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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Heat storage in alloy transformations

The theory of eutectic transformation was examined to find guidelines to the best material combinations to examine. The heats of transformation were measured calorimetrically, and the volume changes of expanding solid mixtures and homogeneous liquid solutions, especially during the transformation between the two states at fixed temperature, were measured by changes in X-ray absorption. Heat flow models appropriate to storage in phase change materials were developed along with efficient calculating procedures so that the relative importance of the problems associated with energy storage density, heat conduction, and similar properties could be assessed.

Birchenall, C. E.↗

Thermal energy storage heat exchanger: Molten salt heat exchanger design for utility power plants

The use of thermal energy storage (TES) in the latent heat of molten salts as a means of conserving fossil fuels and lowering the cost of electric power was evaluated. Public utility systems provided electric power on demand. This demand is generally maximum during late weekday afternoons, with considerably lower overnight and weekend loads. Typically, the average demand is only 60% to 80% of peak load. As peak load increases, the present practice is to purchase power from other grid facilities or to bring older less efficient fossil-fuel plants on line which increase the cost of electric power. The widespread use of oil-fired boilers, gas turbine and diesel equipment to meet peaking loads depletes our oil-based energy resources. Heat exchangers utilizing molten salts can be used to level the energy consumption curve. The study begins with a demand analysis and the consideration of several existing modern fossil-fuel and nuclear power plants for use as models. Salts are evaluated for thermodynamic, economic, corrosive, and safety characteristics. Heat exchanger concepts are explored and heat exchanger designs are conceived. Finally, the economics of TES conversions in existing plants and new construction is analyzed. The study concluded that TES is feasible in electric power generation. Substantial data are presented for TES design, and reference material for further investigation of techniques is included.

Ferarra, A.↗

Heat Storage and Transport

System for storing large amounts of heat per unit volume comprises encapsulated sealed pellets of phase-change materials dispersed and suspended in inert fluid-transport medium.

Bahrami, P. A.↗

Southern Ocean Heat Storage, Reemergence, and Winter Sea Ice Decline Induced by Summertime Winds

The observational record shows a substantial 40-yr upward trend in summertime westerly winds over the Southern Ocean, as characterized by the southern annular mode (SAM) index. Enhanced summertime westerly winds have been linked to cold summertime sea surface temperature (SST) anomalies. Previous studies have suggested that Ekman transport or upwelling is responsible for this seasonal cooling. Here, another process is presented in which enhanced vertical mixing, driven by summertime wind anomalies, moves heat downward, cooling the sea surface and simultaneously warming the subsurface waters. The anomalously cold SSTs draw heat from the atmosphere into the ocean, leading to increased depth-integrated ocean heat content. The subsurface heat is returned to the surface mixed layer during the autumn and winter as the mixed layer deepens, leading to anomalously warm SSTs and potentially reducing sea ice cover. Observational analyses and numerical experiments support our proposed mechanism, showing that enhanced vertical mixing produces subsurface warming and cools the surface mixed layer. Nevertheless, the dominant driver of surface cooling remains uncertain; the relative importance of advective and mixing contributions to the surface cooling is model dependent. Modeling results suggest that sea ice volume is more sensitive to summertime winds than sea ice extent, implying that enhanced summertime westerly winds may lead to thinner sea ice in the following winter, if not lesser ice extent. Thus, strong summertime winds could precondition the sea ice cover for a rapid retreat in the following melt season.

Southern Ocean↗

Measured performance of a 1089 K (1500 deg F) heat storage device for sun-shade orbital missions

Tubes designed for a solar heat receiver to serve as an energy source for a Brayton power system were tested for 2002 hours and 1251 sun-shade cycles. The tubes were designed to transfer a constant thermal input to the Brayton system during an orbit. Excess solar energy during a sun period is stored as heat of fusion of lithium fluoride. The niobium - 1% zirconium tubes accommodate the 23 percent volume decrease of LiF during freezing. Test results showed slight, local distortions. The gas discharge temperature varied from 16 K (29 F) below to 28 K (50 F) above the nominal value of 1089 K (1500 F). The tube surface temperatures ranged from 1039 K (1410 F) to 1183 K (1670 F).

Namkoong, D.↗

Building with integral solar-heat storage--Starkville, Mississippi

Column supporting roof also houses rock-storage bin of solar-energy system supplying more than half building space heating load. Conventional heaters supply hot water. Since bin is deeper and narrower than normal, individual pebble size was increased to keep airflow resistance at minimum.

Source record↗

Thermal analysis of heat storage canisters for a solar dynamic, space power system

A thermal analysis was performed of a thermal energy storage canister of a type suggested for use in a solar receiver for an orbiting Brayton cycle power system. Energy storage for the eclipse portion of the cycle is provided by the latent heat of a eutectic mixture of LiF and CaF2 contained in the canister. The chief motivation for the study is the prediction of vapor void effects on temperature profiles and the identification of possible differences between ground test data and projected behavior in microgravity. The first phase of this study is based on a two-dimensional, cylindrical coordinates model using an interim procedure for describing void behavor in 1-g and microgravity. The thermal analysis includes the effects of solidification front behavior, conduction in liquid/solid salt and canister materials, void growth and shrinkage, radiant heat transfer across the void, and convection in the melt due to Marangoni-induced flow and, in 1-g, flow due to density gradients. A number of significant differences between 1-g and o-g behavior were found. This resulted from differences in void location relative to the maximum heat flux and a significantly smaller effective conductance in 0-g due to the absence of gravity-induced convection.

Wichner, R. P.↗

Heat storage in alloy transformations

The feasibility of using metal alloys as thermal energy storage media was investigated. The elements selected as candidate media were limited to aluminum, copper, magnesium, silicon, zinc, calcium, and phosphorus on the basis of low cost and latent heat of transformation. Several new eutectic alloys and ternary intermetallic phases were determined. A new method employing X-ray absorption techniques was developed to determine the coefficients of thermal expansion of both the solid and liquid phases and the volume change during phase transformation. The method and apparatus are discussed and the experimental results are presented for aluminum and two aluminum-eutectic alloys. Candidate materials were evaluated to determine suitable materials for containment of the metal alloys. Graphite was used to contain the alloys during the volume change measurements. Silicon carbide was identified as a promising containment material and surface-coated iron alloys were also evaluated. System considerations that are pertinent if alloy eutectics are used as thermal energy storage media are discussed. Potential applications to solar receivers and industrial furnaces are illustrated schematically.

Birchenall, C. E.↗

Heat storage in alloy transformations

The feasibility of using metal alloys as thermal energy storage media was determined. The following major elements were studied: (1) identification of congruently transforming alloys and thermochemical property measurements; (2) development of a precise and convenient method for measuring volume change during phase transformation and thermal expansion coefficients; (3) development of a numerical modeling routine for calculating heat flow in cylindrical heat exchangers containing phase change materials; and (4) identification of materials that could be used to contain the metal alloys. Several eutectic alloys and ternary intermetallic phases were determined. A method employing X-ray absorption techniques was developed to determine the coefficients of thermal expansion of both the solid and liquid phases and the volume change during phase transformation from data obtained during one continuous experimental test. The method and apparatus are discussed and the experimental results are presented. The development of the numerical modeling method is presented and results are discussed for both salt and metal alloy phase change media.

Birchenall, C. E.↗

Thermal control and heat storage by melting and freezing. Space thermal control development

Current results of an experimental study of increasing phase change material thermal diffusivity by means of solid fillers are reported. Aluminum honeycomb appears to offer the best improvement of any of the fillers investigated to date. Details of the experimental method developed in the present study for rapidly determining thermal diffusivities with a precision of about 10 percent are also reported. Further concepts regarding phase change material thermal diffusivity enhancement and of phase change material operation are discussed.

Grodzka, P. G.↗

Experimental simulation of latent heat thermal energy storage and heat pipe thermal transport for dish concentrator solar receiver

Test results on a modular simulation of the thermal transport and heat storage characteristics of a heat pipe solar receiver (HPSR) with thermal energy storage (TES) are presented. The HPSR features a 15-25 kWe Stirling engine power conversion system at the focal point of a parabolic dish concentrator operating at 827 C. The system collects and retrieves solar heat with sodium pipes and stores the heat in NaF-MgF2 latent heat storage material. The trials were run with a single full scale heat pipe, three full scale TES containers, and an air-cooled heat extraction coil to replace the Stirling engine heat exchanger. Charging and discharging, constant temperature operation, mixed mode operation, thermal inertial, etc. were studied. The heat pipe performance was verified, as were the thermal energy storage and discharge rates and isothermal discharges.

Narayanan, R.↗

A point focusing collector for an integrated water/power complex

The utilization potential of the point focusing parabolic dish is identified. Its main design parameters are summarized. Performance tests and the utilization of the collector as primary energy source in a food-water-power complex are described. Process heat, heat storage, heat transfer, and cogeneration are discussed.

Zewen, H.↗

Dish-mounted latent heat buffer storage

Dish-mounted latent heat storage subsystems for Rankine, Brayton, and Stirling engines operating at 427 C, 816 C, and 816 C respectively are discussed. Storage requirements definition, conceptual design, media stability and compatibility tests, and thermal performance analyses are considered.

Manvi, R.↗

Fusible pellet transport and storage of heat

A new concept for both transport and storage of heat at high temperatures and heat fluxes is introduced and the first steps in analysis of its feasibility is taken. The concept utilizes the high energy storage capability of materials undergoing change of phase. The phase change material, for example a salt, is encapsulated in corrosion resistant sealed pellets and transported in a carrier fluid to heat source and storage. Calculations for heat transport from a typical solar collector indicate that the pellet mass flow rates are relatively small and that the required pumping power is only a small fraction of the energy transport capability of the system. Salts and eutectic salt mixtures as candidate phase change materials are examined and discussed. Finally, the time periods for melting or solidification of sodium chloride pellets is investigated and reported.

Bahrami, P. A.↗

Active heat exchange system development for latent heat thermal energy storage

Active heat exchange concepts for use with thermal energy storage systems in the temperature range of 250 C to 350 C, using the heat of fusion of molten salts for storing thermal energy are described. Salt mixtures that freeze and melt in appropriate ranges are identified and are evaluated for physico-chemical, economic, corrosive and safety characteristics. Eight active heat exchange concepts for heat transfer during solidification are conceived and conceptually designed for use with selected storage media. The concepts are analyzed for their scalability, maintenance, safety, technological development and costs. A model for estimating and scaling storage system costs is developed and is used for economic evaluation of salt mixtures and heat exchange concepts for a large scale application. The importance of comparing salts and heat exchange concepts on a total system cost basis, rather than the component cost basis alone, is pointed out. The heat exchange concepts were sized and compared for 6.5 MPa/281 C steam conditions and a 1000 MW(t) heat rate for six hours. A cost sensitivity analysis for other design conditions is also carried out.

Lefrois, R. T.↗

Metal-halide mixtures for latent heat energy storage

Some candidates for alkali metal and alkali halide mixtures suitable for thermal energy storage at temperatures 600 C are identified. A solar thermal system application which offer advantages such as precipitation of salt crystals away from heat transfer surfaces, increased thermal conductivity of phase change materials, corrosion inhibition, and a constant monotectic temperature, independent of mixture concentrations. By using the lighters, metal rich phase as a heat transfer medium and the denser, salt rich phase as a phase change material for latent heat storage, undesirable solidification on the heat transfer surface may be prevented, is presented.

Chen, K.↗

Storage systems for solar thermal power

The development status is reviewed of some thermal energy storage technologies specifically oriented towards providing diurnal heat storage for solar central power systems and solar total energy systems. These technologies include sensible heat storage in caverns and latent heat storage using both active and passive heat exchange processes. In addition, selected thermal storage concepts which appear promising to a variety of advanced solar thermal system applications are discussed.

Calogeras, J. E.↗

Storage systems for solar thermal power

A major constraint to the evolution of solar thermal power systems is the need to provide continuous operation during periods of solar outage. A number of high temperature thermal energy storage technologies which have the potential to meet this need are currently under development. The development status is reviewed of some thermal energy storage technologies specifically oriented towards providing diurnal heat storage for solar central power systems and solar total energy systems. These technologies include sensible heat storage in caverns and latent heat storage using both active and passive heat exchange processes. In addition, selected thermal storage concepts which appear promising to a variety of advanced solar thermal system applications are discussed.

Calogeras, J. E.↗