Search NASA⌕ Search

SEARCH · Search NASA

Results for “Microwave reactions”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

UARS in-flight jitter study for EOS

Response data collected from gyroscopes on board the Upper Atmosphere Research Satellite (UARS) provided a unique opportunity to analyze actual flight pointing jitter data. Flight modal frequencies and damping values are derived from the measured data using an Eigensystem Realization Algorithm (ERA). Flight frequencies at various solar array positions are compared to analytical predictions obtained with a Finite Element Model. The solar array modal frequencies change with position due to the modes acting about different spacecraft inertial axes. Higher order modes were difficult to identify due to the limited instrumentation. Future flight jitter studies on other spacecraft would be significantly aided by additional instrumentation. Spacecraft jitter due to continuous disturbance sources such as the 1.6 meter scanning microwave antenna, the solar array drive, and reaction wheels is presented. The solar array drive disturbance dominates the spacecraft response during normal operation.

Molnar, John↗
NASA NTRS2001

Control For NO(x) Emissions From Combustion Sources

The Environmental Program Office at the Kennedy Space Center is interested in finding solutions and to promote R&D that could contribute to solve the problems of air, soil and groundwater contamination. This study is undertaken as part of NASA's environmental stewardship program. The objective of this study involves the removal of nitrogen oxides from the flue gases of the boilers at KSC using hydrogen peroxide. Phases 1 and 2 of this study have shown the potential of this process to be used as an alternative to the current methods of treatment used in the power industry. This report summarizes the research done during the 10-week summer program. During this period, support has been given to implement the modifications suggested for Phase 3 of the project, which focus on oxidation reactions carried at lower temperatures using a microwave source. The redesign of the flue gas inlet and optimization for the scrubbing system was the main objective of this research.

PozodeFernandez, Marie E.↗
NASA NTRS1995

Microwave Induced Combustion Synthesis of Ceramic and Ceramic-Metal Composites

In recent years, there has been a renewed interest in combustion synthesis reactions, commonly called self-propagating high-temperature synthesis. These reactions are an attractive, energy efficient approach to the synthesis of high temperature composite materials and metastable phases. Microwaves are used to induce self-propagating high temperature synthesis of ceramic and ceramic-metal composites.

high-temperature ceramics high-temperature synthes↗
NASA NTRS1983

Photochemistry of acetylene at 1849 A

It is pointed out that the photochemistry of acetylene in the 1500-2000 A region at low pressure, particularly the quantum yield of C2H production and the reactions of C2H with H2 and hydrocarbons, is important in understanding the photochemistry of Jovian and Titan atmospheres. The present investigation was initiated to obtain information on these issues. The 1849 A light source used in the study was a sealed quartz tube containing a drop of Hg and 2 torr of Ar excited by a microwave generator. The lamp was attached to a Pyrex reaction cell. The amount of diacetylene produced was measured on the basis of absorption near 1650 A. Reaction mixtures of acetylene with N2, He, C2H6, or C3H8 were prepared. Attention is given to the absorption cross section, the photolysis of acetylene, and the photolysis of acetylene in the presence of other gases. It is found that the photochemical process of acetylene at 1849 A may represent that of acetylene in the Titan atmosphere.

Okabe, H.↗
NASA NTRS1986

The microwave and far-infrared spectra of the O-(18)H radical

Far-infrared laser magnetic resonance (LMR) spectroscopy was used to calculate the frequencies, wavelengths, and line strengths for transitions of O-(18)H molecules at microwave and far-infrared frequencies. In this experiment, a molecular transition frequency is tuned into coincidence with that of a fixed frequency laser by the application of a variable magnetic field. The O-(18)H radicals, detected in natural abundance (0.20 percent), were produced by the reaction of hydrogen atoms with nitrogen dioxide. These data together with microwave frequencies ascertained by Gottlieb, Redford, and Smith (1974) were used to determine the parameters of an effective Hamiltonian. Rotational levels up to J = 5.5 were involved. Results are indicated schematically and the low-lying energy levels of O-(18)H are shown. It is concluded that the frequencies of transitions between levels studied directly in the LMR experiment are reliable.

Comben, E. R.↗
NASA NTRS2000

Modeling of Solid Waste Processing Options in BIO-Plex

BIO-Plex is a ground-based test bed currently under development by NASA for testing technologies and practices that may be utilized in future long-term life support missions. All aspects of such an Advanced Life Support (ALS) System must be considered to confidently construct a reliable system, which will not only allow the crew to survive in harsh environments, but allow the crew time to perform meaningful research. Effective handling of solid wastes is a critical aspect of the system, especially when recovery of resources contained in the waste is required. This is particularly important for ALS Systems configurations that include a Biomass Production Chamber. In these cases, significant amounts of inedible biomass waste may be produced, which can ultimately serve as a repository of necessary resources for sustaining life, notably carbon, water, and plant nutrients. Numerous biological and physicochemical solid waste processing options have been considered. Biological options include composting, aerobic digestion, and anaerobic digestion. Physicochemical options include pyrolysis, SCWO (supercritical water oxidation), various incineration configurations, microwave incineration, magnetically assisted gasification, and low temperature plasma reaction. Modeling of these options is a necessary step to assist in the design process. A previously developed top-level model of BIO-Plex implemented in MATLAB Simulink (r) for the use of systems analysis and design has been adopted for this analysis. Presently, this model only considered incineration for solid waste processing. Present work, reported here, includes the expansion of this model to include a wider array of solid waste processing options selected from the above options, bearing in mind potential, near term solid waste treatment systems. Furthermore, a trade study has also been performed among these solid waste processing technologies in an effort to determine the ideal technology for long-term life support missions.

Rodriguez, Luis F.↗
NASA NTRS1990

Containerless synthesis of ceramic materials using microwave heating

It was demonstrated that microwave heating technique may be employed for the synthesis of a number of multicomponent ceramic oxide-based materials, e.g., YBa2Cu3O7 and CuFe2O4. A characteristic, and potentially extremely useful, feature of such synthesis is that they occur in significantly less time than that required using conventional furnace-based techniques. However, the information obtained to date is necessarily rather empirical, and systematic investigations of the use of microwave heating for the synthesis of ceramic materials are required. The synthesis of ceramic materials at high temperatures are often affected by unwanted, deleterious reactions of the reactants and/or products with the reaction container. Consequently, it is of interest to investigate the high temperature synthesis of ceramic materials using microwave heating in a containerless environment.

Dunn, B.↗
NASA NTRS1978

Experimental Studies of the Formation/Deposition of Sodium Sulfate in/from Combustion Gases

Processes related to the hot corrosion of gas turbine components were examined in two separate investigations. Monochromatic laser light was used to probe condensation onset and condensate film growth (via interference of reflected light) on electrically heated ribbons immersed in seeded, flat flame combustion product gases. Boron trichloride is used as the seed gas in these preliminary experiments conducted to obtain precise measurements of the dew point/deposition rates. Because of the importance of gaseous Na(g) as a precursor to NaSO4 formation, the kinetics and mechanisms of the heterogeneous reaction H(g) + NaCl(s) yields Na(g) + HCl(g) was studied using atomic absorption spectroscopy combined with microwave discharge-vacuum flow reactor techniques at moderate temperatures. Preliminary results indicate the H-atom attack of solid NaCl vaporization is negligible; hence the corresponding gas phase (homogeneous) reaction no role in the observed Na(g) production.

Rosner, D. E.↗
NASA NTRS2005

A Kinetic and Product Study of the Cl + HO2 Reaction

Absolute rate data and product branching ratios for the reactions Cl + HO2 to HCl + O2 (k1a) and Cl + HO2 to OH + ClO (k1b) have been measured from 226 to 336 K at a total pressure of 1 Torr of helium using the discharge flow resonance fluorescence technique coupled with infrared diode laser spectroscopy. For kinetic measurements, pseudo-first-order conditions were used with both reagents in excess in separate experiments. HO2 was produced by two methods: through the termolecular reaction of H atoms with O2 and also by the reaction of F atoms with H2O2. Cl atoms were produced by a microwave discharge of Cl2 in He. HO2 radicals were converted to OH radicals prior to detection by resonance fluorescence at 308 nm. Cl atoms were detected directly at 138 nm also by resonance fluorescence. Measurement of the consumption of HO2 in excess Cl yielded k1a and measurement of the consumption of Cl in excess HO2 yielded the total rate coefficient, k1. Values of k1a and k1 derived from kinetic experiments expressed in Arrhenius form are (1.6 +/- 0.2) x 10-11 exp[(249 +/- 34)/T] and (2.8 +/- 0.1) x 10-11 exp[(123 +/- 15)/T] cm3 molecule-1 s-1, respectively. As the expression for k1 is only weakly temperature dependent, we report a temperature-independent value of k1 = (4.5 +/- 0.4) x 10-11 cm3 molecule-1 s-1. Additionally, an Arrhenius expression for k1b can also be derived: k1b = (7.7 +/- 0.8) x 10-11 exp[-(708 +/- 29)/T] cm3 molecule-1 s-1. These expressions for k1a and k1b are valid for 226 K T 336 and 256 K T 296 K, respectively. The cited errors are at the level of a single standard deviation. For the product measurements, an excess of Cl was added to known concentrations of HO2 and the reaction was allowed to reach completion. HCl product concentrations were determined by IR absorption yielding the ratio k1a/k1 over the temperature range 236 K T 296 K. OH product concentrations were determined by resonance fluorescence giving rise to the ratio k1b/k1 over the temperature range 226 K T 336 K. Both of these ratios were subsequently converted to absolute numbers. Values of k1a and k1b from the product experiments expressed in Arrhenius form are (1.5 +/- 0.1) x 10-11 exp[(222 +/- 17)/T] and (10.6 +/- 1.5) x 10-11 exp[-(733 +/- 41)/T] cm3 molecule-1 s-1, respectively. These expressions for k1a and k1b are valid for 256 K T 296 and 226 K T 336 K, respectively. A combination of the kinetic and product data results in the following Arrhenius expressions for k1a and k1b of (1.4 +/- 0.3) x 10-11 exp[(269 +/- 58)/T] and (12.7 +/- 4.1) x 10-11 exp[-(801 +/- 94)/T] cm3 molecule-1 s-1, respectively. Numerical simulations were used to check for interferences from secondary chemistry in both the kinetic and product experiments and also to quantify the losses incurred during the conversion process HO2 to OH for detection purposes.

rate constants↗
NASA NTRS2000

Kinetics of the Cl(2)P(J)) + CH4 Reaction: Effects of Secondary Chemistry Below 300 K

Absolute rate data for the Cl(2)P(J) + CH4 yields HCl + CH3 reaction have been obtained from 218 to 298 K by using the discharge-flow resonance fluorescence technique at I Torr total pressure. The result at 298 K is (10.1 +/- 0.6) x 10(exp -14) cu cm/molecule/s. The temperature dependence in Arrhenius form is (6.5 +/- 0.9 ) x 10(exp -12) exp[(-1235 +/- 34 )/T]. The errors given are one standard deviation; overall experimental error is estimated at +/- 15%. Because of the relatively large disagreement among earlier measurements at low temperatures, the results were examined for possible effects of non-Boltzmann spin distribution and vibrational excitation of CH4, secondary chemistry of CH3 radicals, and impurities in the CH4 source. There was no significant change in the observed rate constant when an efficient spin quencher, CF4, was added and estimates indicate that vibrational partitioning in CH4 should be at the ambient reactor temperature before the start of the reaction. The results were also independent of the source of Cl atoms (microwave discharge or thermal decomposition of Cl2) and whether CH4 was purified in-situ. However, the observed rate constant did depend on initial Cl atom concentrations and to a lesser extent on CH4 concentrations. Numerical simulations were used to assess the importance of secondary chemistry over a range of reactant concentrations

Wang, J. J.↗
NASA NTRS2001

Studies of Elementary Reactions of Chemical Importance in the Atmospheres of Planets

The methyl self-reaction was studied at T = 298 K and 202 K and at three different pressures, P = 0.5, 1.0, and 2.1 Torr. The experimental measurements were performed in our discharge flow-mass spectrometer (DF-MS) apparatus. The methyl radicals were generated by the reaction of F with methane. Passing a mixture of molecular fluorine, F2, in helium through a microwave cavity generated the atomic fluorine reagent. The atomic F enters the flow tube through a rear port on the flow tube. The methane reagent enters the flow tube through a movable injector located coaxial in the flow tube. The decay of methyl radical signal was monitored at a mass/charge ratio (m/z) of 15 as a function of the injector distance. To minimize secondary chemistry from the reaction CH3 + F to CH2 + HF the initial [CH4](sub 0)/[F](sub 0) was above 37.0 and typically 100. This ensures a 1:1 relationship between initial [F] and [CH3]. A titration of F with excess Cl2 yields the initial [F](sub 0). Our experimental methodology to accurately measure the mass spectrometer scaling factor, i.e., the relationship between initial signal and [CH3](sub 0) has been improved. Now we measure the CH3 signal decay under exponential decay conditions at low initial [F](sub 0), 3x10(exp 11) molecule/cc, in the presence of Cl2. This minimizes the second-order decay contributed by the CH3 self-reaction and a simple extrapolation of the 1n(signal) vs time plot to t = 0 gives the initial signal. This provides the desired relationship between initial signal at 15 amu and [CH3](sub 0). The resulting calibration is then applied to the observed decay of the CH3 signal at high concentrations of CH3 assuming linearity of this scaling factor.

Nesbitt, Fred L.↗
NASA NTRS1980

A laboratory study on the dissociative recombination of vibrationally excited O2/+/ions

The dissociative recombination of vibrationally excited O2(+) ions is studied in light of the possible importance of this reaction in upper atmospheric chemistry. A plasma spectroscopy experiment was performed in a microwave cavity filled by an argon-oxygen mixture, with O(1S) production monitored by measurements of the 5577-A afterglow, the O2(+) density and the electron concentration. Plasma and optical data reveal the predominant afterglow ions to be Ar2(+) and O2(+), with an effective O(1S) dissociative recombination coefficient of 2.1 x 10 to the -8th cu cm/sec, corresponding to a quantum yield of 10%. Experiments with an argon-krypton-oxygen mixture reveal that vibrationally excited O2(+) ions are the chief source of the O(1S) atoms, with a specific recombination coefficient for the dissociation of O2(+)(2 pi g) into O(1S) and O(1D) of 4.2 x 10 to the -9th cu cm/sec. A comparison of the laboratory results with Atmospheric Explorer data on the 5577-A airglow implies that O2(+) ions in the sunlit ionosphere are vibrationally excited to the same degree as in the laboratory, with the vibrational relaxation of these ions much slower than dissociative recombination. Results also predict a dawn-twilight asymmetry in the effective O(1S) yield due to the normal variation of electron content.

Zipf, E. C.↗
NASA NTRS1987

The study of excited oxygen molecule gas species production and quenching on thermal protection system materials

The detection of excited oxygen and ozone molecules formed by surface catalyzed oxygen atom recombination and reaction was investigated by laser induced fluorescence (LIF), molecular beam mass spectrometric (MBMS), and field ionization (FI) techniques. The experiment used partially dissociated oxygen flows from a microwave discharge at pressures in the range from 60 to 400 Pa or from an inductively coupled RF discharge at atmospheric pressure. The catalyst materials investigated were nickel and the reaction cured glass coating used for Space Shuttle reusable surface insulation tiles. Nonradiative loss processes for the laser excited states makes LIF detection of O2 difficult such that formation of excited oxygen molecules could not be detected in the flow from the microwave discharge or in the gaseous products of atom loss on nickel. MBMS experiments showed that ozone was a product of heterogeneous O atom loss on nickel and tile surfaces at low temperatures and that ozone is lost on these materials at elevated temperatures. FI was separately investigated as a method by which excited oxygen molecules may be conveniently detected. Partial O2 dissociation decreases the current produced by FI of the gas.

Nordine, Paul C.↗
NASA NTRS1989

Laser/Plasma/Chemical-Vapor Deposition Of Diamond

Proposed process for deposition of diamond films includes combination of plasma induced in hydrocarbon feed gas by microwave radiation and irradiation of plasma and substrate by lasers. Deposition of graphite suppressed. Reaction chamber irradiated at wavelength favoring polymerization of CH2 radical into powders filtered out of gas. CH3 radicals, having desired sp3 configuration, remains in gas to serve as precursors for deposition. Feed gas selected to favor formation of CH3 radicals; candidates include CH4, C2H4, C2H2, and C2H6. Plasma produced by applying sufficient power at frequency of 2.45 GHz and adjusting density of gas to obtain electron kinetic energies around 100 eV in low-pressure, low-temperature regime.

Hsu, George C.↗
NASA NTRS1995

Instruments Sniff Organic Surface Contaminants

Portable instruments detecting both nonvolatile and volatile organic surface contaminants in real time developed. Instruments easy to use: operate under ordinary ambient atmospheric conditions, without need to use messy liquid solvents or install and remove witness plates, and without need to cut specimens from surfaces to be inspected. Principle of detection involves sweeping pure, activated gas across surface spot inspected, then monitoring light emitted at wavelengths characteristic of excited molecules formed by chemical reactions between activated gas and contaminants. Gas activated by dc discharge, radio-frequency induction, microwave radiation, laser beam, hot filaments, or any other suitable means that excites some of gas molecules.

Adler-Golden, Steven↗
NASA NTRS1997

Summary of Research/Publications

Summary of research/publications include:(1) Comment on broadening of water microwave lines by collisions with helium atoms; (2) Calculations of ion-molecule deuterium fractionation reactions involving HD; (3) Ab initio predictions on the rotational spectra of carbon-chain carbene molecules; (4) Theoretical IR spectra of ionized naphthalene; (5) Improved collisional excitation rates for interstellar water; (6) Calculations on the competition between association and reaction for C3H+ + H2; (7) Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons: effect of ionization; (8) Calculations concerning interstellar isomeric abundance ratios for C3H and C3H2; (9) New calculations on the ion-molecule processes C2H2+ + H2 C2H3+ + H and C2H2+ + H2 C2H4+; (10) Anisotropic rigid rotor potential energy function for H2O-H2; (11) A correlated ab initio study of linear carbon-chain radicals CnH (n=2-7); (12) Ab initio characterization of MgCCH, MgCCH+, and MgC2 and pathways to their formation in the interstellar medium; (13) Why HOC+ is detectable in interstellar clouds: The rate of the reaction between HOC+ and H2; (14) A correlated ab initio study of the X 2A 1 and A 2E states of MgCH3; (15) On the stability of interstellar carbon clusters: The rate of the reaction between C3 and O; and (16) The rate of the reaction between CN and C2H2 at interstellar temperatures.

Source record↗
NASA NTRS2013

NASA Tech Briefs, July 2013

Dielectrophoresis-Based Particle Sensor Using Nanoelectrode Arrays; Multi-Dimensional Damage Detection for Surfaces and Structures; ULTRA: Underwater Localization for Transit and Reconnaissance Autonomy; Autonomous Cryogenic Leak Detector for Improving Launch Site Operations; Submillimeter Planetary Atmospheric Chemistry Exploration Sounder; Method for Reduction of Silver Biocide Plating on Metal Surfaces; Silicon Micromachined Microlens Array for THz Antennas; Forward-Looking IED Detector Ground Penetrating Radar; Fully Printed, Flexible, Phased Array Antenna for Lunar Surface Communication, Battery Charge Equalizer with Transformer Array; An Efficient, Highly Flexible Multi-Channel Digital Downconverter Architecture; Dimmable Electronic Ballast for a Gas Discharge Lamp; Conductive Carbon Nanotube Inks for Use with Desktop Inkjet Printing Technology; Enhanced Schapery Theory Software Development for Modeling Failure of Fiber-Reinforced Laminates; High-Performance, Low-Temperature-Operating, Long-Lifetime Aerospace Lubricants; Carbon Nanotube Microarrays Grown on Nanoflake Substrates; Differential Muon Tomography to Continuously Monitor Changes in the Composition of Subsurface Fluids; Microgravity Drill and Anchor System; 20 Granular Media-Based Tunable Passive Vibration Suppressor; 21 Miga Aero Actuator and 2D Machined Mechanical Binary Latch; Micro-XRF for In Situ Geological Exploration of Other Planets; Hydrogen-Enhanced Lunar Oxygen Extraction and Storage Using Only Solar Power; Uplift of Ionospheric Oxygen Ions During Extreme Magnetic Storms; Miniaturized, High-Speed, Modulated X-Ray Source; Hollow-Fiber Spacesuit Water Membrane Evaporator 25 High-Power Single-Mode 2.65-micrometers InGaAsSb/AlInGaAsSb Diode Lasers; Optical Device for Converting a Laser Beam Into Two Co-aligned but Oppositely Directed Beams; A Hybrid Fiber/Solid-State Regenerative Amplifier with Tunable Pulse Widths for Satellite Laser Ranging; X-Ray Diffractive Optics; SynGenics Optimization System (SynOptSys); 29 CFD Script for Rapid TPS Damage Assessment; radEq Add-On Module for CFD Solver Loci-CHEM; Science Opportunity Analyzer (SOA) Version 8; 30 Autonomous Byte Stream Randomizer; Distributed Engine Control Empirical/Analytical Verification Tools; Dynamic Server-Based KML Code Generator Method for Level-of-Detail Traversal of Geospatial Data; Automated Planning of Science Products Based on Nadir Overflights and Alerts for Onboard and Ground Processing; Linked Autonomous Interplanetary Satellite Orbit Navigation; Risk-Constrained Dynamic Programming for Optimal Mars Entry, Descent, and Landing; Scheduling Operations for Massive Heterogeneous Clusters; Deepak Condenser Model (DeCoM); Flight Software Math Library; Recirculating 1-K-Pot for Pulse-Tube Cryostats; 35 Method for Processing Lunar Regolith Using Microwaves; Wells for In Situ Extraction of Volatiles from Regolith (WIEVR); and Estimating the Backup Reaction Wheel Orientation Using Reaction Wheel Spin Rates Flight Telemetry from a Spacecraft.

Source record↗