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Procedures and compositions for producing metallic glasses in bulk at slow cooling rates were investigated. An attempt was made to form the amorphous phase of the tetrahedrally coordinated elements (Si or Ge) by undercooling the melt. The crystal nucleation behavior of pure liquids and glass formers were examined.
Vitreloy, a metallic vitreous glass, was examined as a potential target material for the Genesis Mission solar wind collector. Stepped pyrolysis revealed that He and Ne implanted in Vitreloy were efficiently re-trapped during phase transitions.
Recent experiments indicate that a phase separation in a spherical sample of the metallic glass Au55Pb22.5Sb22.5 occurs near the surface of the sphere. This strongly suggests either a contribution of surface-free energy to the decomposition process or a possible influence of near surface impurities absorbed during synthesis of the sphere. The surface phase separation has been studied as a function of cooling rate of the sphere. At high cooling rates (small sphere sizes), the surface separation disappears altogether suggesting that the surface of the parent liquid droplet is initially homogeneous.
Sliding friction and wear experiments, electron microscopy, and diffraction studies were conducted with an Fe67Co18B14Si1 ferrous-base metallic glass in sliding contact with aluminum oxide at room temperature in air. The results indicate that the amorphous alloy can be crystallized during the sliding process. Crystallization of the wear surface causes high friction. Plastic flow occurred on the amorphous alloy with sliding, and the flow film of the alloy transferred to the aluminum oxide surface. Two distinct types of wear debris were observed as a result of sliding: an alloy wear debris, and powdery and whiskery oxide debris. Generation of oxide wear debris particles on an alloy can cause transitions in friction behavior.
Sliding friction experiments, X-ray photoelectron spectroscopy (XPS) analysis, and electron microscopy and diffraction studies were conducted with ferrous base metallic glasses (amorphous alloys) in contact with aluminum oxide at temperatures to 750 C in a vacuum. Sliding friction experiments were also conducted in argon and air atmospheres. The results of the investigation indicate that the coefficient of friction increases with increasing temperature to 350 C in vacuum. The increase in friction is due to an increase in adhesion resulting from surface segregation of boric oxide and/or silicon oxide to the surface of the foil. Above 500 C the coefficient of friction decreased rapidly. The decrease correlates with the segregation of boron nitride to the surface. Contaminants can come from the bulk of the material to the surface upon heating and impart boric oxide and/or silicon oxide at 350 C and boron nitride above 500 C. The segregation of contaminants is responsible for the friction behavior. The amorphous alloys have superior wear resistance to crystalline 304 stainless steel. The relative concentrations of the various constituents at the surfaces of the amorphous alloys are very different from the nominal bulk compositions.
Sliding friction experiments, X-ray photoelectron spectroscopy (XPS) analysis, and electron microscopy and diffraction studies were conducted with ferrous base metallic glasses (amorphous alloys) in contact with aluminium oxide at temperatures to 750 C in a vacuum. Sliding friction experiments were also conducted in argon and air atmospheres. The results of the investigation indicate that the coefficient of friction increases with increasing temperature to 350 C in vacuum. The increase in friction is due to an increase in adhesion resulting from surface segregation of boric oxide and/or silicon oxide to the surface of the foil. Above 500 C the coefficient of friction decreased rapidly. The decrease correlates with the segregation of boron nitride to the surface. Contaminants can come from the bulk of the material to the surface upon heating and impart boric oxide and/or silicon oxide at 350 C and boron nitride above 500 C. The segregation of contaminants is responsible for the friction behavior. The amorphous alloys have superior wear resistance to crystalline 304 stainless steel. The relative concentrations of the various constituents at the surfaces of the amorphous alloys are very different from the nominal bulk compositions.
Harmonic drives are a highly efficient and compact gearing technology that are widely used in robotics and aerospace applications (e.g. Mars Science Lab) due to their excellent torque-to-mass ratio, low backlash, and high positional accuracy. One major problem using any gearing on other planetary bodies is the need for heaters to keep the gearbox from freezing. Currently the Mars Science Lab uses 40% of its daily power output to operate heaters to keep the grease in the gearboxes from freezing. Also wear can limit the lifetime and performance of these systems. One possible solution to this problem could be to use a relatively new material known as Bulk Metallic Glasses (BMGs, also known as Amorphous Metals). BMGs are non-crystalline metallic alloys that exhibit superior mechanical properties. Compared to modern aerospace steels BMGs have a higher strength, higher elastic limit, and lower density. BMGs used in harmonic drives (especially the flex spline) could lead to longer system lifetimes, lower mass, and increased performance. Jet Propulsion Laboratory (JPL) is researching a new method of manufacturing the flex spline by injection molding and is hoping to have reduced costs as well as the benefits listed above. In conjunction with Kennedy Space Center (KSC), JPL is providing gearboxes that KSC will test greaseless in an extreme environment. KSC has completed the assembly and checkout of a test stand that is capable of testing a gearbox in a vacuum of less than 2 milli torr, 100 Kelvin temperature, 250 Nm of load, input and output torque measurements and 120 RPM input speed.
The Genesis mission collected solar wind atoms for 28 months with a variety of collectors mounted on a spacecraft. A total of fifteen pure materials were selected as collectors based on engineering and science requirements. One of the materials was the bulk metallic glass (BMG). It was intended for collecting noble gases and solar energetic particles (SEP). This material is an amorphous metal which was custom made by C.C. Hays at the California Institute of Technology. The final glass composition is Zr58.5Nb2.8Cu15.6Ni12.8Al10.3 (in atom percent). The BMG was located on top of the wafer array mechanism and was exposed for the entire time the science canister was open (~28 months). Fortunately, the BMG did not suffer any serious damage and was intact after the Genesis canister’s “hard-landing” into the Utah desert (Fig. 1).
Zr58.5Nb2.8Cul5.6Nil2.8All0.3 is the first bulk glass forming liquid that does not contain beryllium to be vitrified by purely radiative cooling in the containerless electrostatic levitation process. The measured critical cooling rate is 1.75 K/s. The sluggish crystallization kinetics enable the determination of the time-temperature-transformation (TTT) diagram between the liquidus and the glass transition temperatures. At the nose of the TTT diagram, the shortest time to reach crystallization in an isothermal experiment is 32 seconds. In contrast to other bulk metallic glasses the scatter in the crystallization onset times are small at both high and low temperatures.
Acoustic fields support and cool liquid particles. Levitated by sound energy, liquid drop in acoustic standing-wave field surrounded by acousticically-induced jet streams. Streaming gas cools drow below its freezing point in small fraction of second. Allows new amorphous alloys including "metallic glass" to be formed.
Uniform hollow spheres of gold/lead/antimony glass formed by blowing bubbles of molten metal into helium-filled drop tube. Useful in fusion target applications.
Friction and wear tests were conducted with 3.2- and 6.4-millimeter-diameter aluminum oxide spheres sliding, in reciprocating motion, on a Fe67Co18B14Si1 metallic foil. Crystallites with a size range of 10 to 150 nanometers were produced on the wear surface of the amorphous alloy. A strong interaction between transition metals and metalloids such as silicon and boron results in strong segregation during repeated sliding, provides preferential transition metal-metalloid clustering in the amorphous alloy, and subsequently produces the diffused honeycomb structure formed by dark grey bands and primary crystals, that is, alpha-Fe in the matrix. Large plastic flow occurs on an amorphous alloy surface with sliding and the flow film of the alloy transfers to the aluminum oxide pin surface. Multiple slip bands due to shear deformation are observed on the side of the wear track. Two distinct types of wear debris were observed as a result of sliding: an alloy wear debris, and/or powdery-whiskery oxide debris.
Friction and wear tests were conducted with 3.2- and 6.4-millimeter-diameter aluminum oxide spheres sliding, in reciprocating motion, on a Fe67Co18B14Si1 metallic foil. Crystallites with a size range of 10 to 150 nanometers were produced on the wear surface of the amorphous alloy. A strong interaction between transition metals and metalloids such as silicon and boron results in strong segregation during repeated sliding, provides preferential transition metal-metalloid clustering in the amorphous alloy, and subsequently produces the diffused honeycomb structure formed by dark grey bands and primary crystals, that is, alpha-Fe in the matrix. Large plastic flow occurs on an amorphous alloy surface with sliding and the flow film of the alloy transfers to the aluminum oxide pin surface. Multiple slip bands due to shear deformation are observed on the side of the wear track. Two distinct types of wear debris were observed as a result of sliding: an alloy wear debris, and/or powdery-whiskery oxide debris.
Friction and wear tests were conducted with 3.2- and 6.4-millimeter-diameter aluminum oxide spheres sliding, in reciprocating motion, on a Fe67Co18B14Si1 metallic foil. Crystallites with a size range of 10 to 150 nanometers were produced on the wear surface of the amorphous alloy. A strong interaction between transition metals and metalloids such as silicon and boron results in strong segregation during repeated sliding, provides preferential transition metal-metalloid clustering in the amorphous alloy, and subsequently produces the diffused honeycomb structure formed by dark grey bands and primary crystals, that is, alpha-Fe in the matrix. Large plastic flow occurs on an amorphous alloy surface with sliding and the flow film of the alloy transfers to the aluminum oxide pin surface. Multiple slip bands due to shear deformation are observed on the side of the wear track. Two distinct types of wear debris were observed as a result of sliding: an alloy wear debris, and/or powdery-whiskery oxide debris.
A description is given of the design and fabrication of candidate flame-resistant woven and knitted fabrics, tapes, webbings, and cords as replacements for those items used in the Apollo spacecraft which were previously made of nylon and polyester. Structures made from Chromel R metal fibers (74% Ni, 20% Cr, 2-1/2% Fe, 2-1/2% Al, 1/2% Si, 1/2% Mo), Beta glass fibers and high-temperature organic fibers such as PBI (polybenzimidazole) were developed and evaluated. The feasibility of improving the performance of selected fabrics by using CNR (carboxy nitroso rubber) or other nonflammable coatings were also investigated.
Plasma spray of Nichrome matrix composite contains dispersed glass for oxidation protection and calcium fluoride for lubrication. Coatings can be applied to bearing journals and bearing bores. Coating was easily machinable and had excellent bond strength on substrate metal.
The first successful formation of submillimeter and millimeter spherical shells of tin and of a gold-lead-antimony alloy by means of the hollow-jet instability technique developed by Kendall is reported. Examination of tin specimens by SEM reveals that surface quality varies from poor to excellent. Whereas the metal is employed only as a convenient and inexpensive material, the gold alloy is important in that it is hard, has a high atomic number, and may be solidified into the amorphous state through the provision of a modest cooling rate. AuPbSb spherules up to 1.5 mm in diameter are produced using LN2 or chilled methanol as a coolant. It is found that these amorphous samples possess a superb surface smoothness compatible with fusion target requirements. It is noted that hollow spheres currently made of this alloy have an average outside diameter of 2000 microns.
Mechanisms are used widely in engineering applications due to their ability to translate force and movement. They are found in kinematic pairs, gears, cams, linkages, and in flexure mechanisms (also known as compliant mechanisms). Mechanisms and flexures are used widely in spacecraft design, especially in the area of optics, where precise positioning of telescope mirrors requires elastic flexing of elements. A compliant mechanism is generally defined as a flexible mechanism that uses an elastic body deformation to cause a displacement (such as positing a mirror). The mechanisms are usually constructed as a single monolithic piece of material, and contain thin struts to allow for large elastic bending with low input force. This creates the largest problem with developing precise mechanisms; they must be fabricated from a single piece of metal, but are required to have strict accuracy on their dimensions. They are generally required to have high strength, elasticity, and low coefficient of thermal expansion.