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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1961

Spontaneous Cracking in Unfired Magnesia Compacts Upon Standing in Air

Analytical-grade magnesium oxide powder without binder was compressed hydrostatically to 50,000 lb. per sq. in. to form compacts. When exposed to moist air immediately after pressing, these compacts developed irregularly shaped cracks. Controlled tests, in which these compacts were exposed for various lengths of time to various atmospheres, indicated that in general water vapor, carbon dioxide, and residual stresses had to be present if cracking was to occur. The probable cause of the cracking was the formation of a less dense and mechanically weak basic carbonate of magnesium at crystallite surface points of high stress concentration which developed during the compacting. The adsorption of dry CO2 at such sites prevented subsequent delayed fracture.

Davies, Myron O.↗
NASA NTRS1975

Boundary lubrication of formulated C-ethers in air to 300 C

Six C-ether formulations (containing organic acid and phosphorus ester additives) were tested in dry (less than 100 ppm H2O) and moist air (relative humidity 50 percent at 25 C) and temperatures from 25 to 300 C, in order to determine the boundary lubricating characteristics and to compare these results to those obtained with a fully formulated Type II ester and the unformulated C-ether base fluid. The apparatus, procedures and detailed results of the test are described. Friction and wear measurements were made on CVM M-50 steel under 1 kg load and 17 meter per minute (100 rpm) surface speed conditions, for a duration of 25 minutes. In general, the C-ether formulations exhibited higher friction coefficients than the ester from 150 to 300 C and similar or lower values from 25 to 150 C, furthermore, in most test conditions the C-ether base fluid and the six C-ether formulations yielded lower wear than the ester. Possible applications in the aerospace industry are mentioned.

Jones, W. R., Jr.↗
NASA NTRS1973

Boundary lubrication of formulated C-ethers in air to 300 C. 2: Organic acid additives

Friction and wear measurements were made on CVM M-50 steel lubricated with three C-ether (modified polyphenyl ether) formulations in dry and moist air. Results were compared to those obtained with a formulated Type 2 ester and the C-ether base fluid. A ball-on-disk sliding friction apparatus was used. Experimental conditions were a 1-kilogram load, a 17-meter/minute surface speed, and a 25 to 300 C (77 to 572 F) disk temperature range. The three C-ether formulations yielded better boundary lubricating characteristics than the Type 2 ester under most test conditions. All C-ether formulations exhibited higher friction coefficients than the ester from 150 to 300 C (302 to 572 F) and similar or lower values from 25 to 150 C (77 to 302 F).

Jones, W. R., Jr.↗
NASA NTRS2002

Advection from the North Atlantic as the Forcing of Winter Greenhouse Effect Over Europe

In winter, large interannual fluctuations in the surface temperature are observed over central Europe. Comparing warm February 1990 with cold February 1996, a satellite-retrieved surface (skin) temperature difference of 9.8 K is observed for the region 50-60 degrees N; 5-35 degrees E. Previous studies show that advection from the North Atlantic constitutes the forcing to such fluctuations. The advection is quantified by Index I(sub na), the average of the ocean-surface wind speed over the eastern North Atlantic when the direction is from the southwest (when the wind is from another direction, it counts as a zero speed to the average). Average I(sub na) for February 1990 was 10.6 m/s, but for February 1996 I(sub na) was only 2.4 m/s. A large value of I(sub na) means a strong southwesterly flow which brings warm and moist air into central Europe at low level, producing a steeper tropospheric lapse rate. Strong ascending motions at 700 mb are observed in association with the occurrence of enhanced warm, moist advection from the ocean in February 1990 producing clouds and precipitation. Total precipitable water and cloud-cover fraction have larger values in February 1990 than in 1996. The difference in the greenhouse effect between these two scenarios, this reduction in heat loss to space, can be translated into a virtual radiative heating of 2.6 W/square m above the February 1990 surface/atmosphere system, which contributes to a warming of the surface on the order of 2.6 K. Accepting this estimate as quantitatively meaningful, we evaluate the direct effect, the rise in the surface temperature in Europe as a result of maritime-air inflow, as 7.2 K (9.8 K-2.6 K). Thus, fractional reinforcement by the greenhouse effect is 2.6/7.2, or 36%, a substantial positive feedback.

Otterman, J.↗
NASA NTRS2001

Three-dimensionally ordered array of air bubbles in a polymer film

We report the formation of a three-dimensionally ordered array of air bubbles of monodisperse pore size in a polymer film through a templating mechanism based on thermocapillary convection. Dilute solutions of a simple, coil-like polymer in a volatile solvent are cast on a glass slide in the presence of moist air flowing across the surface. Evaporative cooling and the generation of an ordered array of breath figures leads to the formation of multilayers of hexagonally packed water droplets that are preserved in the final, solid polymer film as spherical air bubbles. The dimensions of these bubbles can be controlled simply by changing the velocity of the airflow across the surface. When these three-dimensionally ordered macroporous materials have pore dimensions comparable to the wavelength of visible light, they are of interest as photonic band gaps and optical stop-bands.

Non-NASA Center↗
NASA NTRS1994

Two space scatterer formalism calculation of bulk parameters of thunderclouds

In a previous study, we used a modified two-space scatterer formalism of Twersky to establish for a cloud modeled as a statistically homogeneous distribution of spherical water droplets, the dispersion relations that determine its bulk propagation numbers and bulk indexes of refraction in terms of the vector equivalent scattering amplitude and the dyadic scattering amplitude of the single water droplet in isolation. The results were specialized to the forward direction of scattering while demanding that the scatterers preserve the incident polarization. We apply this approach to obtain specific numerical values for the macroscopic parameters of the cloud. We work with a cloud of density rho = 100 cm(exp -3), a wavelength lambda = 0.7774 microns, and with spherical water droplets of common radius alpha = 10 microns. In addition, the scattering medium is divided into three parts, the medium outside the cloud, moist air (the medium inside the cloud but outside the droplets), and the medium inside the spherical water droplets. The results of this report are applicable to a cloud of any geometry since the boundary does not interfere with the calculations. Also, it is important to notice the plane wave nature of the incidence wave in the moist atmosphere.

Phanord, Dieudonne D.↗
NASA NTRS2010

Environmental Stress Testing of the Single Sample Cylinder: A Proven Consensus Standard for Internal Gas Analysis (IGA) or Residual Gas Analysis (RGA)

In August 2008, Schuessler Consulting was contracted by NASA GSFC in support of the NASA Electronic Parts and Packaging (NEPP) program to perform two separate studies on moisture laden air in a stainless steel cylinder that had been designed to become a consensus standard for Test Method 1018. This Test Method was originally released for hybrids under Mil. Std. 883 but was quickly utilized on other microelectronic devices under the auspice of Mil. Std. 750. The cylinder had subsequently been fabricated for the 750 community. It was back-filled with moist air and subsequently analyzed over a period of time under a previous NASA contract. It had been shown that moisture in the 4000 - 5000 ppm range could be analyzed rather precisely with a mass spectrometer, commonly referred to as a Residual Gas Analyzer (RGA). The scope of this study was to ascertain if the composition and precision varied as a function of thermal shock at sub-zero temperatures and whether there was consensus when the standard was submitted to other RGA units. It was demonstrated and published that the consensus standard would yield precise RGA data for moisture within +/- 1% when optimized for a given RGA unit. It has been subsequently shown in this study at Oneida Research Services, that sub-zero storage did not affect that precision when a well-defined protocol for the analysis was followed. The consensus standard was taken to a second facility for analysis where it was found that moisture adsorption on the transfer lines caused precision to drop to +/- 12%. The Single Sample Cylinder (SSC) is a one liter stainless steel cylinder with associated sampling valves and has considerable weight and volume. But this considerable size allows for approximately 300 gas samples of the same composition to be delivered to any RGA unit. Lastly, a smaller cylinder, approximately 75 cc, of a second consensus standard was fabricated and tested with a different mix of fixed gases where moisture was kept in the 100 ppm range. This second standard has the potential of providing 30 gaseous samples and can be readily shipped to any analytical facility that desires to generate comparison RGA data. A series of comparison residual gas analyses was performed at the Honeywell Federal Manufacturing & Technologies facility in the National Nuclear Facility Administration s plant in Kansas City to complete this project. It was shown that improvements in the precision of a given RGA unit can be done by controlling the cycle time for each analysis and increasing analysis temperatures to minimize moisture adsorption. It was also found that a "one time event" in the subzero storage of the large SSC did not effect the units ability to continuously supply precise samples of the same chemistry, however the "event" caused a permanent +8% shift in the reported value of the moisture content. Lastly, a set of SSC RGA results was plotted on a common graph with DSCC "correlation study" RGA data. The result demonstrates the ability of the SSC to remove many of the individual variances that single, individual samples introduce. The consensus standards are now in storage at Oneida Research Services, one of the DSCC certified houses that does RGA to Military Standards, where they await future studies. The analytical data and the operational parameters of the instruments used are provided in the following discussion. Limitations and suggested means for improvement of both precision and accuracy are provided.

Schuessler, Philipp WH↗
NASA NTRS1936

Procedure for Determining Speed and Climbing Performance of Airships

The procedure for obtaining air-speed and rate-of-climb measurements in performance tests of airships is described. Two methods of obtaining speed measurements, one by means of instruments in the airship and the other by flight over a measured ground course, are explained. Instruments, their calibrations, necessary correction factors, observations, and calculations are detailed for each method, and also for the rate-of-climb tests. A method of correction for the effect on density of moist air and a description of other methods of speed course testing are appended.

Thompson, F L↗
NASA NTRS1993

Moisture and heat budgets of a cirrus cloud from aircraft measurements during FIRE

This study is based on the NCAR King Air aircraft and radiosonde observations on 31 October 1986 during the FIRE in Wisconsin over Oshkosh. Aircraft step-up and spiral descent flights are used to obtain kinematic and thermodynamic data. In the step-up maneuver, six different penetrations were made between 1528 and 1616 UTC. Each penetration was about 30 km long separated in the vertical by about 300 m. The time difference between the two spiral soundings was about 43 min. The aircraft descended at a rate of 1.5 m/s during these spiral soundings. Kinematic, cloud physical, and radiometric observations from various instruments are used to estimate the different terms in the moisture- and heat-budget equations. The results show that the advection terms, estimated using the mean longitudinal wind and vertical velocities, and radiative fluxes are important in forming budgets for the cirrus layers. Ice-crystal growth is significant in the upper layers. The maintenance of cirrus can be attributed to relatively warm and moist air advection, radiative cooling at upper levels, and moisture advection in the vertical. Turbulent heat and moisture fluxes are found to be significant in the low levels of cirrus.

Gultepe, Ismail↗
NASA NTRS1969

A new solid lubricant

Friction and wear life studies on burnished films of the compound graphite fluoride have demonstrated its potential as a solid lubricant material. It is effective in moist air, dry air, or in dry argon at temperatures up to approximately 400 degrees C.

Fusaro, R. L.↗
NASA NTRS1970

Frost as an insulator

Insulating qualities of frost and mechanisms for using frost in specific applications in controlled experiments are discussed. With available supply of moist air, frost possesses inherent advantage of easy insulation of cryogenic lines and improvement of overall system efficiency.

Bronson, J. C.↗
NASA NTRS1971

Improved high-temperature metal-sheathed cables

Process prevents moist air degradation of cables insulated with magnesium oxide. Electrical-grade silicone oil is polymerized by heat application to produce water repellant surface coating. Insulation treated with this oil repels moisture.

Fox, H. A., Jr.↗
NASA NTRS1971

Psychrometric chart for physiological research

Chart facilitates use of graphical techniques for solving problems involving thermodynamic properties of moist air. The properties are presented, and their units of measurement are listed. Chart presenting conditions at standard atmosphere pressure at sea level is most useful.

Chambers, A. B.↗
NASA NTRS1973

Techniques for lithium removal from 1040 C aged tantalum alloy, T-111

The liquid ammonia and vacuum distillation techniques were found to be satisfactory for removing lithium from 1040 C aged T-111 (tantalum - 8-percent tungsten- 2-percent hafnium). Results of ductility tests and chemical analysis show that these two methods are adequate for removing lithium without embrittlement or contamination of the T-111. Moist air exposure of T-111 with traces of lithium on the surface produced mixed results. Some specimens were ductile; others were brittle. Brittle T-111 had an increased hydrogen content. Water removal of lithium from T-111 caused brittleness and an increased hydrogen concentration.

Gahn, R. F.↗
NASA NTRS1975

Organopolysiloxane-bonded graphite fluoride as a solid lubricant

A study was conducted on the lubricating properties of organopolysiloxane-bonded graphite fluoride (CF sub 1.1) sub n films. The effects of temperature, atmosphere, composition of organopolysiloxane, and burnishing additional (CF sub 1.1) sub n powder onto the film surface were studied. For comparison, similar experiments were conducted on organopolysiloxane-bonded MoS2 films. The results are equivalent for both films, except that in a moist air environment the wear lives of the films formulated with (CF sub 1.1) sub n are up to 10 times longer than the wear lives of the MoS2-formulated films. Comparison to other (CF sub 1.1) sub n films showed organopolysiloxane films to give better lubrication results than hand-burnished (CF sub 1.1) sub n films but not as good as polyimide-bonded (CF sub 1.1) sub n films.

Fusaro, R. L.↗
NASA NTRS1978

Effect of thermal exposure on lubricating properties of polyimide films and polyimide-bonded graphite fluoride films

The effect of thermal exposure on the weight loss, adherence, friction, and wear properties of polyimide films and polyimide bonded graphite fluoride films was investigated. Films bonded to 304 stainless steel or 440C-HT steel were thermally exposed at temperatures of 315 ,345, 370, or 400 C for 100 hours or more and then evaluated, using a pin-on-disk machine, at temperatures of 25, 315, or 345 C in atmospheres of dry or moist air. Polyimide films were brittle after thermal exposure. Polyimide bonded graphite fluoride films had adherence and gave low friction and wear results; thus, they appear to be good candidates for solid lubrication applications where long thermal soaks are prevalent.

Fusaro, R. L.↗
NASA NTRS1978

A Comparison of the Lubricating Mechanisms of Graphite Fluoride and Molybdenum Disulfide Films

A microscopic study of 440C steel sliding surfaces lubricated by graphite fluoride or molybdenum disulfide solid lubricant rubbed films was conducted. The sliding surfaces, along with the friction, wear, and wear life were observed as a function of the number of sliding revolutions in three different atmospheres: moist air, dry air, or dry argon. In general, the lubricating mechanisms of the two solid lubricants were found to be relatively similar; that is, a dynamic, thin, layer-like film was formed between the two metallic surfaces. The mechanisms of failure were found to be somewhat different, however. Failure of MoS2 films was very dependent on atmospheric degradation, while that of graphite fluoride films was more dependent on flow of the lubricant film out of the contact zone.

Fusaro, R. L.↗