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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

M/P Ratios—A Call for Consistency

This is an article for the Illuminating Engineering Society's LD+A magazine. It addresses Melanopic/Photopic ratios, a metric that roughly calculates the portion of the visible spectrum from a light source that contributes to the ipRGC response, relative to the traditional photopic response. The paper explains weighting functions, and that there are four ways to calculate M/P ratios. These four methods produce different values, so it is incumbent on recommendations for M/P ratios (usually for health-related design) to list the method to use. Better still, the lighting and medical communities should standardize on one approach.

M/P ratios, melanopic/photopic ratios, spectral we↗
DOE OSTI2025

Exploring the Effects of Varying Pre-Chamber Geometry in a Heavy-Duty Natural Gas Optical Engine under Dilution Conditions

Pre-chamber combustion is an advanced ignition strategy that has been shown to enhance spark ignition (SI) combustion stability in natural gas (NG) engines by providing distributed ignition sites from turbulent jets and enhancing main-chamber turbulence. Pre-chamber combustion has been proven especially advantageous compared to SI in ultra-lean and dilute operating conditions. This work involves experimental investigation of the effects of varying passive pre-chamber nozzle configuration on pre-chamber and main chamber combustion under simulated exhaust gas recirculation (EGR) dilution (0 and 20%) conditions in a heavy-duty, single-cylinder, optically accessible NG engine at stoichiometric fuel-air ratio. Pre-chamber nozzle configurations include four pre-chambers with constant nozzle area to pre-chamber volume ratio (A/V) with different nozzle sizes and orientations and one configuration with larger nozzles. The optical engine is operated in a skip-fire sequence consisting of 18 motored cycles followed by two consecutive fired cycles to elucidate the effect of combustion residuals (internal EGR) on combustion evolution. Pressure-based diagnostics are used to monitor pre-chamber and subsequent main chamber combustion, and optical diagnostics include high-speed OH* chemiluminescence to visualize the development of pre-chamber jets and the resulting ignition of the main chamber charge. Heat release analysis of the in-cylinder pressure data indicates that a faster pre-chamber pressure rise does not always translate into faster main-chamber combustion. The pre-chamber with the smallest nozzle diameter produced the highest pre-chamber pressure rise and fastest combustion under non-diluted conditions. However, dilution delays the main chamber ignition for smaller nozzles despite a comparable rise in pre-chamber pressure compared to configurations with larger nozzles. This effect is more pronounced for cycles with in-cylinder combustion residuals in addition to external dilution. Additionally, it was observed that pre-chambers with swirling nozzles have a faster pressure rise in the pre-chamber and main chamber under dilute conditions. Optical diagnostics suggest that the main reason for the delay between the pre-chamber pressure rise and main-chamber combustion lies in jet quenching and delayed re-ignition, which can even lead to misfire if jets emitted from small nozzles combined with dilution fail to re-ignite.

Dhotre, Akash [University Of Minnesota-Twin Cities↗
DOE OSTI2021

Release-to-Birth Ratios for AGR-5/6/7 Operating Cycles 162B–168A

This engineering calculations and analysis report (ECAR) documents the release-to-birth ratios of the Advanced Gas Reactor (AGR) experiment, AGR-5/6/7, which was irradiated in the Advanced Test Reactor (ATR) Northeast Flux Trap from February 16, 2018 to July 22, 2020.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

A review of zirconia oxygen, NO x , and mixed potential gas sensors – History and current trends

Zirconia-based electrochemical sensors have revolutionized oxygen monitoring and combustion control. Here, these robust, solid-state devices are found in virtually every internal combustion engine today providing feedback information for tight air to fuel ratio control thus minimizing unwanted emissions and improving engine efficiency. Variations on the sensor design and operational mode enable the measurement of nitrogen oxides to part per million levels, providing control information for exhaust after-treatment systems. Emerging designs include the development of "gas analyzers on a chip" capable of monitoring oxygen, carbon monoxide, nitrogen oxides, ammonia and hydrocarbons.

47 OTHER INSTRUMENTATION↗
DOE OSTI2025

Comparison of a Full-Scale and a 1:10 Scale Low-Speed Two-Stroke Marine Engine Using Computational Fluid Dynamics

International marine shipping is a growing component of international trade; a vast majority of all the world’s goods are being transported on large ocean-going vessels. The International Maritime Organization (IMO) introduced the Energy Efficiency Design Index in 2013, a regulatory framework of associated metrics for reducing emissions of CO 2 per tonne-mile from shipping by approximately 10% each decade. Therefore, decarbonizing the maritime sector requires the development of new fuel sources. Because of the extremely large physical size of the internal combustion engines present in shipping vessels, experimental iterative development of the engine and fuel system is cost-prohibitive. Thus, the ability to perform combustion system development in a scaled platform that can be more easily operated and modeled computationally is of interest. To that end, scaling relationships are needed to translate the results from a smaller engine to a larger counterpart. Scaling studies to date have been restricted to low scaling ratios, four-stroke light-duty engines, and under-resolved computational fluid dynamic simulations that likely do not accurately capture the physics of scaling. In this work, computational models of a 1:10 scale and a full-scale two-stroke crosshead low-speed marine engine were created and validated against experiments obtained in a real 1:10 scale engine installed at Oak Ridge National Laboratory. Further, due to the large size of the full-scale engine, the model required large high-performance computing resources to be evaluated. The availability of high-performance computing resources at the Department of Energy’s Leadership Computing Facilities is an enabler of the current work. The results of the small- and large-scale engine simulations were compared to analyze the effectiveness of the appropriate scaling laws under these extreme scaling ratio conditions.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2025

Chemo-Mechanical Behavior and Stability of High-Loading Cathodes in Solid-State Batteries

Solid-state batteries can offer higher energy density and improved safety compared to lithium ion batteries, which use flammable liquid electrolytes. Increasing the ratio of cathode active materials in composite cathodes enhances the energy density and reduces manufacturing costs. Changes in the ratio of cathode active materials alter the microstructure and chemo-mechanical response of a cathode during operation. Understanding the relationship between composition, microstructure, and chemo-mechanical interactions is critical for optimizing solid-state cathodes. Here, in this study, we engineered composite cathodes with varying ratios of LiNi 0.8 Co 0.1 Mn 0.1 O 2 and Li 6 PS 5 Cl to systematically investigate the role of microstructural evolution in long-term chemo-mechanical transformations. Chemo-mechanical stresses resulting from the volume changes of the cathode active materials led to degradation mechanisms, such as fracture and interfacial delamination. Active material fracture and delamination led to underutilization of active material and significant capacity decay during cycling. Coatings that suppress active material-active material interactions during cycling may aid in suppressing the generation of local stress hotspots.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Evaluation of Distributed Power Apportioning with Net Load Management Engine in Microgrids Using Power Hardware-in-the-Loop Simulation

This article presents the performance evaluation of ratio consensus-based distributed power apportioning engine along with centralized net load management (NLM) engine that ensures viable and stable operation of an islanded microgrid. Managing net load variability in a microgrid with high penetrations of uncertain renewable generation and ever-changing load demands is a crucial need in order to ensure viable and stable operation of the microgrid. Centralized “dispatch-rule”-based and/or multi-agent-based distributed control of distributed energy resources (DERs) in microgrid are well accepted for microgrid by adapting ANSI/ISA-95-based hierarchical control architecture. In the application where microgrid network has large geographical span with multiple DERs dispersed in the network, high penetration of uncertain renewable energy resources, and ever-changing load demands, a judicious selection of techniques/solutions for managing net-load resources for maintaining viability and stability is required. With this motivation, this article proposes a novel solution to mitigate the challenges by incorporating a mixed centralized NLM engine and distributed power apportioning control of DERs and loads. A power-hardware-in-the-loop (PHIL) -based experiment is conducted with the centralized NLM engine and the distributed power apportioning engine along with two commercial inverters. The experimental results validates the efficacy of the proposed method in ensuring viability and stability of a microgrid.

hardware-in-the-loop simulation↗
DOE OSTI2021

The development of a Sustained High Power Density (SHPD) facility

A Sustained High Power Density (SHPD) facility is being planned within the U.S. as a non DT device which can be a bridge to a Compact Fusion Pilot Plant (CFPP) DT operated facility with the future capacity to produce a levelised cost of electricity at a rate competitive with current power generating systems. To accomplish this a review of ITER cost data and recent next step physics/engineering studies that promoted technology development, physics enhancements and innovated configuration improvements that increase operating availability have been injected into a proposed PPPL SHPD design. Much of the physics and engineering design basis for this effort centers on a series of ST studies carried out in recent years attempting to maximize the low aspect ratio (AR) ST performance within realistic engineering constraints of this compact fusion device. One issue found in the low AR design is the lack of volt-seconds generated by a small central solenoid that resides in the available space left after sizing the TF structure to support the high current density/HTS TF coil. Although not required in a larger pilot plant device, a solenoid wrapped around the plasma side of the SC TF coil was considered for the small low aspect ratio SHPD device. Adding a solenoid to the plasma side of the TF imposes a major change to the device configuration – a change which has been found to have cost and assembly issues when compared with an OH solenoid located at the machine center. Finally, the inclusion of a liquid metal first wall divertor system, the integration of local pairs of outboard DCLL blanket segments and a summary of physics performance conditions will be presented.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Fabrication of bulk alumina structures with humidity sensing capabilities using direct ink write technique

Purpose The purpose of this study is to evaluate different 3D structures for humidity sensing that will enable the fabrication of complex geometries with high moisture sensitivity. Design/methodology/approach Humidity sensors based on alumina ceramics were fabricated using direct ink write (DIW) technique. Different engineered surface area, polymer binder ratio and post-processing treatment were considered to increase moisture sensitivity. Findings It was found that the binder ratio plays an important role in controlling the rheology of the paste during printing and determining the pore size after post-processing treatment. The sensibility of the fabricated humidity sensor was investigated by measuring its capacitance response toward relative humidity (RH) varying from 40% to 90% RH at 25°C. It is shown that using 3D lattice design, printed alumina humidity sensor could improve sensitivity up to 31.6 pF/RH%, over an order of magnitude higher than solid alumina. Originality/value Most of the alumina humidity sensors available are films in nature because of manufacturing difficulties, which limited its potential of higher sensitivity, and thus broader applications. In this paper, a novel 3D alumina humidity sensor was fabricated using DIW 3D printing technology.

Engineering↗
DOE OSTI2025

Embedded 3D printing of isotropically enhanced lattice structure with programmable elasticity via three-dimensional fiber alignment

Engineered composites with fiber orientation in a complete three-dimensional (3D) context are highly desired for maximizing structural performance as they mimic the well-organized fiber arrangement in natural composites. However, most fabrication techniques lack the capability for through-plane (z-axis) alignment, limiting the possibility for structural design and performance optimization. In this study, we present an embedded 3D printing approach that enables complete 3D fiber alignment, including region-specific alignment control along the through-plane direction. Our method utilizes the extrusion and suspension of composite inks within a supporting matrix. By regionally adjusting the ink extrusion rate and nozzle translation rate, we locally manipulated the fiber arrangement within the composite 3D architecture. Here, we demonstrate that the 3D alignment of carbon fibers in a structural composite significantly enhances both mechanical properties and thermal conductivity in the in-plane and through-plane directions. Furthermore, by strategically arranging regional fiber orientations within micro-architected materials, we fabricated metamaterial engineered composites with programmable anisotropy ratio and directional moduli.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Colloidal AInSe 2 (A = K, Rb, Cs) Nanocrystals with Tunable Crystal and Band Structures

Wide band gap AInSe 2 (A = K, Rb, Cs) is an important interlayer material for improving the efficiency of Cu(In,Ga)(S,Se) 2 (CIGS) solar cells. Compared to high-vacuum deposition and solid-state synthesis, a less energyintensive method is of interest for its fabrication. Herein, we present the rapid, low-temperature colloidal synthesis of AInSe 2 nanocrystals that opens a pathway for convenient solution processing. The crystal structures and electronic band structures of the nanocrystals were studied, and their particle morphology was found to be dependent on the choice of alkali metal and selenium precursors. Homogeneous solid solution (K,Rb,Cs)InSe 2 nanocrystals were synthesized using a mixture of alkali metal precursors. Their compositions, lattice parameters, and band gaps were easily tuned based on the K:Rb:Cs precursor ratio, providing potential for interface engineering of CIGS nanocrystal-based solar cells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Multi-Defect Detection in Additively Manufactured Lattice Structures Using 3D Electrical Resistance Tomography

Cellular lattice structures possess high strength-to-weight ratios suitable for advanced lightweight engineering applications. However, their quality and mechanical performance can degrade because of defects introduced during manufacturing or in-service. Their complexity and small length scale features make defects difficult to detect using conventional nondestructive evaluation methods. Here we propose a current injection-based method, electrical resistance tomography (ERT), that can be used to detect damaged struts in conductive cellular lattice structures with their intrinsic electromechanical properties. The reconstructed conductivity distributions from ERT can reveal the severity and location of damaged struts without having to probe each strut. However, the low central sensitivity of ERT may result in image artifacts and inaccurate localization of damaged struts. To address this issue, this study introduces an absolute, high throughput, conductivity reconstruction algorithm for 3D ERT. The algorithm incorporates a strut-based normalized sensitivity map to compensate for lower interior sensitivity and suppresses reconstruction artifacts. Numerical simulations and experiments on fabricated representative cellular lattice structures were performed to verify the ability of ERT to quantitatively identify single and multiple damaged struts. The improved performance of this method compared with classical ERT was observed, based on greatly decreased imaging and reconstructed value errors.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Hydrokinetic energy conversion using flow induced oscillations of single-cylinder with large passive turbulence control

Various types of flow-induced oscillations (FIOs) have been implemented in development of marine hydrokinetic (MHK) energy converters. With passive turbulence control (PTC), energy harvesting starts at a flow speed of about 0.5 m/s. However, there is worldwide MHK energy available in even slower currents. In the present study, the effect of damping on FIO and power extraction is investigated for a converter with large turbulence stimulation (PTC) consisting of straight strips with a height of 15% of the cylinder diameter and placed symmetrically on the cylinder surface. The oscillating amplitude decreases, as the damping ratio increases, with unchanged sinusoidal pattern of the displacement time-history. The frequency ratio is also affected by damping especially in the VIV initial branch and transition region between VIV and galloping. An important flow characteristic of the large-PTC cylinder is that a recirculation region is formed behind the PTC, causing appreciable disturbance to the flow past the cylinder. Power can be harvested in the whole FIO range and the harnessed power maximum appears at the largest inflow velocity tested. However, the optimum of harnessing efficiency is located at the beginning of the VIV upper branch. The gap between VIV and galloping is bridged when large PTC is used, eliminating the drop in power and efficiency even at higher damping, which would be a weakness of regular-PTC cylinder for energy harvesting. Finally, the mechanism behind the variation of harnessing efficiency with inflow velocity and damping ratio is revealed, and the optimality criterion for the converter design is discussed.

16 TIDAL AND WAVE POWER↗
DOE OSTI2021

Conducting thermal energy to the membrane/water interface for the enhanced desalination of hypersaline brines using membrane distillation

Membrane distillation (MD) is a membrane-based thermal desalination process capable of treating hypersaline brines. Standard MD systems rely on preheating the feed to drive the desalination process. However, relying on the feed to carry thermal energy is limited by a decline of the thermal driving force as the water moves across the membrane, and temperature polarization. In contrast, supplying heat directly into the feed channel, either through the membrane or other channel surfaces, has the potential of minimizing temperature polarization, increasing single-pass water recoveries, and decreasing the number of heat exchangers in the system. When solar thermal energy can be utilized, particularly if the solar heat is optimally delivered to enhance water evaporation and process performance, MD processes can potentially be improved in terms of energy efficiency, environmental sustainability, or operating costs. Here we describe an MD process using layered composite membranes that include a high-thermal-conductivity layer for supplying heat directly to the membrane-water interface and the flow channel. Here, the MD system showed stable performance with water flux up to 9 L/m 2 /hr, and salt rejection >99.9% over hours of desalinating hypersaline feed (100 g/L NaCl). In addition to bench-scale system, we developed a computational fluid dynamics model that successfully described the transport phenomena in the system.

42 ENGINEERING↗
DOE OSTI2023

Engineering custom morpho- and chemotypes of Populus for sustainable production of biofuels, bioproducts, and biomaterials

Humans have been modifying plant traits for thousands of years, first through selection (i.e., domestication) then modern breeding, and in the last 30 years, through biotechnology. These modifications have resulted in increased yield, more efficient agronomic practices, and enhanced quality traits. Precision knowledge of gene regulation and function through high-resolution single-cell omics technologies, coupled with the ability to engineer plant genomes at the DNA sequence, chromatin accessibility, and gene expression levels, can enable engineering of complex and complementary traits at the biosystem level. Populus spp., the primary genetic model system for woody perennials, are among the fastest growing trees in temperate zones and are important for both carbon sequestration and global carbon cycling. Ample genomic and transcriptomic resources for poplar are available including emerging single-cell omics datasets. To expand use of poplar outside of valorization of woody biomass, chassis with novel morphotypes in which stem branching and tree height are modified can be fabricated thereby leading to trees with altered leaf to wood ratios. These morphotypes can then be engineered into customized chemotypes that produce high value biofuels, bioproducts, and biomaterials not only in specific organs but also in a cell-type-specific manner. For example, the recent discovery of triterpene production in poplar leaf trichomes can be exploited using cell-type specific regulatory sequences to synthesize high value terpenes such as the jet fuel precursor bisabolene specifically in the trichomes. By spatially and temporally controlling expression, not only can pools of abundant precursors be exploited but engineered molecules can be sequestered in discrete cell structures in the leaf. The structural diversity of the hemicellulose xylan is a barrier to fully utilizing lignocellulose in biomaterial production and by leveraging cell-type-specific omics data, cell wall composition can be modified in a tailored and targeted specific manner to generate poplar wood with novel chemical features that are amenable for processing or advanced manufacturing. Precision engineering poplar as a multi-purpose sustainable feedstock highlights how genome engineering can be used to re-imagine a crop species.

09 BIOMASS FUELS↗
DOE OSTI2021

Assessment of Turbulent Combustion Models for Simulating Prechamber Ignition in a Natural Gas Engine

Lean combustion is a promising strategy to increase thermal efficiency in an internal combustion engine, by exploiting a favorable specific heat ratio of the fresh mixture while simultaneously suppressing the heat losses to the cylinder wall. However, unstable ignition and slow flame propagation at fuel-lean conditions lead to large cycle-to-cycle variability and limit the high-efficiency engine operating range. Prechamber ignition is considered an effective concept to extend the lean operating limit, by providing spatially distributed ignition with multiple turbulent flame-jets and enabling a faster combustion rate compared to the conventional spark ignition approach. From a numerical modeling standpoint to date science base and available simulation tools are inadequate to properly understand and predict the combustion processes in prechamber ignited engines. In this paper, conceptually different Reynolds-averaged Navier–Stokes (RANS) combustion models widely adopted in the engine modeling community are used to simulate the ignition and combustion processes in a medium-duty natural gas engine with a prechamber spark-ignition system. Here, a flamelet-based turbulent combustion model, i.e., G-equation, and a multizone well-stirred reactor model are employed for this modeling study. Simulation results are compared with experimental data in terms of in-cylinder pressure and heat release rate. Finally, the analysis of the performance of the two models is carried out to highlight the strengths and limitations of the two evaluated approaches.

42 ENGINEERING↗
DOE OSTI2022

A novel hardmask-to-substrate pattern transfer method for creating 3D, multi-level, hierarchical, high aspect-ratio structures for applications in microfluidics and cooling technologies

Abstract This letter solves a major hurdle that mars photolithography-based fabrication of micro-mesoscale structures in silicon. Conventional photolithography is usually performed on smooth, flat wafer surfaces to lay a 2D design and subsequently etch it to create single-level features. It is, however, unable to process non-flat surfaces or already etched wafers and create more than one level in the structure. In this study, we have described a novel cleanroom-based process flow that allows for easy creation of such multi-level, hierarchical 3D structures in a substrate. This is achieved by introducing an ultra-thin sacrificial silicon dioxide hardmask layer on the substrate which is first 3D patterned via multiple rounds of lithography. This 3D pattern is then scaled vertically by a factor of 200–300 and transferred to the substrate underneath via a single shot deep etching step. The proposed method is also easily characterizable—using features of different topographies and dimensions, the etch rates and selectivities were quantified; this characterization information was later used while fabricating specific target structures. Furthermore, this study comprehensively compares the novel pattern transfer technique to already existing methods of creating multi-level structures, like grayscale lithography and chip stacking. The proposed process was found to be cheaper, faster, and easier to standardize compared to other methods—this made the overall process more reliable and repeatable. We hope it will encourage more research into hybrid structures that hold the key to dramatic performance improvements in several micro-mesoscale devices.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2025

Neutronics analysis of spin-polarized fuel in spherical tokamaks

The effect of spin-polarized deuterium–tritium fuel on the blanket, magnets, and surrounding structures is analyzed for a spherical tokamak fusion power plant. The focus of this paper is the neutron flux distribution in the fusion device and the corresponding engineering considerations, such as tritium breeding ratio (TBR) and magnet fluence. Significant benefits were found for anti-aligned polarization: a 2.7% increase in the total TBR (which could increase significantly with further optimization) and an approximately 68% increase in the magnet lifetime. If the inboard breeding blanket can be replaced with extra shielding and magnets, then it could significantly increase fusion power with no loss of magnet lifetime. This would be accomplished by increasing the toroidal field strength.

fusion↗