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27 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Post-eruptive alteration of silicic ignimbrites and lavas, Gran Canaria, Canary Islands - Strontium, neodymium, lead, and oxygen isotopic evidence

The isotopic composition of lavas from oceanic islands provides important information about the composition and evolution of the earth's mantle. Isotopic analyses of Miocene comenditic, pantelleritic, and trachyphonolitic ignimbrites and lavas from the Canary islands were performed. Results provide evidence for posteruptive mobility of Rb and Sr during low temperature postemplacement interaction with circulating ground water. Calculated Sr isotope ratios define a magmatic trend in the stratigraph section. 87Sr/86Sr ratios in hydrated vitrophyte and devitrified matrix separates indicate significant posteruptive interaction with meteoric water starting soon after deposition. This process extends patchily through the entire pyroclastic flow and may be ongoing. 87Sr/86Sr ratios determined by whole rock analysis of silicic rocks from oceanic islands are suspect and should not be incorporated into mantle tracer studies. Anorthoclase phenocrysts are resistant to these processes and may produce useful data.

Cousens, Brian L.↗
NASA NTRS1983

Samarium-146 in the early solar system - Evidence from neodymiun in the Allende meteorite

A carbon-chromite fraction from the Allende C3V chondrite shows strikingly large isotopic enrichments of neodymium-142 (0.47 percent) and neodymium-143 (36 percent). Both apparently formed by alpha decay of samarium-146 and samarium-147 (half-lives 1.03 x 10 to the 8th and 1.06 x 10 to the 11th years), but the isotopic enrichment was greatly magnified by recoil of residual nuclei into a carbon film surounding the samarium-bearing grains. These data provide an improved estimate of the original abundance of extinct samarium-146 in the early solar system, Sm-146/Sm-144 = (4.5 + or - 0.5) x 10 to the -3rd, higher than predicted by some models of p-process nucleosynthesis. It may be possible to use this isotopic pair as a chronometer of the early solar system.

Lugmair, G. W.↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Terrestrial Planets: Building Blocks and Differentiation

The session "Terrestrial Planets: Building Blocks and Differentiation: included the following topics:Magnesium Isotopes in the Earth, Moon, Mars, and Pallasite Parent Body: High-Precision Analysis of Olivine by Laser-Ablation Multi-Collector ICPMS; Meteoritic Constraints on Collision Rates in the Primordial Asteroid Belt and Its Origin; New Constraints on the Origin of the Highly Siderophile Elements in the Earth's Upper Mantle; Further Lu-Hf and Sm-Nd Isotopic Data on Planetary Materials and Consequences for Planetary Differentiation; A Deep Lunar Magma Ocean Based on Neodymium, Strontium and Hafnium Isotope Mass Balance Partial Resetting on Hf-W System by Giant Impacts; On the Problem of Metal-Silicate Equilibration During Planet Formation: Significance for Hf-W Chronometry ; Solid Metal-Liquid Metal Partitioning of Pt, Re, and Os: The Effect of Carbon; Siderophile Element Abundances in Fe-S-Ni-O Melts Segregated from Partially Molten Ordinary Chondrite Under Dynamic Conditions; Activity Coefficients of Silicon in Iron-Nickel Alloys: Experimental Determination and Relevance for Planetary Differentiation; Reinvestigation of the Ni and Co Metal-Silicate Partitioning; Metal/Silicate Paritioning of P, Ga, and W at High Pressures and Temperatures: Dependence on Silicate Melt Composition; and Closure of the Fe-S-Si Liquid Miscibility Gap at High Pressure and Its Implications for Planetary Core Formation.

Source record↗
NASA NTRS1986

Significance of the Sm-Nd isotopic systematics of the Akilia Association

Samarium-Neodymium analyses were carried out on fourteen samples of basic to ultrabasic metavolcanics from several enclaves of the Amitsoq gneisses (T = to or approximately 3,700 Ma). Field observations suggest that all the analyzed rocks belong to the pre-Amitsoq Akilia Association. Consequently, a minimum age of 3,700 Ma is postulated for the emplacement of their protoliths. When all the data points are put together in a conventional isochron diagram, no clear isochron relationship can be discerned. However, the points seem to fall within a band broadly corresponding to an age of 3,600 Ma. The isotopic results are difficult to interpret satisfactorily. Two contrasting interpretations are offered and summarized: (1) data scatter as a result of open system behavior; and (2) data scatter due to a melange of data sets defining two distinct isochrons.

Gruau, G.↗
NASA NTRS1986

Implications of isotope data for the origin of the moon

Lunar isotope data are studied in terms of lunar reservoir models. An analysis is performed to determine how the samarium-neodymium and rubidium-strontium systems evolve in terms of a two-reservoir model. Isotope data from lunar rocks show much more variability than similar data from terrestrial rocks. The midocean ridge basalts yield consistent isotope signatures on a worldwide basis suggesting that vigorous mantle convection has mixed and homogeneized the upper mantle beneath the lithosphere plates. The variability of the lunar data is taken as evidence for distinct source regions which in effect support a relatively cool origin of the moon.

Turcotte, D. L.↗
NASA NTRS2017

Interpretation of Ferroan Anorthosite Ages and Implications for the Lunar Magma Ocean

Ferroan Anorthosites (FANs) are considered to have purportedly crystallized directly from the lunar magma ocean (LMO) as a flotation crust. LMO modeling suggests that such anorthosites started to form only after greater than 70 percent of the LMO had crystallized. Recent age dates for FANs have questioned this hypothesis as they span too large of an age range. This means a younger age for the Moon-forming giant impact or the LMO hypothesis is flawed. However, FANs are notoriously difficult to age-date using the isochron method. We have proposed a mechanism for testing the LMO hypothesis through using plagioclase trace element abundances to calculate equilibrium liquids and compare them with LMO crystallization models. We now examine the petrography of the samples that have Sm-Nd (Samarium-Neodymium) age dates (Rb-Sr (Rubidium-Strontium) isotopic systematics may have been disturbed) and propose a relative way to age date FANs.

Neal, C. R.↗
NASA NTRS1994

REE chemistry and Sm-Nd systematics of late Archean weathering profiles in the Fortescue Group, Western Australia

Two weathering profiles, each consisting of an upper, sericite-rich zone and a lower, chlorite-rich zone, are preserved between flows of the Mt. Roe Basalt in the Fortescue Group, Hamersley Basin, Western Australia. REE concentrations in samples from these two profiles, which originally developed ca 2,760 Ma, show large variations depending on stratigraphic position. LREE abundances and (La/Yb)N are greatest at depths of 3-6 m below the paleosurface of the Mt. Roe #1 profile and are somewhat lower in samples above this level. The LREEs reach concentrations 6-9 times greater than in the underlying basalt, and thus appear to have been mobilized downward in the paleosol and concentrated in its middle part. LREE concentrations in the #2 profile show a similar distribution but with a sharp increase in all REE concentrations within 50 cm of the paleosurface. The distinction between the REE profiles in the two paleosols may be related to the difference in the overlying material. The #1 paleosol is overlain by a few meters of sediments and then by basalt, whereas the #2 paleosol is directly overlain by basalt. The LREEs appear to have been mobilized both during chemical weathering of the parental basalt and during later lower-greenschist-facies metamorphism and metasomatism of the paleosols. Remobilization of the REEs during the regional metamorphism of the Fortescue Group is confirmed by a whole-rock Sm-Nd reference isochron of Mt. Roe #1 samples with an age of 2,151 +/- 360 Ma. Variable initial 143Nd/144Nd values of unweathered basalt samples which may represent the paleosol protolith prevents a confident determination of the magnitude of LREE mobility. Both the initial mobilization of the REEs during weathering and the metasomatic remobilization appear to have taken place under redox conditions where Ce was present dominantly as Ce3+, because Ce anomalies are not developed within the sericite zone samples regardless of concentration. Europium anomalies in the paleoweathering profile are somewhat variable and were probably modified by mobilization of Eu2+ at metamorphic conditions. In all samples, the HREEs appear to have been relatively immobile and correlate with Al, Ti, Cr, V, Zr, and Nb. Sm-Nd systematics and REE patterns of four unweathered basalt samples indicate derivation of the Mt. Roe Basalts from a heterogeneous and enriched source having epsilon Nd between -4.0 and -7.4. Initial 143Nd/144Nd values of these basalts are even lower than those reported by NELSON et al. (1992) for Fortescue Group basalts and indicate a substantial crustal component in the generation of Mt. Roe Basalts.

NASA Discipline Exobiology↗
NASA NTRS1992

Samarium-neodymium evolution of meteorites

The feasibility of using Sm-147 and Sm-146 as chronometers was investigated using Sm-Nd data obtained on three meteorites: Ibitira, Morristown, and Acapulco. The results of isotope analyses demonstrate the presence of in situ decay of short-lived Sm-146 in these meteorites with initial abundances of Sm-146/Sm-144 between 0.009 and 0.007 in different meteorites. Precisely defined Sm-147/Nd-143 internal isochrons were obtained yielding ages equal to 4.46 +/-0.02 AE for Ibitira, 4.47 +/-0.02 AE for Morristown, and 4.60 +/-0.03 AE for Acapulco. However, detailed examination of the coupled Sm-147/Nd-143 and Sm-146/Nd-142 parent-daughter systematics and of initial Nd-143/Nd-144 values indicated the presence of inconsistencies in the data in spite of the precise isochrons, indicating the need for care in the interpretation of the parent-daughter systematics, even when they appear well behaved.

Prinzhofer, A.↗
NASA NTRS2006

Constraints on the Formation of the Moon from High-Precision ND-Isotopic Measurements of Lunar Basalts

The most widely accepted theory for the formation of the Earth-Moon system proposes a giant impact model, where Earth collided in its later stages of accretion with a body of the approximate size of Mars [1, 2]. In this model, the Moon ultimately formed from hot debris generated during this giant impact. Short-lived radioisotopes such as Sm-146 (t(sub 1/2) = 103 Ma) may be useful in determining the chronology of the events that formed the Earth-Moon system and for how these terrestrial bodies evolved following accretion. New high-precision samarium-neodymium data showed that chondritic meteorites are on average 20 ppm lower in 142Nd/144Nd than terrestrial samples [3]. These data suggest that if the bulk silicate Earth (BSE) has a Sm/Nd ratio within the range measured for chondrites, the higher-than-chondritic Nd-142/Nd-144 ratio of terrestrial materials requires that the silicate Earth experienced a global chemical differentiation during the lifetime of Sm-146. If the Moon has super-chondritic Nd-142/Nd-144 identical to the Earth, as suggested by available data [4], then the giant impact must have occurred into an already differentiated Earth, predominantly sampling the Nd-depleted reservoir. In order to test this hypothesis, high-precision Nd-isotope ratios were obtained on a Thermo-Finnigan Triton TIMS for six lunar basalts that span the compositional range of lavas from the Moon: Samples 15555 and LAP 02205 represent low-Ti basalts; 70017 and 74275 are high-Ti basalts; 15386 and SAU 169 are KREEP basalts.

Rankenburg, K.↗