Low temperature heat capacities of superconducting molybdenum carbides.
Low temperature heat capacities for molybdenum carbides studied for similarities of thermodynamic and superconducting properties
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Low temperature heat capacities for molybdenum carbides studied for similarities of thermodynamic and superconducting properties
Four dates of Heat Capacity Mapping Mission (HCMM) data were analyzed in order to evaluate HCMM thermal data use in estimating near-surface soil moisture in a complex agricultural landscape. Because of large spatial and temporal ground cover variations, HCMM radiometric temperatures alone did not correlate with soil water content. The radiometric temperatures consisted of radiance contributions from different canopies and their respective soil backgrounds. However, when surface soil temperatures were empirically estimated from HCMM temperatures and percent cover of each pixel, a highly significant correlation was obtained between the estimated soil temperatures and near-surface soil water content.
Part I of the paper discussed the temperature dependencies of the electrical resistivities, thermal conductivities, thermal diffusivities and total hemispherical emissivities of several vacuum plasma sprayed (VPS) and cold sprayed copper alloy monolithic coatings, VPS NiAl, VPS NiCrAlY, extruded GRCop-84 and as-cast Cu-17(wt.%)Cr-5%Al. Part II discusses the temperature dependencies of the constant pressure specific heat capacities, CP, of these coatings. The data were empirically were regression-fitted with the equation: CP = AT4 + BT3 + CT2 + DT +E where T is the absolute temperature and A, B, C, D and E are regression constants. The temperature dependencies of the molar enthalpy, molar entropy and Gibbs molar free energy determined from experimental values of molar specific heat capacity are reported. Calculated values of CP using the Neumann-Kopp (NK) rule were in poor agreement with experimental data. Instead, a modification of the Neumann-Kopp rule was found to predict values closer to the experimental data with an absolute deviation less than 6.5%. The specific molar heat capacities for all the alloys did not agree with the Dulong-Petit law, and CP is greater than 3R, where R is the universal gas constant, were measured for all the alloys except NiAl for which CP is less than 3R at all temperatures.
A measurement of the heat capacity singularity of helium at the lambda transition was performed with the aim of improving tests of the Renormalization Group (RG) predictions for the static thermodynamic behavior near the singularity. The goal was to approach as closely as possible to the lambda-point while making heat capacity measurements of high accuracy. To do this, a new temperature sensor capable of unprecedented resolution near the lambda-point, and two thermal control systems were used. A short description of the theoretical background and motivation is given. The initial apparatus and results are also described.
The AEM-1 satellite, the Heat Capacity Mapping Mission, has acquired high-quality thermal infrared data at times of day especially suited for studying the earth's surface and the exchange of heat and moisture with the atmosphere. Selected imagery illustrates the considerable variability of surface temperature in and around cities, in the dry southwestern United States, in the Appalachian Mountains, and in agricultural areas. Through simplifying assumptions, an analytic experience is derived that relates day/night temperature differences to the near-surface layer (thermal inertia) and to meteorological factors. Analysis of the result suggests that, in arid regions, estimates of relative thermal inertia may be inferred, whereas, in agricultural areas, a hydrologic interpretation is possible.
The rationale and procedures used in the radiometric calibration and correction of Heat Capacity Mapping Mission (HCMM) data are presented. Instrument-level testing and calibration of the Heat Capacity Mapping Radiometer (HCMR) were performed by the sensor contractor ITT Aerospace/Optical Division. The principal results are included. From the instrumental characteristics and calibration data obtained during ITT acceptance tests, an algorithm for post-launch processing was developed. Integrated spacecraft-level sensor calibration was performed at Goddard Space Flight Center (GSFC) approximately two months before launch. This calibration provided an opportunity to validate the data calibration algorithm. Instrumental parameters and results of the validation are presented and the performances of the instrument and the data system after launch are examined with respect to the radiometric results. Anomalies and their consequences are discussed. Flight data indicates a loss in sensor sensitivity with time. The loss was shown to be recoverable by an outgassing procedure performed approximately 65 days after the infrared channel was turned on. It is planned to repeat this procedure periodically.
Results of engineering analyses assessing the conceptual feasibility of a large capacity heat pump for enhancing active cooling of hypersonic aircraft structure are presented. A unique heat pump arrangement which permits cooling the structure of a Mach 6 transport to aluminum temperatures without the aid of thermal shielding is described. The selected concept is compatible with the use of conventional refrigerants, with Freon R-11 selected as the preferred refrigerant. Condenser temperatures were limited to levels compatible with the use of conventional refrigerants by incorporating a unique multipass condenser design, which extracts mechanical energy from the hydrogen fuel, prior to each subsequent pass through the condenser. Results show that it is technically feasible to use a large capacity heat pump in lieu of external shielding. Additional analyses are required to optimally apply this concept.
Linear high polymers heat capacity measurements theory emphasizing simple mechanical systems and contribution of lattice vibrations
Low temperature heat capacities of superconducting niobium and tantalum carbides measured for carbon concentration and crystal structure effects
The mechanics of phonon transport in membrane-isolated superconducting transition edge sensors is discussed. Surveys of the literature on this type of sensor reveal a number of designs with excess heat capacity and a smaller subset that exhibit decoupling of the superconducting film from the underlying dielectric. A simple model is addressed in which the membrane, despite its thermal isolation, fails to fully thermalize to the temperature of the metal film heating it. A population of phonons exists which is emitted by the metal film, partially thermalizes the dielectric and is then reabsorbed in the metal film without escaping from the device structure to the thermal bath. The size of this population and its contribution to the heat capacity are estimated for several device scenarios.
The mechanics of phonon transport in membrane-isolated superconducting transition edge sensors is discussed. Surveys of the literature on this type of sensor reveal a number of designs with excess heat capacity and a smaller subset that exhibit decoupling of the superconducting film from the underlying dielectric. A simple model is addressed in which the membrane, despite its thermal isolation, fails to fully thermalize to the temperature of the metal film heating it. A population of phonons exists which is emitted by the metal film, partially thermalizes the dielectric and is then reabsorbed in the metal film without escaping from the device structure to the thermal bath. The size of this population and its contribution to the heat capacity are estimated for several device scenarios.
A viewgraph presentation describing thermoelectric materials, an algorithm for heat capacity measurements and the process of flash thermal diffusivity. The contents include: 1) What are Thermoelectrics?; 2) Thermoelectric Applications; 3) Improving Thermoelectrics; 4) Research Goal; 5) Flash Thermal Diffusivity; 6) Background Effects; 7) Stainless Steel Comparison; 8) Pulse Max Integral; and 9) Graphite Comparison Algorithm.
Temperature dependence of short wavelength magnon energies correlated with heat capacity
Excessheat capacity in a bolometric detector has the consequence of increasing or leading to multiple device time con-stants.The Mo/Au bilayer transition edge sensor (TES) bolo-metric detectors intended for the high resolution mid-infrared spectrometer (HIRMES) have two response time, one of which is a few times longer than that estimated from materials used in the design. The relative contribution of this settling time to the overall time response of the detectors is roughly proportional with the pixel area, which ranges between ~0.3 and 2.6 mm2.Use of laser ablation to remove sections of the silicon membranes comprising the pixels results in a detector response with a smaller contribution from the secondary time constant.Additional information about the nature of this excess heat capacity is gleaned from glancing in-cidence x-ray diffraction, which reveals the presence of molyb-denum silicides near the silicon surface from the bi-layer deposi-tion.Quantitative analysis of the concentration of excess molyb-denum, estimated with secondary ion mass spectroscopy, is com-mensurate to the additional heat capacity needed to explain the anomalous time response of the detectors.
To encourage wide use of the Heat Capacity Mapping Mission (HCMM) data, especially among the scientific community, special notifications were prepared to inform them about the data's availability, its form, and the procedures for obtaining them. To achieve the widest distribution to the primary audiences of interest, mailings were made to scientists associated with the OSTA Resource Observation Division programs and to scientific and professional societies and journals. Accompanying the notifications to the societies and journals were samples of the HCMM imagery and a description of the image's predominant characteristics. A follow-up survey was completed to determine the effectiveness of the HCMM notifications.
New measurements of the heat capacity of a sample of helium 3-mm high are reported, which extend to within 5 x 10 to the -8th deg of the lambda transition at the vapor pressure. From an analysis of the results allowing for the effect of gravity, the values -0.0127 + or - 0.0026 (2 sigma) for the exponent alpha (= alpha-prime) and 1,058 + or - 0.004 for the leading singularity ratio A/A-prime are obtained. These values are in closer agreement with the theoretical predictions than those reported previously.
Heat Capacity Mapping Mission thermal-inertia images of a diversity of terrains and geologic settings were examined in conjunction with topographic, geologic, geophysical, and LANDSAT data. The images were found to have attributes similar to bedrock maps. In the Cascades region, two new features were identified and a method was developed to characterize regional terranes using linear feature data. Two northeast-trending Lineaments were discovered in the Overthrust Belt of Montana and Idaho. The longer of the two extends from the Idaho-Oregon border, through the Idaho batholith and across the Lewis thrust. It coincides, along segments, with mapped faults and an aeromagnetic pattern change. A major lineament crossing the Colorado Plateau and the Southern Rocky Mountians was detected on several thermal-inertial images and evidence was found for the existence of a geologic discontinuity. Vegetation-covered areas in Richfield and the Silver City quadrangle (Arizona and New Mexico) displayed thermal-inertia differences within heavily vegetation areas although no apreciable correlation was found between vegetation cover and thermal inertia. Resistant ridges and knolls have high thermal inertias and thermal-inertia contrasts occurred at lithologic and fault contacts. In the heavy vegetated Pinaleno Mountains, Arizona, a Lithologic unit obscured on LANDSAT MSS data due to the vegetation cover, exhibited a thermal-inertia contrast with its surroundings.