Annealing of radiation damage in lithium doped silicon.
Li doped Si solar cell, studying irradiation damage, recovery effect, carrier removal, time dependency and annealing
SOLAR CELL↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Radiation kinetics in electronic materials Semiannual report
Degradation and recovery of minority carriers in solar cells including lithium
Sosin, A.↗
Kinetic equation of annealing in lithium- diffused silicon
Annealing properties of radiation damage in lithium-diffused silicon, formulating kinetic equation to describe processes associated with recovery and instability
Fang, P. H.↗
Experience with and future of lithium containing silicon solar cells.
Li doped Si solar cells noting fabrication, preradiation behavior, changes with temperature, recovery and I-V characteristics after irradiation
SILICON↗
Instrument for Analysis of Greenland's Glacier Mills
A new instrument is used to study the inner workings of Greenland s glacier mills by riding the currents inside a glacier s moulin. The West Greenland Moulin Explorer instrument was deployed into a tubular shaft to autonomously record temperature, pressure, 3D acceleration, and location. It is built with a slightly positive buoyancy in order to assist in recovery. The unit is made up of several components. A 3-axis MEMS (microelectromechanical systems) accelerometer with 0.001-g resolution forms the base of the unit. A pressure transducer is added that is capable of withstanding 500 psi (=3.4 MPa), and surviving down to -40 C. An Iridium modem sends out data every 10 minutes. The location is traced by a GPS (Global Positioning System) unit. This GPS unit is also used for recovery after the mission. Power is provided by a high-capacity lithium thionyl chloride D-sized battery. The accelerometer is housed inside a cylindrical, foot-long (=30 cm) polyvinyl chloride (PVC) shell sealed at each end with acrylic. The pressure transducer is attached to one of these lids and a MEMS accelerometer to the other, recording 100 samples per second per axis.
Behar, Alberto E.↗
Determination of oxygen in lithium by the vacuum distillation method.
Vacuum distillation determination of O in Li, evaluating accuracy through O additions and recoveries, method blank and residue identification
Gahn, R. F.↗
Lithium-doped solar cell pilot line fabrication and test programs
An investigation was conducted to determine the technology readiness of lithium-doped silicon solar cells with respect to use in space programs. A pilot line fabrication program was established, in which the pilot line cells were evaluated after being exposed to environments ordinarily imposed on nonlithium-doped silicon solar cells. Results indicate that further process improvements are required, particularly with respect to the P/N junction diffusion and the electrical contacting technique (including solder coating). It is concluded that lithium-doped cells can be fabricated to exhibit (1) high efficiencies, (2) uniform cell-to-cell recovery characteristics after exposure to 1-MeV electrons; and (3) good stability in most environments investigated (the only exception being the thermal shock environment).
Berman, P. A.↗
Study to determine and improve design for lithium-doped solar cells
Solar cell experiments show that a single lithium density parameter, the lithium density gradient, calculated from nondestructive capacitance measurements, provides the basis for accurate predictions of lithium cell behavior in a 1-MeV electron environment for fluences ranging between 3 X 10 to the 13th power e/sq cm and 3 X 10 to the 15th power/e sq cm. The oxygen-rich (quartz crucible) lithium cell with phosphorous starting dopant and lithium gradient between approximately 5 X 10 to the 18th power and 1.5 x 10 to the 19th power/cm to the 4th power was found superior in performance to the commercial 10 ohm-cm n/p control cells. Post-recovery stability of oxygen-rich cells was satisfactory. An average post-recovery current drop of approximately 1 mA was observed for 70 crucible cells after 1 year-equivalent storage time at 80 C. In contrast the oxygen-poor (float zone and Lopex) lithium cells displayed spotty initial performance and stability problems at room temperature.
Brucker, G.↗
Power Hibernation for Low-Cost Solar Powered Lunar Missions
Lunar Surface temperatures can span from equatorial highs near 400K and polar lows of 50K. The extreme cold combined with the 354-hour duration of the lunar night is particularly challenging for small robotic lander missions. NASA’s Commercial Lunar Payload Services (CLPS) missions involve robotic landers intended to provide low-cost access to the lunar surface. Current CLPS Missions are solar powered and are only intended to survive a single lunar day. The ability to survive the night and continue operations over many lunar cycles would provide a dramatic increase in science productivity. The Power Hibernation approach relies on battery cells that can tolerate the extreme cold night and recover once temperatures return to normal. System recovery from hibernation depends on power electronics that can “cold start” at lunar dawn and operate on solar array output alone. Once battery and avionics systems are restored the spacecraft resumes daytime operations. The challenge is to achieve this capability with minimum impact to the spacecraft design and payload capacity. This talk will describe recent and ongoing investigations in battery and electronics technologies that will enable power hibernation and recovery.
Space Power↗
Power Hibernation for Low-Cost Solar Powered Lunar Missions
Lunar Surface temperatures can span from equatorial highs near 400K and polar lows of 50K. The extreme cold combined with the 354-hour duration of the lunar night is particularly challenging for small robotic lander missions. NASA’s Commercial Lunar Payload Services (CLPS) missions involve robotic landers intended to provide low-cost access to the lunar surface. Current CLPS Missions are solar powered and are only intended to survive a single lunar day. The ability to survive the night and continue operations over many lunar cycles would provide a dramatic increase in science productivity. The Power Hibernation approach relies on battery cells that can tolerate the extreme cold night and recover once temperatures return to normal. System recovery from hibernation depends on power electronics that can “cold start” at lunar dawn and operate on solar array output alone. Once battery and avionics systems are restored the spacecraft resumes daytime operations. The challenge is to achieve this capability with minimum impact to the spacecraft design and payload capacity. This talk will describe recent and ongoing investigations in battery and electronics technologies that will enable power hibernation and recovery.
Space Power↗
Increased radiation resistance in lithium-counterdoped silicon solar cells
Lithium-counterdoped n(+)p silicon solar cells are found to exhibit significantly increased radiation resistance to 1-MeV electron irradiation when compared to boron-doped n(+)p silicon solar cells. In addition to improved radiation resistance, considerable damage recovery by annealing is observed in the counterdoped cells at T less than or equal to 100 C. Deep level transient spectroscopy measurements are used to identify the defect whose removal results in the low-temperature aneal. It is suggested that the increased radiation resistance of the counterdoped cells is primarily due to interaction of the lithium with interstitial oxygen.
Weinberg, I.↗
Effects of intrinsic region width in Si/Li/ p-i-n diodes
Description of certain effects related to the width of the intrinsic region produced in a silicon p-i-n diode by lithium ion drifting. It is found that for wider intrinsic regions at large forward biases there is a larger ohmic drop across the region and a correspondingly smaller current. Moreover, the recovery time decreases with increasing intrinsic region width. Conversely, the decay phase time increases with increasing intrinsic region width and with increasing current levels.
Harman, T. L.↗
Low temperature performance tests
Lithium cell performance at extremely low temperatures was tested and materials which could be used to make a cell completely electro-chemically inert for the purpose of deactivation were investigated. The effects of temperature and current density on polarization and performance loss are discussed along with discharge recovery behavior.
Goebel, F.↗
The Extended Duration Orbiter Regenerable CO2 Removal System
A new carbon dioxide scrubber system is undergoing development for extended duration orbiter (EDO) missions. The EDO requirements of missions up to 18 days and the capability for future missions up to 30 days necessitated the development and implementation of a regenerative CO2 removal process. This new system will reduce the launch weight and stowage volume as compared to the present method of CO2 removal, lithium hydroxide, which is stowed in canisters. The selected design, called the Regenerable CO2 Removal System (RCRS), uses a solid amine material to adsorb carbon dioxide and water vapor and periodically desorb these to space vacuum. The RCRS, which is located below the middeck floor, interfaces with the orbiter's cabin Atmospheric Revitalization System and is adjustable from four to seven crewmembers. The RCRS is designed to automatically cycle the beds from absorb to vacuum-desorb every 30 minutes. Also incorporated into the design are features such consumable recovery, external leak protection, trace contaminant control and automatic control logic operation.
Ouellette, Fred A.↗
Reliable Power Hibernation and Recovery for Solar Powered Lunar Missions
NASA Glenn Research Center has been working on a solution to surviving the lunar night based on the discovery that Li-Ion cells can survive the freeze/thaw process. This implies that a lunar surface spacecraft could hibernate through the coldest portions of the night and recover at lunar dawn. Survival and recovery also depend on power electronics capable of tolerating the cold and reliably starting at lunar dawn based on solar array output alone. GRC is working with STMD Space Technology Research Grant investigators to characterize Li-ion cells through the freeze-thaw process and fully understand the electro-chemical and thermal-mechanical processes to assure reliable cell hibernation and recovery. Further, we are working with investigators to determine what power semiconductor material, transistor technology, and power architecture is best suited for reliable cold start at lunar dawn and methodically restoring the power system to full operation for the next lunar cycle.
Spacecraft Power↗
Optical Property Evaluation of Next Generation Thermal Control Coatings
Next generation white thermal control coatings were developed via the Small Business Innovative Research program utilizing lithium silicate chemistry as a binder. Doping of the binder with additives yielded a powder that was plasma spray capable and that could be applied to light weight polymers and carbon-carbon composite surfaces. The plasma sprayed coating had acceptable beginning-of-life and end-of-live optical properties, as indicated by a successful 1.5 year exposure to the space environment in low Earth orbit. Recent studies also showed the coating to be durable to simulated space environments consisting of 1 keV and 10 keV electrons, 4.5 MeV electrons, and thermal cycling. Large scale deposition was demonstrated on a polymer matrix composite radiator panel, leading to the selection of the coating for use on the Gravity Recovery And Interior Laboratory (GRAIL) mission.
Jaworske, Donald A.↗
Carbon Dioxide Removal via Passive Thermal Approaches
A paper describes a regenerable approach to separate carbon dioxide from other cabin gases by means of cooling until the carbon dioxide forms carbon dioxide ice on the walls of the physical device. Currently, NASA space vehicles remove carbon dioxide by reaction with lithium hydroxide (LiOH) or by adsorption to an amine, a zeolite, or other sorbent. Use of lithium hydroxide, though reliable and well-understood, requires significant mass for all but the shortest missions in the form of lithium hydroxide pellets, because the reaction of carbon dioxide with lithium hydroxide is essentially irreversible. This approach is regenerable, uses less power than other historical approaches, and it is almost entirely passive, so it is more economical to operate and potentially maintenance- free for long-duration missions. In carbon dioxide removal mode, this approach passes a bone-dry stream of crew cabin atmospheric gas through a metal channel in thermal contact with a radiator. The radiator is pointed to reject thermal loads only to space. Within the channel, the working stream is cooled to the sublimation temperature of carbon dioxide at the prevailing cabin pressure, leading to formation of carbon dioxide ice on the channel walls. After a prescribed time or accumulation of carbon dioxide ice, for regeneration of the device, the channel is closed off from the crew cabin and the carbon dioxide ice is sublimed and either vented to the environment or accumulated for recovery of oxygen in a fully regenerative life support system.
Lawson, Michael↗
Performance Characterization and Simulation of Amine-Based Vacuum Swing Sorption Units for Spacesuit Carbon Dioxide and Humidity Control
Controlling carbon dioxide (CO2) and water (H2O) vapor concentrations in a space suit is critical to ensuring an astronauts safety, comfort, and capability to perform extra-vehicular activity (EVA) tasks. Historically, this has been accomplished using lithium hydroxide (LiOH) and metal oxide (MetOx) canisters. Lithium hydroxide is a consumable material that requires priming with water before it becomes effective at removing carbon dioxide. MetOx is regenerable through a power-intensive thermal cycle but is significantly heavier on a volume basis than LiOH. As an alternative, amine-based vacuum swing beds are under aggressive development for EVA applications. The vacuum swing units control atmospheric concentrations of both CO2 and H2O through fully-regenerative process. The current concept, referred to as the rapid cycle amine (RCA), has resulted in numerous laboratory prototypes. Performance of these prototypes have been assessed experimentally and documented in previous reports. To support developmental e orts, a first principles model has also been established for the vacuum swing sorption technology. For the first time in several decades, a major re-design of Portable Life Support System (PLSS) for the extra-vehicular mobility unit (EMU) is underway. NASA at Johnson Space Center built and tested an integrated PLSS test bed of all subsystems under a variety of simulated EVA conditions of which the RCA prototype played a significant role. The efforts documented herein summarize RCA test performance and simulation results for single and variable metabolic rate experiments in an integrated context. In addition, a variety of off-nominal tests were performed to assess the capability of the RCA to function under challenging circumstances. Tests included high water production experiments, degraded vacuum regeneration, and deliberate valve/power failure and recovery.
Swickrath, Michael J.↗