to be in agreement with constraints imposed by mass conservation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Measurement of ion temperature and toroidal flow during magnetic reconnection with a large guide field

Here, ion temperature and toroidal flow along the guide field direction are measured using a new ion tomographic diagnostic on the Magnetic Reconnection eXperiment (MRX) during magnetic reconnection with a guide field strength of about 1.4 and 2.1 times the strength of the reconnecting component. Strong toroidal flows, beyond what has been measured in anti-parallel and lower guide field conditions on MRX, are observed. Sustained ion heating with no discernible structure within the measurement region is also observed. Probe measurements including Langmuir and Mach probe measurements are made to support the tomographic inversion of line-integrated measurements, as well as to provide local measurements of plasma parameters. Measurements of toroidal velocity and ion temperature are supported with time series data. Energy flow into and out of the X-line region is estimated using a guiding center framework and presented in the Appendix of this manuscript, suggesting an outsized role played by parallel electric field in energizing ions. The guiding center approximation is not well satisfied in the region of interest; however, the estimates provide a springboard for future, further experimentation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Decoupling of peeling and ballooning thresholds for pedestal stability and reduction in ELM frequency via enhanced turbulence with edge electron cyclotron heating in DIII-D

Abstract The edge localized mode (ELM) frequency ( f ELM ) decreased by 63% when electron cyclotron heating (ECH) deposition location is shifted from ρ = 0.4 to ρ = 0.8 in DIII-D discharges where the power ratio between neutral beam injection (NBI) and ECH ( P NBI / P ECH ) is kept at ∼1. The performance of the pedestal in the ECH heated case is compared with a pure NBI reference discharge while keeping the total input power constant. All these discharges are performed at balanced input torque conditions. Furthermore, in the pure NBI discharge a strong decoupling of the peeling–ballooning (PB) thresholds is observed. The PB decoupling is preserved when the ECH is deposited at ρ = 0.8 and P NBI / P ECH ∼ 1, while the thresholds manifest a closed stability boundary when the ECH is deposited at ρ = 0.4. The inter-ELM pedestal recovery time is considerably larger for the ECH at ρ = 0.8 case. Increased pedestal turbulence is observed in beam emission spectroscopy (BES), Doppler backscattering and magnetic diagnostics for the ECH at the ρ = 0.8 case. Strong growth of a TEM-like mode is observed in BES and the mode growth is correlated with the decrease in f ELM . In view of these observations, the increased pedestal turbulence seems to be the plausible reason behind the delayed pedestal recovery following an ELM event in the ECH at ρ = 0.8 case, and the preservation of PB decoupling through temperature pedestal profile widening. TRANSP interpretative simulations show that the ECH at the ρ = 0.8 case is more susceptible to ITG/TEM turbulence.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Comparison of Doppler back-scattering and charge exchange measurements of E × B plasma rotation in the DIII-D tokamak under varying torque conditions

Measurements of the E × B toroidal angular velocity, $\omega_{E \times B}\,=\,E_\mathrm{r}/RB_\theta$ ($E_\mathrm{r}$ is the radial electric field, B θ is the poloidal magnetic field), are made using the Doppler back-scattering (DBS) and charge-exchange recombination (CER) spectroscopy diagnostics. DBS uses the Doppler shift of wavenumber-resolved density fluctuations while CER uses the Doppler shift of impurity emission lines to independently measure plasma parameters for calculating the local radial electric field. DBS and CER profiles of $\omega_{E \times B}$ as a function of normalized toroidal flux (ρ) are compared at various levels of neutral beam applied torque on the plasma. Under standard neoclassical theory $\omega_{E\times B}$ is a flux surface quantity, making it appropriate to compare across diagnostics. DBS and CER generally show good agreement when comparing $\omega_{E \times B}$ profiles at different levels of neutral beam injection-applied torque. Furthermore, the DBS values have close to the same precision as CER values when averaged over a similar time-scale and effects, such as prompt-torque are considered. DBS is able to observe the rapid ($\lt$10 ms) modification of the $E_\mathrm{r}$ profile by the diagnostic neutral beam 'blips'. This modification is most pronounced when the blip applies a large relative change in torque on the plasma. Overall, these results could have implications on transport analysis and suggests using DBS and CER in conjunction to constrain values of the E × B-shear (sometimes called $\gamma_{E \times B}$).

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Precision spectroscopy of fast, hot, exotic isotopes using machine-learning-assisted event-by-event Doppler correction

We propose an experimental scheme for performing sensitive, high-precision laser spectroscopy studies on fast exotic isotopes. By inducing a stepwise resonant ionization of the atoms traveling inside an electric field and subsequently detecting the ion and the corresponding electron, time-, and position-sensitive measurements of the resulting particles can be performed. Using a mixture density network, we can leverage this information to predict the initial energy of individual atoms and thus apply a Doppler correction of the observed transition frequencies on an event-by-event basis. We conduct numerical simulations of the proposed experimental scheme and show that kHz-level uncertainties can be achieved for ion beams produced at extreme temperatures ( > 10 8 K), with energy spreads as large as 10 keV and nonuniform velocity distributions. The ability to perform in-flight spectroscopy, directly on highly energetic beams, offers unique opportunities to study short-lived isotopes with lifetimes in the millisecond range and below, produced in low quantities, in hot and highly contaminated environments, without the need for cooling techniques. Such species are of marked interest for nuclear structure, astrophysics, and new physics searches. Published by the American Physical Society 2024

Udrescu, S. M. (ORCID:000000021989576X)↗
DOE OSTI2025

High-resolution spectroscopy of uranium laser-produced plasma using saturated absorption spectroscopy

High-resolution spectroscopy of laser ablation plumes or laser-produced plasmas (LPPs) is valuable for various applications, including measuring crowded spectral features, determining spectroscopic constants, characterizing plasmas, and performing isotopic analysis. However, various line broadening mechanisms in plasmas limit its use for several applications. Here, in this study, we present the use of saturated absorption spectroscopy (SAS) for Doppler-free linewidth analysis in a uranium LPP. We demonstrate that SAS is effective in obtaining Doppler-free Lamb dip profiles with linewidths on the order of ≤ 20 MHz. The effects of saturation on the Doppler-broadened absorption and Lamb dip profiles at different pressures and probe intensities are quantified, and their impact on measurements of plasma properties is discussed. Finally, we show that the linewidths of the Lamb dips can be used for quantitative estimates of pressure and natural broadening in the plasma.

Absorption spectroscopy↗
DOE OSTI2025

Influence of Water, Vacuum, and Temperature on Surface Conditions of a Zeolite‐based Molecular Sieve

Molecular sieves such as zeolite-based materials are ubiquitous in industrial separation processes. However, there is a significant gap in understanding the surface properties and adsorption mechanisms for commercial zeolites, as most research focuses on pure zeolite powders rather than industrially relevant forms. Here, this work addresses this gap in understanding by employing advanced characterization techniques, including positron annihilation spectroscopy, X-ray diffraction, scanning electron microscopy, X-ray fluorescence spectroscopy, X-ray photoelectron spectroscopy, liquid nitrogen sorption, and Fourier-transform infrared spectroscopy, to investigate the adsorption and desorption behavior of water in commercial zeolite 13X. Our research reveals insights into the pore-filling mechanisms, the impact of material binders on adsorption properties, and the dynamics of hydration and drying processes for zeolites. Monitoring changes on a minute scale allowed the distinction between fast and slow processes leading to sample drying. The identification of positronium bound to Na + ions indicated that water molecules remain in the vicinity of Na + ions after air-drying zeolite 13X. These findings highlight the importance of various environmental conditions in restoring zeolite properties to baseline after hydration, with significant implications for optimizing industrial processes. This work sets the direction for further research aimed at developing more efficient and robust separation techniques.

Beads Binder↗
DOE OSTI2024

Wavelength modulation laser-induced fluorescence for plasma characterization

Laser-Induced Fluorescence (LIF) spectroscopy is an essential tool for probing ion and atom velocity distribution functions (VDFs) in complex plasmas. VDFs carry information about the kinetic properties of species that is critical for plasma characterization. Accurate interpretation of these functions is challenging due to factors such as multicomponent distributions, broadening effects, and background emissions. Our research investigates the use of Wavelength Modulation (WM) LIF to enhance the sensitivity of VDF measurements. Unlike standard Amplitude Modulation (AM) methods, WM–LIF measures the derivative of the LIF signal. This approach makes variations in VDF shape more pronounced. VDF measurements with WM–LIF were investigated with both numerical modeling and experimental measurements. The developed model enables the generation of both WM and AM signals, facilitating comparative analysis of fitting outcomes. Experiments were conducted in a weakly collisional argon plasma with magnetized electrons and non-magnetized ions. Measurements of the argon ion VDFs employed a narrow-band tunable diode laser, which scanned the 4p 4 D 7/2 –3d 4 F 9/2 transition centered at 664.553 nm in vacuum. A lock-in amplifier detected the second harmonic WM signal, which was generated by modulating the laser wavelength with an externally controlled piezo-driven mirror of the diode laser. Finally, our findings indicate that the WM–LIF signal is more sensitive to fitting parameters, allowing for better identification of VDF parameters such as the number of distribution components, their temperatures, and velocities. In addition, WM–LIF can serve as an independent method to verify AM measurements and is particularly beneficial in environments with substantial light noise or background emissions, such as those involving thermionic cathodes and reflective surfaces.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Lifetime measurements of excited states in 15 O

The CNO cycle is the main energy source in stars more massive than our Sun, it defines the energy production and the cycle time that lead to the lifetime of massive stars, and it is an important tool for the determination of the age of globular clusters. One of the largest uncertainties in the CNO chain of reactions comes from the uncertainty in the 14 N(p,γ) 15 O reaction rate. This uncertainty arises predominantly from the uncertainty in the lifetime of the subthreshold state in 15 O at E x = 6792 keV. Previous measurements of this state's lifetime are significantly discrepant. Here, we report on a new lifetime measurement of this state, as well as the excited states in 15 O at E x = 5181 keV and E x = 6172 keV, populated via the 14 N(p,γ) 15 O reaction at proton energies of E p = 1020 keV and E p = 1570 keV. Furthermore, the lifetimes have been determined with the Doppler-Shift Attenuation Method (DSAM) with three separate, nitrogen-implanted targets with Mo, Ta, and W backing. We obtained lifetimes from the weighted average of the three measurements, allowing us to account for systematic differences between the backing materials. For the 6792 keV state, we obtained a τ = 0.6 ± 0.4 fs. To provide cross-validation of our method, we measured the known lifetimes of the states at 5181 and 6172 keV to be τ = 7.5 ± 3.0 and τ = 0.7 ± 0.5 fs, respectively, in good agreement with previous measurements.

6 ≤ A ≤ 19↗
DOE OSTI2021

Coincidence Doppler Broadening Analysis Program

A graphical user interface (GUI) that helps analyze data from coincidence Doppler broadening positron annihilation spectroscopy. It is a quick tool to rapidly reduce large data and conveniently analyze multiple datasets.

Watkins, JosephM.↗
DOE OSTI2025

Measurement and analysis of the Doppler broadened energy spectra of gamma radiation originating from the annihilation of positrons incident on clean and adsorbate-covered surfaces

We present measurements and theoretical modeling demonstrating the capability of coincidence Doppler broadened (CDB) annihilation gamma spectroscopy to provide element-specific information from the topmost atomic layer of surfaces. Our measurements show that the energy spectra of Doppler-shifted annihilation gamma photons emitted following the annihilation of positrons from the topmost atomic layers of clean and adsorbate covered surfaces of gold (Au), silver (Ag) and copper (Cu) differ significantly. The shape of the Doppler-broadened gamma spectrum, as analyzed using ratio curves, indicates that the elemental composition of the surface can still be identified despite contributions from positronium annihilation and a significant reduction in core electron annihilation. We estimate the chemical composition of the various probed surfaces by modeling the ratios of the measured Doppler spectra with respect to the Doppler spectra from a clean Cu surface using a linear combination of calculated ratio curves. The fitting of the experimental ratio curves was used to obtain an estimate of the elemental composition of Cu surfaces with sulfur segregation, oxygen adsorption, a thin film of Selenium (Se), and a single layer of graphene (SLG). A similar analysis was performed on the Ag surface with environmental adsorbates, the same surface after argon ion sputtering, as well as a sputter cleaned Au surface. The surface compositions obtained from the analysis of the CDB data were compared to the compositions obtained using positron annihilation induced Auger electron spectroscopy (PAES). Our results show that CDB can detect, identify, and quantify, sub-monolayer adsorbates and a single atomic layer deposited on metal substrates.

Lotfimarangloo, Sima [Univ. of Texas, Arlington, T↗
DOE OSTI2021

TOI 540 b: A Planet Smaller than Earth Orbiting a Nearby Rapidly Rotating Low-mass Star

We present the discovery of TOI 540 b, a hot planet slightly smaller than Earth orbiting the low-mass star 2MASS J05051443-4756154. The planet has an orbital period of P = 1.239149 days (±170 ms) and a radius of r=0.903±0.052R{sub ⊕}, and is likely terrestrial based on the observed mass–radius distribution of small exoplanets at similar insolations. The star is 14.008 pc away and we estimate its mass and radius to be M=0.159±0.014 M{sub ⊙} and R=0.1895±0.0079R{sub ⊙}, respectively. The star is distinctive in its very short rotational period of P{sub rot}=17.4264±0.0094 hr and correspondingly small Rossby number of 0.007 as well as its high X-ray-to-bolometric luminosity ratio of L{sub X}/L{sub bol}=0.0028 based on a serendipitous XMM-Newton detection during a slew operation. This is consistent with the X-ray emission being observed at a maximum value of L{sub X}/L{sub bol}≃10{sup −3} as predicted for the most rapidly rotating M dwarfs. TOI 540 b may be an alluring target to study atmospheric erosion due to the strong stellar X-ray emission. It is also among the most accessible targets for transmission and emission spectroscopy and eclipse photometry with the James Webb Space Telescope, and may permit Doppler tomography with high-resolution spectroscopy during transit. This discovery is based on precise photometric data from the Transiting Exoplanet Survey Satellite and ground-based follow-up observations by the MEarth team.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗