Development of high energy density primary batteries Second quarterly report, 22 Sep. - 21 Dec. 1965
Copper fluoride-lithium high energy density battery development
BATTERY↗
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Results for “High energy density”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Electrode phenomena in high energy density discharges as applied to plasma acceleration problems
Electrode surface structure and morphology changes in high energy density discharges as applied to plasma acceleration problems
MORPHOLOGY↗
High-energy-density cylindrical capacitors
Manufacturing technique produces high quality metalized-film cylindrical capacitors of energy density greater than 0.1 J/g uncased, using either 24-gage polyvinylidene flouride or 14-gage polycarbonate film. Components are wound wrinkle-free on hollow PTFE cores, using winding machine that applies constant dynamically controlled tension to film during winding operation.
Parker, R. D.↗
An Accurate Quartic Force Field, Fundamental Frequencies, and Binding Energy for the High Energy Density Material T(d)N4
The CCSD(T) method has been used to compute a highly accurate quartic force field and fundamental frequencies for all N-14 and N-15 isotopomers of the high energy density material T(sub d)N(sub 4). The computed fundamental frequencies show beyond doubt that the bands observed in a matrix isolation experiment by Radziszewski and coworkers are not due to different isotopomers of T(sub d)N(sub 4). The most sophisticated thermochemical calculations to date yield a N(sub 4) -> 2N(sub 2) heat of reaction of 182.22 +/- 0.5 kcal/mol at 0 K (180.64 +/- 0.5 at 298 K). It is hoped that the data reported herein will aid in the ultimate detection of T(sub d)N(sub 4).
Lee, Timothy J.↗
Development of high energy density primary batteries 200 watt hours per pound total battery weight minimum Final report, 10 Jun. 1964 - 9 Jun. 1965
High energy density lithium-anode primary cells developed with energy-to-weight ratios over 200 watt hours per pound
BATTERY↗
Development of high energy density primary batteries Third quarterly report, 22 Dec. 1965 - 21 Mar. 1966
Copper fluoride-lithium system study for development of high energy density primary batteries
LITHIUM↗
A program to develop a high-energy density primary battery with a minimum of 200 watt hours per pound of total battery weight fourth quarterly report, apr. - jun., 1965
High energy density primary battery development - anode-electrolyte, cupric fluoride cathode, and chemical stability tests
COPPER FLUORIDE↗
High Energy Density Additives for Hybrid Fuel Rockets to Improve Performance and Enhance Safety
We propose a conceptual study of prototype strained hydrocarbon molecules as high energy density additives for hybrid rocket fuels to boost the performance of these rockets without compromising safety and reliability. Use of these additives could extend the range of applications for which hybrid rockets become an attractive alternative to conventional solid or liquid fuel rockets. The objectives of the study were to confirm and quantify the high enthalpy of these strained molecules and to assess improvement in rocket performance that would be expected if these additives were blended with conventional fuels. We confirmed the chemical properties (including enthalpy) of these additives. However, the predicted improvement in rocket performance was too small to make this a useful strategy for boosting hybrid rocket performance.
strained hydrocarbons↗
A program to develop a high-energy density primary battery with a minimum of 200 watt hours per pound of total battery weight Quarterly report, 1 Oct. - 31 Dec. 1966
High energy density primary battery - film formation on cupric fluoride cathodes discharged in organic electrolytes
COPPER FLUORIDE↗
High-Energy-Density Fuel Blending Strategies and Drop Dispersion for Fuel Cost Reduction and Soot Propensity Control
The idea that low soot propensity of high-energy-density (HED) liquid sooting fuels and cost reduction of a multicomponent energetic fuel can be achieved by doping a less expensive, less sooting liquid fuel with HED is tested through numerical simulations.
low soot propensity HED cost reduction axisymmetri↗
A program to develop a high-energy density primary battery with a minimum of 200 watt hours per pound of total battery weight Fifth quarterly report, 1 Jul. - 30 Sep. 1965
High energy density primary battery development - electrochemical half-cell screening of anode- electrolyte combinations, cell discharge, and potential studies
ELECTROCHEMICAL CELL↗
A program to develop a high-energy density primary battery with a minimum of 200 watt hours per pound of total battery weight Seventh quarterly report, Jan. 1 - Mar. 31, 1966
Cathodic materials for high energy density storage battery
ENERGY STORAGE DEVICE↗
A program to develop a high-energy density primary battery with a minimum of 200 watt hours per pound of total battery weight Final report, Jul. 1964 - Sep. 1967
Electrolytes, anodes, and cathodes for high energy density battery with 200 watt hours per pound of total battery weight
Amlie, R. F.↗
High Energy Density Regenerative Fuel Cell Systems for Terrestrial Applications
Regenerative Fuel Cell System (RFCS) technology for energy storage has been a NASA power system concept for many years. Compared to battery-based energy storage systems, RFCS has received relatively little attention or resources for development because the energy density and electrical efficiency were not sufficiently attractive relative to advanced battery systems. Even today, RFCS remains at a very low technology readiness level (TRL of about 2 indicating feasibility has been demonstrated). Commercial development of the Proton Exchange Membrane (PEM) fuel cells for automobiles and other terrestrial applications and improvements in lightweight pressure vessel design to reduce weight and improve performance make possible a high energy density RFCS energy storage system. The results from this study of a lightweight RFCS energy storage system for a remotely piloted, solar-powered, high altitude aircraft indicate an energy density up to 790 w-h/kg with electrical efficiency of 53.4% is attainable. Such an energy storage system would allow a solar-powered aircraft to carry hundreds of kilograms of payload and remain in flight indefinitely for use in atmospheric research, earth observation, resource mapping. and telecommunications. Future developments in the areas of hydrogen and oxygen storage, pressure vessel design, higher temperature and higher- pressure fuel cell operation, unitized regenerative fuel cells, and commercial development of fuel cell technology will improve both the energy density and electrical efficiency of the RFCS.
Burke, Kenneth A.↗
A program to develop a high-energy density primary battery with a minimum of 200 watt hours per pound of total battery weight Quarterly report, Jul. 1 - Sep. 30 1966
Evaluation of various anode-electrolyte and cathode-electrolyte combinations for high energy density battery
BATTERY↗
Theoretical Studies of Possible Synthetic Routes for the High Energy Density Material Td N4: Excited Electronic States
Vertical electronic excitation energies for single states have been computed for the high energy density material (HEDM) Td N4 in order to assess possible synthetic routes that originate from excited electronic states of N2 molecules. Several ab initio theoretical approaches have been used, including complete active space self-consistent field (CASSCF), state averaged CASSCF (SA-CASSCF), singles configuration interaction (CIS), CIS with second-order and third-order correlation corrections [CIS(D)) and CIS(3)], and linear response singles and doubles coupled-cluster (LRCCSD), which is the highest level of theory employed. Standard double zeta polarized (DZP) and triple zeta double polarized (TZ2P) one-particle basis sets were used. The CASSCF calculations are found to overestimate the excitation energies, while the SA-CASSCF approach rectifies this error to some extent, but not completely. The accuracy of the CIS calculations varied depending on the particular state, while the CIS(D), CIS(3), and LRCCSD results are in generally good agreement. Based on the LRCCSD calculations, the lowest six excited singlet states are 9.35(l(sup)T1), 10.01(l(sup)T2), 10.04(1(sup)A2), 10.07(1(sup)E), 10.12(2(sup)T1), and 10.42(2(sup)T2) eV above the ground state, respectively. Comparison of these excited state energies with the energies of possible excited states of N2+N2 fragments, leads us to propose that the most likely synthetic route for Td N4 involving this mechanism arises from combination of two bound quintet states of N2.
Lee, Timothy J.↗
High energy density batteries for satellite applications
The performance requirements of high-energy batteries for terrestrial applications were examined to establish whether or not these systems showed any promise in aerospace applications. The technology assessment is reported and consists of a battery technology evaluation, preliminary engineering studies, and system selection. Major candidate systems are compared and a program schedule is provided.
Marcoux, L.↗
High energy density aluminum-oxygen cell
An alternative to a secondary battery as the power source for vehicle propulsion is a fuel cell. An example of this is the metal-air fuel cell using metals such as aluminum, zinc, or iron. Aluminum is a particularly attractive candidate, having high energy and power densities, being environmentally acceptable, and having a large, established industrial base for production and distribution. An aluminum-oxygen system is currently under development for a UUV test vehicle, and recent work has focussed upon low corrosion aluminum alloys and an electrolyte management system for processing the by-products of the energy-producing reactions. This paper summarizes the progress made in both areas. Anode materials capable of providing high utilization factors over current densities ranging from S to 150 mA/sq cm have been identified. These materials are essential to realizing an acceptable mission life for the UUV. With respect to the electrolyte management system, a filter/precipitator unit has been successfully operated for over 250 hours in a large scale, half-cell system.
Rudd, E. J.↗