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Results for “Effective connectivity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Plasma screening in mid-charged ions observed by K-shell line emission

Dense plasma environment affects the electronic structure of ions via variations of the microscopic electrical fields, also known as plasma screening. This effect can be either estimated by simplified analytical models, or by computationally expensive and to date unverified numerical calculations. We have experimentally quantified plasma screening from the energy shifts of the bound-bound transitions in matter driven by the x-ray free electron laser (XFEL). This was enabled by identification of detailed electronic configurations of the observed Kα, Kβ and Kγ lines. This work paves the way for improving plasma screening models including connected effects like ionization potential depression and continuum lowering, which will advance the understanding of atomic physics in the Warm Dense Matter regime.

Physics - Plasma physics↗
DOE OSTI2025

Deciphering the Evolution of Current Distribution in Hybrid Silver Vanadium Oxide / Carbon Monofluoride Cathodes within Lithium Primary Batteries

For batteries to function effectively all active material must be accessible requiring both electron and ion transport to each particle. A common approach to generating the needed conductive network is the addition of carbon to create a composite electrode. An alternative approach is the electrochemically induced formation of conductive reaction products where the electrochemically generated materials are in intimate contact with the active material contributing to effective connection of each active particle. Furthermore, this study probes silver vanadium oxide (Ag 2 V 4 O 11 , SVO), carbon monofluoride (CF x ), and hybrid SVO/CF x electrodes in lithium batteries. Ex situ XRD identifies Ag 0 as a reduction product from SVO and LiF from CF x that can be followed as a function of depth-of-discharge (DOD). Spatially-resolved operando energy dispersive x-ray diffraction reveals that the presence of SVO alleviates reaction heterogeneity in the electrodes which are electron transfer limited in the absence of sufficient Ag 0 . Synchrotron X-ray tomography on discharged cathodes reveals the distribution of silver particles where the particles are more closely spaced near the current collector indicating multiple nucleation sites for their formation. Finally, operando isothermal microcalorimetry is used to determine the heat dissipation of the parent and hybrid battery types. Using material enthalpy potentials, we determine the current distribution between the two active materials for the discharging hybrid cathode adding further insight to the diffraction analysis. Taken together, these results provide a comprehensive understanding of hybrid SVO/CF x cathodes and give guidance on optimal compositions that balance power and energy density considerations.

36 MATERIALS SCIENCE↗
DOE OSTI2021

The X-ray emission of cerium oxide

Using a combination of spectral simulation with FEFF and experimental data for metallic Ce, it has been possible to extract the Cerium Oxide-only M 4,5 X-ray Emission Spectrum (XES) from an experimental result, which had been produced utilizing a combined CeOxide/Ce sample. In this paper, it is shown that the XES emission for CeOxide-only is significantly different for the M 4 and M 5 edges, with the M 4 XES consistent with normal XES and the M 5 XES exhibiting a continued enhancement associated with a threshold effect, connected to Resonant Inverse Photoelectron Spectroscopy (RIPES).

36 MATERIALS SCIENCE↗
DOE OSTI2021

Solubility Behavior of CO 2 in Ionic Liquids Based on Ionic Polarity Index Analyses

Ionic liquids (ILs) can serve as effective CO 2 solvents with an appropriate selection of different anions and cations. However, due to the large library of potential IL compositions, rapid screening methods are needed for characterizing and ranking the expected properties. We have recently proposed the ionic polarity index (IPI) parameter, effectively connecting volume-based approaches and electrostatic potential analyses, providing a single metric that can potentially be used to rapidly screen for desirable IL properties. In this work, the corresponding anion and cation IPIs are used to generate correlations with respect to the CO 2 volumetric solubility in ILs. The relationships are generally applicable to groups of ILs within a homologous ion series, and this can be particularly valuable for pre-screening different ion pairings for maximizing gas solvation performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Wear Mechanism Analysis of a New Rotary Shear Biomass Comminution System

A new biomass comminution system, Crumbler rotary shear, was developed to process fuel-grade biomass. The rotary shear is more efficient than the traditional hammer mill in comminuting high-moisture biomass and producing more uniform particles with minimal fines. However, the milling unit experiences significant wear in processing dirty woodchips. This study investigated the wear mechanisms of the rotary shear system based on analysis of the minerals carried by woodchips and characterization of actual worn components. Abrasive wear was found to be the dominant effect, and localized adhesive wear (material transfer), microfracture (chipping), and plastic deformation were additional effects. Connections have been made between the wear progression of key cutting components and the particle size change of biomass extrinsic minerals. On the basis of the wear mechanism understanding, mitigations based on advanced tool materials and optimized tool geometric designs are being developed for improving the tool life and cutting efficiency.

09 BIOMASS FUELS↗
DOE OSTI2020

Structure of an Atmospheric River over Australia and the Southern Ocean. Part I: Tropical and Midlatitude Water Vapor Fluxes

An atmospheric river (AR) impacting Australia-Tasmania and the Southern Ocean during the Austral summer on 28-29 January 2018 during the SOCRATES campaign is analyzed using both a modeling and observational approach. Gulfstream-V dropsonde measurements and GPM radar analyses were used in conjunction with Weather Research and Forecasting model simulations with water vapor tracers to investigate the relative contributions of tropical and mid-latitude moisture sources to the AR. Moisture associated with a monsoonal tropical depression became entrained into a mid-latitude frontal system that extended to 60°S over the Southern Ocean reaching the associated low pressure system 850 km off the east coast of Antarctica – effectively connecting the tropics and the polar region. Tropical moisture contributed to about 50% of the precipitable water within the AR. The tropical contribution to precipitation decreased with latitude, from > 70% over the Australian continent, to ~50% off the Australian coast, to less than 10% poleward of 60°S. Precipitation in the AR conformed to a seeder-feeder model, the seeder precipitation forming primarily from tropical sourced moisture above the altitude of the 0°C isotherm, and the feeder precipitation sourced from mid-latitude sourced moisture below the altitude of the 0°C isotherm. The integrated vapor transport (IVT) through the core of the AR reached above 500 kg m-1s-1 during 1200 UTC 28 January to 0600 UTC 29 January 29, 1.29 times the average amount of water carried by the world’s largest river, the Amazon. The high IVT strength might be attributed to the higher water vapor content associated with the warmer temperatures in Austral summer.

Rauber, Robert M.↗
DOE OSTI2025

Subsurface Cooling and Sea Surface Temperature Pattern Formation Over the Equatorial Pacific

Abstract The equatorial cold tongue region has not warmed up in response to historical radiative forcing in the real world, contrary to the strong warming often simulated by climate models. Here we demonstrate that climate models fail to represent one or both of the key processes driving observed sea surface temperature (SST) pattern formation: a realistic surface wind stress pattern shaping subsurface cooling through wind‐driven circulation changes, and effective connectivity between subsurface and surface temperatures via upwelling and mixing. Consequently, none of the models approximate the observed lack of cold tongue SST warming and strengthening of zonal SST gradient across the equatorial Pacific. Furthermore, those that come closest achieve this due to interhemispheric warming differences rather than equatorial dynamics as observed. Addressing different origins of subsurface cooling in observations and simulations, and how they connect to SST, will lead to improved understanding of tropical Pacific SST changes to date and how they will evolve in the future.

Jiang, Feng [Lamont‐Doherty Earth Observatory Colu↗
DOE OSTI2024

Validation of prediction capability of operating space for plasma initiation in MAST-U

DYON is a plasma initiation modelling code that solves the differential equation system of the full circuit equations (plasma current, active coil currents and eddy currents in full passive structures) and 0D global energy and particle balance equations (Kim 2022 Nucl. Fusion 62 126012). In order to test the capability of the full electromagnetic plasma initiation model to predict individual discharges in experiments and thus the operating space in the device, a dedicated experimental database was built in MAST-U by scanning the prefilled gas pressure p 0 and the induced loop voltage V loop . In the experimental operating space of p 0 and V loop the lower and the upper limits of p 0 are determined by the plasma breakdown failure and the plasma burn-through failure, respectively. The lower limit of V loop is determined by the plasma burn-through failure. By directly reading the control room data used in each discharge (i.e. currents in the solenoid, poloidal field coils, and toroidal field coils, p 0 , and gas puffing rate), the full electromagnetic DYON consistently predicted the failed breakdown, failed burn-through, and successful plasma initiation discharges in the experimental database, demonstrating its capability to predict the operating space for inductive plasma initiation. The Paschen curve calculated with the effective connection length in MAST-U indicates a much higher p 0 required for plasma breakdown than the experimental data, indicating that individual field line evaluation is necessary to calculate the quantitative requirements for Townsend breakdown. The demonstration in this paper shows that the full electromagnetic DYON could be a useful simulation tool to assess the feasibility of inductive plasma initiation and to optimise operating scenarios in future devices.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Assessing complexity and dynamics in epidemics: geographical barriers and facilitators of foot-and-mouth disease dissemination

Introduction: Physical and non-physical processes that occur in nature may influence biological processes, such as dissemination of infectious diseases. However, such processes may be hard to detect when they are complex systems. Because complexity is a dynamic and non-linear interaction among numerous elements and structural levels in which specific effects are not necessarily linked to any one specific element, cause-effect connections are rarely or poorly observed. Methods: To test this hypothesis, the complex and dynamic properties of geo-biological data were explored with high-resolution epidemiological data collected in the 2001 Uruguayan foot-and-mouth disease (FMD) epizootic that mainly affected cattle. County-level data on cases, farm density, road density, river density, and the ratio of road (or river) length/county perimeter were analyzed with an open-ended procedure that identified geographical clustering in the first 11 epidemic weeks. Two questions were asked: (i) do geo-referenced epidemiologic data display complex properties? and (ii) can such properties facilitate or prevent disease dissemination? Results: Emergent patterns were detected when complex data structures were analyzed, which were not observed when variables were assessed individually. Complex properties–including data circularity–were demonstrated. The emergent patterns helped identify 11 counties as ‘disseminators’ or ‘facilitators’ (F) and 264 counties as ‘barriers’ (B) of epidemic spread. In the early epidemic phase, F and B counties differed in terms of road density and FMD case density. Focusing on non-biological, geographical data, a second analysis indicated that complex relationships may identify B-like counties even before epidemics occur. Discussion: Geographical barriers and/or promoters of disease dispersal may precede the introduction of emerging pathogens. If corroborated, the analysis of geo-referenced complexity may support anticipatory epidemiological policies.

60 APPLIED LIFE SCIENCES↗
NASA NTRS1980

A note on sound radiation into a uniformly flowing fluid

Sound radiation generated by mechanical or vibratory source arrangements and, in some instances of planar or piston types, encompasses all magnitudes of the wavelength or frequency as well as disposition of the observation site. The comparative increase in average total radiated power from infinitesimally small or point sources of periodic strength, on passing from rest to steady rectilinear motion, depends only on Mach number in the noncompact case; and a formally analogous rise in output is linked, to the presence of a steady parallel flow past a rigid plane wall in which a compact circular piston executes normal oscillations. The perspective of effects connected with such a background is flow is widened by regard for an elongated or strip piston, which prototype permits a straightforward and general analysis.

Levine, H.↗
NASA NTRS2005

Simulator of Space Communication Networks

Multimission Advanced Communications Hybrid Environment for Test and Evaluation (MACHETE) is a suite of software tools that simulates the behaviors of communication networks to be used in space exploration, and predict the performance of established and emerging space communication protocols and services. MACHETE consists of four general software systems: (1) a system for kinematic modeling of planetary and spacecraft motions; (2) a system for characterizing the engineering impact on the bandwidth and reliability of deep-space and in-situ communication links; (3) a system for generating traffic loads and modeling of protocol behaviors and state machines; and (4) a system of user-interface for performance metric visualizations. The kinematic-modeling system makes it possible to characterize space link connectivity effects, including occultations and signal losses arising from dynamic slant-range changes and antenna radiation patterns. The link-engineering system also accounts for antenna radiation patterns and other phenomena, including modulations, data rates, coding, noise, and multipath fading. The protocol system utilizes information from the kinematic-modeling and link-engineering systems to simulate operational scenarios of space missions and evaluate overall network performance. In addition, a Communications Effect Server (CES) interface for MACHETE has been developed to facilitate hybrid simulation of space communication networks with actual flight/ground software/hardware embedded in the overall system.

Clare, Loren↗
DOE OSTI2021

Effects of Pore Connectivity on the Sorption of Fluids in Nanoporous Material: Ethane and CO2 Sorption in Silicalite

Adsorption of fluids in nanoporous materials is important for several applications including gas storage and catalysis. The pore network in natural, as well as engineered, materials can exhibit different degrees of connectivity between pores. While this might have important implications for the sorption of fluids, the effects of pore connectivity are seldom addressed in the studies of fluid sorption. We have carried out Monte Carlo simulations of the sorption of ethane and CO2 in silicalite, a nanoporous material characterized by sub-nanometer pores of different geometries (straight and zigzag channel like pores), with varied degrees of pore connectivity. The variation in pore connectivity is achieved by selectively blocking some pores by loading them with methane molecules that are treated as a part of the rigid nanoporous matrix in the simulations. Normalized to the pore space available for adsorption, the magnitude of sorption increases with a decrease in pore connectivity. The increased adsorption in the systems where pore connections are removed by blocking them is because of additional, albeit weaker, adsorption sites provided by the blocker molecules. By selectively blocking all straight or zigzag channels, we find differences in the absorption behavior of guest molecules in these channels.

Gautam, Siddharth (ORCID:0000000314435382)↗
DOE OSTI2021

Effect of Pore Connectivity on the Behavior of Fluids Confined in Sub-Nanometer Pores: Ethane and CO2 Confined in ZSM-22

The behavior of fluids under nano-confinement varies from that in bulk due to an interplay of several factors including pore connectivity. In this work, we use molecular dynamics simulations to study the behavior of two fluids—ethane and CO2 confined in ZSM-22, a zeolite with channel-like pores of diameter 0.55 nm isolated from each other. By comparing the behavior of the two fluids in ZSM-22 with that reported earlier in ZSM-5, a zeolite with pores of similar shape and size connected to each other via sinusoidal pores running perpendicular to them, we reveal the important role of pore connectivity. Further, by artificially imposing pore connectivity in ZSM-22 via inserting a 2-dimensional slab-like inter-crystalline space of thickness 0.5 nm, we also studied the effect of the dimensionality and geometry of pore connectivity. While the translational motion of both ethane and CO2 in ZSM-22 is suppressed as a result of connecting the pores by perpendicular quasi-one-dimensional pores of similar dimensions, the effect of connecting the pores by inserting the inter-crystalline space is different on the translational motion of the two fluids. For ethane, pores connected via inter-crystalline space facilitate translational motion but suppress rotational motion, whereas in the case of CO2, both types of motion are suppressed by pore connection due to the strong interaction of CO2 with the surface of the substrate.

Kummali, Mohammed Musthafa (ORCID:000000028082555X↗
DOE OSTI2021

Connectivity and edge effects increase bee colonization in an experimentally fragmented landscape

Though landscape corridors increase dispersal of many animals and plants, it remains unknown whether these positive effects extend to the process of colonization and establishment of new populations in fragments. Working in experimentally fragmented landscapes, we tested how two aspects of habitat fragments altered by corridors – connectivity and edge-to-area ratio – determine patterns of colonization by a solitary, cavity-nesting bee Megachile rotundata. We found that though connectivity initially affected rates of nest-site occupation, edge-to-area ratio ultimately determined the final patterns of patch occupation and nest building, likely due to habitat selection by our focal species. Bee colonization was also higher in patches with higher abundances of their preferred food resources, flowers from the Fabaceae family. Our results show the importance of considering the effects of both connectivity and edge on population dynamics in habitat-based conservation.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1932

The Effect of Connecting-passage Diameter on the Performance of a Compression-ignition Engine with a Precombustion Chamber

Results of motoring tests are presented showing the effect of passage diameter on chamber and cylinder compression pressures, maximum pressure differences, and f.m.e.p. over a speed range from 300 to 1,750 r.p.m. Results of engine performance tests are presented which show the effect of passage diameter on m.e.p., explosion pressures, specific fuel consumption, and rates of pressure rise for a range of engine speeds from 500 to 1,500 r.p.m. The cylinder compression pressure, the maximum pressure difference, and the f.m.e.p. decreased rapidly as the passage diameter increased to 29/64 inch, whereas further increase in passage diameter effected only a slight change. The most suitable passage diameter for good engine performance and operating characteristics was 29/64 inch. Passage diameter became less critical with a decrease in engine speed. Therefore, the design should be based on maximum operating speed. Optimum performance and satisfactory combustion control could not be obtained by means of any single diameter of the connecting passage.

Moore, C S↗
DOE OSTI2022

Effect of network connectivity on behavior of synthetic Broborg hillfort glasses

There is wide industrial interest in developing robust models of long-term (>100 years) glass durability. Archeological glass analogs, glasses of similar composition, and alteration conditions to those being tested for durability can be used to evaluate and inform such models. Two such analog glasses from a 1500-year-old vitrified hillfort near Uppsala, Sweden have previously been identified as potential analogs for low concentration Fe-bearing aluminosilicate nuclear waste glasses. However, open questions remain regarding the melting environment from which these historic glasses were formed and the effect of these conditions on their chemical durability. A key factor to answering the previous melting and durability questions is the redox state of Fe in the starting and final materials. Past work has shown that the melting conditions of a glass-forming melt may influence the redox ratio value (Fe +3 /ΣFe), a measure of a glass's redox state, and both melting conditions and the redox ratio may influence the glass alteration behavior. Synthetic analogs of the hillfort glasses have been produced using either fully oxidized or reduced Fe precursors to address this question. In this study, the melting behavior, glass transition temperature, oxidation state, network structure, and chemical durability of these synthesized glass analogs is presented. Resulting data suggests that the degree of network connectivity as impacted by the oxidation state of iron impacted the behavior of the glass-forming melt but in this case does not affect the chemical durability of the final glass. Glasses with a lower degree of melt connectivity were found to have a lower viscosity, resulting in a lower glass transition temperature and softening temperature, as well as in a lower temperature of foam onset and temperature of foam maximum. This lower degree of network connectivity most likely played a more significant role in accelerating the conversion of batch chemicals into glass than the presence of water vapor in the furnace's atmosphere. Future work will focus on using the results from this work with outcomes from other aspects of this project to evaluate long-term glass alteration models.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Effect of network connectivity on the mechanical and transport properties of block copolymer gels

Establishing the independent tunability of transport and mechanical properties in polymer gels would significantly contribute to their implementation as transdermal drug delivery media, among other things. The work conducted herein uses facile changes in the formulation of physically crosslinked styrenic ABA/AB block copolymer organogels to alter their mechanical properties independently from the mass transport of an internally-loaded nanocarrier. Therefore, such independent tunability is made possible by altering the relative amounts of ABA triblock and AB diblock copolymers while holding total copolymer concentration fixed. Specifically, three series of gels each with a fixed total copolymer concentration (10, 20, or 30 wt%) comprised of varying triblock copolymer concentration are studied. Small angle x-ray scattering confirms that, at the nanoscale, only gel network connectivity changes within each series, while mechanical and release experiments show that increasing network connectivity leads to significant growth of gel moduli, but little change in nanocarrier release rate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗