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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Towards Understanding of Cracking during Drying of Thick Aqueous-Processed LiNi 0.8 Mn 0.1 Co 0.1 O 2 Cathodes

Replacing N-methyl-2-pyrrolidone (NMP) with water for processing of lithium-ion battery (LIB) electrodes has both cost and environmental benefits, which include reduced drying time, lower dryer capital cost, elimination of NMP recovery capital equipment, and no release of volatile organic compounds (VOCs) into the environment. However, aqueous-processed thick cathodes (≳4 mAh/cm 2 ) typically exhibit detrimental cracking during drying that is not observed for the NMP-based counterpart. The reasons for cracking of these water-based thick electrodes are still not well understood due to the complex nature of the colloidal dispersions used in the LIB electrode processing steps. In this work, the contributions of various factors responsible for cracking are discussed. We show that eliminating hydrogen evolution due to corrosion of the aluminum current collector eliminated the majority of the cracks regardless of the coating thickness, identifying the gas evolution as the primary reason for electrode cracking. Some secondary cracks and pinhole-type defects remained after addressing the aluminum current collector corrosion, which are thought to be caused by an inferior binding network formed by carbon black and binder in aqueous-processed cathodes compared to those processed with NMP. The thick aqueous processed cathodes are not able to sufficiently withstand the drying stresses without crack formation. We demonstrate reduction of these secondary defects by either improving the binding network or by reducing the drying stress. The former was achieved by replacing carbon black with vapor grown graphite tubes (VGGTs) that caused a more efficient utilization of the emulsion binder. Here, the latter was achieved by adding a small amount of IPA as a co-solvent that has been shown to reduce capillary stresses.

25 ENERGY STORAGE↗

Rheo-electric measurements of carbon black suspensions containing polyvinylidene difluoride in N -methyl-2-pyrrolidone

Lithium-ion battery cathode slurries have a microstructure that depends sensitively on how they are processed due to carbon black's (CB) evolving structure when subjected coating flows. While polyvinylidene difluoride (PVDF), one of the main components of the cathode slurry, plays an important role in modifying the structure and rheology of CB, a quantitative understanding is lacking. In this work, we explore the role of PVDF in determining the structural evolution of Super C65 CB in N-methyl-2-pyrrolidinone (NMP) with rheo-electric measurements. We find that PVDF enhances the viscosity of NMP resulting in a more extensive structural erosion of CB agglomerates with increasing polymer concentration and molecular weight. We also show that the relative viscosity of all suspensions can be collapsed by the fluid Mason number (Mnf), which compares the hydrodynamic forces imposed by the medium to cohesive forces holding CB agglomerates together. Using simultaneous rheo-electric measurements, we find at high Mnf, the dielectric strength (Δε) scales with Mnf, and the power-law scaling can be quantitatively predicted by considering the self-similar break up of CB agglomerates. The collapse of the relative viscosity and scaling of Δε both suggest that PVDF increases the hydrodynamic force of the suspending medium without directly changing the CB agglomerate structure. These findings are valuable for optimizing the rheology of lithium ion battery cathode slurries. We also anticipate that these findings can be extended to understand the microstructure of similar systems under flow.

Mechanics↗

Developing a corss-project support system during mission operations: Deep Space 1 extended mission flight control

NASA is focusing on small, low-cost spacecraft for both planetary and earth science missions. Deep Space 1 (DS1) was the first mission to be launched by the NMP. The New Millennium Project (NMP) is designed to develop and test new technology that can be used on future science missions with lower cost and risk. The NMP is finding ways to reduce cost not only in development, but also in operations. DS 1 was approved for an extended mission, but the budget was not large, so the project began looking into part time team members shared with other projects. DS1 launched on October 24, 1998, in it's primary mission it successfully tested twelve new technologies. The extended mission started September 18, 1999 and ran through the encounter with Comet Borrelly on September 22,2001. The Flight Control Team (FCT) was one team that needed to use part time or multi mission people. Circumstances led to a situation where for the few months before the Borrelly encounter in September of 2001 DSl had no certified full time Flight Control Engineers also known as Aces. This paper examines how DS 1 utilized cross-project support including the communication between different projects, and the how the tools used by the Flight Control Engineer fit into cross-project support.

New Millennium Project NMP DS flight control↗

Technology readiness levels for the new millennium program

NASA's New Millennium Program (NMP) seeks to advance space exploration by providing an in-space validating mechanism to verify the maturity of promising advanced technologies that cannot be adequately validated with Earth-based testing alone. In meeting this objective, NMP uses NASA Technology Readiness Levels (TRL) as key indicators of technology advancement and assesses development progress against this generalized metric. By providing an opportunity for in-space validation, NMP can mature a suitable advanced technology from TRL 4 (component and/or breadboard validation in laboratory environment) to a TRL 7 (system prototype demonstrated in an Earth-based space environment). Spaceflight technology comprises a myriad of categories, types, and functions, and as each individual technology emerges, a consistent interpretation of its specific state of technological advancement relative to other technologies is problematic.

technology readiness TRL New Millennium Program NM↗

Coordination polymers based on zinc(II) and manganese(II) with 1,4-cyclohexanedicarboxylic acid

Three new metal-organic coordination polymers were obtained namely, [Mn{sub 3}(chdc){sub 3}-(NMP){sub 2}(DMF){sub 2}] (1, chdc{sup 2–} is trans-1,4-cyclohexanedicarboxylate, NMP is N-methylpyrrolidone, DMF is N,N-dimethylformamide), [Zn{sub 3}(chdc){sub 3}(NMP){sub 2}]•2NMP (2), and [Zn{sub 3}(chdc){sub 3}(ur)-(DMF){sub 0.5}]•DMF (3, ur is the urotropine). The crystal structures of polymers 1, 2, and 3 were determined by single-crystal X-ray crystallography. All three compounds were found to contain a trinuclear secondary building unit {M_3(OOC)_6}. Coordination polymers 1 and 2 have a layered structure, while polymer 3 has a three-dimensional coordination framework with isolated pores formed due to the presence of urotropine bridging molecules. Compounds 1 and 3 were characterized by IR spectroscopy, thermogravimetric and elemental analysis data, powder X-ray diffraction. Compound 3 was also characterized by UV-Vis diffuse reflectance spectrum.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Metal-organic frameworks based on magnesium(II): adsorption and luminescence properties

Two new metal-organic frameworks based on magnesium(II) ions, [Mg{sub 4}(bdc){sub 3}(dma){sub 6}(NO{sub 3}){sub 2}]•DMA (1; bdc is 1,4-benzenedicarboxylate; dma, DMA is N,N-dimethylacetamide) and [Mg{sub 3}(bpdc){sub 3}(nmp){sub 4}] (2; bpdc is 4,4´-biphenyldicarboxylate; nmp is N-methylpyrrolidone), were synthesized in DMA or NMP, respectively. According to the single-crystal X-ray diffraction data, compound 1 is built of binuclear carboxylate units {Mg_2(O_2CR)_3}, which were previously not observed in metal-organic frameworks. Compound 2 is based on trinuclear carb oxylate units {Mg_3(O_2CR)_6}. Compound 1 has a layered structure (hcb topology), whereas compound 2 has a distorted three-dimensional cubic structure (pcu topology). The phase purity and chemical identity of the compounds were confirmed by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction. Photoluminescence properties of both compounds are indicative of intraligand charge-transfer transitions of one (for 1) or two (for 2) types. Textural characteristics of an activated sample of 1 were measured by nitrogen and hydrogen adsorption at 77 K and by carbon dioxide adsorption at 195 K.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A cradle-to-grave life-cycle-assessment of dry-processed Li-ion batteries for electric vehicles

Maxwell-type dry processing has emerged as a promising manufacturing technology for high-areal-loading Li-ion battery electrodes, offering a significant advantage by eliminating the use of the toxic and costly NMP solvent. This study developed a cradle-to-grave life-cycle-assessment model to evaluate the environmental impacts of this innovative technology, benchmarking the results against the conventional NMP-based technique for a configured 42 kWh NMC622-graphite battery pack. Furthermore, the findings reveal that the dry-processing method merits a 4.8% lower energy consumption and achieves environmental impacts up to 47.5% lower in 12 out of 13 categories, highlighting its environmental benefits compared with the NMP-based manufacturing processes.

Electrode↗

Investigating the impact of micropore volume of aminosilica functionalized SBA-15 on catalytic activity for amine-catalyzed reactions

Mesoporous materials such as SBA-15 are used in many applications since the materials are robust and have tunable properties. Whereas these materials are thought to be ideal, the materials are complex with the common synthesis methods producing materials that contain micropores. This work will investigate the impact of micropores on catalytic activity of aminosilica materials. For comparison, materials are formed using a standard method that produces materials with micropores (REG-SBA-15) and using a modified method that produces materials with negligible micropore volume (NMP-SBA-15). After grafting the calcined support with an aminosilane (either (N-methyl amino propyl) trimethoxy silane (denoted as 2°Am) or (N,N-diethyl-3-amino propyl) trimethoxy silane (3°Am)), catalytic testing experiments reveal that NMP-SBA-15 functionalized materials are more active than REG-SBA-15 functionalized materials for a range of reactions. The reactions include (a) glucose isomerization where amines interacting with surface silanols limit catalytic activity and (b) aldol and Knoevenagel chemistry where amine-silanol interactions increase the reaction rate. For aldol chemistry, the observed difference in rate is further investigated using site quantification experiments. Interestingly, the results reveal that three types of sites exist for each material, including sites that are (1) highly active, (2) intermediate active, and (3) inactive. Additionally, NMR experiments indicate that amines immobilized on REG-SBA-15 supports are less mobile than amines on NMP-SBA-15. For REG-SBA-15, the materials are found to have aminosilanes that have limited mobility and the largest fraction of inactive sites, which suggests that the inactive catalytic sites are in the micropores. Overall, the design of highly active catalytic materials can be achieved using materials that have limited micropore volumes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effect of solvents on the electrochemical properties of binder-free sulfur cathode films in lithium–sulfur batteries

Highlights: • The binder-free sulfur electrode with high sulfur contents of 75 wt.% was fabricated. • The binder-free sulfur electrode using NMP solvents showed 784 mAh g{sup −1} after 40 cycles. • The solvent affect the electrochemical properties of binder-free sulfur electrode films. - Abstract: The effects of solvents on the preparation of sulfur cathodes were investigated by fabricating binder-free sulfur electrode films using three different solvents: 1-methyl-2-pyrrolidinone (NMP), acetonitrile, and deionized water. These solvents are commonly employed to dissolve binders used to prepare sulfur cathodes for lithium–sulfur batteries. The sulfur electrode fabricated with NMP had a higher discharge capacity and longer cycle life than the ones fabricated with acetonitrile and deionized water. Better adhesion between the current collector and the sulfur electrode accounted for the improved capacity and cycle life of the battery. In addition, the stability of the electrode in the electrolyte was a result of the solubility of sulfur in the solvent. We thus concluded that the solvents used in the fabrication of sulfur electrodes had a positive influence on the electrochemical properties of Li–S batteries.

36 MATERIALS SCIENCE↗

Chain Conformations of TEMPO-Based Organic Radical Polymers with Varying Radical Loading and Temperature in Battery-Relevant Solvents

Poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA) is an organic radical polymer that is a promising active material in organic batteries. The proximity of the radical groups impacts the nature of charge transfer, in which closer packing promotes electron exchange; however, the chain conformation of PTMA is not well understood. Here, the conformation of PTMA in, and its thermodynamic interactions with, battery-relevant solvents is determined using small-angle neutron scattering (SANS). N-methyl-2-pyrrolidone (NMP) and 50:50 (wt %) ethylene carbonate/dimethyl carbonate (EC/DMC) mixtures with PTMA of varying radical content (68 vs 98%) and temperature (25 and 60 °C) are examined. Both solvents are theta solvents for PTMA irrespective of radical loading and temperature. PTMA attains an expanded chain conformation in NMP and a more compact polymer chain conformation in EC/DMC. Lastly, the electrochemical performance of PTMA films formed from EC/DMC shows improved performance relative to those cast from NMP, which is interpreted to indicate that the compact conformation of PTMA in EC/DMC enables improved inter- and intrachain charge transfer.

25 ENERGY STORAGE↗

Nonlinear magneto-plasmonics

Nonlinear magneto-plasmonics (NMP) describes systems where nonlinear optics, magnetics and plasmonics are all involved. In such systems, nonlinear magneto-optical Kerr effect (nonlinear MOKE) plays an important role as a characterization method, and Surface Plasmons (SPs) work as catalyst to induce many new effects. Magnetization-induced second-harmonic generation (MSHG) is the major nonlinear magneto-optical process involved. The new effects include enhanced MSHG, controlled and enhanced magnetic contrast, etc. Nanostructures such as thin films, nanoparticles, nanogratings, and nanoarrays are critical for the excitation of SPs, which makes NMP an interdisciplinary research field in nanoscience and nanotechnology. In this review article, we organize recent work in this field into two categories: surface plasmon polaritons (SPPs) representing propagating surface plasmons, and localized surface plasmons (LSPs), also called particle plasmons. We review the structures, experiments, findings, and the applications of NMP from various groups.

36 MATERIALS SCIENCE↗

In-Situ Liquid Cell Transmission Electron Microscopy of Nanoparticles from Spent Nuclear Fuel

Noble Metal Particles (NMP) that are present in SNF play an important role in the Fuel Matrix Degradation (FMD) Model that is being considered for predicting the release rate of radionuclides from a waste package. Previous characterization of chemically separated NMP from SNF showed that these were well-crystallized nanoparticles containing Mo, Tc, Ru, Rh, and Pd with some evidence of actinides. These same chemically separated particles were re-characterized following 10 years of storage as the separated material in water. Scanning Transmission Electron Microscopy (STEM) analysis revealed that significant alteration had occurred in this material during storage, resulting in the almost complete degradation of the NMP. We hypothesized that radiolytic damaged had occurred in the material. To support these concepts, we synthesized a mixed Ru-Pd nanoparticle and subjected it to irradiation in the electron microscope in an in-situ liquid cell. We demonstrated that intense radiation can lead to the decomposition of these metallic particles.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Improving Scientific Capabilities in Space in the 21st Century: The NASA New Millennium Program

NASA's New Millennium Program (NMP) has been chartered to identify and validate in space emerging, revolutionary technologies that will enable less costly, more capable future science missions. The program utilizes a unique blend of science guidance and industry partnering to ferret out technology solutions to enable science capabilities in space which are presently technically infeasible, or unaffordable. Those technologies which present an unacceptably high risk to future science missions (whether small PI-led or operational) are bundled into technology validation missions. These missions seek to validate the technologies in a manner consistent with their future uses, thus reducing the associated risk to the first user, and obtaining meaningful science data as well. The Space Readiness Coherent Lidar Experiment (SPARCLE) was approved as the second NMP Earth Observing mission (EO2) in October 1997, and assigned to Marshall Space Flight Center for implementation. Leading up to mission confirmation, NMP sponsored a community workshop in March 1996 to draft Level-1 requirements for a doppler wind lidar mission, as well as other space-based lidar missions (such as DIAL). Subsequently, a study group was formed and met twice to make recommendations on how to perform a comparison of coherent and direct detection wind lidars in space. These recommendations have guided the science validation plan for the SPARCLE mission, and will ensure that future users will be able to confidently assess the risk profile of future doppler wind missions utilizing EO2 technologies. The primary risks to be retired are: (1) Maintenance of optical alignments through launch and operations on orbit, and (2) Successful velocity estimation compensation for the Doppler shift due to the platform motion, and due to the earth's rotation. This includes the need to account for all sources of error associated with pointing control and knowledge. The validation objectives are: (1) Demonstrate measurement of tropospheric winds from space using a scanning coherent Doppler lidar technique that scales to meet future research (e.g. ESSP) and operational (e.g. NPOESS) mission requirements. Specifically, produce and validate LOS wind data with single shot accuracy of 1-2 m/s in regions of high signal-to-noise ratio (SNR), and low atmospheric wind turbulence and wind shear, (2) Collect the atmospheric and instrument performance data in various scanning modes necessary to validate and improve instrument performance models that will enable the definition of future missions with greater confidence. Such data include aerosol backscatter data over much of the globe, and high SNR data such as that from surface returns, and (3) Produce a set of raw instrument data with which advanced signal processing techniques can be developed. This objective will permit future missions to better understand how to extract wind information from low backscatter regions of the atmosphere.

Raymond, Carol A.↗

The New Millennium Program: Validating Advanced Technologies for Future Space Missions

This presentation reviews the activities of the New Millennium Program (NMP) in validating advanced technologies for space missions. The focus of these breakthrough technologies are to enable new capabilities to fulfill the science needs, while reducing costs of future missions. There is a broad spectrum of NMP partners, including government agencies, universities and private industry. The DS-1 was launched on October 24, 1998. Amongst the technologies validated by the NMP on DS-1 are: a Low Power Electronics Experiment, the Power Activation and Switching Module, Multi-Functional Structures. The first two of these technologies are operational and the data analysis is still ongoing. The third program is also operational, and its performance parameters have been verified. The second program, DS-2, was launched January 3 1999. It is expected to impact near Mars southern polar region on 3 December 1999. The technologies used on this mission awaiting validation are an advanced microcontroller, a power microelectronics unit, an evolved water experiment and soil thermal conductivity experiment, Lithium-Thionyl Chloride batteries, the flexible cable interconnect, aeroshell/entry system, and a compact telecom system. EO-1 on schedule for launch in December 1999 carries several technologies to be validated. Amongst these are: a Carbon-Carbon Radiator, an X-band Phased Array Antenna, a pulsed plasma thruster, a wideband advanced recorder processor, an atmospheric corrector, lightweight flexible solar arrays, Advanced Land Imager and the Hyperion instrument

Minning, Charles P.↗

Space Technology 5: Pathfinder for Future Micro-Sat Constellations

The Space Technology 5 (ST-5) Project, currently in the implementation phase, is part of the National Aeronautics and Space Administration (NASA) s New Millennium Program (NMP). ST-5 will consist of a constellation of three miniature satellites, each with mass less than 25 kg and size approximately 60 cm by 30 cm. ST-5 addresses technology challenges, as well as fabrication, assembly, test and operations strategies for future micro-satellite missions. ST-5 will be deployed into a highly eccentric, geo-transfer orbit (GTO). This will expose the spacecraft to a high radiation environment as well as provide a low level magnetic background. A three-month flight demonstration phase is planned to validate the technologies and demonstrate concepts for future missions. Each ST-5 spacecraft incorporates NMP competitively-selected breakthrough technologies. These include Cold Gas Micro-Thrusters for propulsion and attitude control, miniature X-band transponder for space-ground communications, Variable Emittance Coatings for dynamic thermal control, and CULPRiT ultra low power logic chip used for Reed-Solomon encoding. The ST-5 spacecraft itself is a technology that can be infused into future missions. It is a fully functional micro-spacecraft built within tight volume and mass constraints. It is built to withstand a high radiation environment, large thermal variations, and high launch loads. The spacecraft power system is low-power and low-voltage, and is designed to turn on after separation &om the launch vehicle. Some of the innovations that are included in the ST-5 design are a custom spacecraft deployment structure, magnetometer deployment boom, nutation damper, X-band antenna, miniature spinning sun sensor, solar array with triple junction solar cells, integral card cage assembly containing single card Command and Data Handling and Power System Electronics, miniature magnetometer, and lithium ion battery. ST-5 will demonstrate the ability of a micro satellite to perform research-quality science. Each ST-5 spacecraft will deploy a precision magnetometer to be used both for attitude determination and as a representative science instrument. The spacecraft has been developed with a low magnetic signature to avoid interference with the magnetometer. The spacecraft will be able to detect and respond autonomously to science events, i.e. significant changes in the magnetic field measurements. The three spacecraft will be a pathfinder for future constellation missions. They will be deployed to demonstrate an appropriate geometry for scientific measurements as a constellation. They will be operationally managed as a constellation, demonstrating automation and communication strategies that will be useful for future missions. The technologies and future mission concepts will be validated both on the ground and in space. Technologies will be validated on the ground by a combination of component level and system level testing of the flight hardware in a thermal vacuum environment. In flight, specific validation runs are planned for each of the technologies. Each validation run consists of one or more orbits with a specific validation objective. This paper will describe the ST-5 mission, and the applicability of the NMP technologies, spacecraft, and mission concepts to future missions. It will also discuss the validation approach for the ST-5 technologies and mission concepts.

Carlisle, Candace↗

Fabrication of Polyimide-Matrix/Carbon and Boron-Fiber Tape

The term HYCARB denotes a hybrid composite of polyimide matrices reinforced with carbon and boron fibers. HYCARB and an improved process for fabricating dry HYCARB tapes have been invented in a continuing effort to develop lightweight, strong composite materials for aerospace vehicles. Like other composite tapes in this line of development, HYCARB tapes are intended to be used to build up laminated structures having possibly complex shapes by means of automated tow placement (ATP) - a process in which a computer-controlled multiaxis machine lays down prepreg tape or tows. The special significance of the present process for making dry HYCARB for ATP is that it contributes to the reduction of the overall cost of manufacturing boron-reinforced composite-material structures while making it possible to realize increased compression strengths. The present process for making HYCARB tapes incorporates a "wet to dry" process developed previously at Langley Research Center. In the "wet to dry" process, a flattened bundle of carbon fiber tows, pulled along a continuous production line between pairs of rollers, is impregnated with a solution of a poly(amide acid) in N-methyl-2-pyrrolidinone (NMP), then most of the NMP is removed by evaporation in hot air. In the present case, the polyamide acid is, more specifically, that of LaRC. IAX (or equivalent) thermoplastic polyimide, and the fibers are, more specifically, Manganite IM7 (or equivalent) polyacrylonitrile- based carbon filaments that have a diameter of 5.2 m and are supplied in 12,000-filament tows. The present process stands in contrast to a prior process in which HYCARB tape was made by pressing boron fibers into the face of a wet carbon-fiber/ poly(amide acid) prepreg tape . that is, a prepreg tape from which the NMP solvent had not been removed. In the present process, one or more layer(s) of side-by-side boron fibers are pressed between dry prepreg tapes that have been prepared by the aforementioned gwet to dry h process. The multilayer tape is then heated to imidize the matrix material and remove most of the remaining solvent, and is pressed to consolidate the multiple layers into a dense tape. For tests, specimens of HYCARB tapes and laminated composite panels made from HYCARB tape were prepared as follows: HYCARB tapes were fabricated as described above. Each panel was made by laying down ten layers of tape, containing, variously, one, two, or three boron-fiber plies and the remainder carbon- fiber-only plies (see figure). Each panel was made by laying down ten layers of tape. Each panel was then cured by heating to a temperature of 225 C for 15 minutes, then pressing at 200 psi (A1.4 MPa) while heating to 371 C, holding at 371 C for 1 hour, then continuing to hold pressure during cooling. Control specimens that were otherwise identical except that they did not contain boron fibers also were prepared. In room-temperature flexural tests, the HYCARB specimens performed comparably to the control specimens; in room-temperature, open-hole compression tests, the HYCARB specimens performed slightly better, by amounts that increased with boron content.

Belvin, Harry L.↗

Modeling and analysis of solvent removal during Li-ion battery electrode drying

In this paper, we study the design aspects and process dynamics of solvent removal from Lithium-ion battery electrode coatings. For this, we use a continuum level mathematical model to describe the physical phenomenon of cathode drying involving coupled simultaneous heat and mass transfer with phase change. Our results indicate that around 90% of solvent is removed in less than half of the overall drying time. We study the effect of varying temperature and air velocity on the drying process. We show that the overall drying energy can be reduced by at least 50% by using a multi-zone drying process. Also, the peak solvent flux can be reduced by at least 40%. We further present the effect of using an aqueous solvent instead of N-Methyl-2-pyrrolidone (NMP) in electrode drying. Our results indicate that Water dries nearly 4.5 times faster as compared to NMP and requires nearly 10 times less overall drying energy per kg of solvent.

25 ENERGY STORAGE↗

The New Millennium Program: Technology for the 21(sup st) Century

NASA's New Millennium Program (NMP) is a space flight technology demonstration program that will validate the technologies needed to carry out the science missions that NASA envisions for the 21(sup st)century. The NMP is employing an innovative decision making process to select the specific technologies that will be flight validated.

Space flight technology decision-making process NM↗