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Nanophase Carbonates on Mars: Implications for Carbonate Formation and Habitability

Despite having an atmosphere composed primarily of CO2 and evidence for abundant water in the past, carbonate minerals have only been discovered in small amounts in martian dust [1], in outcrops of very limited extent [2, 3], in soils in the Northern Plains (the landing site of the 2007 Phoenix Mars Scout Mission) [4] and may have recently been detected in aeolian material and drilled and powdered sedimentary rock in Gale Crater (the Mars Science Laboratory [MSL] landing site) [5]. Thermal analysis of martian soils by instruments on Phoenix and MSL has demonstrated a release of CO2 at temperatures as low as 250-300 degC, much lower than the traditional decomposition temperatures of calcium or magnesium carbonates. Thermal decomposition temperature can depend on a number of factors such as instrument pressure and ramp rate, and sample particle size [6]. However, if the CO2 released at low temperatures is from carbonates, small particle size is the only effect that could have such a large impact on decomposition temperature, implying the presence of extremely fine-grained (i.e., "nanophase" or clay-sized) carbonates. We hypothesize that this lower temperature release is the signature of small particle-sized (clay-sized) carbonates formed by the weathering of primary minerals in dust or soils through interactions with atmospheric water and carbon dioxide and that this process may persist under current martian conditions. Preliminary work has shown that clay-sized carbonate grains can decompose at much lower temperatures than previously thought. The first work took carbonate, decomposed it to CaO, then flowed CO2 over these samples held at temperatures >100 degC to reform carbonates. Thermal analysis confirmed that carbonates were indeed formed and transmission electron microsopy was used to determine crystal sized were on the order of 10 nm. The next step used minerals such as diopside and wollastonite that were sealed in a glass tube with a CO2 and H2O source. After reacting these materials for a number of hours, thermal analysis demonstrated the formations of carbonates that decomposed at temperatures as low as 500 degC [7]. Further work is underway to carry out the weathering process under more Mars-like conditions (low pressure and low temperature) to determine if the carbonate decomposition temperature can be shifted to even lower temperatures, consistent with what has been detected by thermal analysis instruments on Mars.

Archer, P. Douglas, Jr.↗

Guidelines for Successful Use and Communication of Instrument Heritage in Early Mission Development with a Focus on Spectrometers

Heritage is important for both cost and risk related issues and as such, it is heavily discussed in NASA proposal evaluations. If used and communicated efficiently, heritage can lower both the perception of risk and the associated costs. Definitions of heritage vary between engineering, cost, and scientific communities, but when applied appropriately, heritage provides a benefit to the proposed mission. By making an instrument at least once before, the cost of producing it again can be reduced. The time and effort needed to develop the instrument concept and test the product represent an expense that can be lowered through the use of a previously built and developed instrument. This same thought can be applied when using a flight spare or build-to-print model of the heritage instrument. The lowered perception of risk is a result of the confidence gained in the instrument through successful use in the target environment. This is extremely important in early mission development to the evaluation board. This analysis will use JPL-managed proposals from 2003 to 2011, including Discovery, New Frontiers, and Mars Scout missions. Through the examination of these proposals and their associated debriefs, a set of guidelines have been created for successful use and communication of instrument heritage in early mission development

specrtometers↗

Ground Ice at the Phoenix Landing Site: A Preflight Assessment

One of the objectives of the Mars Scout mission, Phoenix, is to characterize the present state of water in the martian environment, in a location where water may play a significant role in the present and past habitability of Mars. Given the generally dry and cold climate of Mars today any substantial amount of water is expected to occur in the form of ground ice (subsurface ice) within the regolith. The Mars Odyssey Gamma Ray Spectrometer has indicated abundant subsurface hydrogen and inferred ground ice at high latitudes. Therefore, the Phoenix mission will be targeted to land in the northern high latitudes (approximately 65 degrees N - 75 degrees N) where ground ice is expected to be abundantly available for analysis. The lander will be capable of excavating, sampling, and analyzing, dry and water-rich/icy soils. The location and depth of excavation necessary to achieve the goals of sampling and analysis of icy material become important parameters to assess. In the present work we ask two key questions: 1) At what depth within the regolith do we expect to find ice? 2) How might this depth vary over the region of potential landing sites? Numerous lines of evidence can be employed to provide an indication of the presence or absence of shallow ground ice at the potential landing sites. For example geomorphology, neutrons, gamma rays, and theory each contribute clues to an overall understanding of the distribution of ice. Orbital observations provide information on a variety of spatial scales, typically 10 s of meters (patterned ground) to 100 s of kilometers (gamma rays). While information on all of these scales are important, of particular interest is how the presence and depth of ground ice might vary on spatial scales comparable to the lander and its work area. While ground ice may be stable (and present) on a regional scale, local-scale slopes and changes in the physical characteristics of soils can result in significant variations in the distribution of ice.

Mellon, M. T.↗

Vertical Lift Planetary Aerial Vehicles: Three Planetary Bodies and Four Conceptual Design Cases

NASA Ames Research Center has been studying the feasibility of vertical lift aerial vehicles to support planetary science and exploration missions. Besides Earth, it appears that there are three planetary bodies within our solar system where vertical flight might not only be theoretically feasible, but would also have unique mission capabilities that no other platform (ground-based, aerial, or orbital) could provide. Several vertical lift vehicle configurations might be applicable for planetary science missions. This paper presents a few representative conceptual design cases and the design challenges inherent in their development. Finally, more detailed comments are directed to the issues inherent in developing a NASA Mars Scout mission employing the use of a Martian autonomous rotorcraft.

Young, Larry A.↗

Acquisition of a High-resolution Inductively Coupled Plasma Mass Spectrometer for Cosmochemical and Geochemical Research

The primary goal of our research in this program is to develop new techniques for the analysis of volatile trace elements in very small samples using inductively coupled plasma mass spectrometry (ICP-MS) in preparation for samples returned by the Stardust mission. The instrument that will serve as the basis of our experiments is the ELEMENT2 high-resolution ICP-MS. We have spent the past year designing the laboratory to house this instrument as well as space to store and prepare samples returned by the Stardust mission. Unfortunately, the location that we had initially selected for the instrument turned out to be insufficient for our needs. This was determined almost eight months into the first year of our funding cycle, after extensive work including the production of engineering drawings. However, during this time the Lunar and Planetary Laboratory was selected to lead Phoenix, the first Mars Scout mission. As a result of this award LPL purchased a new, 50,000 square foot building. We have acquired 1400 square feet of laboratory space in this new facility. Four-hundred square feet will be used for a class-100 clean room. This area is designated for storage and preparation of extraterrestrial materials. The additional 1000 square feet will house the ELEMENT2 ICP-MS and peripheral devices. This is an enormous amount of space for this instrument, but it provides plenty of room for expansion in the future. The ICP-MS and the clean room facilities have been purchased. The instrument has been delivered. The startup time for this instrument is relatively short and we expect to be collecting our first data by mid-summer.

Lauretta, D. S.↗

Preliminary Design and Analysis of the ARES Atmospheric Flight Vehicle Thermal Control System

The Aerial Regional-scale Environmental Survey (ARES) is a proposed 2007 Mars Scout Mission that will be the first mission to deploy an atmospheric flight vehicle (AFV) on another planet. This paper will describe the preliminary design and analysis of the AFV thermal control system for its flight through the Martian atmosphere and also present other analyses broadening the scope of that design to include other phases of the ARES mission. Initial analyses are discussed and results of trade studies are presented which detail the design process for AFV thermal control. Finally, results of the most recent AFV thermal analysis are shown and the plans for future work are discussed.

Gasbarre, J. F.↗

Phoenix Mars Scout Parachute Flight Behavior and Observations

The data returned from the successful Phoenix Mars Scout mission are analyzed in order to determine characteristics and behaviors of the supersonic parachute that was used to slow the entry body during its descent to the surface. At least one significant drag reduction event was observed when the vehicle was traveling at Mach 1.6; this is consistent with previously reported terrestrial high altitude testing and is likely associated with an area oscillation of the parachute. The parachute is shown to possess some lateral instability relative to the anti-velocity vector that is also at a level that is consistent with the same historic data. Ramifications of the lateral instability and, in particular, the unsteadiness in the parachute drag are discussed as energizing elements of the entry body wrist mode. The apparent coefficient of drag for the parachute is calculated and shown to have relatively small variations on an average basis over the supersonic portion of flight.

Dynamics↗

JPL Power Systems for Current Planned Missions

The viewgraph presentation includes fact sheets, instrument lists, and mission parameters for 13 future missions. Those missions include Moon Mineralogy Mapping (MMM), Space Interferometry Mission (SIM), New Millennium--Space Technology-8 (ST-8), Ocean Salinity Mapping Orbiter (Aquarius), Ocean Surface Topology Mission (OSTM), Asteroid Rendezvous Mission-SEP (Dawn), Mars Scout Lander Mission (Phoenix), Solar Powered Jupiter Orbiter (Juno), Earth orbiting carbon observatory (OCO), planet finder observatory (Kepler), far infrared/sub-millimeter telescope (Hershel), Wide-field Infrared Survey Explorer (WISE), and Mars Science Laboratory-Rover (MSL). The presentation also contains a table of current missions and instruments.

Phoenix↗

Mars Scout: Micromissions to Investigate Martian Environments

Environments can be local, regional, or global. They can include one or more geological, morphological, climatological, and biological types. An environment also represents all the interactions that take place in the identified boundaries. Current planned missions to Mars in the Surveyor Program assume a good knowledge of the Martian environment that we do not have because it cannot be obtained only from orbit. There is a missing step between orbital data and the complex Surveyor missions to be landed that needs to be filled. The Ames/IRSPS Scout Mission Concept originally proposed in February 1999 filled this gap by landing a series of small (less than 10 kgs. each) scout missions. The Mars Environment Scout Mission Concept is being developed to explore the possibility of sending a series of small, simple, and inexpensive stations to the surface of Mars. The objective(s) would be to document either: (a) the environmental diversity of Mars, (b) a specific Martian environment, and/or (c) a region of interest. This type of mission will provide critical information about environments that is currently not available, and could also be used as precursors helping the design, preparation, and planning of more complex future missions to come.

Cabrol, N. A.↗

Phoenix Mars Scout UHF Relay-Only Operations

The Phoenix Mars Scout Lander will launch in August 2007 and land on the northern plains of Mars in May of 2008. In a departure from traditional planetary surface mission operations, it will have no direct-to-Earth communications capability and will rely entirely on Mars-orbiting relays in order to facilitate command and control as well as the return of science and engineering data. The Mars Exploration Rover missions have demonstrated the robust data-return capability using this architecture, and also have demonstrated the capability of using this method for command and control. The Phoenix mission will take the next step and incorporate this as the sole communications link. Operations for 90 Sols will need to work within the constraints of Odyssey and Mars Reconnaissance Orbiter communications availability, anomalies must be diagnosed and responded to through an intermediary and on-board fault responses must be tolerant to loss of a relay. These and other issues pose interesting challenges and changes in paradigm for traditional space operations and spacecraft architecture, and the approach proposed for the Phoenix mission is detailed herein.

fault protection↗

Thermal and Evolved Gas Behavior of Calcite Under Mars Phoenix TEGA Operating Conditions

The Mars Phoenix Scout Mission with its diverse instrument suite successfully examined several soils on the Northern plains of Mars. The Thermal and Evolved Gas Analyzer (TEGA) was employed to detect organic and inorganic materials by coupling a differential scanning calorimeter (DSC) with a magnetic-sector mass spectrometer (MS). Martian soil was heated up to 1000 C in the DSC ovens and evolved gases from mineral decomposition products were examined with the MS. TEGA s DSC has the capability to detect endothermic and exothermic reactions during heating that are characteristic of minerals present in the Martian soil. Initial TEGA results indicated the presence of endothermic peaks with onset temperatures that ranged from 675 C to 750 C with corresponding CO2 release. This result suggests the presence of calcite (CaCO3. CaO + CO2). Organic combustion to CO2 is not likely since this mostly occurs at temperatures below 550 C. Fe-carbonate and Mg-carbonate are not likely because their decomposition temperatures are less than 600 C. TEGA enthalpy determinations suggest that calcite, may occur in the Martian soil in concentrations of approx.1 to 5 wt. %. The detection of calcite could be questioned based on previous results that suggest Mars soils are mostly acidic. However, the Phoenix landing site soil pH was measured at pH 8.3 0.5, which is typical of terrestrial soils where pH is controlled by calcite solubility. The range of onset temperatures and calcite concentration as calculated by TEGA is poorly con-strained in part because of limited thermal data of cal-cite at reduced pressures. TEGA operates at <30 mbar while most calcite literature thermal data was obtained at 1000 mbar or higher pressures.

Ming, D.W.↗

Summary of Results from the Mars Phoenix Lander's Thermal Evolved Gas Analyzer

The Mars Phoenix Scout Mission with its diverse instrument suite successfully examined several soils on the Northern plains of Mars. The Thermal and Evolved Gas Analyzer (TEGA) was employed to detect evolved volatiles and organic and inorganic materials by coupling a differential scanning calorimeter (DSC) with a magnetic-sector mass spectrometer (MS) that can detect masses in the 2 to 140 dalton range [1]. Five Martian soils were individually heated to 1000 C in the DSC ovens where evolved gases from mineral decompostion products were examined with the MS. TEGA s DSC has the capability to detect endothermic and exothermic reactions during heating that are characteristic of minerals present in the Martian soil.

Sutter, B.↗

Sulfur Mineralogy at the Mars Phoenix Landing Site

The Mars Phoenix Scout mission landed at the northernmost location (approx.68deg N) of any lander or rover on the martian surface. This paper compares the S mineralogy at the Phoenix landing site with S mineralogy of soils studied by previous Mars landers. S-bearing phases were not directly detected by the payload onboard the Phoenix spacecraft. Our objective is to derive the possible mineralogy of S-bearing phases at the Phoenix landing site based upon Phoenix measurements in combination with orbital measurements, terrestrial analog and Martian meteorite studies, and telescopic observations.

Ming, Douglas W.↗