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All sourcesNASA NTRSDOE OSTI
NASA NTRS2006

Initial Isotopic Heterogeneities in ZAGAMI: Evidence of a Complex Magmatic History

Interpretations of Zagami s magmatic history range from complex [1,2] to relatively simple [3]. Discordant radiometric ages led to a suggestion that the ages had been reset [4]. In an attempt to identify the mechanism, Rb-Sr isochrons were individually determined for both fine-grained and coarse-grained Zagami [5]. Ages of approx.180 Ma were obtained from both lithologies, but the initial Sr-87/Sr-86 (ISr) of the fine-grained lithology was higher by 8.6+/-0.4 e-units. Recently, a much older age of approx.4 Ga has been advocated [6]. Here, we extend our earlier investigation [5]. Rb-Sr Data: In [5] we applied identical, simplified, procedures to both lithologies to test whether a grain-size dependent process such as thermally-driven subsolidus isotopic reequilibration had caused age-resetting. Minerals were separated only by density. In the present experiment, purer mineral separates were analysed with improved techniques. Combined Rb-Sr results give ages (T) = 166+/-12 Ma and 177+/-9 Ma and I(subSr) = 0.72174+/-9 and 0.72227+/-7 for the coarse-grained and fine-grained lithologies, respectively. ISr in the fine-grained sample is thus higher than in the coarse-grained sample by 7.3+/-1.6 e-units. The results for the coarse-grained lithology are in close agreement with T = 166+/-6 Ma, ISr = 0.72157+/-8 for an adjacent sample [7] and T = 178+/-4 Ma, ISr = 0.72151+/-5 [4, adjusted] for a separate sample. Thus, fine-grained Zagami appears on average to be less typical of the bulk than coarse-grained Zagami.

Nyquist, L. E.↗
NASA NTRS2010

Soil Components in Heterogeneous Impact Glass in Martian Meteorite EETA79001

Martian soil composition can illuminate past and ongoing near-surface processes such as impact gardening [2] and hydrothermal and volcanic activity [3,4]. Though the Mars Exploration Rovers (MER) have analyzed the major-element composition of Martian soils, no soil samples have been returned to Earth for detailed chemical analysis. Rao et al. [1] suggested that Martian meteorite EETA79001 contains melted Martian soil in its impact glass (Lithology C) based on sulfur enrichment of Lithology C relative to the meteorite s basaltic lithologies (A and B) [1,2]. If true, it may be possible to extract detailed soil chemical analyses using this meteoritic sample. We conducted high-resolution (~0.3 m/pixel) element mapping of Lithology C in thin section EETA79001,18 by energy dispersive spectrometry (EDS). We use these data for principal component analysis (PCA).

Schrader, C. M.↗
NASA NTRS2010

Mineralogy of Pyroxene and Olivine in the Almahata Sitta Ureilite

The Almahata Sitta meteorite (hereafter "Alma") is the first example of a recovered asteroidal sample that fell to earth after detection still in the orbit (2008TC3 asteroid), and thus is critical to understand the relationship between meteorites and their asteroidal parent bodies [1]. Alma is a polymict ureilite showing a fine-grained brecciated texture with variable lithologies from black, porous to denser, white stones [1]. It is an anomalous ureilite because of wide compositional ranges of silicates with abundant pores often coated by vapor-deposit crystals [1]. Nevertheless, Alma has general similarities to all ureilites because of reduction textures of silicates suggestive of rapid cooling from high temperature as well as heterogeneous oxygen isotope compositions [e.g., 1-5]. Alma is especially unique because it spans the compositional range of known ureilites [1]. In this abstract we report detailed mineralogical and crystallographic investigations of two different fragments to further constrain its thermal history with regards to the nature of the ureilite parent body.

Mikouchi, T.↗
NASA NTRS2016

Unique View of C Asteriod Regolith from the Jbilet Winselwan CM Chondrite

C-class asteroids frequently exhibit reflectance spectra consistent with thermally metamor-phosed carbonaceous chondrites, or a mixture of phyllosilicate-rich material along with regions where they are absent. One particularly important example appears to be asteroid 162173 Ryugu, the target of the Hayabusa 2 mission, although most spectra of Ryugu are featureless, suggesting a heterogeneous regolith. Here we explore an alternative cause of dehydration of regolith of C-class asteroids impact shock melting. Impact shock melting has been proposed to explain some mineralogical characteristics of CB chondrites, but has rarely been considered a major process for hydrous carbonaceous chondrites. Jbilet Winselwan (JW) is a very fresh CM breccia from Morocco, with intriguing characteristics. While some lithologies are typical of CM2s, other clasts show evidence of brief, though significant impact brecciation and heating. The first evidence for this came from preliminary petrographic and stable isotope studies. We contend that highly-brecciated, partially-shocked, and dehydrated lithologies like those in JW dominate C-class asteroid regolith.

Zolensky, Michael↗
NASA NTRS1986

Two contrasting metamorphosed ultramafic-mafic complexes from greenstone belts, the northern Kaapvaal Craton and their significance in Archaen tectonics

The character of Archaean ultramafic-mafic complexes can, given their prominance in greenstone belts, provide critical clues to help deduce the tectonic setting of these belts. Here are described two contrasting, metamorphosed, ultramafic-mafic complexes, the first a partially serpentinized dunitic body with associated chromite from Lemoenfontein, one of several peridotitic bodies occurring as discrete lenses and pods in granulite facies gneisses of the northern Kaapvaal craton. The second, the Rooiwater complex is a major layered igneous body, now metamorphosed in the amphibolite facies, but without pervasive deformation, which crops out in the northern Murchison greenstone belt. The Lemoenfontein chromites and associated ultramafic rocks are lithologically and chemically similar to their Phanerozoic equivalents of ophiolitic origin, interpreted as obducted oceanic crust. The Lemoenfontein complex is a remnant of Archaean oceanic material. In contrast, the Rooiwater complex is, despite the lack of exposed intrusive contacts, similar to layered igneous complexes such as Ushushwana or Bushveld. These complexes are intrusive in continental environments. It is concluded that contrasting ultramafic-mafic complexes represent a heterogeneity in greenstone belts with either oceanic or continental environments involved.

Smit, C. A.↗
NASA NTRS2017

Impact Record of a Asteroid Regolith Recorded in a Carbonaceous Chrondrite

C-class asteroids frequently exhibit reflectance spectra consistent with thermally metamor-phosed carbonaceous chondrites [1], or a mixture of phyllosilicate-rich material along with regions where they are absent [2]. One particularly important example appears to be asteroid 162173 Ryugu, the target of the Hayabusa 2 mission [1], although most spectra of Ryugu are featureless, suggesting a heterogeneous regolith [3]. Here we explore an alternative cause of dehydration of regolith of C-class asteroids - impact shock melting. Impact shock melting has been proposed to ex-plain some mineralogical characteristics of CB chondrites [4], but has rarely been considered a major process for hydrous carbonaceous chondrites [5]. Jbilet Winselwan (JW) is a very fresh CM breccia from Morocco, with intriguing characteristics. While some lithologies are typical of CM2s (Figure 1, top), other clasts show evidence of brief, though significant impact brecciation and heating. The first evidence for this came from preliminary petrographic and stable isotope studies [6,7]. We contend that highly-brecciated, partially-shocked, and dehydrated lithologies like those in JW dominate C-class asteroid regolith.

Zolensky, Michael↗
NASA NTRS1981

Lead isotopic studies of the Samail ophiolite, Oman

The isotopic composition of Pb and the concentrations of U, Th, and Pb are determined for samples from massive sulfides and lithologic units of the Samail ophiolite. It is shown that the magma that formed the ophiolite was probably derived from a depleted mantle, similar in Pb isotopic composition to the source area of mid-ocean ridge basalt. The gross geochemical characteristics of the mantle sources have remained almost unchanged for the last 100 million years. It is also shown that the U-Th-Pb systematics of the Samail formation indicate that local vertical heterogeneity in the oceanic crust can result from crystal fractionation and metasomatism at, and near, an oceanic spreading center.

Chen, J. H.↗
NASA NTRS1989

Heterogeneous dissemination of projectile materials in the impact melts from Wabar crater, Saudi Arabia

The initial observations of Spencer (1933) that two distinct impact melts coexist at the 90-m-diameter Wabar crater, Saudi Arabia, is confirmed. A dark or 'black' melt contains on the order of 4 percent meteoritic contamination, while the transparent or 'white' melt contains less than 1 percent. The Fe/Ni ratios in both varieties exhibit considerable scatter on electron-microprobe scales, akin to those reported by others for metal spherules in the black melt. If the meteoritic component is subtracted, both melts are chemically very similar. Clasts engulfed by the Wabar melts were investigated also, as they represent the progenitor lithologies from which the melts formed. Bulk compositions for these clasts reveal subtle differences in modal feldspar content within the quartz-rich Wabar target. Both melts require that a minimum of two target lithologies be present in the Wabar melt zone.

Horz, F.↗
NASA NTRS2013

Evidence for a "Wet" Early Moon

The Moon was thought to have lost its volatiles during impact(s) of a Mars-size planetesimal with the proto Earth [1] and during degassing of an early planet-wide magma ocean [2]. This view of an anhydrous Moon, however, has been challenged by recent discoveries of water on its surface [3-5] and in lunar volcanics [6-10] and regoliths [11]. Indigenous water is suggested to be heterogeneously distributed in the lunar interior and some parts of lunar mantle may contain as much water as Earth's upper mantle [6,10]. This water is thought to have been brought in part through solar wind implantation [3-5,8,11] and meteorite/cometary impacts [3,4,8,12] after the formation of the primary crust. Here we measured water in primary products of the Lunar Magma Ocean (LMO) thereby by-passing the processes of later addition of water to the Moon through impact events or during mantle overturn as suggested by previous studies (e.g., [8,12]). So far, ferroan anorthosite (FAN) is the only available lithology that is believed to be a primary product of the LMO [2]. It is generally accepted that plagioclase, after crystallization, floated in the LMO and formed FAN as the original crust [2]. Therefore, any indigenous water preserved in FAN was partitioned from the LMO. These data can be used to estimate the water content of the magma ocean at the time of plagioclase crystallization, as well as that of the mare magma source regions.

Hui, Hejiu↗
NASA NTRS2014

Composition of Rheasilvia Basin on Asteroid Vesta

The focus of the present study is the compositional analysis of small-scale surface features within the Rheasil-Aa basin on asteroid Vesta. We are using data acquired by the Visible and InfraRed mapping Spectrometer (VIR) on the Dawn mission. Nominal spatial resolution of the data set considered in this study is 70m/px. The portion of Rheasil-Aa basin below 65degS has a howarditic composition, with the higher concentration of diogenitic versus eucritic material in the region between 45deg and 225degE-lon. However, there are several locations, such as craters Tarpeia and Severina and Parentatio Rupes, with lithologic characteristics different from the surroundings regions. Tarpeia crater has a eucritic patch in the west side of the crater, the bottom part ofthe wall and part of the floor. Severina, located in a region of Mg-rich pyroxene, has some diogenitic units on the walls of the crater. Also the Parentatio Rupes has an ob-AOUS diogenitic unit. These units extend for 10-20km, and their location, especially in the case of the two craters, suggests they formed before the cratering events and also before the Rheasil-Aa impact event. The origin of these units is still unclear; however, their characteristics and locations suggests heterogeneity in the composition of the ancient Vestan crust in this particular location of the surface.

Ammannito, Eleonora↗
NASA NTRS2012

Vesta and the HED Meteorites: Comparison of Spectral Properties

We present the main results obtained comparing the visible-near infrared (VIS-NIR) spectra Vesta s surface with howardites, eucrites, diogenites (HEDs). HEDs are commonly associated with Vesta based on spectral similarities. Because of such association, much effort is being made to merge the information from HEDs as well as Vestoids with that from Vesta to characterize the lithologic diversity of the surface of this asteroid and to infer clues regarding its thermal history. The Dawn spacecraft, orbiting around Vesta since July 2011, is performing detailed observations of this body and thus improving our knowledge of its properties. Dawn s scientific payload includes an imaging spectrometer, VIR-MS, sensitive to the VIS-NIR spectral range. VIR-MS began acquiring spectra during the approach phase that started in May 2011 and will continue its observations through July 2012 when the spacecraft will depart Vesta to travel to Ceres. The observations are uniformly distributed in latitude and longitude, allowing a global view of Vesta s crustal spectral properties. Using the information provided by VIR spectra, we studied the distribution of the spectral heterogeneities on the surface and used our findings to perform a comparison with HED spectra in the VIS-NIR spectral range searching for analogies and/or incompatibilities. In our analysis, we utilized a method to compare the results obtained at microscopic scale on HED samples and the one obtained at macroscopic scale on the surface of Vesta. The intent of this study is to improve our understanding of the connection between Vesta and the HEDs, which is one of the primary Dawn scientific objectives. Dawn VIR spectra are characterized by pyroxene absorptions and most of the surface materials exhibit howardite-like spectra. However, some large areas can be interpreted to be material richer in diogenite (based on pyroxenes band depths and band centers) and some others like eucrite-rich howardite terrains. In particular, VIR data strongly indicate in the south polar region (Rheasilvia) the presence of Mg-pyroxene-rich terrains. The hypothesis that Vesta is the HED parent body is consistent with, and strengthened by, the geologic and spectral context for pyroxene distribution provided by VIR on Dawn.

Ammannito, E.↗
NASA NTRS2019

New Insights into the Heterogeneity of the Tagish Lake Meteorite: Soluble Organic Compositions of Variously Altered Specimens

The Tagish Lake carbonaceous chondrite exhibits a unique compositional heterogeneity that may be attributed to varying degrees of aqueous alteration within the parent body asteroid. Previous analyses of soluble organic compounds from four Tagish Lake meteorite specimens (TL5b, TL11h, TL11i, TL11v) identified distinct distributions and isotopic compositions that appeared to be linked to their degree of parent body processing (Herd et al. 2011; Glavin et al. 2012; Hilts et al. 2014). In the present study, we build upon these initial observations and evaluate the molecular distribution of amino acids, aldehydes and ketones, monocarboxylic acids, and aliphatic and aromatic hydrocarbons, including compound‐specific δ13C compositions, for three additional Tagish Lake specimens: TL1, TL4, and TL10a. TL1 contains relatively high abundances of soluble organics and appears to be a moderately altered specimen, similar to the previously analyzed TL5b and TL11h lithologies. In contrast, specimens TL4 and TL10a both contain relatively low abundances of all of the soluble organic compound classes measured, similar to TL11i and TL11v. The organic‐depleted composition of TL4 appears to have resulted from a relatively low degree of parent body aqueous alteration. In the case of TL10a, some unusual properties (e.g., the lack of detection of intrinsic monocarboxylic acids and aliphatic and aromatic hydrocarbons) suggest that it has experienced extensive alteration and/or a distinct organic‐depleted alteration history. Collectively, these varying compositions provide valuable new insights into the relationships between asteroidal aqueous alteration and the synthesis and preservation of soluble organic compounds.

Tagish Lake↗
NASA NTRS1990

Lunar meteorite Yamato-86032 - Mineralogical, petrological, and geochemical studies

Yamato-86032 is a shock-lithified anorthositic fragmental breccia. It consists mainly of highly feldspathic meta-breccias and meta-meltrocks and possibly contains a small contribution from mare lithologies, but there is no indication of a KREEP component. In many respects Y-86032 is similar to the previously described lunar meteorites Y-82192/3, but there are some notable differences. We have analyzed about 40 major and trace elements in bulk matrix, impact melt, and clast samples from two chips of Y-86032. The abundances of most lithophile and incompatible elements are lower in Y-86032 than in Y-82192 (which contains very low abundances compared to normal lunar highland rocks). The REE abundances are comparable to those of Y-82192. The elements Sc, Cr, Mn, Fe and Co have significantly lower abundances than in Y-82192, and the siderophile element pattern is also different. Since cosmic ray exposure data indicate pairing of Y-86032 with Y-82192/3, the source region for these meteorites on the moon must have been fairly heterogeneous.

Koeberl, Christian↗
NASA NTRS1986

Nitrogen and light noble gases in Shergotty

Two samples of Shergotty and a sample of EETA 79001's lithology A have been analyzed for N, He, Ne, and Ar abundances and isotopic composition. After correcting for spallogenic nitrogen, the nitrogen isotopic ratios were found to be close to that of the terrestrial atmosphere. The spallogenic noble gas data are consistent with cosmic ray irradiation of both Shergotty and EETA 79001 at shallow shielding depths. Cosmic ray exposure ages were estimated to be in the range of 0.5-0.8 Myr for EETA 79001, and of 2.0-5.2 Myr for Shergotty, depending on the choice of object size and shielding. Among the two Shergotty samples, the contents of Ar-40 differed by a factor of 3. This difference can be attributed to either a small-scale mineralogical inhomogeneity or a significant variation in the degree of degassing of minerals during shock, although the presence of trapped argon with a high Ar-40/Ar-36 ratio and its heterogeneous distribution cannot be ruled out.

Becker, R. H.↗
NASA NTRS1994

Assimilation by lunar mare basalts: Melting of crustal material and dissolution of anorthite

We discuss techniques for calculating the amount of crustal assimilation possible in lunar magma chambers and dikes based on thermal energy balances, kinetic rates, and simple fluid mechanical constraints. Assuming parent magmas of picritic compositions, we demonstrate the limits on the capacity of such magmas to melt and dissolve wall rock of anorthitic, troctolitic, noritic, and KREEP (quartz monzodiorite) compositions. Significant melting of the plagioclase-rich crustal lithologies requires turbulent convection in the assimilating magma and an efficient method of mixing in the relatively buoyant and viscous new melt. Even when this occurs, the major element chemistry of the picritic magmas will change by less than 1-2 wt %. Diffusion coefficients measured for Al2O3 from an iron-free basalt and an orange glass composition are 10(exp -12) sq m/s at 1340 C and 10(exp -11) sq m/s at 1390 C. These rates are too slow to allow dissolution of plagioclase to significantly affect magma compositions. Picritic magmas can melt significant quantities of KREEP, which suggests that their trace element chemistry may still be affected by assimilation processes; however, mixing viscous melts of KREEP composition with the fluid picritic magmas could be prohibitively difficult. We conclude that only a small part of the total major element chemical variation in the mare basalt and volcanic glass collection is due to assimilation/fractional crystallization processes near the lunar surface. Instead, most of the chemical variation in the lunar basalts and volcanic glasses must result from assimilation at deeper levels or from having distinct source regions in a heterogeneous lunar mantle.

Finnila, A. B.↗
NASA NTRS1994

Assimilation by Lunar Mare Basalts: Melting of Crustal Material and Dissolution of Anorthite

We discuss techniques for calculating the amount of crustal assimilation possible in lunar magma chambers and dikes based on thermal energy balances, kinetic rates, and simple fluid mechanical constraints. Assuming parent magmas of picritic compositions, we demonstrate the limits on the capacity of such magmas to melt and dissolve wall rock of anorthitic, troctolitic, noritic, and KREEP (quartz monzodiorite) compositions. Significant melting of the plagioclase-rich crustal lithologies requires turbulent convection in the assimilating magma and an efficient method of mixing in the relatively buoyant and viscous new melt. Even when this occurs, the major element chemistry of the picritic magmas will change by less than 1-2 wt %. Diffusion coefficients measured for Al2O3 from an iron-free basalt and an orange glass composition are 10(exp -12) m(exp 2) s(exp -1) at 1340 C and 10(exp -11) m(exp 2) s(exp -1) at 1390 C. These rates are too slow to allow dissolution of plagioclase to significantly affect magma compositions. Picritic magmas can melt significant quantities of KREEP, which suggests that their trace element chemistry may still be affected by assimilation processes; however, mixing viscous melts of KREEP composition with the fluid picritic magmas could be prohibitively difficult. We conclude that only a small part of the total major element chemical variation in the mare basalt and volcanic glass collection is due to assimilation/fractional crystallization processes near the lunar surface. Instead, most of the chemical variation in the lunar basalts and volcanic glasses must result from assimilation at deeper levels or from having distinct source regions in a heterogeneous lunar mantle.

Finnila, A. B.↗
NASA NTRS2011

Macro vs. Micro: Relating the Spectral Properties of Vesta and the HED Meteorite

We present the main results obtained comparing the visible-near infrared (VIS-NIR) spectra Vesta s surface with howardites, eucrites, diogenites (HED). HEDs are commonly associated with Vesta s composition based on spectral similarities. Because of such association, much effort is being made to merge the information from HEDs as well as Vestoids - with that from Vesta to characterize the lithologic diversity of the surface of this asteroid and to infer clues regarding its thermal history. However, while the HEDs are a class of meteorites well studied in the laboratory, the only spectral data available for Vesta until now were telescopic observations which are limited in terms of observation conditions, spatial resolution and Signal to Noise Ratio. The Dawn spacecraft, orbiting around Vesta since July 2011, is performing detailed observations of this body and thus improving our knowledge of its properties. Dawn s scientific payload includes an imaging spectrometer, VIR-MS, sensitive to the VIS-NIR spectral range. VIR-MS began acquiring spectra during the approach phase started in May 2011 and will continue its observations through July 2012 when the spacecraft will depart Vesta to travel to Ceres. The VIR-MS spatial resolution depends upon the mission phase (approach, survey, high altitude, low altitude). However, spectra acquired by VIR-MS have already exceeded the spatial resolution of ground-based telescopic observations, with resolution in the approach phase ranging from 2.5 up to 0.8 km/pixel. Moreover, the observations are uniformly distributed in latitude and longitude allowing us to have a global view of Vesta s crust spectral properties. Using the information provided by VIR spectra, we studied the distribution of the spectral heterogeneities on the surface and we used our findings to perform a comparison with HEDs spectra in the VIS-NIR spectral range searching for analogies and/or incompatibilities. In our analysis, we focused on a method to compare the results obtained at microscopic scale on HEDs samples and the one obtained at macroscopic scale on the surface of Vesta. Finally, we discuss our results in the context of vestan thermal history. The intent of this study is to improve our understanding of the connection between Vesta and the HED samples, which is one of the primary Dawn scientific objectives. This work is supported by an Italian Space Agency (ASI) grant and by NASA through the Dawn project and a Dawn at Vesta Participating Scientist grant.

Ammannito, E.↗
NASA NTRS2023

Investigating the Impact of X-Ray Computed Tomography Imaging on Soluble Organic Matter in the Murchison Meteorite: Implications for Bennu Sample Analyses

X-ray computed tomography (XCT) is a valuable reconnaissance tool for three-dimensional imaging and identification of distinct lithologies in extraterrestrial samples. It will be used as part of the preliminary examination of samples returned from asteroid (101955) Bennu by the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission. However, it must first be established whether x-rays generated during XCT could degrade or alter the organic composition of the returned samples by radiolysis. To test this, we split a crushed sample of the Murchison CM2 meteorite, kept one portion as a control, and irradiated the other portion up to the maximum x-ray dosage (~180 Gy) that a Bennu sample would experience during an XCT imaging experiment. We then extracted organic compounds from both splits and conducted (i) nontargeted soluble organic analyses to compare the chemical distributions of C-, H-, O-, N-, and S-bearing species and (ii) targeted measurements to quantify the abundances of 96 individual soluble organic molecules that included protein amino acids, amines, carboxylic acids, hydroxy acids, carbonyl compounds, polycyclic aromatic hydrocarbons, alcohols, sugars, and N-heterocycles. We found that XCT imaging of the Murchison meteorite had no measurable impact on the relative abundances or enantiomeric compositions of most of the soluble organic compounds targeted in this study. Elevated total abundances of several soluble organic compound classes were observed in the XCT-scanned Murchison sample relative to the control. This is likely related to particle size heterogeneity and specific surface area differences between the sample aliquots used for the extractions, rather than a result of the x-ray exposure. Assuming the samples returned from asteroid Bennu by OSIRIS-REx have a similar composition to carbonaceous chondrites, these data provide confidence that XCT will not significantly alter their soluble organic compositions.

Daniel P Glavin↗