NASA NTRS1991
The N2O infrared spectrum from 900 to 4700/cm has been studied with a high-resolution Fourier-transform spectrometer. Measurements were made of line frequencies of several N2O isotopes for several ground-state and hot bands. These bands include the 1530-0330, 2330-0330, 0441-0440, 0441-0330, 0531-0330, and 1331-0330 bands of (N-14)2(O-16). Also, perturbation-enhanced transitions in the 0710-0110 and 0730-0110 bands were assigned and measured. The frequencies have been analyzed to obtain a unique set of effective vibration-rotation parameters for each vibrational state. The results obtained from this research are of high accuracy for the ground-state, and the first-excited-state bands of (N-14)2(O-16), in which the computed frequencies derived from the least-squares fits, are known to an absolute uncertainty of only +/-4 x 10 exp -5 for nonperturbed transitions.