SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Electronic oscillator strengths for nitrogen second positive and nitrogen first negative systems from observations of shock layers about hypersonic projectiles
Thermal energy transfer between free electrons and molecular vibration
Transition probabilities of nitrogen-nitrogen collision obtained with time-dependent wave functions of forced harmonic oscillator and by numerical methods
Auroral excitation rates and molecular vibrational tempratures in nitrogen 2PG from Franck-Condon factors obtained from intensity measurements and high resolution absorption spectral data
Two-phonon Raman scattering in cubic crystals, noting use of polarization effect to determine active irreducible representations
Vibration-rotation interaction effect on Franck- Condon factors for band system of RbH molecule
Wave interaction dynamics of far IR ELECTROMAGNETIC radiation generation by coherent molecular vibrations or phonons excited by stimulated Raman scattering and resonant phase matching condition
Molecular vibrational rotational parameters measured with IR heterodyning technique
Here we report pump-probe measurements of a hydrogen molecule (H 2 ) in the tunnel junction of a scanning tunneling microscope (STM) coupled to ultrashort terahertz (THz) pulses. The coherent oscillation of the THz induced DC tunneling current at a frequency of ~0.5 THz fingerprints the absorption by H 2 as a two-level system (TLS). Two components of the oscillatory signal are observed and point to both photon and field aspects of the THz pulses. A few loosely bound states with similar energies for the upper state of the TLS are evidenced by the coherent revival of oscillatory signal. Furthermore, the comparison of spectroscopic features of H 2 with different tips provides an understanding of the TLS for H 2 .
Crystalline materials with uniform molecular-sized pores are desirable for a broad range of applications, such as sensors, catalysis, and separations. However, it is challenging to tune the pore size of a single material continuously and to reversibly distinguish small molecules (below 4 angstroms). We synthesized a series of ionic covalent organic frameworks using a tetraphenoxyborate linkage that maintains meticulous synergy between structural rigidity and local flexibility to achieve continuous and reversible (100 thermal cycles) tunability of “dynamic pores” between 2.9 and 4.0 angstroms, with resolution below 0.2 angstroms. This results from temperature-regulated, gradual amplitude change of high-frequency linker oscillations. These thermoelastic apertures selectively block larger molecules over marginally smaller ones, demonstrating size-based molecular recognition and the potential for separating challenging gas mixtures such as oxygen/nitrogen and nitrogen/methane.
Electronic coherences in molecules are ultrafast charge oscillations on the molecular frame (MF) and their direct observation and separation from electronic population dynamics is challenging. Here we present a valence shell lab frame (LF) scattering method suited to probing electronic coherences in isolated systems. MF electronic coherences lead to LF electronic anisotropies observable by ultrafast angle-resolved scattering. Moment analysis of the LF anisotropy completely separates electronic coherences from population dynamics, demonstrated in excited state NH 3 using ultrafast time-energy-angle-resolved photoelectron spectroscopy. Overall, this general approach applies equally to attosecond/femtosecond electronic coherences in isolated systems.
It is hypothesized that observations of the Doppler shifting of IR and UV absorption lines may furnish a powerful method for the detection of 4.5-9 min standing acoustic waves trapped in a wave duct beneath the Jupiter tropopause. Similarly, data could be obtained on Jupiter's thermal and density structure, and on the depth to which its zonal winds penetrate. The present model of standing oscillations in the molecular hydrogen envelope gives attention to theoretical eigenfrequencies and to such forcing functions for wave generation as coupling with turbulent and convective motions, thermal instability due to radiative transfer, wave propagation effects in a saturated atmosphere, and ortho-to-parahydrogen conversion. The small contribution that the forcing mechanisms make to velocity amplitudes implies that the Doppler shifting caused by the waves may only be resolvable through the superposition of oscillation records to enhance S/N ratios.
The UCB/MPE Submillimeter Heterodyne Spectrometer is a system for astronomical spectroscopy in the high-frequency atmospheric windows from 500 to 1000 GHz. It contains a molecular laser local oscillator, a cooled Schottky open structure mixer, a quasi-optical coupling system, and an acoustooptical spectrometer. The compact receiver mounts at the Cassegrain focus of large infrared astronomical telescopes. The receiver noise temperature on the telescope is approximately 3500 K (DSB) during observations of the CO J = 7-6 line at 806.652 GHz. The spectrometer's frequency resolution and instantaneous bandwidth (less than 2 MHz resolution across 1.1 GHz) are well suited for observations of molecular emission lines from a variety of astronomical sources.
Carbon and nitrogen abundances have been obtained for a sample of 11-F- and G-type dwarfs covering a range in Fe/H abundance ratio from -0.8 to +0.3. Model atmospheres, which included the effects of convection and line blanketing, were used to calculate synthetic spectra of the CH, CN, and NH molecular bands. Effective oscillator strengths for the bands studied were found by matching synthetic spectra calculated from a model solar atmosphere with the observed solar bands. Many of the metal-poor stars, and particularly the high-velocity stars, were found to have substantial nitrogen over-deficiencies, suggesting that N is manufactured mostly in a secondary manner. The carbon-to-iron ratios were similar to the solar ratio, although there may be slight C over-deficiencies in metal-poor stars. However, the variation in C/Fe is not as marked as that found recently by Hearnshaw (1974). A comprehensive discussion of the theoretical errors is given, and some applications to Galactic evolution are noted.
Absolute absorption values of four strongest bands in molecular N dipole, determining oscillator strengths
Abstract Rectification, the preferential transport of a current in one direction through a system, has garnered significant attention in molecules because of its importance for controlling thermal and electronic currents at the nanoscale. Here, we report the presence of energy storage rectification effects in a molecular chain. This phenomenon is generated by subjecting a harmonic molecular chain to an oscillating temperature gradient and showing that the energy absorption rate of the system depends on the direction of the gradient. We examine how the energy storage rectification ratios in the chain are affected by the oscillating gradient, asymmetry in the chain, and the system parameters. We find that energy storage rectification can be observed in harmonic lattice structures with time-dependent temperatures and that, correspondingly, anharmonicity is not required to generate this rectification mechanism in such systems.
Molecular hydrogen-CO fuel cells operation, studying natural voltage oscillations due to repeated electrode poisoning and reactivation
The basis and techniques are presented for generating opacity probability distribution functions for the CN molecule (red and violet systems) and the C2 molecule (Swan, Phillips, Ballik-Ramsay systems), two of the more important diatomic molecules in the spectra of carbon stars, with a view to including these distribution functions in equilibrium model atmosphere calculations. Comparisons to the CO molecule are also shown. T he computation of the monochromatic absorption coefficient uses the most recent molecular data with revision of the oscillator strengths for some of the band systems. The total molecular stellar mass absorption coefficient is established through fifteen equations of molecular dissociation equilibrium to relate the distribution functions to each other on a per gram of stellar material basis.