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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Green syntheses of stable and efficient organic dyes for organic hybrid light-emitting diodes

Organic hybrid light-emitting diodes (hybrid-LEDs) employ organic dyes as light converters on top of commercial blue inorganic LEDs, replacing incumbent inorganic phosphor light converters synthesized from rare-earth and/or toxic metallic elements to optimize device environmental sustainability. Here, we present two naturally derived organic dyes for hybrid-LEDs, highlighting stability and efficiency enhancement based on a novel “acceptor–acceptor” molecular design. This “acceptor–acceptor” skeleton comprises theobromine and thiadiazole, two electron-withdrawing groups that lower energy levels and suppress photooxidation. This differentiates these dyes from the widely adopted “donor–acceptor” skeleton, where photooxidation is facilitated by the presence of electron-donating units. Simultaneously, sidechains on organic dyes used to enhance solution processability, crucial for film transparency, introduce an additional photooxidation pathway. With this “acceptor–acceptor” skeleton, the destabilization from sidechains was offset by the stability enhancement from the electronic effects in the backbone. Additionally, when blended within an industrial polymer, poly(styrene-butadiene-styrene) (SBS), their enhanced solubility enables the formation of highly transparent films, crucial for reducing scattering loss in LEDs. Furthermore, resultant dye-SBS films achieved photoluminescence quantum yields (PLQYs) of around 90% under ambient conditions. Taking advantage of their transparency and solution processability, we fabricated a waveguide with this theobromine-dye-SBS composite, which was subsequentially assembled into an edge-lit LED device of no glare and enhanced aesthetics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Green genes from blue greens: challenges and solutions to unlocking the potential of cyanobacteria in drug discovery

Cyanobacteria are prolific producers of biologically active compounds that are important in influencing ecology, behavior of interacting organisms, and as leads in drug discovery efforts. Here we discuss the challenges faced by all natural product researchers, especially those that focus on cyanobacteria, and then describe progress that has been made in these areas. We also propose some solutions, paths forward, and thoughts for consideration on these challenges.

Philmus, Benjamin↗

Green and non-green callus induction from excised rice (Oryza sativa) embryos: effects of exogenous plant growth regulators

Calli were induced either from excised rice embryos or from whole seeds in the presence of 1 to 5 mg l-1 NAA. After 12 days of culture, calli were induced only from excised rice embryos. We found that excised embryos accumulated NAA up to 6 times higher concentration than did whole seeds. In the presence of 1 to 5 mg l-1 NAA and 2 to 10 mg l-1 kinetin, chlorophyllous calli were induced from excised rice embryos. Chlorophyll contents in the callus tissue increased with increasing kinetin concentration while percent callus induction decreased. The total chlorophyll content was linearly correlated with the ratio of kinetin to NAA in the medium.

NASA Discipline Number 40-50↗

Green Light for Green Flight: NASA's Contributions to Environmentally Friendly Aviation

Although the shape and speed of commercial airliners have not changed significantly since the late-1950s, many aspects of performance such as range and fuel efficiency, and environmental impacts including noise and emissions have improved tremendously. By the beginning of the 21st century, however, it became clear that more work was necessary. Heightened sensitivity to, and understanding of, the impact of aviation on the environment and the reduced availability of low-cost energy placed the spotlight directly on aircraft efficiency and reducing environmental impacts. This realization spawned one of NASA's most ambitious aviation projects to date - the Environmentally Responsible Aviation project.

Peter W. Merlin↗

Competing effects of soil fertility and toxicity on tropical greening

Tropical forests are expected to green up with increasing atmospheric CO 2 concentrations, but primary productivity may be limited by soil nutrient availability. However, rarely have canopy-scale measurements been assessed against soil measurements in the tropics. Here, we sought to assess remotely sensed canopy greenness against steep soil nutrient gradients across 50 1-ha mature forest plots in Panama. Contrary to expectations, increases in in situ extractable soil phosphorus (P) and base cations (K, Mg) corresponded to declines in remotely sensed mean annual canopy greenness (r 2 = 0.77– 0.85; p < 0.1), controlling for precipitation. The reason for this inverse relationship appears to be that litterfall also increased with increasing soil P and cation availability (r 2 = 0.88–0.98; p < 0.1), resulting in a decline in greenness with increasing annual litterfall (r 2 = 0.94; p < 0.1). As such, greater soil nutrient availability corresponded to greater leaf turnover, resulting in decreased greenness. However, these decreases in greenness with increasing soil P and cations were countered by increases in greenness with increasing soil nitrogen (N) (r 2 = 0.14; p < 0.1), which had no significant relationship with litterfall, likely reflecting a direct effect of soil N on leaf chlorophyll content, but not on litterfall rates. In addition, greenness increased with extractable soil aluminum (Al) (r 2 = 0.97; p < 0.1), but Al had no significant relationship with litterfall, suggesting a physiological adaptation of plants to high levels of toxic metals. Thus, spatial gradients in canopy greenness are not necessarily positive indicators of soil nutrient scarcity. Using a novel remote sensing index of canopy greenness limitation, we assessed how observed greenness compares with potential greenness. We found a strong relationship with soil N only (r 2 = 0.65; p < 0.1), suggesting that tropical canopy greenness in Panama is predominantly limited by soil N, even if plant productivity (e.g., litterfall) responds to rock-derived nutrients. Moreover, greenness limitation was also significantly correlated with fine root biomass and soil carbon stocks (r 2 = 0.62–0.71; p < 0.1), suggesting a feedback from soil N to canopy greenness to soil carbon storage. Altogether, these data point to the potential utility of a remote sensing product for assessing belowground properties in tropical ecosystems.

54 ENVIRONMENTAL SCIENCES↗

Strong influence of convective heat transfer efficiency on the cooling benefits of green roof irrigation

Abstract By enhancing evapotranspiration (ET), green roofs provide cooling benefits for the urban environment and are recognized as a promising heat mitigation strategy. The evaporative cooling effects of green roofs strongly depend on the soil moisture conditions and thus irrigation may be needed to sustain the cooling benefits. It has been shown that the magnitude of cooling benefits offered by green roof irrigation varies spatially, but its controlling factors remain elusive. In this study, we combine a surface energy balance (SEB) model with global simulations generated by an improved Earth System Model to illustrate the key factors controlling the cooling benefits of green roof irrigation. We employ a simple irrigation scheme, which is only active when there is no ice in soil layers and when the soil moisture is below field capacity. As a result, most of the irrigation water leaves the green roof system via ET. We find that the magnitude and also the spatial variability of the cooling benefits of green roof irrigation are controlled by the irrigation amount, and a surface energy redistribution factor that encodes the efficiencies of different SEB components in transferring heat. Further analysis indicates that the enhancement of latent heat flux due to irrigation is largely balanced by the reduction of sensible heat flux on green roofs. Therefore, the amount of irrigation needed per unit decrease of green roof surface temperature is mainly controlled by the convective heat transfer efficiency. A lower convective heat transfer efficiency (e.g. under a lower wind speed) helps reduce the amount of irrigation needed per unit decrease of green roof surface temperature. This study highlights the importance of SEB in constraining the cooling benefits of green roof irrigation and provides valuable guidance for urban planners and policy makers in terms of heat mitigation and sustainable water management.

Wang, Linying (ORCID:0000000308769220)↗

Analyzing the co-evolution of green technology diffusion and consumers’ pro-environmental attitudes: An agent-based model

Massive diffusion of green technologies is significant for building a cleaner world. However, the process of technology diffusion is usually slow and complex. An in-depth understanding of the mechanism regarding green technology diffusion is an essential precondition for effectively stimulating this process. Green technology diffusion heavily involves both social and technological changes. Although existing studies have provided rich knowledge about identifying critical drivers and barriers affecting green technology diffusion, research that considers consumers’ pro-environmental attitudes and green technology diffusion as an evolving system is still sparse. Aiming at exploring the co-evolution of consumers’ pro-environmental attitudes and green technology diffusion, this paper builds an agent-based model that integrates the relative agreement model with technology diffusion theories to conduct a sequence of controlled numerical experiments, which progressively unveil how attitudinal and technological factors impact green technology diffusion. The main findings include that (1) improving consumers’ pro-environmental attitudes is prominently beneficial to green technology diffusion and maturation; (2) technology maturity has very limited impact on consumers’ first-time purchases but significantly affects consumers’ satisfaction, which would further impact consumers’ repeat purchases; (3) consumers that do not support green technologies frequently emerge during the evolution of attitudes (despite the high technology maturity), which corresponds to the emergence of the anti-environmental groups observed in the real world; (4) active interactions between non-adopters enable their attitudes to converge, which results in the polarization of consumers’ attitudes.

ABM↗

NASA 2018 Green Propulsion Roadmap

The Green Propulsion Working Group (GPWG) is a technical guidance working group formed April 2017 under the Agency's Capability Leadership Team The GPWG was tasked with recommending an agency road map and providing guidance to NASA on green propulsion technology development and infusion The GPWG's efforts focus on ionic liquid propellants and related technologies The GPWG was chartered with three representatives from NASA Centers currently exploring green propulsion technologies As other Centers may explore programs that utilize green propulsion, membership of the working group can be expanded to include more interested parties Working group also solicits and coordinates with other government agencies (e.g. AFRL, MDA) In 2015, JANNAF hosted a Technical Interchange Meeting (TIM) on Green Monopropellant Alternatives to Hydrazine (GMAH) Included both Government and non-Government contributions on the State-of-the-Art in Green Propulsion Technology Following the TIM, a Government-only session (USAF/AFRL/NASA/MDA/DLA) reviewed and identified remaining technical gaps in Green Propulsion In 2016, an inter-agency team (AFRL/NASA/MDA) worked together to develop an informal inter-agency "roadmap" based on the outcome of the TIM Approach consisted of near-term, mid-term, and long-term technology advancement areas, approaching incrementally larger thrust classes The NASA Green Propulsion Working Group reviewed the work of the 2016 Inter-Agency Working Group, and concurs that the identified technical gaps and technology development areas are still relevant and necessary to see green propulsion technology advanced The GPWG recommends the 2016 roadmap be adopted as baseline for NASA needs, with some additions The focus of the 2016 inter-agency roadmap was primarily on the thruster technology. The Agency must also invest in understanding the broader propulsion system-level technology gaps in parallel. Timeframes are considered suggested from a priority standpoint, but are also flexible as some efforts will need to occur in the nearer term or concurrently in order to meet specific mission requirements The GPWG developed 2018 roadmap breaks down the technology development goals into Technology Development Areas (TDA's), and identifies the near-, mid, and long-term sub-goals within those areas. Those TDA's are: Thruster Hardware Development Modeling & Tools Development Materials Properties and Compatibility Propellant Development.

Cavender, Dan↗

A comparative analysis of green building rating systems in China and the United States

Several studies have compared green building rating systems (GBRSs) in China and the United States, Nonetheless, few studies included in-depth analysis on specific rating tools with project specific data validating green building technologies and actual performance. This study conducted a comprehensive data-driven comparison of the GBRSs of China and the United States. The goal was to understand the current status and further improve China's GBRS and promote green building technologies. The study first conducted thorough comparisons of GBRSs in China and the U.S. by selecting a series of distinct rating tools. Then, it analyzed each tool's development objectives, contents, and rating score settings. Further, the comparison concludes the future development needs for China's GBRS. In addition to standard comparison, green building technologies applied in certified projects were also summarized. The results demonstrated that GBRSs in both China and the U.S. reflect well the technical paths to achieve green building sustainable development. By analyzing certified projects, it was also found that the incremental costs of green building technologies were controllable. Finally, based on the comparison and case analysis, the study provide a set of policy recommendations to further improve China's green building standards.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Repainting the colour–mass diagrams by unearthing the green mountain: dust-rich S0 galaxies in the colour–(galaxy stellar mass) diagram, and the colour–(black hole mass) relations for dust-poor versus dust-rich galaxies

ABSTRACT Lenticular galaxies are notoriously misclassified as elliptical galaxies and, as such, a (disc inclination)-dependent correction for dust is often not applied to the magnitudes of dusty lenticular galaxies. This results in overly red galaxy colours, impacting their distribution in the colour–magnitude diagram. It is revealed how this has led to an underpopulation of the ‘green valley’ by hiding a ‘green mountain’ of massive dust-rich lenticular galaxies – known to be built from gas-rich major mergers – within the ‘red sequence’ of colour–(stellar mass) diagrams. Correcting for dust, a ‘green mountain’ appears at M*,gal ∼ 1011 M⊙, along with signs of an extension to lower masses producing a ‘green range’ or ‘green ridge’ on the green side of the ‘red sequence’ and ‘blue cloud.’ The ‘red sequence’ is shown to be comprised of two components: a red plateau defined by elliptical galaxies with a near-constant colour and by lower-mass dust-poor lenticular galaxies, which are mostly a primordial population but may include faded/transformed spiral galaxies. The presence of the quasi-triangular-shaped galaxy evolution sequence, previously called the ‘Triangal’, is revealed in the galaxy colour–(stellar mass) diagram. It tracks the speciation of galaxies and their associated migration through the diagram. The connection of the ‘Triangal’ to previous galaxy morphology sequences (Fork, Trident, and Comb) is also shown herein. Finally, the colour–(black hole mass) diagram is revisited, revealing how the dust correction generates a blue–green sequence for the spiral and dust-rich lenticular galaxies that is offset from a green–red sequence defined by the dust-poor lenticular and elliptical galaxies.

Graham, Alister W. (ORCID:0000000264969414)↗

Green-light supplementation for enhanced lettuce growth under red- and blue-light-emitting diodes

Plants will be an important component of future long-term space missions. Lighting systems for growing plants will need to be lightweight, reliable, and durable, and light-emitting diodes (LEDs) have these characteristics. Previous studies demonstrated that the combination of red and blue light was an effective light source for several crops. Yet the appearance of plants under red and blue lighting is purplish gray making visual assessment of any problems difficult. The addition of green light would make the plant leave appear green and normal similar to a natural setting under white light and may also offer a psychological benefit to the crew. Green supplemental lighting could also offer benefits, since green light can better penetrate the plant canopy and potentially increase plant growth by increasing photosynthesis from the leaves in the lower canopy. In this study, four light sources were tested: 1) red and blue LEDs (RB), 2) red and blue LEDs with green fluorescent lamps (RGB), 3) green fluorescent lamps (GF), and 4) cool-white fluorescent lamps (CWF), that provided 0%, 24%, 86%, and 51% of the total PPF in the green region of the spectrum, respectively. The addition of 24% green light (500 to 600 nm) to red and blue LEDs (RGB treatment) enhanced plant growth. The RGB treatment plants produced more biomass than the plants grown under the cool-white fluorescent lamps (CWF treatment), a commonly tested light source used as a broad-spectrum control.

Non-NASA Center↗

The Vegetation Greenness Trend in Canada and US Alaska from 1984-2012 Landsat Data

To assess the North American high-latitude vegetation response to the rising temperature, we derived NDVI end for 91.2% of the non-water, non-snow land area of Canada and Alaska using the peak-summer Landsat surface reflectance data of 19842012. Our analysis indicated that 29.4% and 2.9 of the land area of Canada and Alaska showed statistically significant positive (greening) and negative (browning) trends respectively, at significance level p b 0.01, after burned forest areas were masked out. The area with greening trend dominated over that with browning trend for all land cover types. The greening occurred primarily in the tundra of western Alaska, along the north coast of Canada and in northeastern Canada; the most intensive and extensive greening occurred in Quebec and Labrador. The browning occurred mostly in the boreal forests of eastern Alaska. The Landsat-based greenness trend is broadly similar to the 8-km GIMMS AVHRR-based trend for all vegetation zones. However, for tundra, the Landsat data indicated much less extensive greening in Alaska North Slope and much more extensive greening in Quebec and Labrador, and substantially less extensive browning trend in the boreal forests that were free of fire disturbances. These differences call for further validation of the Landsat reflectance and the AVHRR NDVI datasets. Correlation study with local environmental factors, such as topography, glacial history and soil condition, will be needed to understand the heterogeneous greenness change at the Landsat scale.

Ju, Junchang↗

Will Consumers Really Pay for Green Electricity? Comparing Stated and Revealed Preferences for Residential Programs in the United States

Public support is growing for policy initiatives to spur a transition from a fossil to renewable energy portfolio in the electricity sector. Some utilities in the United States offer programs that allow consumers to voluntarily pay premiums (0.1-7.0 cents/kWh) for electricity from renewable sources. However, it is unclear whether public support translates to paying for green electricity if given the option. Our analysis employs data from two national, longitudinal surveys on energy attitudes and willingness to pay for renewables to investigate whether environmental concerns and stated preferences for renewable energy translate to consumer behavior as measured through ratepayer participation in voluntary utility renewable energy programs known as utility green pricing. We find higher green pricing program participation rates in areas where consumers have stronger feelings about the environmental impacts of energy. Consumers in high-participation areas also have a higher stated willingness to pay for renewable energy, on average, than consumers in low-participation areas. We also find income, homeownership, and home value explain some of the difference between high- and low-participation programs. Further, program participation is lower in areas where utilities charge higher green pricing program premiums. These findings suggest that green power programs - such as utility green pricing - offer a market-based mechanism for consumers to realize their desire to purchase renewable energy. Policymakers may use these results to support further expansion of green power programs in areas where customers currently lack accessible and affordable options to act on their environmental beliefs and concerns.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Will cities keep getting hotter? The interplay of urban expansion and greening reshapes future urban heat trajectories

Urban heat islands (UHIs) pose growing risks to public health, infrastructure, and resilience. While often assumed to intensify with urban growth, dynamic changes in urban expansion and vegetation greenness complicate UHI trajectories, which remain poorly understood. This study investigated the interplay of urban expansion and greenness change on UHI spatial profile across 36 Chinese megacities during 2003–2018 using multiple satellite products. We introduce a framework that classifies urban areas into four dynamic development pathways based on impervious surface area (ISA) and enhanced vegetation index (EVI) trends: urbanized-greening, urbanized-browning, urbanizing-greening (UingG), and urbanizing-browning (UingB). While most urbanized centers exhibited greening driven by targeted initiatives and urbanizing suburbs showed browning due to vegetation loss, about 30% urban areas showed the reverse pattern, revealing overlooked complexity in urban development. Urban expansion and browning strengthened UHI in suburban areas, whereas greening initiatives mitigated UHI in urban center and mitigated UHI enhancement in suburban areas. Slowed warming in urban centers together with accelerated warming in suburban areas flattened the temperature gradient between urban centers and suburbs. This dynamic expanded the spatial extent of elevated temperatures and reshaped the classic urban-to-rural UHI profile into a flatter form. In UingB areas, UHI intensification was jointly driven by increase in ISA, vegetation loss, and their interaction, while in UingG areas, EVI increases and a negative interaction together offset over half of the warming driven by urban expansion. These findings reveal that UHI evolution is not unidirectional but depends on localized urbanization and greening dynamics, offering pathways for strategic heat mitigation.

greening initiative↗

A green sulfur bacterium from epsomitic Hot Lake, Washington, USA

Hot Lake is a small heliothermal and hypersaline lake in far north–central Washington State (USA) and is limnologically unusual because MgSO 4 rather than NaCl is the dominant salt. In late summer, the Hot Lake metalimnion becomes distinctly green from blooms of planktonic phototrophs. In a study undertaken over 60 years ago, these blooms were predicted to include green sulfur bacteria, but no cultures were obtained. We sampled Hot Lake and established enrichment cultures for phototrophic sulfur bacteria in MgSO 4 -rich sulfidic media. Most enrichments turned green or red within 2 weeks, and from green-colored enrichments, pure cultures of a lobed green sulfur bacterium (phylum Chlorobi) were isolated. Phylogenetic analyses showed the organism to be a species of the prosthecate green sulfur bacterium Prosthecochloris. Cultures of this Hot Lake phototroph were halophilic and tolerated high levels of sulfide and MgSO 4 . In addition, unlike all recognized species of Prosthecochloris, the Hot Lake isolates grew at temperatures up to 45°C, indicating an adaptation to the warm summer temperatures of the lake. Photoautotrophy by Hot Lake green sulfur bacteria may contribute dissolved organic matter to anoxic zones of the lake, and their diazotrophic capacity may provide a key source of bioavailable nitrogen, as well.

59 BASIC BIOLOGICAL SCIENCES↗