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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2012

Descent with Modification: Thermal Reactions of Subsurface H2O2 of Relevance to Icy Satellites and Other Small Bodies

Laboratory experiments have demonstrated that magnetospheric radiation in the Jovian system drives reaction chemistry in ices at temperatures relevant to Europa and other icy satellites. Similarly, cosmic radiation (mainly protons) acting on cometary and interstellar ices can promote extensive chemical change. Among the products that have been identified in irradiated H20-ice is hydrogen peroxide (H202), which has been observed on Europa and is suspected on other worlds. Although the infrared spectra and radiation chemistry of H2O2-containing ices are well documented, the thermally-induced solid-phase chemistry of H2O2 is largely unknown. Therefore, in this presentation we report new laboratory results on reactions at 50 - 130 K in ices containing H2O2 and other molecules, both in the presence and absence of H2O. As an example of our results, we find that warming H2O + H2O2 + SO2 ices promotes SO2 oxidation to SO4(2-). We suspect that such redox chemistry may explain some of the observations related to the presence and distribution of H2O2 across Europa's surface as well as the lack of H2O2 on Ganymede and Callisto. If other molecules prove to be just as reactive with frozen H2O2 then it may explain why H2O2 has been absent from surfaces of many of the small icy bodies that are known to be exposed to ionizing radiation. Our results also have implications for the survival of H2O2 as it descends towards a subsurface ocean on Europa.

Hudson, Reggie L.↗
NASA NTRS2010

The Other Chemistry of the Jovian Icy Satellites - Low Energy and Sulfurous

Spectra of Jupiter's icy satellites reveal surfaces dominated by H2O-ice with minor amounts of SO2 and other materials. The co-existence of H2O and SO2 in surfaces exposed to jovian magnetospheric radiation suggests that sulfuric acid (H2SO4) also could be present. This was noted by Carlson et al. (1999), who supported this suggestion with assignments of near-IR bands in Europa spectra to hydrated H2SO4. Laboratory experiments since have demonstrated radiolytically-driven syntheses in S- and SO2-containing H2O-Ices (Carlson et al., 2002; Moore et al., 2006). In the Cosmic Ice Laboratory, we recently have investigated the thermal chemistry of SO2 trapped in H2O-ice. IR spectra of H2O + SO2 mixtures recorded at 10 to 230 K were used to follow low-temperature reactions in the absence of radiation effects. No SO2 reactions were found at 10 K, but warming to more-relevant Europa temperatures produced both HSO3(-) and S2O5(2-). Added NH3 shifted the product composition toward SO3(2-) and away from the other ions. We find that H2O and SO2 react to produce sulfur oxyanions, such as bisulfite, that as much as 30% of the SO2 can be consumed through this reaction, and that the products remain in the ice when the temperature is lowered, indicating that these reactions are irreversible. Our results suggest that thermally-induced reactions can alter the chemistry at and below the surfaces of the icy satellites in the jovian system.

Hudson, Reggie L.↗
NASA NTRS2018

Thermal Analysis of Propulsion Components for the Europa Clipper Mission

This presentation describes the thermal analysis and model development that occurred for selected components on the propulsion module subsystem of the Europa Clipper mission, which will fly to Jupiter's icy moon Europa and collect science data from orbit. An overview of a bipropellant system is given, as well as a description of a typical thermal propulsion design. A comparison is also provided, describing the unique Europa Clipper thermal design, which is atypical in many respects. The engine thermal model development is also discussed, including hot-firing tests with nozzle convection correlation, as well as thermal vacuum tests to measure and correlate the emissivity of critical nozzle surfaces. A description of engine firing, as well as valve soak back, is also provided, including temperature maps and results of engine cases. A summary is also provided, of lessons learned regarding thermal propulsion considerations.

propulsion module subsystem↗
NASA NTRS2024

Subsurface Thermophysical Properties of Europa's Leading and Trailing Hemispheres as Revealed by ALMA

We present best-fit values of porosity—and the corresponding effective thermal inertiae—determined from three different depths in Europa's near-subsurface (∼1–20 cm). The porosity of the upper ∼20 cm of Europa's subsurface varies between 75% and 50% (Γeff ≈ 50–140 J m −2 K −1 s −1/2 ) on the leading hemisphere and 50%–40% (Γeff ≈ 140–180 J m −2 K −1 s −1/2 ) on the trailing hemisphere. Residual maps produced by comparison with these models reveal thermally anomalous features that cannot be reproduced by globally homogeneous porosity models. These regions are compared to Europa's surface terrain and known compositional variations. We find that some instances of warm thermal anomalies are co-located with known geographical or compositional features on both the leading and trailing hemisphere; cool temperature anomalies are well correlated with surfaces previously observed to contain pure, crystalline water ice and the expansive rays of Pwyll crater. Anomalous regions correspond to locations with subsurface properties different from those of our best-fit models, such as potentially elevated thermal inertia, decreased emissivity, or more porous regolith. We also find that ALMA observations at ∼3 mm sound below the thermal skin depth of Europa (∼10–15 cm) for a range of porosity values, and thus do not exhibit features indicative of diurnal variability or residuals similar to other frequency bands. Future observations of Europa at higher angular resolution may reveal additional locations of variable subsurface thermophysical properties, while those at other wavelengths will inform our understanding of the regolith compaction length and the effects of external processes on the shallow subsurface.

Alexander E Thelen↗
NASA NTRS2017

Design and Development of the Heat Redistribution System for the Mission to Europa Spacecraft:

This paper details the conceptual design of the Heat Redistribution System (HRS) used for thermal control of the Europa Clipper spacecraft. The solar powered spacecraft will launch in the early 2020s and will study Jupiter’s Icy moon, Europa, where previous investigations have indicated the possibility of a liquid water ocean underneath its ice-encrusted surface. The spacecraft will execute multiple flybys of Europa while relying on the HRS for thermal control of the spacecraft bus. The HRS utilizes a Mechanically Pumped Fluid Loop (MPFL) to reclaim waste heat from an avionics and payload electronics compartment and redistribute it to other parts of the spacecraft, such as the propulsion module structure and the louver-radiator assembly. A “replacement heater block” provides supplemental heat when needed to maintain the spacecraft hardware above its allowable flight temperatures. Additionally, a set of thermal control valves autonomously actuate to reduce the fluid flow through the radiator during cold environment cases. The HRS was used in previous flight projects at JPL such as Mars Science Laboratory, but the uniqueness of the Europa Clipper mission has mandated changes to previous HRS designs; the most significant design drivers and design changes for this iteration of the HRS are discussed.

Bertagne, Christopher↗
DOE OSTI2026

Passive Microwave Radiometry and Active Radar Sounding as Complementary Tools for Geophysical Investigations of Icy Ocean Worlds

Juno Microwave Radiometer (MWR) observations of Europa and Ganymede offer critical insights into the icy shells of these moons ahead of NASA's Europa Clipper and ESA's JUpiter ICy moons Explorer (JUICE) missions. Both missions are equipped with active radar sounders designed to address key unknowns such as ice shell thickness, thermal state, and composition. In this study, we explore how passive microwave radiometry and active radar sounding can constrain ice shell properties, focusing on Europa. Using modeled microwave brightness temperature observations at 0.6 and 1.2 GHz alongside simulated radar attenuation rate observations, we show that each instrument can independently produce robust ice shell thickness constraints under idealized conditions. We then relax these assumptions, quantifying how uncertainties from non-ideal properties—including convective layers, freezing-point depression, and chloride-doped ice—affect thickness estimates. Finally, we demonstrate how combining observations from these complementary techniques breaks degeneracies between ice shell properties, enabling more robust constraints than either method alone. This approach will maximize the science return of Europa Clipper and JUICE, advancing our understanding of the thermophysical structure and habitability of icy ocean worlds.

58 GEOSCIENCES↗
NASA NTRS1987

Spectral reflectance (0.4 - 5.0 microns) of sulfur related compounds and mixtures

Studied and quantified were: (1) the spectral properties of sulfur related compounds and materials; (2) the effects of thermal history, temperature and mixing ratios on the spectral properties of these materials; and (3) the application of these results to the Jovian system, in particular, the surfaces of Io, Europa, and Amalthea, and the chromophores in the Jovian atmosphere. Major results of the study include: (1) a study of how sulfur deposition affects the band strengths in various silicates; (2) a study of how the ultraviolet absorption band of sulfur is affected by dilution in ice; (3) the application of these two sets of experimental studies to Io, in the case of silicate band strengths, and Europa, as in the case of sulfur dilution in ices.

Gradie, Jonathan C.↗
NASA NTRS2021

Europa Clipper Magnetometer Thermal Design Evolution, Validation, and Verification

Europa Clipper Spacecraft is exposed to a high radiation environment and is limited with power. This makes the thermal design of Europa Clipper magnetometer more challenging. The design is required to be highly insulated and at the same time magnetically clean. This paper describes the thermal design evolution of Europa Clipper Magnetometer. A thermal vacuum test is conducted in Europa Clipper orbit’s relevant environment to characterize the requirements and estimate the power consumption. A flight-like engineering model magnetometer from the University of California at Los Angeles (UCLA) is used for this test. Magnetically clean Cernox temperature measurement sensors with the accuracy of ±0.1ºC are used to measure the temperature value inside the sensor head and across the main frame interfaces. This level of accuracy in temperature measurement is required to capture the temperature gradient across the sensor head in a relevant environment which impacts the magnetometer measurement accuracy. Test data is used to correlate the thermal model and characterize the heat leak across the interfaces. Validated thermal model is used as a verification tool for power consumption and thermal requirements.

Caron, Ryan↗
NASA NTRS2020

Characterization Testing of Space-Flight Lockheed Martin Micro1-2 Cryocooler for the Mapping Imaging Spectrometer for Europa (MISE)

The Mapping Imaging Spectrometer for Europa (MISE) instrument on the Europa Clipper mission uses a Lockheed Martin “high-power” Micro1-2 pulse tube cryocooler with a heat rejection temperature around 220 K to provide cooling at 80 K. This paper describes the thermal performance and exported forces characterization testing and results of the space-flight Lockheed Martin Micro1-2 cooler optimized for these conditions. Prior to these characterization tests, the cooler passed random vibration and thermal vacuum cycling at Lockheed Martin.

Rodriguez, Jose↗
NASA NTRS2021

Europa Environmental Testing of Thermal Hardware for the Mapping Imaging Spectrometer for Europa (MISE) Instrument

The Europa Clipper spacecraft, scheduled for launch in June 2022, hosts a suite of instruments including the Mapping Imaging Spectrometer for Europa (MISE). MISE is a high-optical through-put pushbroom infrared imaging spectrometer that can collect measurements within Europa’s challenging radiation environment. It is externally mounted to the spacecraft and as a result is exposed to high radiation levels and cold temperatures. The instrument consists of a scan mirror assembly, an optical bench including a Dyson spectrometer and a telescope, and a structure that supports a cryocooler and a radiator. The cryocooler is used to actively cool the focal plane array and the spectrometer. The heat from the cryocooler is rejected through pyrolytic graphite sheet thermal straps to a honeycomb radiator. MISE will implement thermal hardware that will either not be used on other parts of the spacecraft or have a more extreme environment than the spacecraft. As a result, the MISE instrument performed numerous environmental tests on its thermal hardware. This paper discusses the results of the thermal cycling and radiation tests performed on the MISE thermal hardware including a Lockheed Martin Micro1-2 cryocooler, Pyrolytic graphite sheet thermal straps, Annealed pyrolytic graphite K-Core, Rosemount Platinum Resistance Thermometers, Tayco Kapton Thermofoil heaters, Dale Ohm resistors, and aluminum honeycomb and facesheets.

Strong, Patrick↗
NASA NTRS2003

An Examination of Issues Related to a Europa Subsurface Component for the JIMO Mission

The Galileo Europa data set served to revolutionize our view of Europa. In particular the strong evidence of a large, cold, salty Ocean beneath 5-30 km of ice has profoundly altered the significance of Europa in our thinking, especially of context of habitability in the solar system. While much remains to be learned from spacecraft observations of several sorts, there are significant questions answerable only by in-situ techniques; these relate to the formation of Europa, the nature of its ocean, and the prospects for life in its ocean, sediments, and ice. We feel that wide-ranging discussion of an in-situ subsurface mission to Europa, as part of JIMO, should proceed. The science objective of the mission is to characterize the icy shell of Europa to resolve its provenance, estimate the composition of brine of the Europa ocean, and search for evidence of Earth-like life. Probably anyone would agree that an in-situ mission to Europa would be of great value, but he or she would also immediately take the position that such a mission is utterly impractical. We take the position here of defining the least complex mission that can nonetheless justify its cost and to argue that such a mission is realistic enough that it should be seriously considered. Our mission thinking has been: 1) Soft landing. A soft lander is required on a site sufficiently flat to offer a stable platform; no further site selectivity is required. 2) Subsurface exploration. The Europa subsurface must be examined. Surficial processes on Europa arguably have exposed the upper 200 m of shell to chemical effects from the Jovian radiation belts as well as cometary infall, etc; to examine native ice we must descend below that point to, for discussion, 300 m. At that depth we argue that the ice is characteristic of ice at depth and possibly is effectively sea ice. 3) Science data. A few simple measurements at various depths and at 300 m constitute a scientifically successful mission. Measurements would include analysis of meltwater for a few inorganic ions and amino acids and an optical examination of the borehole wall. 4) Communication. Transmission of data to an orbiter is essential, but we will constrain the landed mission to a daily communication over a few days. 5) Subsurface access. Drilling to 300 m is a significant challenge; it can be addressed by several means: Thermal Probe (Cryobot) which permits water to refreeze above the vehicle. This is our tentative choice with plutonium as the fuel to generate thermal energy for drilling and electrical power for operations. Open Hole Drill, a thermal system in which the meltwater is removed for greater thermal efficiency. Meltwater removal on Europa is both a complexity and a risk, but analysis is improved. Mechanical Drilling in which cutting or grinding generates ice chips which are removed. This is too complex at Europa temperatures. The measurement objectives for the mission will be: Obj. 1: Determine the concentration of simple inorganic salts in the Europa Ice Shell and, by extrapolation, of the ocean. These data will also validate spaceborne sensors. Obj. 2: Determine the nature and abundance of amino acids in the ice such that cometary infall material in the upper ice can be compared to material at depth. Obj. 3: Optically examine the ice to resolve inclusion structure, particulate content, and stratification. Access to 300 m depth is a significant if not audacious plan; we are aware that this has not been done on any planetary body. Our approach is the use of a plutonium heat source; to overcome Europa's surface temperature and to melt ice a significant amount of plutonium is needed, and significant shielding and other protective steps will be required. The quantity of plutonium is a key concern. The mission will require subsurface collection and processing of samples for in situ analysis, calling for a miniature, high pressure micro-sampling system designed to meet needs of instruments that require low presses for operation. The inlet system itself collects a micro-sample in the external high pressure environment, then transfers it into a protected low pressure environment for analysis.

Carsey, F. D.↗
NASA NTRS2015

Survival of Organic Materials in Ancient Cryovolcanically-Produced Halite Crystals

Spectroscopic evidence supports the presence of Mg-Na-K salts derived from cryovolcanism on the surface of Europa. Halite (NaCl) is effective at very long-term preservation of organic phases and structures. Collection of salt crystals from Europan plumes would provide solid inclusions of organics, potentially also biomaterials, all suitable for analysis. Two thermally-metamorphosed ordinary chondrite regolith breccias (Monahans 1998 (H5) and Zag (H3-6)) contain fluid and solid inclusion-bearing halite crystals, dated to approximately 4.5 billion years, and thus the trapped aqueous fluids and solids are at least as old. Heating/freezing studies of the aqueous fluid inclusions in these halites demonstrated that they were trapped near 25 degrees Centigrade, and their continued presence in the halite grains requires that their incorporation into the H chondrite asteroid occurred after that body's metamorphism ended, since heating would have dessicated the halite. O and H isotopes of the trapped fluids are consistent with mixing of asteroidal and cometary water. Cryovolcanic Origin of the Halite: We hypothesize that these meteoritic halites derive from ancient cryovolcanism based on the following points. (1) Salts crystals are observed as products of current cryovolcanism on Enceladus. (2) In-situ spacecraft analysis of some of the icy grains associated with the Enceladus salt found minor organic or siliceous components, including methane, also found in the Monahans halite. (3) Cryovolcanic fluids are observed to be in chemical disequilibrium, reflecting incomplete reactions between interior volatiles and rocky materials. The coexistence of N2 and HCN in Enceladus' cryovolcanic fluids requires that the plume consists of a mixture of materials whose sources experienced different degrees of aqueous processing, including primordial material trapped in ice that has not been in contact with liquid water. The observed mineral assemblage within the Monahans and Zag halites is also far from equilibrium. Cryovolcanoes on Ceres are a potential source of our halite, however the processes that form halite should also be operating within Europa. Dissolution of Monahans halite grains has revealed a remarkable variety of organics, which dominate the population of solid inclusions. Thermal alteration of this macromolecular carbon (measured by Raman spectroscopy) shows remarkable diversity. We have identified highly-condensed aromatics, diamond, carbonates and chloromethane. Light organic compounds like methane tend to be water soluble and require cold formation temperatures at high hydrogen fugacity - i.e. require water ice. Another indication that these halites have not been heated is that light organics readily volatilize or aromaticize into PAHs. We are currently analyzing the organics by Raman and C-XANES, and measuring the content and exploring the potential chirality of amino acids in the halite. Implications for Europa Plumes: Organic materials and structures erupted by a Europa cryovolcano should be similarly preserved within halite, and other salts, which will be a convenient form for capture and analysis, since halite will serve to encapsulate and protect the organics from spacecraft contamination. Also, being transparent at many wavelengths halite will permit analysis by spacecraft-mounted spectroscopic techniques. In addition, halite is readily dissolved, permitting further analysis of entrained organics.

Zolensky, M.↗
NASA NTRSDate not supplied

Thermal Control Coating Charging Tests for the Europa Clipper Mission

Thermal control coatings are an essential part of spacecraft systems. Typically, these coatings are directly exposed to the space environment, which means they must be designed and applied in a manner that can withstand exposure to radiation, ultra-violet light, thermal cycles, etc. In the case of the Europa Clipper mission, the thermal control coatings must also have relatively low resistivity in order to minimize electrostatic charging (and discharging) due to the abundant low-energy plasma populations in the Jovian environment. This paper will present the results of a test campaign led by NASA’s Jet Propulsion Laboratory (JPL) to find thermal control coating solutions that minimized the occurrence of electrostatic discharges – even at cryogenic temperature conditions. The customized laboratory test system at NASA’s Marshall Space Flight Center will be described, along with the test requirements and conditions. Finally, a summary of the coatings with the best electrostatic characteristics will be provided.

Thermal Control Coatings↗
NASA NTRS2019

Novel concept for detection of a fluid flow fault in a pumped fluid heat rejection system

A pumped fluid heat rejection system (HRS) requires continuous flow of the working fluid to ensure that the components controlled by the HRS stay within their allowable temperature limits. An interruption of flow could result in violations of hardware qualification limits and mission failure. Some of these violations can happen within a few hours. Hence, quick detection of a flow fault to invoke mitigation measures is very critical. In typical pumped fluid HRS, dual or triple pumps are employed to switch the backup units in case the primary unit were to fail. The key metric for the selection of a fault detection system is that it should detect the fault much before the fault’s impact on the thermal health of the HRS controlled components is realized. A trade study was conducted to select such a system for the Europa Clipper Mission to Europa, a moon of Jupiter that is planned for a launch in 2023. Out of the several concepts studied, the most attractive one was a novel and simple concept that uses a low power film heater attached to a section of the HRS tubing. While the fluid flows at its nominal rate, the high thermal coupling of the flowing fluid leads to the tube being close to the fluid’s temperature. However, when the flow stops, the heater warms the small thermal mass of the tubing to a high temperature in a short span of time (~15 minutes). This large temperature rise would then imply that the flow must have stopped. This paper will describe the various concepts considered, the chosen concept, its implementation, and the results of developments tests to validate its performance.

Schmidt, Tyler↗
NASA NTRS2018

Characterization Testing of Lockheed Martin Micro1-2 Cryocoolers Optimized for 220 K Environment

The Mapping Imaging Spectrometer for Europa (MISE) Instrument on the Europa Clipper mission has baselined a Lockheed Martin high-power Micro1-2 pulse tube cryocooler operating at 135 Hz with a 220 K heat rejection temperature. This paper describes the testing and results of two Lockheed Martin Micro1-2 coolers optimized for these conditions. The thermal performance of the microcoolers was measured in vacuum for heat reject temperatures between 220 and 230 K. The coolers were operated with input powers ranging from 5 W to 40 W and drive frequency between 125 Hz and 145 Hz. The optimal drive frequency was strongly dependent on heat reject temperature. In addition, the exported forces and torques of the coolers were measured at 300 K heat rejection for input powers ranging from 5 W to 60 W and drive frequency between 120 Hz and 160 Hz. The exported forces were dependent on both piston amplitude and drive frequency. Moreover, the following were measured on one of the coolers: DC and AC magnetic fields at various locations, the off-state conductance of the pulse tube, and the effect of inclination angle of the pulse tube relative to gravity on the performance of the cooler. Finally, one of the coolers was subjected to random vibration testing.

Rodriguez, J.I.↗
NASA NTRS1989

Thermal state of an ice shell on Europa

The thickness of the ice shell presently hypothesized for Europa, which is decoupled from a silicate core by a liquid water layer, is calculated as a function of colatitude and longitude under suitable assumptions for two plausible ice rheology behaviors: that of Maxwell type, and that of generalized flow-law rheology. Due to the dissipation rate's pronounced temperature dependence, virtually all tidal dissipation is found to concentrate in the lowest few kilometers of the shell. While for some parameter choices an insulating regolith that raises the near-surface temperature by more than a few tens of degrees C may stabilize the shell against polar wander, a modest regolith may enhance the probability of such wander's occurrence through the reduction of the shell's retarding friction.

Ojakangas, Gregory W.↗
NASA NTRS2008

Extreme Environment Technologies for Space and Terrestrial Applications

Over the next decades, NASA's planned solar system exploration missions are targeting planets, moons and small bodies, where spacecraft would be expected to encounter diverse extreme environmental (EE) conditions throughout their mission phases. These EE conditions are often coupled. For instance, near the surface of Venus and in the deep atmospheres of giant planets, probes would experience high temperatures and pressures. In the Jovian system low temperatures are coupled with high radiation. Other environments include thermal cycling, and corrosion. Mission operations could also introduce extreme conditions, due to atmospheric entry heat flux and deceleration. Some of these EE conditions are not unique to space missions; they can be encountered by terrestrial assets from the fields of defense,oil and gas, aerospace, and automotive industries. In this paper we outline the findings of NASA's Extreme Environments Study Team, including discussions on state of the art and emerging capabilities related to environmental protection, tolerance and operations in EEs. We will also highlight cross cutting EE mitigation technologies, for example, between high g-load tolerant impactors for Europa and instrumented projectiles on Earth; high temperature electronics sensors on Jupiter deep probes and sensors inside jet engines; and pressure vessel technologies for Venus probes and sea bottom monitors. We will argue that synergistic development programs between these fields could be highly beneficial and cost effective for the various agencies and industries. Some of these environments, however, are specific to space and thus the related technology developments should be spear headed by NASA with collaboration from industry and academia.

extreme environments↗
NASA NTRS2002

Thickness Constraints on the Icy Shells of the Galilean Satellites from a Comparison of Crater Shapes

A thin outer ice shell on Jupiter's large moon Europa would imply easy exchange between the surface and any organic or biotic material in its putative subsurface ocean. The thickness of the outer ice shell is poorly constrained, however, with model-dependent estimates ranging from a few kilometers of depths of impact craters on Europa, Ganymede and Callisto that reveal two anomalous transitions in crater shape with diameter. The first transition is probably related to temperature-dependent ductility of the crust at shallow depths (7-8 km on Europa). The second transition is attributed to the influence of subsurface oceans on all three satellites, which constrains Europa's icy shell to be at least 19 km thick. The icy lithospheres of Ganymede and Callisto are equally ice-rich, but Europa's icy shell has a thermal structure about 0.25-0.5 times the thickness of Ganymede's or Callisto's shells, depending on epoch. The appearances of the craters on Europa are inconsistent with thin-ice-shell models and indicate that exchange of oceanic and surface material could be difficult.

Schenk, Paul M.↗