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Microgravity Science and Applications Program Tasks, 1984 Revision

This report is a compilation of the active research tasks as of the end of the fiscal year 1984 of the Microgravity Science and Applications Program, NASA-Office of Space Science and Applications, involving several NASA centers and other organizations. The purpose of the document is to provide an overview of the program scope for managers and scientists in industry, university, and government communities. The report is structured to include an introductory description of the program, strategy and overall goal; identification of the organizational structures and people involved; and a description of each research task, together with a list of recent publications. The tasks are grouped into six categories: (1) electronic materials; (2) solidification of metals, alloys, and composites; (3) fluid dynamics and transports; (4) biotechnology; (5) glasses and ceramics; and (6) combustion.

Elizabeth Pentecost

Raman and Infrared Spectroscopy of Yttrium Aluminum Borate Glasses and Glass-ceramics

Raman spectra of glasses and glass-ceramics in the Y2O3-Al2O3-B2O3 system are reported. Glasses with B2O3 contents ranging from 40 to 60 mole percent were prepared by melting 20 g of the appropriate oxide or carbonate powders in alumina crucibles at 1400 C for 45 minutes. Subsequent heat treatments of the glasses at temperatures ranging from 600 to 800 C were performed in order to induce nucleation and crystallization. It was found that Na2CO3 added to the melt served as a nucleating agent and resulted in uniform bulk crystallization. The Raman spectra of the glasses are interpreted primarily in terms of vibrations of boron - oxygen structural groups. Comparison of the Raman spectra of the glass-ceramic samples with spectra of aluminate and borate crystalline materials reveal that these glasses crystallize primarily as yttrium aluminum borate, YAl3(BO3)4.

J Bradley

The Effect of Gravity on the Combustion Synthesis of Porous Ceramics and Metal Matrix Composites

Combustion synthesis (self propagating, high temperature synthesis-SHS) is a novel technique that is capable of producing many advanced materials. The ignition temperature (Tig) of such combustion synthesis reactions is often coincident with that of the lowest melting point reactant. The resultant liquid metal wets and spreads around the other solid reactant particles of higher melting points, thereby improving the reactant contact and kinetics, followed by formation of the required compounds. This ignition initiates a combustion propagating wave whose narrow reaction front rapidly travels through the reactants. Since this process is highly exothermic, the heat released by combustion often melts the reactant particles ahead of the combustion front and ignites the adjacent reactant layer, resulting in a self-sustaining reaction. Whenever a fluid phase (liquid or gas) is generated by the reaction system, gravity-driven phenomena can occur. Such phenomena include convective flows of fluid by conventional or unstable convection and settling of the higher density phases. A combustion process is often associated with various kinds of fluid flow. For instance, if the SHS reaction is carried out under inert or reactive gas atmospheres, or a volatile, e.g., B2O3, is deliberately introduced as a reactant, convective flows of the gas will occur due to a temperature gradient existing in the atmosphere when a combustion wave is initiated. The increased gas flow will produce a porous (or expanded) SHS product. Owing to the highly exothermic nature of many SHS reactions, liquid phase(s) can also form before, at, or after the combustion front. The huge temperature gradient at the combustion front can induce convective flows (conventional or unstable) of the liquid phase. Each of these types of convective fluid flow can change the combustion behavior of the synthesizing reaction, and, therefore, the resultant product microstructure. In addition, when two or more phases of different density are produced at or ahead of the propagating combustion front settling of the higher density phase will occur resulting in a non-uniform product microstructure and properties.

J J Moore

Lunar and Planetary Science XXXIV

The 34th Lunar and Planetary Science Conference was held March 17-21, 2003. Topics included planetary exploration, crater research on Mars, Earth, Moon, and other planets or satellites, imaging techniques and image analysis, age determination, albedo studies, petrographic studies, isotope composition studies, instrument design, sampling methods, landform analysis, asteroids, impact analysis, impact melts, and related research.

Lunar and Planetary Institute

Mechanical properties of glasses impacted by debris or micrometeorites

Mechanical strength measurements on five glasses and one glass ceramic exposed on the Long Duration Exposure Facility (LDEF) have revealed no damage exceeding experimental limits of error after exposure. The measurement technique subjected less than 5 percent of the sample surface area to stresses above 90 percent of the failure strength. Seven micrometeorite or space debris impacts occurred at locations which were not in that portion of the sample subjected to greater than 90 percent of the applied stress. In consequence of this, the impact events on the sample were not detected in mechanical strength measurements. The physical form and structure of the impact sites was carefully examined to determine the influence of those events upon stress concentration associated with the impact and the resulting mechanical strength influence. The size of the impact site insofar as it determines flaw size for fracture purposes was examined. Surface topography of the impacts reveals that six of the seven sites display impact melting. The classical melt crater structure is surrounded by a zone of fractured glass. Residual stresses arising from shock compression and from cooling of the impact fused zone cannot be included in fracture mechanics analyses based on simple flaw size analyses. Strategies for refining estimates of mechanical strength degradation by impact events are presented.

Donald L. Kinser

Vaporization Would Cool Primary Battery

Temperature of discharging high-power-density primary battery maintained below specified level by evaporation of suitable liquid from jacket surrounding battery, according to proposal. Pressure-relief valve regulates pressure and boiling temperature of liquid. Less material needed in cooling by vaporization than in cooling by melting. Technique used to cool batteries in situations in which engineering constraints on volume, mass, and location prevent attachment of cooling fins, heat pipes, or like.

Bhandari, Pradeep

The Alpha-Proton-X-Ray Spectrometer Deployment Mechanism: an Anthropomorphic Approach to Sensor Placement on Martian Rocks and Soil

On July 4,1997, the Mars Pathfinder spacecraft lands on Mars and starts conducting technological and scientific experiments. One experiment, the Alpha-Proton-X-ray Spectrometer, uses a sensor head placed against rocks and soil to determine their composition. To guarantee proper placement, a deployment mechanism mounted on the Mars Rover aligns the sensor head to within 20 deg of the rock and soil surfaces. In carrying out its task, the mechanism mimics the action of a human hand and arm. Consisting of a flexible wrist, a parallel link arm, a brush dc motor actuator, and a revolutionary non-pyrotechnic fail-safe release device, the mechanism correctly positions the sensor head on rocks as high as 0.29 m and on targets whose surfaces are tilted as much as 45 deg from the nominal orientation of the sensor head face. The mechanism weighs less than 0.5 kg, can withstand 100 g's, and requires less than 2.8 N x m of actuation torque. The fail-safe coupler utilizes Cerrobend, a metal alloy that melts at 60 C, to fuse the actuator and the rest of the mechanism together. A film heater wrapped around the coupler melts the metal, and Negator springs drive the mechanism into its stowed position. The fail-safe actuates using 6.75 Watts for 5 minutes in the event of an actuator failure.

Richard S Blomquist

Combustion Characteristics of a Solid Propellant With a Charring Binder

A brief investigation of the combustion characteristics of a solid propellant containing a binder which chars, as opposed to melting or volatizing, has been made. The burning rate of the propellant with the charring binder was significantly higher than similar propellants containing non-charring binders. High speed motion pictures of the burning propellant showed that the aluminum burned on the regressing surface, rather than a short distance from it as is typical with composite propellants.

D E Udlock

Lunar and Planetary Science XXXVI, Part 2

Topics covered include: Ringwoodite-olivine assemblages in Dhofar L6 melt veins; Amorphization of forsterite grains due to high energy heavy ion irradiation: Implications for grain processing in ISM; Validation of AUTODYN in replicating large-scale planetary impact events; A network of geophysical observatories for mars; Modelling catastrophic floods on the surface of mars; Impact into coarse grained spheres; The diderot meteorite: The second chassignite; Galileo global color mosaics of Io; Ganymede's sulci on global and regional scales; and The cold traps near the south pole of the moon.

Source record

Up-and-Coming IMCs

While the good oxidation and environmental resistance, high melting points, and comparatively low densities of such ordered intermetallics as Ti 3 Al, NiAl, FeAl, and NbAl 3 render them good candidates for advanced aerospace structures, their poor toughness at low temperatures and low strength at elevated temperatures have prompted the development of fiber-reinforced intermetallic-matrix composites (IMCs) with more balanced characteristics. Fabrication methods for continuous-fiber IMCs under development include the P/M 'powder cloth' method, the foil/fiber method, and thermal spraying. The ultimate success of IMCs depends on fibers truly compatible with the matrix materials.

Randy Bowman

Development of a High Force Thermal Latch

This paper describes the preliminary development of a high force thermal latch (HFTL). The HFTL has one moving part which is restrained in the latched position by a low melting temperature or fusible metal alloy. When heated the fusible alloy flows to a receiving chamber and in so doing at first releases the tension load in the latch bolt and later releases the bolt itself. The HFTL can be used in place of pyrotechnically activated spacecraft release devices in those instances where the elimination of both pyrotechnic shock-loading and rapid strain-energy release take precedence over the near instantaneous release offered by ordnance initiated devices.

William D Nygren

Swamp Works Regolith Compaction Technologies

While the level of compaction below the lunar surface increases quickly after only a few cm of depth, in many cases during a construction mission there will be a need to excavate and transport regolith to a new location for cut-and-fill or horizontal construction of structures such as berms. In these cases to achieve high levels of bulk density, compaction must be per-formed. Additionally, in some cases surface technologies such as systems that sinter/melt the surface may desire the maximum possible compaction at the sur-face to improve melting/heating performance and the final material strength properties. Kennedy Space Center’s (KSC) Swamp Works has developed two means of compaction, lunar and mar-tian compaction. Planetary Autonomous Compaction Technology (PACT) which is part of the Multifunction End Effector for Regolith Compaction Acquisition and Transfer (MEERCAT) robotic arm end effector system’s capabilities and the Site Preparation Tooling for Operations on Mobility Platforms (STOMP) vibratory roller compactor. PACT on MEERCAT has been demonstrated to a TRL 5 and STOMP to a TRL 4 in ambient testing. The results of PACT on MEERCAT and STOMP testing will be shared with results for various simulants including BP-1, ICN-LHT-1G (aka CSM-LHT-1G), RDW-LHT-1GH (a simulant developed for the Mason Tipping Point to match characteristics of ICN-LHT-1G), and Exolith LHS-1E. This will also include discussions on methods used to verify relative density before and after compaction and means to verify density effects below depth. To calculate relative density, maximum and minimum densities for simulants were taken from literature and additional lab testing (publication in work).

redwire

Evaluation of Various Methods for Determining Bulk Compositions of Chondrules and Other Objects in Petrographic Thin Sections

Studies of many objects in petrographic thin section, such as melt inclusions in igneous rocks, chondrules and Ca-Al rich inclusions in chondritic meteorites, or clasts in lunar and other breccias, require or can benefit from knowledge of their bulk compositions. Given the scarcity of these materials, the reluctance of curators to provide more abundant material, and the extreme difficulty of cleanly separating such objects from their rock matrices, geochemical and cosmochemical studies need the ability to determine their bulk compositions from in situ methods, such as defocused beam analysis, or quantitative chemical mapping by electron beam methods.

Daniel Kent Ross

Swamp Works Regolith Compaction Technologies

While the level of compaction below the lunar surface increases quickly after only a few cm of depth, in many cases during a construction mission there will be a need to excavate and transport regolith to a new location for cut-and-fill or horizontal construction of structures such as berms. In these cases to achieve high levels of bulk density, compaction must be per-formed. Additionally, in some cases surface technolo-gies such as systems that sinter/melt the surface may desire the maximum possible compaction at the sur-face to improve melting/heating performance and the final material strength properties. Kennedy Space Center’s (KSC) Swamp Works has developed two means of compaction, lunar and mar-tian compaction. Planetary Autonomous Compaction Technology (PACT) which is part of the Multifunction End Effector for Regolith Compaction Acquisition and Transfer (MEERCAT [1]) robotic arm end effector system’s capabilities and the Site Preparation Tooling for Operations on Mobility Platforms (STOMP [2]) vibratory roller compactor. PACT on MEERCAT has been demonstrated to a TRL 5 and STOMP to a TRL 4 in ambient testing. The results of PACT on MEERCAT and STOMP testing will be shared with results for various simulants including BP-1, ICN-LHT-1G (aka CSM-LHT-1G), RDW-LHT-1GH (a simulant developed for the Mason Tipping Point to match characteristics of ICN-LHT-1G), and Exolith LHS-1E. This will also include discus-sions on methods used to verify relative density before and after compaction and means to verify density effects below depth. To calculate relative density, maximum and minimum densities for simulants were taken from literature [3] [4] [5] and additional lab test-ing (publication in work).

vibration

The Evolution of the Moon and the Terrestrial Planets

The thermal evolutions of the Moon, Mars, Venus, and Mercury are calculated theoretically starting from cosmochemical condensation models. An assortment of geological, geochemical, and geophysical data are used to constrain both the present-day temperatures and the thermal histories of the planets' interiors. Such data imply that the planets were heated during or shortly after formation and that all the terrestrial planets started their differentiations early in their history. Initial temperatures and core formation play the most important roles in the early differentiation. The size of the planet is the primary factor in determining its present-day thermal state. The Moon, smallest in size, is characterized as a differentiated body with a crust, a thick solid mantle, and an interior region which may be partially molten. It is presently cooling rapidly and is relatively inactive tectonically. Mercury, which probably has a large core, may have a 500-km-thick solid lithosphere and a partially molten core, if it is assumed that some heat sources exist in the core. If this is not the case, the planet's interior temperatures are everywhere below the melting curve for iron. The thermal evolution is dominated by the core separation and the high conductivity of iron that makes up the bulk of Mercury. Mars, intermediate in size, is assumed to have differentiated an Fe-FeS core. While the formation of an early crust is evident, large-scale melting and differentiation of the mantle silicates has occurred at least up until 1 b.y. ago. Present-day temperature profiles indicate moderate tectonic activity at the present time. Venus is characterized as a planet not unlike the Earth in many respects. Core formation has occurred probably during the first billion years after the formation. The present-day temperatures indicate a partially molten upper mantle overlain by a 100-km-thick lithosphere and a molten Fe-Ni core. We can expect that today Venus may have tectonic processes similar to the Earth's.

M Nafi Toksöz

Petermann Glacier on the Brink: Progress, Challenges and Insights

Petermann Glacier, the largest marine-terminating glacier in northern Greenland based on catchment area and ice discharge, plays a key role in regulating ice discharge from the Greenland Ice Sheet into the Arctic Ocean. With an upstream catchment connected to the ice sheet interior via a deep subglacial canyon, its future stability has major implications for sea level rise. In this review, we synthesize recent advances in understanding Petermann’s dynamics across three critical interfaces: the ice–ocean, ice–atmosphere, and ice–bed boundaries. At the surface, observations show that reanalysis products underestimate air temperatures and melt, while regional climate models diverge significantly in their estimates of surface mass balance, underscoring the need for improved in situ data and models. At the ocean boundary, enhanced basal melting driven by both subglacial runoff and Atlantic water intrusions is identified as the dominant driver of recent mass loss of Petermann Glacier, with continued warming posing a serious threat to the stability of the floating tongue. At the bed, new geophysical synthesis reveals complex geology, likely spatial variability in geothermal heat flux, and the influence of the megacanyon on seasonal hydrology and velocity fluctuations. Petermann’s mass balance has been negative in recent decades without corresponding flow acceleration. However, the glacier has undergone significant calving events, and the current rifting that began in September 2025 highlights its vulnerability. This upcoming calving event underscores the timeliness of this review, as it will put Petermann Glacier’s terminus at its most retreated position since records began in 1923. The anticipated retreat of the ice tongue also reduces buttressing and brings the terminus closer to the grounding zone, and modeling studies suggest that calving within 12 km of the grounding zone could potentially trigger dynamic retreat, accelerating ice discharge, and a doubling of flow speeds. We conclude that improved observations, sustained monitoring of oceanographic and atmospheric properties, and high-resolution modeling are critical to constraining projections of Petermann Glacier’s future and its role in the stability of the Greenland Ice Sheet.

Dominik Fahrner

List of Commercial and Advanced Developmental Niobium-Based Alloys of the Space Age

This report compiles a list of commercial and developmental niobium-based alloys developed during the Space Age (late 1950s through mid-1970s) for extreme-temperature applications, including rocket engine thrust chambers, hypersonic re-entry thermal protection systems, and space fission reactor loops. Niobium (Nb) was widely pursued because it provided the lowest density (~8.6 g/cc) among the primary refractory metals, a high melting temperature (~2470°C), exceptional low-temperature ductility, good formability, and compatibility with liquid alkali metals. An evaluation of physical metallurgy mechanisms, focusing on solid-solution strengthening via heavy refractory solutes (W, Mo, Ta), dual-purpose reactive solutes (Hf, Zr, Ti), and dispersion strengthening using carbides, nitrides, and oxides is presented. Additionally, the report compares Western and Soviet Union metallurgical approaches, explaining how supply chain factors and manufacturing infrastructure influenced element selection, interstitial chemistry, and alloy identification/naming conventions. Cataloging these historical alloy chemical compositions serves as a foundational reference for modern alloy additive manufacturing, thermodynamic CALPHAD modeling, and machine-learning discovery pipelines for next-generation extreme-environment niobium-based alloys.

Physical Metallurgy

The Chemical Composition of the Cores of the Terrestrial Planets and the Moon

Using models of the quasi-chemical theory of solutions, the activity coefficients of silicon are calculated in the melts Fe-Si, Ni-Si, and Fe-Ni-Si. The calculated free energies of solution of liquid nickel and silicon in liquid iron in the interval 0 to 1400 kbar and 1500 to 4000 K, shows that Fe-Ni-Si alloy is stable under the conditions of the outer core of the Earth and the cores of the terrestrial planets. The oxidation-reduction conditions are studied, and the fugacity of oxygen in the mantles of the planets and at the core-mantle boundary are calculated. The mechanism of reduction of silicon is analyzed over a broad interval of P and T. The interaction between the matter of the core and mantle is studied, resulting in the extraction of silicon from the mantle and its solution in the material of the core. It is concluded that silicon can enter into the composition of the outer core of the Earth and Venus, but probably does not enter into the composition of the cores of Mercury, Mars, and the Moon, if in fact the latter possesses one.

O L Kuskov