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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Hydrogen Enrichment for Solid Oxide Fuel Cell Gas Turbine (SOFC/GT) Hybrid Power Generation Systems Using Mechanical Gas Separation

This presentation, given at the 37 th annual Pittsburgh Coal Conference on September 8-11, 2020, includes information on the process, previous work, normal and oblique shocks model, diffuser design model, and calculation results (expansion, recompression with no losses, and recompression with mass depletion). Summary includes the concept of aerodynamic separation of water and carbon dioxide from a SYNGAS stream and that deposition was modeled by mass depletion from a compressible flow.

VanOsdol, John↗

In-gas-jet laser spectroscopy with S 3 -LEB

The Super Separator Spectrometer-Low Energy Branch (S 3 -LEB) is a low-energy radioactive ion beam experiment under commissioning as part of the GANIL-SPIRAL2 facility. It will be used for the production and study of exotic nuclei by in-gas laser ionization and spectroscopy (IGLIS), decay spectroscopy, and mass spectrometry. Here, we report recent results from the off-line commissioning of S 3 -LEB, including first laser spectroscopy measurements in both the gas cell and the supersonic gas jet, the determination of the transport efficiency of laser ions from the gas cell through the RFQ chain, and time-of-flight measurements with the multi-reflection time-of-flight mass spectrometer PILGRIM. The measurements were performed using erbium, introduced by evaporation from a heated filament in the gas environment. The reported laser spectroscopy results include a characterization of the pressure broadening in the gas cell, proof-of-principle isotope shift measurements, and hyperfine-structure measurements.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Machine Learning Tools Set for Natural Gas Fuel Cell System Design

This study is focusing on leveraging the system design tools set for the next-generation solid oxide fuel cell (SOFC) based natural gas fuel cell (NGFC) system. Conventionally, system design and optimization of NGFC systems rely heavily on traditional reduced order model (ROM) techniques and designers’ experience level. For overcoming the technical barriers of system design, multiple multi-physics models and machine learning (ML) tools have been utilized to automate the conceptual design process and enhance the reliability of solutions for the NGFC system. The proposed tools set includes a physics-informed ML tool for automated ROM construction that leverages advances in deep neural networks to significantly reduce ROM prediction error for the NGFC power island compared to traditional approaches. The constructed physics-informed ML ROM can be used in system design, and optimization tools set Institute for the Design of Advanced Energy Systems (IDAES) Process Systems Engineering (PSE) framework. The tools set also provides a user-friendly graphic user interface built within Jupyter Notebooks, and the complete tools set is open-source public available.

Wang, Dewei↗

DEVELOPMENT OF OIL FREE CENTRIFUGAL BLOWER AS ENABLING TECHNOLOGY FOR SOLID OXIDE FUEL CELL ANODE GAS RECYCLING

Broad commercialization of solid oxide fuel cells (SOFCs), requires anode offgas recycle blowers (AORB) that are specifically designed for handling the challenging operating conditions presented by the SOFC process gases. Otherwise, they can be susceptible to frequent maintenance, low reliability, and short life. This work presents details of the development and testing of an oil-free, low cost centrifugal AORB based on compliant foil bearing (CFB) technology for support of a 100 kW solid oxide fuel cell power plant. The advantages of this novel technology are discussed, particularly its long life and maintenance-free operation, which are derived from the use of CFBs. Also included are preliminary techno-economic analysis considerations for cost-effective deployment of the technology.

03 NATURAL GAS↗

Lasergate: A windowless gas target for enhanced laser preheat in magnetized liner inertial fusion

At the Z Facility at Sandia National Laboratories, the magnetized liner inertial fusion (MagLIF) program aims to study the inertial confinement fusion in deuterium-filled gas cells by implementing a three-step process on the fuel: premagnetization, laser preheat, and Z-pinch compression. In the laser preheat stage, the Z-Beamlet laser focuses through a thin polyimide window to enter the gas cell and heat the fusion fuel. However, it is known that the presence of the few μm thick window reduces the amount of laser energy that enters the gas and causes window material to mix into the fuel. These effects are detrimental to achieving fusion; therefore, a windowless target is desired. The Lasergate concept is designed to accomplish this by “cutting” the window and allowing the interior gas pressure to push the window material out of the beam path just before the heating laser arrives. In this work, we present the proof-of-principle experiments to evaluate a laser-cutting approach to Lasergate and explore the subsequent window and gas dynamics. Further, an experimental comparison of gas preheat with and without Lasergate gives clear indications of an energy deposition advantage using the Lasergate concept, as well as other observed and hypothesized benefits. While Lasergate was conceived with MagLIF in mind, the method is applicable to any laser or diagnostic application requiring direct line of sight to the interior of gas cell targets.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Summary for Z-Petawatt Laser Activities (CY2019)

The high-energy upgrade of the Z-Petawatt (ZPW) laser system involved a shot hiatus starting in October 2018 to allow the installation of full-aperture optics in the chain, including in the main amplifier section as well as in the branches associated with the ZPW compressor and co-injection (the narrowband nanosecond operating mode that is co-bored with Z-Beamlet). Laser shots resumed May 1 st , with most shots since being in the ns mode to reduce complexity (while conditioning optics and calibrating diagnostics) as well as to support experimental requests. To facilitate experimental needs while a final full-sized co-injection optic was prepared, a sub-apertured beam has been used for experimental applications and a full-apertured beam has been used to validate the system. In the latter case, the beam is directed to a large calorimeter placed before branching occurs to the ZPW compressor or co-injection. As of September 2019, full-aperture co-injection shots had ramped up to 960J in 2.3ns, with many cross-calibrations being used to map out a relative humidity dependency in the leaky diagnostic mirror. Several such cross-calibration shots have been done using a chirped pulse seed as well, verifying that the diagnostic calibrations are valid in both broadband and narrow-band modes. Summarizing, since May 1 st of 2019 when shots resumed, 93 full system shots were performed with the ZPW laser. This included 2 co-injection shots with ZBL into Z (in support of MagLIF), 26 Pecos gas cell shots (in support of MagLIF), 11 Conchas gas cell shots (in support of UXI applications development), 6 Jemez shots (in support of backlighter development), and 48 calorimeter shots (in support of validating the system performance). Of these 93 shots, 45 shots were in conjunction with ZBL.

43 PARTICLE ACCELERATORS↗

A Novel Multiagent Resource Sharing Algorithm for Control of Advanced Energy Systems

This paper implements a novel resource sharing control strategy on a fuel cell–gas turbine hybrid power system at the National Energy Technology Laboratory’s Hybrid Performance Facility (Hyper). In a fuel cell–gas turbine hybrid power system, the simultaneous interaction of the gas turbine and the fuel cell creates a tightly coupled environment characterized by conflicting dynamics. In this paper, a model-free control approach is applied to solve the tightly coupled control problem posed by this challenging environment. Specifically, this control problem is presented as a resource sharing problem that can be solved using a resource sharing algorithm that is defined based on the distribution construction concept. This algorithm creates computational agents and solves the problem through the distribution and redistribution of shared resources defined as blocks. Furthermore, two agents were created; the first agent (agent 1) controls the gas turbine speed by adjusting the electric load, and the second agent (agent 2) controls the cathode mass flow through the fuel cell using the cold-air bypass valve. A parametric study was performed over the course of 15 experimental tests for both agents 1 and 2 through an evaluation of the responses based on setpoint changes. The algorithm was shown to have behavior comparable to a previously implemented multi-input multioutput state-space controller, which was designed through a model-based control approach. The resource sharing algorithm was able to find stable performance during run-time operations without any prior system knowledge identification on the power plant and without creating models used in traditional control strategies.

25 ENERGY STORAGE↗

In-situ measurement of moist flue gas under high pressure using a nafion dryer and FTIR

The formation of the main flue gas species (NOx, SOx, CO2, and CO) in pressurized oxy-fuel combustion can be fundamentally different from oxy-fuel combustion at atmospheric pressure. To accurately obtain the concentration of these gas species in a pressurized oxy-fuel combustor, a gas measurement which maintains the sampling pressure is needed. Very few published studies have accomplished this, and never under the conditions reported herein. In this work, we fire PRB coal in a 100 kWth staged pressurized oxy-fuel combustor (SPOC) under a pressure 15 bara. We utilize a state-of-the-art FTIR (Thermo Scientific Nicolet iS20) with a novel high-pressure gas cell that is under process pressure to measure the in-situ flue-gas concentration in a sampled flow. However, water vapor can significantly interfere with the FTIR measurement, particularly under pressure. To address this problem, we have developed a high-pressure nafion dryer to selectively remove the water vapor from the flue gas while retaining the flue gas species. This approach can significantly increase the signal-noise ratio for the FTIR. By integrating the nafion dryer and the high-pressure gas cell, we were able to successfully measure flue gas species at system pressure with the FTIR.

Cheng, Mao↗

Techno-Economic Analysis of Natural Gas Fuel Cell Plant Configurations

The United States (U.S.) Department of Energy (DOE) Office of Fossil Energy and Carbon Management (FECM) and the National Energy Technology Laboratory (NETL) have been pursuing the development of solid oxide fuel cell (SOFC) technology to enable future power generation systems that are consistent with the cornerstones of the DOE mission—to ensure America’s security and prosperity by addressing its energy and environmental challenges through transformative science and technology solutions. The U.S. DOE FECM SOFC Program is currently focused on the development of low-cost, highly efficient, and reliable SOFC power systems. NETL’s SOFC technology development roadmap is aligned with near-term market opportunities in the distributed generation sector to validate and advance the technology while paving the way for utility-scale (> 50 MW) natural gas and coal-derived synthesis gas-fueled applications via progressively larger system demonstrations. The present study represents a part of a series of system evaluations being developed at NETL to aid in prioritizing technological advances along research pathways to the realization of utility-scale SOFC systems, a transformational goal of the fuel cell program. In particular, the system performance of utility-scale natural gas fuel cell (NGFC) systems with and without carbon dioxide (CO 2 ) capture is presented. The objective of the study is to provide targeted research and development (R&D) guidance to the FECM SOFC Program and SOFC commercial developers to accelerate technology deployment.

03 NATURAL GAS↗

Effect of collisions on the shape of the coherent population trapping resonance detected by the Ramsey method

We report on a theoretical model of the effect of coherent population trapping in alkali atoms in an optically thin gas cell with a buffer gas at a nonzero temperature in a pulsed laser field. The shape of the Ramsey resonance is analysed for two different temperature ranges, i. e. for a ‘cold’ atomic ensemble and for an ensemble of ‘hot’ atoms in a cell with a buffer gas. The influence of the hyperfine structure of the excited level on the shift of the central Ramsey resonance is investigated. (paper)

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

X-ray absorption spectroscopy measurements of radiatively ionized argon gas

X-ray absorption spectroscopy is a diagnostic tool that can characterize the temperature and ionization state of a plasma. This technique requires experiments to characterize the platform, careful data calibration, and comparison with atomic models to understand the plasma parameters. We performed ionizing radiation wave experiments at the OMEGA Laser Facility that used an ∼ 80 eV X-ray source to heat an Argon (Ar) gas cell at fill pressures of 3 atm. To diagnose the Ar plasma, we used a capsule backlighter offset 10 mm from the gas cell, to produce X-rays that were absorbed by the ionized Ar gas. The absorption analysis was calibrated using the significant line structure in the backlighter spectrum, which served as independent energy fiducials enabling definitive measurements of a 50-eV shift in the energy of the Ar K-edge due to ionization. We compare the measured absorption spectra to two independent atomic models, PrismSPECT and SCRAM, and show that the observed K-edge shift in the heated gas is consistent with ionization up to Ar 4+ and temperatures of 10 eV.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Magnetic field effects on laser energy deposition and filamentation in magneto-inertial fusion relevant plasmas

We report on experimental measurements of how an externally imposed magnetic field affects plasma heating by kJ-class, nanosecond laser pulses. The experiments reported here took place in gas cells analogous to magnetized liner inertial fusion targets. We observed significant changes in laser propagation and energy deposition scale lengths when a 12T external magnetic field was imposed in the gas cell. We find evidence that the axial magnetic field reduces radial electron thermal transport, narrows the width of the heated plasma, and increases the axial plasma length. Reduced thermal conductivity increases radial thermal gradients. This enhances radial hydrodynamic expansion and subsequent thermal self-focusing. Our experiments and supporting 3D simulations in helium demonstrate that magnetization leads to higher thermal gradients, higher peak temperatures, more rapid blast wave development, and beam focusing with an applied field of 12T.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Atomic kinetics of laboratory photoionized plasmas relevant to astrophysics. Final report

The major goal of this project was to study the atomic and radiation physics of photoionized plasmas driven by a broadband x-ray flux and its impact on plasma x-ray heating and ionization, emissivity and opacity, and radiation-hydrodynamics. This problem is relevant to the physics of accretion disks surrounding black holes, x-ray binaries, and active galactic nuclei in astrophysics. In addition, it is also important for understanding non-equilibrium laboratory plasmas driven by a distribution of photons. To this end, and motivated by previous and ongoing gas-cell experiments performed by the PI at the Z facility of Sandia National Laboratories, we developed a new experimental platform at the 1MA Zebra pulsed power accelerator of the University of Nevada, Reno based on using a gas jet produced by a supersonic nozzle. The gas jet is turned into a photoionized plasma driven by the x- ray flux from a wire-array z-pinch. Establishing this new experimental platform at Zebra was a major goal of this project. In addition, we have also dedicated effort to continue complementary experiments at the Z facility using the gas-cell photoionized plasma set up with support from the Fundamental Science Program at Z as well as to perform data processing and analysis, and theory and modeling simulations, including electron kinetics and radiation-hydrodynamics. Since we seek to test and establish what physics models are needed to describe photoionized plasma guided by experimental observation, these complementary experimental efforts were central to achieving the goals of this project.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Metal-Supported Solid Oxide Fuel Cells for Natural Gas

Solid oxide fuel cells (SOFCs) are high temperature energy conversion devices that produce electricity efficiently and sustainably. High operating temperatures required for SOFC function endow these devices with many advantages including fuel flexibility and high conversion efficiencies. Fuel flexibility, in particular, distinguishes SOFCs from other types of fuel cells that operate with clean H 2 only, and enables operation with natural gas (NG). LBNL has developed metal supported SOFCs (MS-SOFCs) with unique symmetrical architecture that offer several advantages over state of the art (SoA) ceramic SOFC models including inexpensive materials, rapid start up capability, increased mechanical strength and high tolerance to thermal cycling, Fig 1. These advantages make LBNL MS-SOFCs uniquely suited for fast start-up, portable, and mobile backup generator applications. Specifically motivating this work was a scenario of backup generators fueled by pipeline natural gas delivered from SoCalGas in the event of an electric grid shut down. This project investigates the feasibility of using MS-SOFCs with pre-reformed natural gas as well as direct on-cell reforming of simulated natural gas both with and without sulfur.

03 NATURAL GAS↗