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At least 37 records · Page 2

Five year global dataset: NMC operational analyses (1978 to 1982)

This document describes procedures used in assembling a five year dataset (1978 to 1982) using NMC Operational Analysis data. These procedures entailed replacing missing and unacceptable data in order to arrive at a complete dataset that is continuous in time. In addition, a subjective assessment on the integrity of all data (both preliminary and final) is presented. Documentation on tapes comprising the Five Year Global Dataset is also included.

Straus, David↗

A reduced version of the NMC DERF 2 data set

The National Meterological Center (NMC) Dynamical Extended Range Forecast (DERF 2) data represents a major computational effort to better ascertain the potential for extended range forecasts and to develop a strategy for performing operational extended range forecasts using dynamical models. A major stumbling block for using this data has been the sheer volume of data that must be processed to perform even simple calculations. The product of the data reduction described is a manageable data set that fits comfortably on five magnetic tapes or on one compact disc. The document outlines the data reduction process of the second phase of DERF data. It contains the description of the fields and the resolution of both the original and final fields. In order to assist the users of this data set, maps of selected fields, using both the original truncation at rhomboidal 30 and the truncation of the final data at triangular 20, are displayed.

Schubert, Siegfried↗

A simulation of the winter and summer circulations with the NMC Global Spectral Model

The medium range forecast model of the NMC has been integrated to produce winter and summer simulations. It is found that the model climatology is similar to that of the observed atmosphere as well as climatologies of other general circulation models. The stationary and transient features of the model circulation are described, including both tropical and extratropical regions. The model hydrological cycle, radiative balance, and surface heat budget are discussed. Comparison with observations shows that the model is colder than that observed in the troposphere and cools in the lower stratosphere in the tropics and near the poles in both simulations. It is suggested that the upper branch of the Hadley cell is poorly simulated in the integrated model. The simulations are in reasonable agreement with the observations in sea level pressure, the structure of the tropospheric zonal jets, and the winter hemispheric stationary waves.

Kinter, J. L., III↗

Statistical corrections to the NMC medium range 700 mb height forecasts

This paper examines four statistical procedures for correcting the NMC medium-range forecast (MRF) errors in the 700-mb heights over the Northern Hemisphere. The tests were designed to include normal operational constraints, such as frequent changes in the forecast model and the lack of long-term forecast histories on which to base estimates of systematic errors and climate drifts. It was found that the two statistical procedures which provided a substantial reduction in mean square error were a procedure based on simple regression correction at each grid point and one based on lagged-average correction with one day lag at each grid point.

Schemm, Jae-Kyung E.↗

Use of GEMPAK at NMC

This paper considers the use of the General Meteorological Package (GEMPAK) system developed by the NASA Goddard Space Flight Center. The interactive capabilites included in the GEMPAK are examined, and the changes of GEMPACK necessary for the accommodation of the large volume of gridded NMC data are discussed. Some preliminary results are presented.

Petersen, Ralph A.↗

Predictions of zonal wind and angular momentum by the NMC medium-range forecast model during 1985-89

This paper investigates the quality of weather predictions of the atmosphere's relative angular momentum (M) made by the most recent version of the NMC medium-range forecast model (MRF88) during December 1985-1989. It was found that, compared with older versions of MRF, bias errors in the MRF88 forecasts of M became more prominent, while random errors were not affected. Both types of errors in the M forecasts could be traced to problems with forecasts in the zonal mean zonal wind in the tropics.

Rosen, Richard D.↗

The stratospheric 4-day wave in NMC data

The observed characteristics of the 4-day eastward-moving wave 1 in the Southern Hemisphere polar winter stratosphere are surveyed using ten years of National Meteorological Center (NMC) geopotential height data. The 4-day wave is shown to be an ubiquitous feature in the Southern Hemisphere polar winter stratosphere and is usually prominent during July and August. Growth of the 4-day wave is characterized by two types of structures. Some episodes exhibit NW to SE phase tilts and a single high-latitude maximum. Others show NE to SW phase tilts during growth and a high-latitude maximum out of phase with a secondary lower-latitude maximum. Stability analyses show that all characteristics of the first type of episode are consistent with barotropic instability of the stratospheric polar night jet. Analyses of climatological fields suggest that characteristics of the second type of episode may be consistent with barotropic instability of the double-peaked mesospheric jet.

Manney, Gloria L.↗

Impact of increased TOVS signal on the NMC global spectral model - A tropical-plume case study

Temperature and moisture signals are extracted from operationally available TOVS channel radiances for a tropical plume that developed over the North Pacific in January 1989, and are inserted into the NMC's operational medium-range forecast model. Several 48-h forecasts are made to test the impact of the additional information. It is shown, at least within a single tropical plume event, that there is still unutilized information within operational TOVS satellite observations. This information resides in the moisture channels and within small-amplitude, but horiontally coherent, thermal features. Perturbed upper-tropospheric relative humidity patterns are smoother and more consistent with satellite imagery than is the historical forecast.

Mcguirk, James P.↗

Observations of the 2-day wave in NMC stratospheric analyses

Observational characteristics of the 2-day wave, a westward-propagating zonal wave 3 oscillation in the summer subtropical upper stratosphere and mesosphere, are studied based on five years of National Meteorological Center (NMC) operational stratospheric analyses. These data show episodic occurrence of the 2-day wave in the upper stratosphere in January (centered near 20 deg S) and July - August (centered near 20 deg N). These episodes are strongly correlated with observed reversals of the zonal mean potential vorticity gradient near the core of the summer easterly jet, consistent with previous suggestions that the 2-day wave is generated by an in situ instability of this jet. On the other hand, the horizontal and vertical structure of the waves is very similar to that calculated by Salby for a global normal-mode Rossby wave. The combination of normal-mode structure and instability signature suggests that the 2-day wave is a near-resonant mode forced by dynamical instability.

Randel, William J.↗

Stratospheric aerosol acidity, density, and refractive index deduced from SAGE 2 and NMC temperature data

Water vapor concentrations obtained by the Stratospheric Aerosol and Gas Experiment 2 (SAGE 2) and collocated temperatures provided by the National Meteorological Center (NMC) from 1986 to 1990 are used to deduce seasonally and zonally averaged acidity, density, and refractive index of stratospheric aerosols. It is found that the weight percentage of sulfuric acid in the aerosols increases from about 60 just above the tropopause to about 86 at 35 km. The density increases from about 1.55 to 1.85 g/cu cm between the same altitude limits. Some seasonal variations of composition and density are evident at high latitudes. The refractive indices at 1.02, 0.694, and 0.532 micrometers increase, respectively, from about 1.425, 1.430, and 1.435 just above the tropopause to about 1.445, 1.455, and 1.458 at altitudes above 27 km, depending on the season and latitude. The aerosol properties presented can be used in models to study the effectiveness of heterogeneous chemistry, the mass loading of stratospheric aerosols, and the extinction and backscatter of aerosols at different wavelengths. Computed aerosol surface areas, rate coefficients for the heterogeneous reaction ClONO2 + H2O yields HOCl + HNO3 and aerosol mass concentrations before and after the Pinatubo eruption in June 1991 are shown as sample applications.

Yue, G. K.↗

Comparison of UKMO and NMC Stratospheric Analyses During Northern and Southern Winter

Instruments on board the Upper Atmosphere Research Satellite have been measuring stratospheric temperatures, winds, and constituent species since September 1991. Among the correlative data that aid in interpreting this data are two sets of global meteorological analyses. Meteorological data from the United Kingdom Meteorological Office (UKMO), and the US National Meteorological Center (NMC) are discussed.

arctic antarctic atmosphere research satellite met↗

OGCM Simulations of Equatorial Pacific Current and Temperature to ERS-1, FSU and NMC Surface Winds and to Assimilation of Subsurface Temperature Data

The relative accuracies of three surface wind data products for the tropical Pacific Ocean during April 1992 to March 1994 were examined by analyzing temperature and current fields along the equator, which were simulated with an ocean general circulation model. Simulations were made with and without assimilation of surface and subsurface temperature data. Simulated currents were compared with observations at three sites (170oW, 140oW, 110oW) at the equator. Model-generated currents and temperatures indicated that the ERS-1 westward wind speeds were low compared to the FSU and NMC winds. With data assimilation, the agreement between simulated and observed currents was highest at 170oW and lowest at 110oW.

ERS-1 FSU↗

pCAM precursor produced from electroextraction technology and its application in synthesis of NMC 811 cathode material

The synthesis and characterization of LiNi 0.8 Co 0.1 Mn 0.1 O 2 (LNMC811) cathodes produced from recycled hydroxide precursors obtained from spent lithium-ion batteries is evaluated. Two precursor batches (Sample 1 and Sample 2) are prepared using modified recycling processes to examine how residual impurities and processing conditions influence the properties of the regenerated materials. Structural and compositional characterization by X-ray diffraction, ICP and SEM shows that the recycled precursors exhibit layered hydroxide structures containing both α Ni(OH) 2 and β Ni(OH) 2 phases. Trace impurities including sodium, boron, and aluminum are detected and partially mitigated during processing, with boron found to play a beneficial role in electrochemical behavior. Following lithiation with lithium carbonate and lithium hydroxide at 800 °C under an oxygen rich atmosphere, the resulting LNMC811 materials show electrochemical performance comparable to conventionally synthesized cathodes. Sample 2, which contains higher boron levels and improved cation ordering, delivers an initial discharge capacity of 174 mAh g -1 and retains more than 93 percent of its capacity after 50 cycles. The stable cycling behavior and structural integrity of these materials demonstrate that recycled precursors can be converted into high performance layered cathodes and support recycling as a practical and sustainable route for lithium-ion battery manufacturing.

25 ENERGY STORAGE↗

One-step atmospheric microplasma synthesis of an NMC-type lithium-ion battery cathode

The manufacture of battery cathode materials is the most energy-intensive step in the production of commercial lithium-ion batteries; specifically, the synthesis of the widely used transition metal oxide cathodes can require tens of hours at temperatures exceeding 700 °C. Attempts to limit the reaction time and energy required to form crystalline cathode materials often still include a heating or calcination step. This communication aims to highlight a nascent yet novel synthesis route: a one-step atmospheric microplasma process for synthesizing cathode particles in less than one second. The hollow-tube reactor employed produces crystalline particles measuring 0.1–3 μm in diameter, displays narrow XRD peaks corresponding to the 003, 104, and 101 planes, and exhibits anodic redox behavior at 3.75 V vs. lithium—characteristic of transition-metal oxide cathode materials—all without requiring an additional calcination step.

25 ENERGY STORAGE↗

Stochastic 3D reconstruction of cracked polycrystalline NMC particles using 2D SEM data

Li-ion battery performance is strongly influenced by the 3D microstructure of its cathode particles. Cracks within these particles develop during calendaring and cycling, reducing connectivity but increasing reactive surface, making their impact on battery performance complex. Understanding these contradictory effects requires a quantitative link between particle morphology and battery performance. However, informative 3D imaging techniques are time-consuming, costly and rarely available, such that analyses often have to rely on 2D image data. This paper presents a novel stereological approach for generating virtual 3D cathode particles exhibiting crack networks that are statistically equivalent to those observed in 2D sections of experimentally measured particles. Consequently, 2D image data suffices for deriving a full 3D characterization of cracked cathodes particles. Such virtually generated 3D particles could serve as geometry input for spatially resolved electro-chemo-mechanical simulations to enhance our understanding of structure-property relationships of cathodes in Li-ion batteries.

36 MATERIALS SCIENCE↗

On Rate-Limiting Mechanisms in NMC Cathodes: The Interplay of Low and High Current Constraints

In this study, we investigate the rate performance limits in LiNi 0.6 Mn 0.2 Co 0.2 O 2 cathodes for lithium-ion batteries, focusing on how cathode thickness, porosity, and threshold voltage impact discharge capacity. By conducting galvanostatic discharge experiments across a wide range of current densities using cathodes of varying thicknesses and porosities, we identify two distinct rate-limiting mechanisms: ionic liquid-diffusion and Ohmic/charge-transfer limitations. Our findings show that thick, dense cathodes are primarily limited by lithium diffusion in the electrolyte, while thinner and more porous cathodes are dominated by Ohmic/charge-transfer limitations, particularly at higher lower cutoff voltages. Crucially, these results allow us to identify the rate-limiting mechanisms in different cathode configurations, offering clear insights into how cathode design can be optimized for improved performance. Understanding these mechanisms is essential for designing next-generation batteries with enhanced rate performance, which is critical for applications such as electric vehicles and renewable energy storage systems.

Brischetto, Martin (ORCID:0000000339865813)↗