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At least 37 records · Page 2

Thermocapillary migration of liquid droplets in a temperature gradient in a density matched system

An experimental investigation of thermocapillary flow in droplets of a vegetable oil (partially hydrogenated soybean oil) immersed in silicone oil was conducted in a test cell with a heated top wall and a cooled bottom wall. The liquids are nearly immiscible and have equal densities at a temperature below the room temperature, thus providing a simulation of low-gravity conditions by reducing the buoyancy forces. The interfacial tension between the two oils was measured in the temperature range 20 to 50 C using a capillary tube and (d sigma)/(d T) was determined to be negative. Droplets ranging in sizes from 3 mm to 1 cm diameter were injected into the silicone oil. The vertical temperature profile in the bulk liquid (silicone oil) produces temperature variations along the interface which induce variations in the interfacial tension. The flow inside the droplet driven by the resulting interfacial shear stresses was observed using a laser light-sheet flow visualization technique. The flow direction is consistent with the sign of (d sigma)/(d T). The observed maximum surface velocities are compared to the theoretical predictions of Young et al. (1959).

Rashidnia, N.

Motion driven by the interface

Due to the reduction in buoyant forces aboard orbiting spacecraft such as the Space Shuttle, fluid motion driven by gradients in interfacial tension will be important in the processing of materials in space. In this paper, preliminary results from a study of surface tension driven flow in a pendant drop are reported. The drop is heated from above, and the resulting temperature gradients on the drop surface give rise to interfacial tension gradients. These, in turn, drive a circulation in the drop which is made visible by suitable tracers. The velocities are measured using a video technique, and the data on core velocities are found to agree well with results from a predictive theoretical model.

Jayaraj, K.

Thermocapillary migration of bubbles and droplets

A discussion is presented concerning the motion of droplets in a surrounding fluid induced by a temperature gradient. Such 'thermocapillary migration' may be characterized as the tangential stress at the interface that is induced by the temperature gradient's variation of interfacial tension, causing motion in the neighboring fluid both inside and outside the droplet. As a result, the droplet moves in the direction of the pole with the lower interfacial tension. An analysis is conducted in the creeping flow limit, for the case of small Marangoni number values. The method of matched asymptotic expansions is used for the solution of the field equations.

Subramanian, R. S.

Cell Partition in Two Polymer Aqueous Phases

In a reduced gravity environment the two polymer phases will not separate via density driven settling in an acceptably short length of time. It is to be expected that a certain amount of phase separation will take place, however, driven by the reduction in free energy gained when the interfacial area is reduced. This stage of separation process will therefore depend directly on the magnitude of the interfacial tension between the phases. In order to induce complete phase separation in a short time, electric field-induced separation which occurs because the droplets of one phase in the other have high electrophoretic mobilities which increase with droplet size was investigated. These mobilities are significant only in the presence of certain salts, particularly phosphates. The presence of such salts, in turn has a strong effect on the cell partition behavior in dextran-poly (ethylene glycol) (PEG) systems. The addition of the salts necessary to produce phase drop mobilities has a large effect on the interfacial tensions in the systems.

Brooks, D. E.

Interfacial strength development in thermoplastic resins and fiber-reinforced thermoplastic composites

An experimental program to develop test methods to be used to characterize interfacial (autohesive) strength development in polysulfone thermoplastic resin and graphite-polysulfone prepreg during processing is reported. Two test methods were used to examine interfacial strength development in neat resin samples. These included an interfacial tension test and a compact tension (CT) fracture toughness test. The interfacial tensile test proved to be very difficult to perform with a considerable amount of data scatter. Thus, the interfacial test was discarded in favor of the fracture toughness test. Interfacial strength development was observed by measuring the refracture toughness of precracked compact tension specimens that were rehealed at a given temperature and contact time. The measured refracture toughness was correlated with temperature and contact time. Interfacial strength development in graphite-polysulfone unidirectional composites was measured using a double cantilever beam (DCB) interlaminar fracture toughness test. The critical strain energy release rate of refractured composite specimens was measured as a function of healing temperature and contact time.

Howes, Jeremy C.

Study Of Bubble-Count Measurement Of Surface Tension

Report presents study of bubble-count method of measurement of surface or interfacial tension of liquids. In method, gas or liquid pumped at known rate along capillary tube. One end of tube open and immersed in liquid that wets tube. Pumped gas or liquid forms bubbles, detaching themselves from immersed open end of tube, and one measures average period, Pi, for formation and detachment of bubbles.

Nishioka, Gary M.

Thermocapillary migration of a drop: an exact solution with Newtonian interfacial rheology and stretching/shrinkage of interfacial area elements for small Marangoni numbers

In this paper we analyze the effects of the following phenomena associated with the thermocapillary migration of a drop. The first is the influence of Newtonian surface rheology of the interface and the second is that of the energy changes associated with stretching and shrinkage of the interfacial area elements, when the drop is in motion. The former occurs because of dissipative processes in the interfacial region, such as when surfactant molecules are adsorbed at the interface in sufficient concentration. The interface is typically modeled in this instance by ascribing to it a surface viscosity. This is a different effect from that of interfacial tension gradients arising from surfactant concentration gradients. The stretching and shrinkage of interfacial area elements leads to changes in the internal energy of these elements that affects the transport of energy in the fluids adjoining the interface. When an element on the interface is stretched, its internal energy increases because of the increase in its area. This energy is supplied by the neighboring fluids that are cooled as a consequence. Conversely, when an element on the interface shrinks, the adjoining fluids are warmed. In the case of a moving drop, elements of interfacial area are stretched in the forward half of the drop, and are shrunk in the rear half. Consequently, the temperature variation on the surface of the drop and its migration speed are modified. The analysis of the motion of a drop including these effects was first performed by LeVan in 1981, in the limit when convective transport of momentum and energy are negligible. We extend the analysis of LeVan to include the convective transport of momentum by demonstrating that an exact solution of the momentum equation is obtained for an arbitrary value of the Reynolds number. This solution is then used to calculate the slightly deformed shape of the drop from a sphere.

Rheology/methods

Surface Tension and Fingering of Miscible Interfaces

Experiments on miscible, buoyantly unstable reaction-diffusion fronts and non-reacting displacement fronts in Hele-Shaw cells show a fingering-type instability whose wavelengths (lambda*) are consistent with an interfacial tension (sigma) at the front caused by the change in chemical composition, even though the solutions are miscible in all proportions. In conjunction with the Saffman-Taylor model, the relation sigma = K/tau, where tau is the interface thickness and K approximately equal 4 +/- 2 x 10(exp -6) dyne, enables prediction of our measured values of lambda* as well as results from prior experiments on miscible interfaces. These results indicate that even for miscible fluids, surface tension is generally a more significant factor than diffusion in interfacial stability and flow characteristics.

Abib, Mohammed

Thermocapillary Convection in Bubbles and Drops

When bubbles or drops are present in an immiscible liquid in reduced gravity and the temperature of the liquid is non-uniform, a thermocapillary stress is generated at the interface due to the variation of interfacial tension with temperature. The resulting flow propels the drop freely suspended in the liquid towards warmer regions, so as to minimize the interfacial energy. In this presentation, we will focus on the effect of convective transport of momentum and energy, that are characterized by the Reynolds number and the Marangoni number, respectively. The results of asymptotic analyses for the speed of the drop for low and large values of these parameters will be discussed. These predictions as well as those from numerical simulations will be compared with reduced gravity experimental results obtained from experiments performed aboard the space shuttle.

Balassubramaniam

Surface-Tension Driven Convection

The present experiments are directed to examine surface-tension gradients. The surface-tension induced convection under reduced gravity it's comparison with normal gravity convection with all other identical conditions are studied. The intensities of such flows and their penetration depth below the free surface are also determined. In this way, the dominant role of a free surface in a reduced-gravity environment is indicated. The interface between two fluid phases can influence the motion of fluids when either the interface has finite curvature or when the interfacial tension varies from point to point. In both cases, forces appear in the interfacial region that can affect or generate fluid motions.

Ostrach, S.

Unsteady Thermocapillary Migration of Isolated Drops in Creeping Flow

The problem of an isolated immiscible drop that slowly migrates due to unsteady thermocapillary stresses is considered. All physical properties except for interfacial tension are assumed constant for the two Newtonian fluids. Explicit expressions are found for the migration rate and stream functions in the Laplace domain. The resulting microgravity theory is useful, e.g., in predicting the distance a drop will migrate due to an impulsive interfacial temperature gradient as well as the time required to attain steady flow conditions from an initially resting state.

Dill, Loren H.

Dynamic Nucleation of Supercooled Melts and Measurement of the Surface Tension and Viscosity

We investigate the phenomenon of acoustic pressure-induced nucleation by using a novel approach involving the large amplitude resonant radial oscillations and collapse of a single bubble intentionally injected into a supercooled liquid. Using a combination of previously developed and proven techniques, the bubble is suspended in a fluid host by an ultrasonic field which supplies both the levitation capability as well as the forcing of the radial oscillations. We observe the effects of an increase in pressure (due to bubble collapse) in a region no larger than 100 microns within the supercooled melt to rigorously probe the hypothesis of pressure-induced nucleation of the solid phase. The use of single bubbles operating in narrow temporal and spatial scales will allow the direct and unambiguous correlation between the origin and location of the generation of the disturbance and the location and timing of the nucleation event. In a companion research effort, we are developing novel techniques for the non-contact measurements of the surface tension and viscosity of highly viscous supercooled liquids. Currently used non-invasive methods of surface tension measurement for the case of undercooled liquids generally rely of the quantitative determination of the resonance frequencies of drop shape oscillations, of the dynamics of surface capillary waves, or of the velocity of streaming flows. These methods become quickly ineffective when the liquid viscosity rises to a significant value. An alternate and accurate method which would be applicable to liquids of significant viscosity is therefore needed. We plan to develop such a capability by measuring the equilibrium shape of levitated undercooled melt droplets as they undergo solid-body rotation. The experimental measurement of the characteristic point of transition (bifurcation point) between axisymmetric and two-lobed shapes will be used to calculate the surface tension of the liquid. Such an approach has already been validated through the experimental verification of numerical modeling results. The experimental approach involves levitation, melting, and solidification of undercooled droplets using a hybrid ultrasonic-electrostatic technique in both a gaseous as well as a vacuum environment. A shape relaxation method will be investigated in order to derive a reliable method to measure the viscosity of undercooled melts. The analysis of the monotonic relaxation to equilibrium shape of a drastically deformed and super-critically damped free drop has been used to derive interfacial tension of immiscible liquid combinations where one of the component has high viscosity. A standard approach uses the initial elongation of a droplet through shear flows, but an equivalent method could involve the initial deformation of a drop levitated in a gas by ultrasonic radiation pressure, electric stresses, or even solid body rotation. The dynamic behavior of the free drop relaxing back to equilibrium shape will be modeled, and its characteristic time dependence should provide a quantitative means to evaluate the liquid viscosity.

Trinh, E. H.

Thermal buoyancy and Marangoni convection in a two fluid layered system - A numerical study

Thermal buoyancy and surface tension driven convection is numerically investigated in a system with two, immiscible fluids. The geometry investigated, has an open cavity configuration with the lighter fluid situated on top of the heavier fluid, forming a stable layered system. The upper fluid meniscus and the interface are assumed to be flat and undeformable in the calculations. The governing equations and boundary/interface conditions are solved by a control volume based finite difference scheme for two pairs of immiscible fluids; the water-hexadecane system and a so called generic system. The steady state calculations show, that dramatically different flows are predicted when the interfacial tension effects are included or excluded from the system model. These differences are particularly appreciable in surface tension dominated flows, that are typical of microgravity situations. Complex flow patterns, with induced secondary flows are noticed in both the fluids. In general, the overall system heat transfer is found to increase with increases in the thermal buoyancy and surface tension effects, but the behavior of the system flow and thermal fields is not easy to characterize, when different combinations of these forces are considered.

Ramachandran, N.

A permeable rotating-wheel solvent extractor

Column-type device reported employs circular permeable structures of wire mesh screen for extracting solvents from systems with low density differences and low interfacial tensions. Rotating screen wheels of structure fasten to shaft; stationary screen structures are supported by circular bands connected by radial metal arms.

Kahn, D. R.

Convection phenomena at reduced gravity of importance for materials processing

The basic aspects of convection processes are delineated. It is shown that even in weak gravitational fields buoyancy can induce fluid motions. Furthermore, at reduced gravity other nongravity forces such as surface or interfacial tensions, g-jitter, therma-volume expansions, density differences due to phase changes, and magnetic and electric fields can induce fluid motions. The various types of flow possible with these various driving forces are described and criteria for determining the extent and nature of the resulting flows and heat transfer are presented. The various physical mechanisms that can occur separately and in combination are indicated and the present state of knowledge of each of the phenomena is outlined.

Ostrach, S.

Convection phenomena of importance for materials processing in space

The basic aspects of convection processes are delineated. It is shown that even in weak gravitational fields buoyancy can induce fluid motion. Furthermore, at reduced gravity, other nongravity forces such as surface or interfacial tensions, g jitter, thermal volume expansions, density differences due to phase changes, and magnetic and electric fields can induce fluid motions. The types of flows possible with these various driving forces are described, and criteria for determining the extent and nature of the resulting flows and heat transfer are presented. The different physical mechanisms that can occur separately and in combination are indicated, and the present state of knowledge of each of the phenomena is outlined. Specific research problems are described for many of the types of convection that are necessary to obtain greater understanding of their implications for space processing.

Ostrach, S.