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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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31 records · Page 2

Measured electron contribution to Shuttle plasma environment: Abbreviated update

The differential energy spectra of electrons between 1 and 100 eV were measured by an electron spectrometer flown on an early shuttle. This energy range was scanned in 64 incremental steps with a resolution of 7%. The most striking feature that was observed throughout these spectra was a relatively flat distribution of the higher energy electrons out to 100 eV. This is in contrast to normal ambient spectra which consistently show a rapid decline in quantitative flux beyond 50 to 55 eV. The lower energy (1 to 2 eV) end of these spectra showed steep thermal trails comparable to normal ambient spectral structure. In general, daytime fluxes were significantly higher than those obtained during nighttime measurements. Quantitative flux excursions which may possibly be associated with thruster firing were frequently observed. Spectral structure suggestive of the N2 vibrational excitation energy loss mechanism was also seen in the data from some measurement periods. Examples of these spectra are shown and possible correlations are discussed.

Mcmahon, W.↗

Gasifiable carbon-graphite fibers

Fine, carbon-graphite fibers do not combust during the combustion of a composite and are expelled into the air as fine conductive particles. Coating of the fibers with a salt of a metal having a work function below 4.2 eV such as an alkaline earth metal salt, e.g., calcium acetate, catalytically enhances combustion of the fibers at temperatures below 1000.degree. C. such that the fibers self-support combustion and burn to produce a non-conductive ash. Fire-polishing the fibers before application of the coating is desirable to remove sizing to expose the carbon surface to the catalyst.

Humphrey, Marshall F.↗

CARVE: The Carbon in Arctic Reservoirs Vulnerability Experiment

The Carbon in Arctic Reservoirs Vulnerability Experiment (CARVE) is a NASA Earth Ventures (EV-1) investigation designed to quantify correlations between atmospheric and surface state variables for the Alaskan terrestrial ecosystems through intensive seasonal aircraft campaigns, ground-based observations, and analysis sustained over a 5-year mission. CARVE bridges critical gaps in our knowledge and understanding of Arctic ecosystems, linkages between the Arctic hydrologic and terrestrial carbon cycles, and the feedbacks from fires and thawing permafrost. CARVE's objectives are to: (1) Directly test hypotheses attributing the mobilization of vulnerable Arctic carbon reservoirs to climate warming; (2) Deliver the first direct measurements and detailed maps of CO2 and CH4 sources on regional scales in the Alaskan Arctic; and (3) Demonstrate new remote sensing and modeling capabilities to quantify feedbacks between carbon fluxes and carbon cycle-climate processes in the Arctic (Figure 1). We describe the investigation design and results from 2011 test flights in Alaska.

Arctic Carbon Cycle↗

Fire Protection Engineering Technical Report for Electric Vehicles and Lithium-Ion Batteries

This fire protection engineering technical report discusses and presents the properties, data, and safety of select lithium-ion batteries. Lithium-ion batteries have increased in usage and a fire scenario analysis must be created for each situation where they may be introduced in buildings to determine the risk associated if a battery failure were to occur.

25 ENERGY STORAGE↗

Degradation and Accelerated Recovery of Surface Passivation in n+, p+, and Intrinsic Poly-Si/SiOx Passivating Contacts for Silicon Solar Cells

We report on the degradation and recovery of surface passivation of fired poly-Si/SiOx passivating contacts with hydrogen containing Al2O3 during annealing in the dark and under illumination. Upon firing to a peak temperature of 670 degrees C, the iVoc for symmetric test structures with n+, p+, and intrinsic poly-Si/SiOx contacts decreases due to a loss of surface passivation. Upon further annealing over the temperature range of 200-350 degrees C in the dark, depending on the type of doping, the surface passivation either shows further degradation followed by recovery, or direct recovery to the initial iVoc. Annealing at higher temperatures and/or higher illumination intensities accelerates the kinetics for both degradation and recovery processes. We show that the degradation and recovery processes are thermally activated and proceed identically in subsequent firing and annealing steps showing their cyclic nature. We present a series reaction model to explain the kinetics of degradation and recovery processes for n+ and intrinsic poly-Si/SiOx contacts. By fitting the model's rate expressions to the data, the determined effective activation energy barriers for degradation and recovery for n+ poly-Si/SiOx contacts in the dark are 1.24 and 1.51 eV, which are lowered under 7.5 Suns illumination to 0.76 and 1.15 eV, respectively.

14 SOLAR ENERGY↗

Plasma diagnostics package assessment of the STS-3 orbiter environment and systems for science

Primary objectives of the Plasma Diagnostics Package (PDP) on STS-3 as part of the OSS-1 'Pathfinder' payload were to measure aspects of the Orbiter's induced environment and to utilize Orbiter crew and subsystems in the conduct of scientific investigations. Instrumentation temperatures were found to be within predicted limits, payload bay pressure varied from ambient up to 0.001 torr with thruster firings, EMI levels were found to be below worst case estimates, and V x B motional potentials were observed to vary + or - 5 V with respect to Orbiter ground. These parameters exhibited orbit-period modulation. Payload bay plasma varied in density and composition from ambient to a rarefied mixture with Orbiter-produced H2O(+). Energetic electrons and ions with energies up to 10's of eV were observed occasionally. Primary and vernier thrusters induce a momentary perturbation to the electron density, to the pressure and to the electric field with low energy ions and electrons occasionally produced. With the PDP on the RMS, both automode and manual modes were used to seek sources of EMI, to characterize the Orbiter's plasma wake and to measure beam-plasma phenomena.

Shawhan, S. D.↗

Performance of MODIS Thermal Emissive Bands On-orbit Calibration Algorithms

Two nearly identical copies of the Moderate Resolution Imaging Spectroradiometer (MODIS) are currently operated on-board the Terra and Aqua spacecrafts, launched in December 1999 and May 2002, respectively. Together, they have produced an unprecedented amount of science data products, which are widely used for the studies of changes in the Earth's system of land, oceans, and atmosphere. MODIS is a cross-track scanning radiometer, which uses a two-sided scan mirror and collects data continuously over a wide scan angle range (+/-55 degree relative to the instrument nadir) each scan of 1.47 seconds. It has 36 spectral bands with wavelengths ranging from visible (VIS) to long-wave infrared (LWIR). MODIS bands 1-19 and 26 are the reflective solar bands (RSB) and bands 20-25 and 27-36 are the thermal emissive bands (TEB). MODIS was developed and designed with improvements made over its heritage sensors (such as AVHRR and Landsat) and, in particular, with more stringent calibration requirements. Because of this, MODIS was built with a set of state-of-art on-board calibrators (OBC), which include a solar diffuser (SD), a solar diffuser stability monitor (SDSM), a blackbody (BB), a spectroradiometric calibration assembly (SRCA), and a space view (SV) port. With the exception of view angle differences, MODIS OBC measurements and the Earth View (EV) observations are made via the same optical path. MODIS TEB have a total of 160 individual TEB detectors (10 per band), which are located on two cold focal plane assemblies (CFPA). For nominal on-orbit operation, the CFPA temperature is controlled at 83K via a passive radiative cooler. For the TEB, the calibration requirements at specified typical scene radiances are less than or equal to 1% with an exception for the fire detection (low gain) band. MODIS TEB on-orbit calibration is performed on a scan-by-scan basis using a quadratic calibration algorithm, and data collected from sensor responses to the onboard BB and SV. The BB serves as the thermal calibration source and the SV provides measurements for the sensor's background and offsets. MODIS on-board BB is a v-grooved plate with its temperature measured using 12 platinum resistive thermistors (PRT) uniformly embedded in the BB substrate. All the BB thermistors were characterized pre-launch with reference to the NIST temperature standards. Unlike typical BB operations in many heritage sensors, which have no temperature control capability, the MODIS on-board BB can be operated at any temperatures between instrument ambient (about 270K) and 315K and can also be varied continuously within this range. This feature has significantly enhanced the MODIS' capability of tracking and updating the TEB nonlinear calibration coefficients over its entire mission. Following a brief description of MODIS TEB on-orbit calibration methodologies and its onboard BB operational activities, this paper provides a comprehensive performance assessment of MODIS TEB quadratic calibration algorithm. It examines the scan-by-scan, orbit-by-orbit, daily, and seasonal variations of detector responses and associated impact due changes in the CFPA and instrument temperatures. Specifically, this paper will analyze the contribution by each individual thermal emissive source term (BB, scan cavity, and scan mirror), the impact on the Level 1 B data product quality due to pre-launch and on-orbit calibration uncertainties. A comparison of Terra and Aqua TEB on-orbit performance, lessons learned, and suggestions for future improvements will also be made.

Xiong, Xiaoxiong↗

Battery Energy Storage Systems: A Review of Energy Management Systems and Health Metrics

With increasing concerns about climate change, there is a transition from high-carbon-emitting fuels to green energy resources in various applications including household, commercial, transportation, and electric grid applications. Even though renewable energy resources are receiving traction for being carbon-neutral, their availability is intermittent. To address this issue to achieve extensive application, the integration of energy storage systems in conjunction with these resources is becoming a recommended practice. Additionally, in the transportation sector, the increased demand for EVs requires the development of energy storage systems that can deliver energy for rigorous driving cycles, with lithium-ion-based batteries emerging as the superior choice for energy storage due to their high power and energy densities, length of their life cycle, low self-discharge rates, and reasonable cost. As a result, battery energy storage systems (BESSs) are becoming a primary energy storage system. The high-performance demand on these BESS can have severe negative effects on their internal operations such as heating and catching on fire when operating in overcharge or undercharge states. Reduced efficiency and poor charge storage result in the battery operating at higher temperatures. To mitigate early battery degradation, battery management systems (BMSs) have been devised to enhance battery life and ensure normal operation under safe operating conditions. Some BMSs are capable of determining precise state estimations to ensure safe battery operation and reduce hazards. Precise estimation of battery health is computed by evaluating several metrics and is a central factor in effective battery management systems. In this scenario, the accurate estimation of the health indicators (HIs) of the battery becomes even more important within the framework of a BMS. This paper provides a comprehensive review and discussion of battery management systems and different health indicators for BESSs, with suitable classification based on key characteristics.

Nazaralizadeh, Solmaz (ORCID:0009000737004039)↗

Detecting Short Circuits: Post Accident Electric Vehicle Battery Safety Check

Fast and accurate detection of soft short circuits (SCs) in the battery packs of damaged electric vehicles is needed by first responders and mechanics to mitigate the potential risk from battery fires that may occur hours, days, or weeks after an accident. Here, this paper presents an SC-detection algorithm for potentially damaged lithium-ion batteries that works quickly and without a priori knowledge of the battery-pack chemistry, capacity, state of charge, or state of health. The proposed universal SC-detection algorithm is designed to be implemented on an inexpensive handheld device that can connect to and monitor the voltages of all cells in a pack. Transient filtering and linear-quadratic state observation provide estimates of normalized SC current for every cell in the pack. Cells with SC-current estimates outside a sigma-based threshold are detected. Simulations, experiments, and electric vehicle (EV) crash data are used to verify the speed, sensitivity, and accuracy of the method, demonstrating 96% accurate detection of 0.0027 C SCs in under 1 h for 5S cell groups in the lab and no false positives for crashed Volkswagen, Chevrolet, and Tesla vehicles without SCs.

25 - ENERGY STORAGE↗

Demand Response in Residential Energy Code: Technical Brief

As buildings account for over 75% of U.S. electricity use, effectively managing their loads can greatly facilitate the transition towards a clean, reliable grid. Grid-interactive efficient buildings (GEBs) combine efficiency and demand flexibility with smart technologies and communication to provide occupant comfort and productivity while serving the grid as a distributed energy resource (DER). In turn, GEBs can play a key role in ensuring access to an affordable, reliable, sustainable, and modern U.S. electric power system. Their national adoption could provide $\$$100-200 billion in U.S. electric power system cost savings over the next two decades. The associated reduction in CO 2 emissions is estimated at 6% per year by 2030 (DOE 2021). Building codes represent standard design practice in the construction industry and continually evolve to include advanced technologies and innovative practices. Historically, national model energy codes establish minimum efficiency requirements for new construction (ICC 2020). Expanding codes to support GEB capabilities is a pivotal step towards realizing demand flexibility in support of a clean grid by addressing capabilities to improve interoperability between smart building systems, the grid, and renewable energy resources. Realizing GEBs requires buildings with automated demand response (DR) capabilities that enable standardized communication with or control of, subject to explicit consumer consent, energy smart appliances or home energy management systems. This is achieved through direct or indirect (i.e., via an aggregator) communication between appliances and the electric grid. Energy codes can also support DR communication standardization and advance the deployment of building-integrated DERs such as energy storage, generation, and electric vehicles (EVs). Incorporating automated DR capabilities in energy codes provides many benefits to the consumers. Specifically, it aligns building electric load demand with intermittent renewable energy source availability, decreases peak load on the electric grid, allows buildings to respond to utility price signals, supports electrical network reliability and market growth of products and processes aligned with clean economic growth. The incorporation of DR into the model residential energy codes was considered for both the 2021 and 2024 International Energy Conservation Code (IECC) code development cycles. The approved DR measures in the 2021 cycle were removed in response to appeals (ICC 2020). Updated language was presented for consideration again for the 2024 IECC, where it was negotiated and again approved, and again removed in response to appeals (ICC 2024). This resulted in many sections, including sections on demand responsive controls, being moved to the credits options or an appendix as a voluntary application. This technical brief updates the proposed DR components such that they can be considered by states and local governments for direct incorporation into their codes, as well as for future IECC energy code development. The proposal refinements are intended to support consistency in approach and provide a degree of certainty for building owners, designers, contractors, manufacturers, and building and fire safety professionals. The scope of this technical brief includes three strategies for DR in residential buildings: 1) smart thermostats with demand-responsive control, 2) electric water heating incorporating demand-responsive controls and communication and 3) grid Integrated solar and energy storage systems.

2021 IECC↗

Novel and effective surface passivation for high efficiency n- and p-type Silicon solar cell

The project objective was to develop a novel Si surface passivation method using chalcogens, sulfur (S) and/or selenium (Se), as passivating elements, to withstand industry-standard high temperature contacting and metallization schemes for p-type Si based passivated emitter and rear contact (p-PERC) solar cells. The back surface passivation of PERC cells has been improved drastically with the invention and successful application of an Al 2 O 3 passivation layer. However, the front n + diffused junction surface is still poorly passivated by the standard amorphous silicon nitride (SiNx) anti-reflection coating (ARC) layer. This project sought to address the passivation challenges of both front n+ emitter and undiffused p-Si back surface. Improved p-PERC solar cell performance with open circuit voltage (V OC ) > 680 mV and efficiency of 22% were targeted to validate superior defect passivation properties as compared to standard SiO 2 / Al 2 O 3 passivation. During this project, we systematically investigated process-structure-properties-performance relationships of this novel advanced defect passivation approach. The S/Se passivation was carried out by reacting industrial Czochralski (Cz) Si wafers in H 2 S and H 2 Se gases in a chemical vapor deposition (CVD) reactor at temperatures up to 700°C. After an exhaustive optimization of the process parameters (temperature, time, and gas concentration), we established an optimized process and demonstrated extremely low surface recombination velocities (SRVs) of 1.5 cm/s and 8 cm/s on n-type and p-type Si, respectively, by S-passivation. In-depth surface and interface characterization were performed using soft x-ray and photoelectron spectroscopies (XPS, UPS, XES), combined with capacitance-voltage-frequency (C-V-f) measurements, to decipher the surface chemical/electronic structure and interface defect state densities. These measurements provided critical understanding of the defect passivation mechanism and elucidated the presence of surface S-Si bonds, a reduction of surface dipoles, and low interface state densities (D it ) < 10 11 cm -2 ev -1 . We also found that the Se-passivation is inferior to the S-passivation (by at least one order of magnitude in SRV). Application of the optimized S-passivation to the n+ diffused emitter surface led to a low surface recombination current density, J0 ≈ 40 fA/cm 2 (~ 1/4 of the industry-standard SiNx-passivation), and high implied V OC (686 mV) in p-PERC solar cell structures. The S-passivation process also was found to improve the bulk quality of the p-type Si, better than the SiO 2 or Al 2 O 3 passivation processes. After successful demonstration of efficient passivation of Si surface defects by S, we extensively studied the air, thermal, and illumination stability of the passivation structure. S-passivation itself degrades in air due to competing reactions with moisture and oxygen to form oxides, which can be eliminated by a SiNx capping layer (also acting as a anti-reflective coating). After SiNx process optimization, we demonstrated illumination and thermally stable S-passivation with SRV < 5 cm/s and J 0 < 80 fA/cm 2 . These enhancements in Si passivation, incorporated into p-PERC cells, achieved an efficiency of 19.93% with V OC = 649 mV, using manufacturing metallization and contacting schemes. The low cell performance (cell V OC is much less than the implied V OC = 686 mV, anticipated from surface passivation) was identified due to degradation of S-passivation during the metal firing step (out-diffusion of S from the Si interface to the SiNx surface). The S-passivation of Si surfaces shows significant promise with excellent passivation quality, essential for high performance (high V OC , high efficiency) solar cells. Integration of this innovative defect passivation into devices, however, demands further development of the capping layer, low temperature (<700°C) metallization process, and/or engineering of advanced device structures. Surface passivation-dominated advanced Si solar cells, such as tunnel oxide passivated contacts and Si heterojunctions, are increasingly of interest due to their high-performance potential and will have a growing photovoltaic market share in the near future.

14 SOLAR ENERGY↗

White Paper on Case Study of Safe Installation of Second-Life Energy Storage System

This technical report provides for a case study for the safe installation of a second-life, or repurposed, battery, that has been reconfigured for use as a stationary energy storage systems (ESS). Driven by legislative requirements such as California Senate Bill 615 and projections that retired EV batteries could meet a substantial portion of U.S. grid ESS needs beginning in 2035, the repurposing of EV batteries is anticipated to grow significantly. However, safety concerns arise from the effects of aging, unknown prior usage history, and changes in thermal runaway behavior, which may increase failure risks compared to new batteries. NFPA 855, the predominant U.S. standard for ESS installation, mandates that second-life batteries meet all requirements for new batteries, with repurposers complying with UL 1974 in addition to obtaining UL 9540 and UL 1973 listings. These are certifications that few repurposers have achieved and represent a regulatory barrier to entry for the market as a whole.

47 OTHER INSTRUMENTATION↗

Pull Force Evaluation of CCS Insulated End Caps

Insulated end caps installed on DC pins of Combined Charging System (CCS) inlets have been identified as potential debris sources within electric vehicle supply equipment (EVSE) connectors, increasing the risk of electric shock and fire hazards. Although standards such as IEC 62196-1:2022 specify mechanical pull-force requirements for these end caps, it remains unclear whether these requirements provide adequate robustness under real-world conditions. To address this concern, the National Charging Experience (ChargeX) Consortium's Hardware Task Force conducted evaluations of insulated end caps used in OEM CCS inlets. This study assesses the performance of insulated end caps used in OEM CCS inlets, specifically those installed on DC pins, using the procedures defined in IEC 62196-1:2022 (Section Sign) 26.7 and SAE J3400, supplemented by additional experimental conditioning. To ensure relevance to real-world conditions, NLR collaborated with charging network operators (CNOs) to guide the selection of charging inlet samples. Material analyses of the insulated end cap samples were conducted to confirm that the tested materials reflected the types and properties commonly observed in the field. The selected samples underwent temperature and humidity conditioning followed by pull-force testing to evaluate the end-cap integrity. Although SAE J3400 inlets were not directly tested due to limited diversity in available field data, the underlying end-cap principles between CCS and SAE J3400 are comparable, allowing the study's insights to be relevant to both technologies. Overall, this study provides a structured evaluation framework to inform potential refinements to mechanical pull-force requirements in charging standards.

33 ADVANCED PROPULSION SYSTEMS↗