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Results for “Hydrogen GaAs”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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23 records · Page 2

Plasma deposited diamondlike carbon on GaAs and InP

The properties of diamond like carbon films grown by RF flow discharge 30 kHz plasma using methane are reported. The Cls XPS line shape of films showed localized hybrid carbon bonds as low as 40 to as high as 95 percent. Infrared spectroscopy and N(15) nuclear reaction profiling data indicated 35 to 42 percent hydrogen, depending inversely on deposition temperature. The deposition rate of films on Si falls off exponentially with substrate temperature, and nucleation does not occur above 200 C on GaAs and InP. Optical data of the films showed bandgap values of 2.0 to 2.4 eV increasing monotonically with CH4 flow rate.

Warner, J. D.↗

Precise Nanoelectronics with Adatom Chains

Adatom chains on an atomically regulated substrate will be building components in future precise nanoelectronics. Adatoms need to be secured with chemical bonding, but then electronic isolation between the adatom and substrate systems is not guaranteed. A one-dimensional model shows that good isolation with existence of surface states is expected on an s-p crossing substrate such as Si, Ge, or GaAs, reflecting the bulk nature of the substrate. Isolation is better if adatoms are electronically similar to the substrate atoms, and can be manipulated by hydrogenation. Chain structures with group IV adatoms with two chemical bonds, or group III adatoms with one chemical bond, are semiconducting, reflecting the surface nature of the substrate. These structures are unintentionally doped due to the charge transfer across the chemical bonds. Physical properties of adatom chains have to be determined for the unified adatom-substrate system.

Yamada, Toshishige↗

Electrochemical Characterization of InP and GaAs Based Structures for Space Solar Cell Applications.

In this paper the emphasis is on accurate majority carrier concentration EC-V profiling of structures based on Indium Phosphide and Gallium Arsenide, using a newly developed electrolyte based on Hydrogen Flouride, Acetic Acid, Phosphoric Acid, 1-phenyl-2-propanamine and Ammonia Diflouride. Some preliminary data on the use of this electrolyte for determining the energy distribution of surface and deep states of these structures, applicable to fabrication process optimization and radiation induced defects studies of solar cells, are also provided.

Faur, Maria↗

Earth Observing System (EOS) Terra Spacecraft 120 Volt Power Subsystem: Requirements, Development and Implementation

Built by the Lockheed-Martin Corporation, the Earth Observing System (EOS) TERRA spacecraft represents the first orbiting application of a 120 Vdc high voltage spacecraft electrical power system implemented by the National Aeronautics and Space Administration (NASA) Goddard Space Flight Center (GSFC). The EOS TERRA spacecraft's launch provided a major contribution to the NASA Mission to Planet Earth program while incorporating many state of the art electrical power system technologies to achieve its mission goals. The EOS TERRA spacecraft was designed around five state-of-the-art scientific instrument packages designed to monitor key parameters associated with the earth's climate. The development focus of the TERRA electrical power system (EPS) resulted from a need for high power distribution to the EOS TERRA spacecraft subsystems and instruments and minimizing mass and parasitic losses. Also important as a design goal of the EPS was maintaining tight regulation on voltage and achieving low conducted bus noise characteristics. This paper outlines the major requirements for the EPS as well as the resulting hardware implementation approach adopted to meet the demands of the EOS TERRA low earth orbit mission. The selected orbit, based on scientific needs, to achieve the EOS TERRA mission goals is a sun-synchronous circular 98.2degree inclination Low Earth Orbit (LEO) with a near circular average altitude of 705 kilometers. The nominal spacecraft orbit is approximately 99 minutes with an average eclipse period of about 34 minutes. The scientific goal of the selected orbit is to maintain a repeated 10:30 a.m. +/- 15 minute descending equatorial crossing which provides a fairly clear view of the earth's surface and relatively low cloud interference for the instrument observation measurements. The major EOS TERRA EPS design requirements are single fault tolerant, average orbit power delivery of 2, 530 watts with a defined minimum lifetime of five years (EOL). To meet these mission requirements, while minimizing mass and parasitic power losses, the EOS TERRA project relies on 36, 096 high efficiency Gallium Arsenide (GaAs) on Germanium solar cells adhered to a deployable flexible solar array designed to provide over 5,000 watts of power at EOL. To meet the eclipse power demands of the spacecraft, EOS TERRA selected an application of two 54-cell series connected Individual Pressure Vessel (IPV) Nickel-Hydrogen (NiH2) 50 Ampere-Hour batteries. All of the spacecraft observatory electrical power is controlled via the TERRA Power Distribution Unit (PDU) which is designed to provide main bus regulation of 120 Vdc +/- -4% at all load interfaces through the implementation of majority voter control of both the spacecraft's solar array sequential shunt unit (SSU) and the two battery bi-directional charge and discharge regulators. This paper will review the major electrical power system requirement drivers for the EOS TERRA mission as well as some of the challenges encountered during the development, testing, and implementation of the power system. In addition, spacecraft test and early on orbit performance results will also be covered.

Keys, Denney J.↗

Hydrogen production by photoelectrolytic decomposition of H2O using solar energy

Photoelectrochemical systems for the efficient decomposition of water are discussed. Semiconducting d band oxides which would yield the combination of stability, low electron affinity, and moderate band gap essential for an efficient photoanode are sought. The materials PdO and Fe-xRhxO3 appear most likely. Oxygen evolution yields may also be improved by mediation of high energy oxidizing agents, such as CO3(-). Examination of several p type semiconductors as photocathodes revealed remarkable stability for p-GaAs, and also indicated p-CdTe as a stable H2 photoelectrode. Several potentially economical schemes for photoelectrochemical decomposition of water were examined, including photoelectrochemical diodes and two stage, four photon processes.

Rauh, R. D.↗