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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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23 records · Page 2

Some recent studies with the solid-ionomer electrochemical capacitor

Giner, Inc. has developed a high-energy-density, all-solid-ionomer electrochemical capacitor, completely free of liquid electrolyte. The novel features of this device include 1) a three-dimensional metal oxide-particulate-ionomer composite electrode structure, and 2) a unitized repeating cell element. The composite electrode structures are bonded to opposite sides of a thin sheet of a solid proton-conducting ionomer membrane and form an integrally bonded membrane and electrode assembly (MEA). Individual MEAs can be stacked in series as bipolar elements to form a multiple cell device. The discharge characteristics and energy storage properties of these devices are described. Typical capacitance measured for a unit cell is 1 F/cm(exp 2). Life testing of a multicell capacitor on an intermittent basis has shown, that over a 10,000 hour period, the capacitance and resistance of the cell has remained invariant. There has been no maintenance required on the device since it was fabricated. Other multicell units of shorter life duration have exhibited similar reliable performance characteristics. Recent work has focused on increasing the capacitance of the unitized structure and improving the low-temperature characteristics. The approaches and experimental results will be presented. Some possible advanced NASA applications for these unique all-solid-ionomer devices will be discussed.

S Sarangapani↗

Characterization of the general purpose research furnace for low-G directional solidification experiments

Preliminary tests have shown that it is possible to control the temperature settings in NASA's General Purpose Research Furnace in such a manner as to obtain a constant rate of movement of a high temperature isotherm down the length of the furnace. These tests also showed that a temperature gradient on the order of 40 deg cm could be obtained in the furnace while moving the particular isotherm of interest, i.e., 900 C. This provides the possibility of performing directional solidification experiments in the furnace on a MEA flight in the low gravity environment provided by the Shuttle. A functional dependency of growth rate on perturbations during the the growth has been derived and shows the importance of avoiding non-steady growth rates and changing temperature gradients.

Crouch, R. K.↗

Design for an Integrated Open-Loop System for Carbon Dioxide Removal using Liquid Amine

Manned Space missions require maintaining a safe environment for the crew that can both sustain a breathable atmosphere and remove pollutants. Carbon dioxide, while not toxic in low concentrations, accumulates as crew members work and breath and can eventually affect the crew’s health. Therefore, a constant, passive system to remove the carbon dioxide build up is necessary for long-term missions. Currently, the prevailing liquid sorbent used in submarines and industrial flue gas utilizes the primary amine, monoethanolamine (MEA), to capture, transfer, and remove carbon dioxide from air. Diglycolamine (DGA) is an alternate primary amine that has similar performance and less volatility. It is currently being studied at Ames Research Center (ARC) and is the primary candidate for the operation of the sub-scale liquid amine test stand. The test stand is used to investigate liquid flow and liquid gas interfaces to assist in a system design for microgravity applications. The test stand includes a wedge design utilizes capillary action to hold the liquid while allowing gas-liquid interaction for carbon dioxide transfer. These wedge trays are placed in a contactor unit to remove carbon dioxide from the air stream, a degasser unit to replenish the liquid amine, and a capillary condensing heat exchanger (CCHX) to recapture water lost in the degasser unit. Nominal operating conditions for the contactor are a gas flow rate of 26scfm enriched with pure CO2 to 2600ppm and a liquid mixture of 65/35 vol% DGA/H2O at 0.65mL/min while the degasser was operated at 100°C and 1 atm. This paper discusses the challenges and limitations of a fully integrated system which will influence the design of a new subscale test stand.

Adrian Cortez↗

Development of Materials Processing Systems for Use in Space on Low-g Simulation Devices

Advanced furnace systems are being developed for use in space. Systems are being tested for current experiment applications and modified for future experiment requirements. Future projects are: (1) fabrication and testing of the Advanced Automated Directional Solidification Furnace (AADSF) flight hardware; (2) development of a Heat Pipe Furnace (HPF) for use in space. Heat pipes will be tested for space flight qualification in conjunction with the furnace development. The HPF design will be based on the AADSF development and will be of modular design including capabilities of operating with or without heat pipes; and (3) the AADSF furnace will be modified and tested to operate at temperatures up to 1700 C in the heated cavity. This will be accomplished by developing a new hot end heating module and insulation package for the existing AADSF. Refurbishment of the Drop Tower Furnace (DTF) is under way. The DTF can operate at temperatures up to 1700 C. The sample size will be approximately 3/8 in. dia. x 5/8 in. long. Design improvements for the General Purpose Rocket Furnace (GPRF) for use in the Material Experiment Assembly (MEA) are to be accomplished.

Aldrich, B. R.↗

Overview of the Dragonfly Entry Aerosciences Measurements (DrEAM) Suite

NASA Ames and Langley arepartnering with DLR to propose acomprehensive instrumentation suite known as the Dragonfly Entry Aerosciences Meas-urements (DrEAM). DrEAM being the first competed mission to fly EDL instrumentation as part of NASA’s Engineering Science Investigation (ESI).DrEAM will provide key aerothermodynamicdata and performance analysisfor Dragonfly’s forebody and backshell therma lprotection system (TPS),and also includes a DLR-provided Data Acquisition System(DAS).Titan’s atmosphere predominantly consists of nitro-gen (~98% by mole) with small amounts of methane(~2% by mole)and other trace gases. CN is a strong ra-diator and is found in nonequilibriumconcentrationsfor Titan entry. The accurate modeling of nonequilibrium CN radiation has proven to be a difficult task. Prompted by the Huygensmission, many experimental campaigns and analyses were performed to better understand the aerothermal environments experience by the probe dur-ing Titan entry[1].However, the Huygens probe carried no heatshieldinstrumentation. Therefore,the DrEAM instrumentation suite will significantly advance the state-of-the-art not only by documenting theenviron-ment and performance of Dragonfly’sentry system but also by making keymeasurements in Titan’s atmos-phere for thefirst time, thus providing new benchmark dataapplicable to entry science more generally. Current Measurement Goals: Aerothermal envi-ronments and TPS responsewill be measured using sen-sors similarto the Mars Entry, Descent, and Landing In-strumentation2 (MEDLI2) Integrated Sensor Plug(MISP) and the COMbined Aerothermaland Radiome-ter Sensor (COMARS)suite[2], with the latter supplied by DLR.For MEDLI2, MISP usedembedded thermo-couples (TCs) todirectly measure in-depth temperature of theTPS at several locations,which can also be used to infer surface environmentsvia inverse analysis. For DrEAM, the MISPstyle plugswill be known as Drag-onfly Sensors for Aero-Thermal Reconstruction (Drag-STR)plugs. On Schiaparelli, the COMARSsuite in-cludedthree total surface-mounted heatflux sensors, three pressure sensors, and one radiometer. For DrEAM, the COMARS package will be known as COmbined Sensor System for Titan Atmosphere (COSSTA). Atmospheric density measurements and capsuleaerodynamic data will be obtained throughthe onboard Inertial Measurement Unit (IMU),supple-mented by pressure transducers similar tothose used by the MEDLI Mars Entry AtmosphericData System (MEADS).The DrEAM pressure sensors will be known as Dragonfly Atmospheric Flight Transducers(DrAFT) Both DragSTR and DrAFThave flight heritagefrom MISP and MEADS on the MSLand Mars 2020mis-sions, and the COMARS suite successfullyflew on the ESA Schiaparelli EDMlander. A preliminary layout of the sensors is shown in Fig. 1. Because Dragonflyuses the same aeroshell provider (i.e., LockheedMartin) and materials for the TPS,with what are expected to be sim-ilar thicknesses as MSL and Mars 2020on both the heat shield and backshell, theDrEAMinstrumentation will look to utilize the same techniques and processes as de-veloped byMEDLI and MEDLI2for vehicle integra-tion. This commonality alsoenables DrEAMto lever-age the extensiveground test qualifications performed forMEDLI and MEDLI2 and claim substantial heritagefor this system.

A Brandis↗