Modeling the ecosystem services of native vegetation management practices at solar energy facilities in the Midwestern United States
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54 ENVIRONMENTAL SCIENCES↗
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Variation in energy balance components from six sites in a native prairie for three years
Six automatic stations were used to evaluate the surface energy and radiation balances on a native prairie near Manhattan, Kansas, using the Bowen ratio technique for a total of 300 days. Data were taken during the periods from May 26 to October 16, 1987, May 10 to September 18, 1988, and July 21 to August 13, 1989. The station site locations were selected to represent burned and unburned treatments on ridges, valley bottoms, and slopes with various aspects. The measured variables were (1) air and wet bulb temperatures at two heights, (2) net radiation, (3) solar radiation (up and down), (4) total hemispherical radiation (up and down), (5) diffuse radiation, (6) soil heat flow and soil temperature, (7) wind speed, (8) wind direction, and (9) precipitation. Energy balance components at the sites were compared for the 3 years. The variation between sites and years was small, even though some sites were as much as 10 km apart and the years had different rainfall amounts. The average values for the four summer intensive field campaigns (IFCs) were as follows: albedo, 0.2; ratio of net radiation to solar radiation, 62 percent; evaporation equivalent, 4 mm/d; Bowen ratio, 0.32; evaporation fraction, 70 percent; and the ratio of evaporation to solar energy, 40 percent. These values were different for the fall IFC. The latent and sensible heat fluxes were more variable than the radiation terms reflecting soil moisture differences between IFCs.
Fritschen, Leo J.↗
Defect Stability in CdTe Based on Formation Energies and Migration Barriers
Native point defects are thought to play a key role in CdTe, either as compensation centers in intentionally doped material, as a source of conductivity in nominally undoped material, or as electron–hole recombination centers. Here, the discussion of their concentration and impact has often centered only on formation energies and transition levels. Using hybrid density functional calculations, including the effects of spin–orbit coupling (SOC), we discuss the stability of native point defects in CdTe based on their formation energies and migration barriers. We show that although Cd interstitials are the lowest energy donor defects, they are unstable at room temperature due to a low migration barrier. They are important for maintaining charge neutrality during growth or annealing at high temperatures, but once the material is brought to room temperature, they are not frozen in as often assumed and are expected to anneal out, leaving the other more stable defects to determine the conductivity. Taking this into account in the solution of the charge neutrality equation, we are able to predict the conductivity type and carrier concentrations that are in good agreement with experimental observations.
14 SOLAR ENERGY↗
White Earth Community Facilities Solar PV Project (Final Report)
Funded project was for the design, installation, and performance monitoring of 2 - 11.4 kW AC and 1-38.0 kW AC ground-mount solar installations for three tribal community facilities, for a total 60.8 kW AC, including a daycare facility and two community centers. Of in excess of 120 tribal buildings these facilities had showed the best promise for implementing solar, based upon site characteristics, roof loads, roof orientation and building size. The White Earth Nation seeks to move forward proactively to address the following project goals and objectives: 1) Reduction of energy costs, 2) Increasing energy security for Indian Tribes and tribal members, 3) Adding 60.8 KW in renewable energy generation (solar PV), 4) Offsets, reduces coal-fired electric energy demand by 76,397 kWh, 817,448 Source Energy Btu annually, and S) Meets the overall solar PV target set in the FOA.
14 SOLAR ENERGY↗
Akiachak Energy Efficiency Retrofit Project
The goal of the project is to reduce the overall energy use of the Akiachak Native Community (ANC) by implementing energy efficiency measures in five high-use Tribal buildings. This project will have the following outcomes: Projected annual energy savings of $17,369; projected annual reduction in fuel oil #1 of 1,200 gallons and electricity of 17,751 kWh; annual reduction in carbon dioxide emissions of approximately 60,340 pounds/year. ANC will install energy efficiency measures in the Laundry, Tribal Indian Reorganization Act (IRA) Office, Clinic, Daycare, and Police Station. ANC obtained energy audits on these buildings in 2018, and this project will implement high-payback recommendations such as replacing lighting with LEDs, installing setback thermostats and occupancy sensors, replacing furnaces with more efficient models, replacing the circulation pumps with variable speed ones, air tightening, and adding insulation. Buildings will see energy cost reductions from 15% to 40%. These retrofits will help build ANC’s long-term vision for sustainable energy usage and address the first goal of the Tribal IRA Council’s Energy Efficiency and Conservation Strategy, to “create and maintain functionally appropriate, sustainable, accessible, high quality tribal infrastructure and facilities.” ANC intends to replicate this project by using the resulting energy savings to address audit recommendations in other buildings as well as to demonstrate the value of energy efficiency to community members. Other outcomes will include an increase in community resiliency, reduced dependence on outside shipments of fuel oil, training for maintenance staff, and no-touch control of building appliances to reduce transmission of diseases such as COVID-19.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Akiachak Energy Efficiency Retrofit Project (Final Technical Report)
The Akiachak Native Community (ANC), a federally recognized Yup'ik Tribe, undertook this energy efficiency initiative to enhance energy performance in key community buildings, including the Tribal IRA Office, Laundry, Police Station, Clinic, and Daycare. Through energy audits and upgrades, the project focused on high-impact improvements like air sealing, LED lighting, and programmable thermostats, primarily in the Tribal Office due to funding constraints. The initiative aims to reduce energy waste, lower heating and electricity costs, and improve facility comfort and longevity. The project aims to generate long-term savings for further improvements by decreasing reliance on imported fuel oil. This initiative aligns with the Tribe's vision for responsible energy use, addressing the challenges of high fuel prices in a remote community, and serves as a model for similar efforts in Akiachak and other Alaska Native villages pursuing energy self-reliance.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Aniak Energy Efficiency Retrofit Project
The Native Village of Aniak (NVA) is a remote Yup’ik community in western Alaska. NVA is proposing to install energy efficiency measures in the Tribal Office, Community Center, Association of Village Council Presidents (AVCP) Office, and Duplex. The goal of the project is to reduce the overall energy use of the NVA by implementing energy efficiency measures in four high-use tribal buildings. This project expects to have the following outcomes: projected annual energy savings of approximately $24,238; projected annual reduction in fuel oil of roughly 1,802 gallons and electricity of around 24,537 kWh; and annual reduction in carbon dioxide emissions of approximately 84,594 pounds/year.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
A designed Copper Histidine-brace enzyme for oxidative depolymerization of polysaccharides as a model of lytic polysaccharide monooxygenase
The “Histidine-brace” (His-brace) copper-binding site, composed of Cu(His) 2 with a backbone amine, is found in metalloproteins with diverse functions. A primary example is lytic polysaccharide monooxygenase (LPMO), a class of enzymes that catalyze the oxidative depolymerization of polysaccharides, providing not only an energy source for native microorganisms but also a route to more effective industrial biomass conversion. Despite its importance, how the Cu His-brace site performs this unique and challenging oxidative depolymerization reaction remains to be understood. To answer this question, we have designed a biosynthetic model of LPMO by incorporating the Cu His-brace motif into azurin, an electron transfer protein. Spectroscopic studies, including ultraviolet-visible (UV–Vis) absorption and electron paramagnetic resonance, confirm copper binding at the designed His-brace site. Moreover, the designed protein is catalytically active towards both cellulose and starch, the native substrates of LPMO, generating degraded oligosaccharides with multiturnovers by C1 oxidation. It also performs oxidative cleavage of the model substrate 4-nitrophenyl-D-glucopyranoside, achieving a turnover number ~9% of that of a native LPMO assayed under identical conditions. This work presents a rationally designed artificial metalloenzyme that acts as a structural and functional mimic of LPMO, which provides a promising system for understanding the role of the Cu His-brace site in LPMO activity and potential application in polysaccharide degradation.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Complex Organic Materials on Planetary Satellites and Other Small Bodies of the Solar System
The search for organic materials on small bodies of the Solar System is conducted spectroscopically from Earth-based telescopes and from spacecraft. Although the carbonaceous meteorites carry a significant inventory of complex organic solids, the sources of these meteorites have not been identified. Infrared spectra of a sample of the suspected sources, the C- and D-class asteroids, including new data from the Spitzer Space Telescope, show signatures of silicates, but none diagnostic of organic compounds. In the absence of discrete spectral features, the low albedos and colors in the visible and near-IR spectral regions are the principal links between the organic-bearing meteorites and the asteroids. While Pluto and a few trans-neptunian objects show spectral signatures of frozen CH4. Solid CH3OH has been identified on two Centaur objects in the outer Solar System. In some cases the red colors of those objects suggest the presence of tholins. The VIMS instrument aboard the Cassini spacecraft in orbit around Saturn has detected near-IR spectral features on at least three of Saturn's satellites that are indicative or suggestive of organic molecules. One entire hemisphere of the satellite Iapetus is covered with low-albedo material that shows a spectral signature of aromatic hydrocarbons (3.3 microns) and the -CH2 stretching mode bands of an aliphatic component. Organics absorbing at 3.44 microns are suspected in the region of the south pole of Enceladus, and also on the surface of Phoebe. Organic material may originate on icy bodies in the current epoch by various processes of energy deposition into native material, or they may fall to the surface from an external (probably cometary) source. Some organic material may be pre-solar, having originated in the interstellar medium before the formation of the Solar System. Using the techniques of remote sensing, its detection and analysis are slow and difficult.
Cruikshank, Dale P.↗
Multi-crystal native-SAD phasing at 5 keV with a helium environment
De novo structure determination from single-wavelength anomalous diffraction using native sulfur or phosphorus in biomolecules (native-SAD) is an appealing method to mitigate the labor-intensive production of heavy-atom derivatives and selenomethionyl substitutions. The native-SAD method is particularly attractive for membrane proteins, which are difficult to produce and often recalcitrant to grow into decent-sized crystals. Native-SAD uses lower-energy X-rays to enhance anomalous signals from sulfur or phosphorus. However, at lower energies, the scattering and absorption of air contribute to the background noise, reduce the signals and are thus adverse to native-SAD phasing. We have previously demonstrated native-SAD phasing at an energy of 5 keV in air at the NSLS-II FMX beamline. Here, the use of a helium path developed to reduce both the noise from background scattering and the air absorption of the diffracted X-ray beam are described. The helium path was used for collection of anomalous diffraction data at 5 keV for two proteins: thaumatin and the membrane protein TehA. Although anomalous signals from each individual crystal are very weak, robust anomalous signals are obtained from data assembled from micrometre-sized crystals. The thaumatin structure was determined from 15 microcrystals and the TehA structure from 18 microcrystals. These results demonstrate the usefulness of a helium environment in support of native-SAD phasing at 5 keV.
59 BASIC BIOLOGICAL SCIENCES↗
Energy balance components from six sites in a native prairie
The surface-flux stations investigated are of similar design and operation, but are located on different slopes and aspects and provided data with significant variations. The largest difference between sites is noticed in the data for soil heat-flux density, and the general variability is theorized to be related to treatment and locations. The number of surface-flux stations required for the prairie topography can be inferred from the results of the data analysis.
Fritschen, Leo J.↗
Pitka's Point/St. Mary's Wind Energy Construction Project. Final report
This is the final report for the St. Mary’s/Pitka’s Point Wind Construction Project. Under the project Alaska Village Electric Cooperative, Inc. (AVEC) constructed and commissioned one new 900 kW-capacity wind turbine at a site in Pitka’s Point about 4 miles from the diesel-fired prime power plant in St. Mary’s. The main objective of this project is to generate electric power from a renewable resource in an effort to reduce the local dependency on fuel oil as the sole source of electric power generation. The wind generator’s output augments the prime source generation provided by the diesel-powered generators.
17 WIND ENERGY↗
Ca-41 in iron falls, Grant and Estherville - Production rates and related exposure age calculations
Results are presented of the first phase of a Ca-41 cosmogenic studies program aimed at establishing baseline concentrations and trends in selected meteorites and the use of Ca-41 in estimating exposure ages and preatmospheric meteorite radii. The average Ca-41 saturation activity recorded in four small iron falls is 24 +/-1 dpm/kg. This finding, together with measurements at the center and surface of the large iron Grant, indicates that production of Ca-41 from spallation on iron is weakly dependent on shielding to depths as large as 250 g/sq cm. The (K-41)-Ca-41 exposure age of Grant is estimated at 330 +/-50 My, and an upper limit to its terrestrial age of 43 +/-15 ky. A comparison of the Ca-41 contents of stony and metallic material separated from the mesosiderite Estherville identifies low-energy neutron capture on native Ca as a second important channel of production. It is found that the Ca-41 signal in the stone phase from three meteorites correlates with their size, and that the inferred low-energy neutron fluxes vary by a factor of at least 20.
Fink, D.↗
Shifting from Fossil Fuel Reliance to Green Energy Sovereignty: Ute Mountain Ute Tribe
Self-determination has been an on-going effort for Native American people and gained much traction with the passing of The Energy Policy Act of 2005, which included the Indian Tribal Energy Development and Self-Determination Act. Congress passed this act to assist Native American tribes and Alaska Native villages with planning, development, and assistance to achieve their energy goals. The Ute Mountain Ute Tribe (UMUT) has relied on oil and natural gas for economic support the last 70 years. Burning fossil fuels, along with oil and gas development, decreases the quality of air and leads to increased greenhouse gas emissions. Subsequently, the burning of fossil fuels to produce energy is now more costly than many renewable energy sources, including solar photovoltaic (PV) systems. Environmental stewardship, along with the need to maintain revenue generation, has led UMUT’s efforts to achieve energy self-determinism employing PV and exploring other technology. In the past, the tribe completed a 1 megawatt PV project near Towaoc, Colorado, which serves as a case study on the tribe’s energy goals: a future where renewables will dominate their energy landscape. This paper explores UMUT’s past and on-going efforts toward energy independence and how it relates to the broader landscape of Native American energy sovereignty.
29 ENERGY PLANNING, POLICY, AND ECONOMY↗
Lunar Thermal Wadis and Exploration Rovers: Outpost Productivity and Participatory Exploration
The presentation introduces the concept of a thermal wadi, an engineered source of thermal energy that can be created using native material on the moon or elsewhere to store solar energy for use by various lunar surface assets to survive the extremely cold environment of the lunar night. A principal benefit of this approach to energy storage is the low mass requirement for transportation from Earth derived from the use of the lunar soil, or regolith, as the energy storage medium. The presentation includes a summary of the results of a feasibility study involving the numerical modeling of the performance of a thermal wadi including a manufactured thermal mass, a solar energy reflector, a nighttime thermal energy reflector and a lunar surface rover. The feasibility study shows that sufficient thermal energy can be stored using unconcentrated solar flux to keep a lunar surface rover sufficiently warm throughout a 354 hour lunar night at the lunar equator, and that similar approaches can be used to sustain surface assets during shorter dark periods that occur at the lunar poles. The presentation includes descriptions of a compact lunar rover concept that could be used to manufacture a thermal wadi and could alternatively be used to conduct a variety of high-value tasks on the lunar surface. Such rovers can be produced more easily because the capability for surviving the lunar night is offloaded to the thermal wadi infrastructure. The presentation also includes several concepts for operational scenarios that could be implemented on the moon using the thermal wadi and compact rover concepts in which multiple affordable rovers, operated by multiple terrestrial organizations, can conduct resource prospecting and human exploration site preparation tasks.
Sacksteder, Kurt↗
Technical Assistance Opportunities for Tribes
The National Renewable Energy Laboratory (NREL) offers many forms of technical assistance for Tribes to support local clean energy priorities and challenges. With broad support from the U.S. Department of Energy (DOE) and local partners, NREL provides technical expertise to enable data-driven, informed clean energy decision making. Technical assistance may address energy strategy, project financing, policy design and development, data analysis, economic development, infrastructure planning, energy justice, climate change, resilience, or other energy priorities. NREL has a long history of partnering with Tribes and Tribal organizations, including in Alaska Native Villages where the extreme Arctic climate poses unique energy challenges. NREL works directly with Tribes to find solutions that address their self-defined energy priorities, challenges, and goals.
Alaska native village↗
Respiratory energy demands and scope for demand expansion and destruction
Photosynthesis is the primary energy input to plants, but most plant metabolic processes are powered much or all of the time by ATP and NAD(P)H that come from respiratory oxidation of photosynthetically produced carbohydrates, that is, “dark respiration” (Amthor, 1994). The processes of growth, nutrient uptake and assimilation, active transport, and maintenance are thus all clients of respiration and compete for their share of a respiratory energy budget that is capped by photosynthate income. The economic principle of opportunity cost applies to these clients’ competing demands: spending respiratory energy on process A means missing the benefit of investing that energy in process B (Mahmoudabadi et al., 2019). This principle is key to assessing prospects for crop improvement by metabolic engineering. As de Lorenzo (2015) put it: “metabolism…frames and ultimately resolves whether a given genetic program (existing…or engineered) can be deployed or not.” Foreign or reconfigured native processes bolted on to a crop-plant’s metabolic chassis must compete for respiratory energy with native ones without crashing the energy economy. A proviso on plant carbon budgets is that photosynthetic carbon fixation (“source activity”) can in certain cases increase to meet increased carbon demand (“sink activity”), that is, budget envelopes are not always fixed (Smith et al., 2018). However, as there is some consensus that productivity is most often limited or co-limited by carbon supply (Ainsworth and Long, 2005; Körner, 2015; Sonnewald and Fernie, 2018), we make this our basal assumption in the analyses below.
59 BASIC BIOLOGICAL SCIENCES↗
Proton irradiation damage and annealing effects in ON Semiconductor J-series silicon photomultipliers
Silicon photomultipliers (SiPMs) have become popular light conversion devices in recent years due to their low bias voltage and sensitivity to wavelengths emitted from common scintillating materials. These properties make them particularly attractive for resource-constrained missions such as space-based detector applications. However, the space radiation environment is known to be particularly harsh on semiconductor devices, where high particle fluences can degrade performance over time. The radiation hardness of a particular SiPM, manufactured by ON Semiconductor (formally SensL), has yet to be studied with high energy protons, which are native to the space radiation environment. As such, to study these effects we have irradiated groups of two SiPMs to four different fluences of 800 MeV protons delivered by the accelerator at the Los Alamos Neutron Science Center. Fluences of 1.68 × 10 9 , 1.73 × 10 10 , 6.91 × 10 10 , and 1.73 × 10 11 protons cm –2 , and their corresponding estimated doses of 0.15, 1.55, 6.19, and 15.5 kRad, were chosen based on estimates of the potential exposure a SiPM might receive during an interplanetary space mission lasting 10 years. We report the effects these doses have on dark current and the self-annealing time.
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗