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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

Optical Characterization and 2,525 micron Lasing of Cr(2+):Cd(0.85)Mn(0.15)Te

Transition metal doped solids are of significant current interest for the development of tunable solid-state lasers for the near and mid-infrared (1-4 pm) spectral region. Applications of these lasers include basic research in atomic, molecular, and solid-state physics, optical communication, medicine, and environmental studies of the atmosphere. In transition metal based laser materials, absorption and emission of light arises from electronic transitions between crystal field split energy levels of 3d transition metal ions. The optical spectra generally exhibit broad bands due to the strong interaction between dopant and host (electron-phonon coupling). Broad emission bands offer the prospect of tunable laser activity over a wide wavelength range, e.g. the tuning range of Ti:Sapphire extends from 700-1100 run. The only current transition metal laser operating in the mid-infrared wavelength region (1.8-2.4 micro-m) is CO(2+):MgF2, but its performance is severely limited due to strong nonradiative decay at room temperature. Based on lifetime data, the quantum efficiency is estimated to be less than 3 deg/0 11,21. In general, the probability for non-radiative decay via multi-phonon relaxation increases with decreasing energy gap between ground and excited state. Therefore, efficient transition metal lasers beyond -1.6 micro-m are rare. Recently, tunable laser activity around 2.3 micro-m was observed from Cr doped ZnS and ZnSe. The new lasing center in these materials was identified as Cr(2+) occupying the tetrahedral Zn site. Tetrahedrally coordinated optical centers are rather unusual among transition metal lasers. Their potential usefulness, however, has been demonstrated by the recent development of near infrared laser materials such as Cr:forsterite and Cr:YAG, which are based on tetrahedrally coordinated Cr(4+) ions. According to the Laporte selection rule, electric-dipole transition within the optically active 3d-electron shells are parity forbidden. However, a static acentric electric crystal field or the coupling of asymmetric phonons can force electric-dipole transitions by the admixture of wave functions with opposite parity. Tetrahedral sites lack inversion symmetry which provides the odd-parity field necessary to relax the parity selection rule. Therefore, high absorption and emission cross sections are observed. An enhanced radiative emission rate is also expected to reduce the detrimental effect of non-radiative decay. Motivated by the initial results on Cr doped ZnS and ZnSe, we have started a comprehensive effort to study Cr(2+) doped II-VI semiconductors for solid-state laser applications. In this paper we present the optical properties and the demonstration of mid-infrared lasing from Cr doped Cd(0.85)Mn(0.15)Te.

Davis, V. R.↗
NASA NTRS2000

Theoretical Analysis of the Electron Spiral Toroid Concept

This report describes the analysis of the Electron Spiral Toroid (EST) concept being promoted by Electron Power Systems Inc. (EPS). The EST is described as a toroidal plasma structure composed Of ion and electron shells. It is claimed that the EST requires little or no external confinement, despite the extraordinarily large energy densities resulting from the self-generating magnetic fields. The present analysis is based upon documentation made available by EPS, a previous description of the model by the Massachusetts Institute of Technology (MIT), and direct discussions with EPS and MIT. It is found that claims of absolute stability and large energy storage capacities of the EST concept have not been substantiated. Notably, it can be demonstrated that the ion fluid is fundamentally unstable. Although various scenarios for ion confinement were subsequently suggested by EPS and MIT, none were found to be plausible. Although the experimental data does not prove the existence of EST configurations, there is undeniable experimental evidence that some type of plasma structures whose characteristics remain to be determined are observed. However, more realistic theoretical models must first be developed to explain their existence and properties before applications of interest to NASA can he assessed and developed.

Cambier, Jean-Luc↗
NASA NTRS1986

The maximum momentum transfer in proton-hydrogen collisions

The upper limit of momentum transfer by a proton to K-shell electrons is calculated in a restricted three-body classical model. The model shows that the infinite upper limit used in practice, is generally good except for low energy protons passing through an extremely rarefied gas.

NASA Discipline Number 22-70↗
NASA NTRS2020

Nuclear Fusion Reactions in Deuterated Metals

Nuclear fusion reactions of D-D are examined in an environment comprised of high density cold fuel embedded in metal lattices in which a small fuel portion is activated by hot neutrons. Such an environment provides for enhanced screening of the Coulomb barrier due to conduction and shell electrons of the metal lattice, or by plasma induced by ionizing radiation (γ quanta). We show that neutrons are far more efficient than energetic charged particles, such as light particles (e−, e+) or heavy particles (p, d, α) in transferring kinetic energy to fuel nuclei (D) to initiate fusion processes. It is well-known that screening increases the probability of tunneling through the Coulomb barrier. Electron screening also significantly increases the probability of large- versus small-angle Coulomb scattering of the reacting nuclei to enable subsequent nuclear reactions via tunneling. This probability is incorporated into the astrophysical factor S(E). Aspects of screening effects to enable calculation of nuclear reaction rates are also evaluated, including Coulomb scattering and localized heating of the cold fuel, primary D-D reactions, and subsequent reactions with both the fuel and the lattice nuclei. The effect of screening for enhancement of the total nuclear reaction rate is a function of multiple parameters including fuel temperature and the relative scattering probability between the fuel and lattice metal nuclei. Screening also significantly increases the probability of interaction between hot fuel and lattice nuclei increasing the likelilhood of Oppenheimer-Phillips processes opening a potential route to reaction multiplication. We demonstrate that the screened Coulomb potential of the target ion is determined by the nonlinear Vlasov potential and not by the Debye potential. In general, the effect of screening becomes important at low kinetic energy of the projectile. We examine the range of applicability of both the analytical and asymptotic expressions for the well-known electron screening lattice potential energy Ue, which is valid only for E >> Ue (E is the energy in the center of mass reference frame). We demonstrate that for E ≤ Ue, a direct calculation of Gamow factor for screened Coulomb potential is required to avoid unreasonably high values of the enhancement factor f (E) by the analytical—and more so by the asymptotic—formulas.

Vladimir Pines↗
NASA NTRSDate not supplied

A Portable High-Density Power Technology for Space, Lunar, and Planetary Applications

A new direct energy conversion concept called Nuclear Thermionic Avalanche Cell (NTAC) combined with a Metallic Junction Thermoelectric (MJ-TE) generator, both invented and patented by NASA, offers high specific power for portable applications. Estimates based on experimental results suggest superior performance compared to radioisotope thermoelectric generators (RTG) by up to two orders of magnitude for the NTAC and three to four times better for the MJ-TE generator for the same mass. The NTAC technology can use a variety of radioisotopes including nuclear waste to liberate a large number of intra-band(IB), inner shell electrons of atoms (105 C/cm3) by gamma-ray photons (100 keV to MeV). In contrast, conventional power generation has poor specific power because they only utilize the valence band electrons (3C/cm3) of the semiconductor or free electrons (8×103 C/cm3) of the conductor.

NTAC↗
NASA NTRS2023

Effect of the Electrostatic Field due to the Surface Monolayer Metal Atoms on the Dissociation of Homonuclear Diatomic Gases in Gas-Metal Surface Reactions

The present paper examines the role of an electrostatic field generated by the outermost monolayer of metal ions prior to gas adsorption in aiding the dissociation of homonuclear diatomic gas molecules. The interaction of five homonuclear diatomic gases, Cl 2 , F 2 , H 2 , N 2 and O 2 , with several pure metals are examined using Coulomb’s law to calculate the attractive and repulsive forces between the electrons or ions in the gas molecule and the free surface metallic electrons or ions assuming a Bohr model. These calculations demonstrate that the total energy of the electrostatic fields from the metals can exceed the molecular binding energies of Cl 2 , F 2 , and O 2 at some distance from the metallic surface thereby suggesting that these gases interact primarily with the metallic surface in their atomic states after molecular bond dissociation prior to reaction. In contrast, H 2 and N 2 gases do not dissociate prior to reaching the metal surface due to the fact that the effective charge of the gas ions is less than the total electron charge at the outermost electronic shell. The present results correlate linearly with the electrochemical series standard reduction potential as well as with the Pauling electronegativity for several metals.

Gas-metal reactions↗
NASA NTRS1977

Angular distribution of Auger electrons due to 3d-shell ionization of krypton

Cross sections for electron impact ionization of krypton due to ejection of a 3rd shell electron have been calculated using screened hydrogenic and Hartree-Slater wave functions for target atom. While the total ionization cross sections in the two approximations are within 10% of each other, the Auger electron angular distribution, related to cross sections for specific magnetic quantum numbers of the 3rd electrons, is widely different in the two approximations. The angular distribution due to Hartree-Slater approximation is in excellent agreement with measurement. The physical reason for the discrepancies in the two approximations is explained.

Omidvar, K.↗
NASA NTRS1977

Angular distribution of Auger electrons due to 3d-shell impact ionization of krypton

Cross sections for electron impact ionization of krypton due to ejection of a 3d-shell electron have been calculated using screened hydrogenic and Hartree-Slater wavefunctions for the target atom. While the total ionization cross sections in the two approximations are within 10% of each other, the Auger electron angular distribution, related to cross sections for specific magnetic quantum numbers of the 3d electrons, are widely different in the two approximations. The angular distribution due to the Hartree-Slater approximation is in excellent agreement with measurement. The physical reason for the discrepancies in the two approximations is explained.

Omidvar, K.↗
NASA NTRS1999

Maximum Energies of Shock-Accelerated Electrons in Young Shell Supernova Remnants

Young supernova remnants (SNRs) are often assumed to be the source of cosmic rays up to energies approaching the slight steepening in the cosmic ray spectrum at around 1000 TeV, known as the "knee." We show that the observed X-ray emission of 14 radio-bright shell remnants, including all five historical shells, can be used to put limits on E(sub max), the energy at which the electron energy distribution must steepen from its slope at radio-emitting energies. Most of the remnants show thermal spectra, so any synchrotron component must fall below the observed X-ray fluxes. We obtain upper limits on E(sub max) by considering the most rapid physically plausible cutoff in the relativistic electron distribution, an exponential, which is as sharp or sharper than found in any more elaborate models. This maximally curved model then gives us the highest possible E(sub max) consistent with not exceeding observed X-rays. Our results are thus independent of particular models for the electron spectrum in SNRs. Assuming homogeneous emitting volumes with a constant magnetic field strength of 10 uG, no object could reach 1000 TeV, and only one, Kes 73, has an upper limit on E(sub max), above 100 TeV. All the other remnants have limits at or below 80 TeV. E(sub max) is probably set by the finite remnant lifetime rather than by synchrotron losses for remnants younger than a few thousand years, so that an observed electron steepening should be accompanied by steepening at the same energy for protons. More complicated, inhomogeneous models could allow higher values of E(sub max) in parts of the remnant, but the emission-weighted average value, that characteristic of typical electrons, should obey these limits. The young remnants are not expected to improve much over their remaining lives at producing the highest energy Galactic cosmic rays; if they cannot, this picture of cosmic-ray origin may need major alteration.

Reynolds, Stephen P.↗
NASA NTRS1973

A cylindrical shell model of the NASA-MPE barium ion cloud experiment.

A computer model is developed using infinitely long concentric cylindrical shells to represent the neutral atoms, ions and electrons in the barium cloud. The neutral shells are given a distribution of positions and velocities whose parameters are chosen to be consistent with the dynamics of the release. From this distribution, the ion and electron shells are generated at random using the observed time constant for photoionization. The ion and electron shells thus formed are followed using self-consistent equations of motion. Various averages which could be compared with observation of the actual cloud are calculated at regular time intervals. An unexpected result is the predicted very early return of the magnetic field within the cloud to its ambient value.

Grauer, A. D.↗
NASA NTRS1986

Diffusive electron acceleration at SNR shock fronts and the observed SNR radio spectral indices

The radio synchrotron emission from relativistic electrons in shell supernova remnants (SNRs) provides a unique opportunity to probe the energy distribution of energetic electrons at their acceleration site (SNR shock fronts). This information provides insight into the acceleration mechanism(s). The implications of these observations for the diffusive (first-order Fermi) acceleration of electrons at the SNR shock fronts are discussed.

Bogdan, T. J.↗
NASA NTRS1985

Onion-shell model for cosmic ray electrons and radio synchrotron emission in supernova remnants

The spectrum of cosmic ray electrons, accelerated in the shock front of a supernova remnant (SNR), is calculated in the test-particle approximation using an onion-shell model. Particle diffusion within the evolving remnant is explicity taken into account. The particle spectrum becomes steeper with increasing radius as well as SNR age. Simple models of the magnetic field distribution allow a prediction of the intensity and spectrum of radio synchrotron emission and their radial variation. The agreement with existing observations is satisfactory in several SNR's but fails in other cases. Radiative cooling may be an important effect, especially in SNR's exploding in a dense interstellar medium.

Beck, R.↗
NASA NTRS1981

An X-ray map of SN 1006 from the Einstein Observatory

An X-ray map of the SN 1006 supernova remnant acquired by the imaging proportional counter of the Einstein Observatory in the energy range 0.1-4 keV is presented. The image obtained from the imaging proportional counter shows a limb-brightened nebula, almost circular in outline with enhanced emission in two quadrants. The hardness ratio map reveals a large range of temperatures over the object, with the highest values near the limbs of the enhanced emission regions. Consideration of a three-dimensional model of the object indicates the presence of a shell of electron temperature varying between 10 to the 6th and 10 to the 7th K and density varying between 0.3 and 6/cu cm surrounding a fairly uniform interior, of electron temperature 1.5 x 10 to the 6th K and density 1.0/cu cm. The optical filaments are observed to lie parallel with the faintest edge of the X-ray shell, about 1 arcmin from the peak of X-ray emission. Mass visible in the X-ray image of 5-15 solar masses suggests that the supernova may have been of type II. No evidence is obtained for a hot stellar remnant.

Pye, J. P.↗
NASA NTRS2011

Positronium and Electron Scattering on Helium

A recent work [1] establishes experimentally that Positronium scattering by atoms of various elements is surprisingly close in total cross-section to that of an isolated electron of the same velocity. In this work we will look at the scattering of Ps on Helium and compare it to a determination of the scattering of an e- with the same element. For both the Ps scattering and the e- scattering on He, we assume the symmetrization of the e- with the closed shell He electrons is the dominant interaction. A local effective potential employed in [2] and [3] is used to model the electron exchange and cross- sections are determined for a set of partial waves. For the Ps scattering we include as a secondary effect the Van der Waals interaction. For single e- scattering of He, we also employ a short range Coulomb potential and dispersion as contributing effects. Results of the cross-sections determined in each case are then compared

DiRienzi, Joseph↗
NASA NTRS1977

Copernicus observations of Nova Cygni 1975

Near-ultraviolet radiation from Nova Cygni 1975 was detected by the Copernicus satellite on five occasions from 1975 September 1 to 1975 September 9. The nova was not seen in the UV after this date. The principal result was the observation of a broad emission feature from the Mg II doublet at 2800 A. The absence of strong UV radiation at shorter wavelengths suggests that these lines are produced by collisional excitation in the outer layers of an expanding shell with electron temperature of approximately 4000 K. The absence of observed emission lines from highly ionized species indicates that the amount of material with log T between 4.4 and 5.7 is less than 0.001 times that which produces the Mg II emission. The continuum flux in the near-UV decreased as the nova evolved, showing that the total luminosity decreased as the nova faded in the visible.

Jenkins, E. B.↗
NASA NTRS1983

Oscillator strengths for OII ions

Oscillator strengths between various doublet states of OII ions are calculated in which extensive multi-configuration wave functions are used. The lower levels for the transitions are of the 2p(3) D(2)o and 2p(3) 2po states, and the upper levels are 2p(4), 3s, and 3d states. The results, which are estimated to have errors of less than 10% for individual transitions, agree quite well with the beam foil experiments, as well as with the calculations by use of the non-closed shell many electron theory (NCMET). The agreement with the rocket measurements is also good except for the 538/581 A pair, in which the 538 A line is believed to be blend with the other stronger quartet line. However, a comparison with the recent branching ratio measurement indicates that discrepances between the present calculation and th experiment do exist for certain transistions.

Ho, Y. K.↗