Search NASA⌕ Search

SEARCH · Search NASA

Results for “Nonhydrostatic pressure”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

28 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Improving equations of state calibrations in the toroidal DAC—The case study of molybdenum

We report an updated isothermal equation of state (EoS) of molybdenum (Mo) obtained by compression in beveled and toroidal diamond-anvil cells (DACs). For an improved compression environment, we developed a copper (Cu) pressure-transmitting medium (PTM) for the toroidal diamond-anvil cell samples, as it is a soft metal compared to Mo with a well calibrated EoS. A Ne PTM was used for the conventional beveled DAC samples. The unit-cell volumes of Mo were measured to 336(1) GPa in the Cu PTM and 231.2(6) GPa in the Ne PTM at room temperature. We additionally calculated elastic stiffness and compliance constants and evaluated the uniaxial stress of Mo and Cu with pressure. A new EoS for Mo is presented from data collected in all sample environments and compared to our theoretical predictions as well as previous compression studies of Mo. The (200) lattice plane of Mo produced the lowest volumes across the pressure range of this study for all compression environments, suggesting that it is less affected by nonhydrostatic stresses in the DAC compared to the other observed diffraction planes. The presented Mo EoS is compatible with extrapolations of EoS fits of Mo in helium (He) within ~1% at 330 GPa. Results from this work demonstrate that compressing a sample in a softer metal in the toroidal DAC can improve the compression environment and result in measured sample volumes comparable to those collected in noble-gas media at multi-megabar conditions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Strength, deformation, and equation of state of tungsten carbide to 66 GPa

Here, strength, texture, and equation of state of hexagonal tungsten monocarbide (WC) have been determined under quasi-hydrostatic and non-hydrostatic compression to 66 GPa using angle-dispersive X-ray diffraction in the diamond anvil cell. Quasi-hydrostatic compression in a Ne pressure medium demonstrates that nanocrystalline WC is slightly less incompressible than bulk-scale WC, with respective bulk moduli of K 0 = 377 ± 7 and 397 ± 7 GPa and pressure derivatives K 0 ’ = 3.8 ± 0.3 and 3.7 ±0.3. This decrease in incompressibility with grain size is similar to behavior observed in other ceramics. Under nonhydrostatic compression, WC supports a mean differential stress of ~12-15 GPa at plastic yielding, which occurs at ~30 GPa. Strength in WC is anisotropic, with the (001) plane supporting 29-42% higher stress than stresses calculated from mean strain. Simulations using an Elasto-ViscoPlastic Self-Consistent model indicate that strength inferred from lattice strain theory may be overestimated due to effects of plastic deformation. Plastic deformation generates a texture maximum near $\langle\bar{2}110\rangle$ in the compression orientation, initially through prismatic slip on the {$10\bar{1}0$}$\langle\bar{1}2\bar{1}0\rangle$ and {$10\bar{1}0$}$\langle0001\rangle$ slip systems, followed by activation of pyramidal slip on {$10\bar{1}1$}$\langle\bar{2}113\rangle$ at ~40-50 GPa.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Figuring Out Gas & Galaxies in Enzo (FOGGIE). VI. The Circumgalactic Medium of L * Galaxies Is Supported in an Emergent, Nonhydrostatic Equilibrium

The circumgalactic medium (CGM) is often assumed to exist in or near hydrostatic equilibrium, with the regulation of accretion and the effects of feedback treated as perturbations to a stable balance between gravity and thermal pressure. We investigate global hydrostatic equilibrium in the CGM using four highly resolved L* galaxies from the Figuring Out Gas & Galaxies in Enzo (FOGGIE) project. The FOGGIE simulations were specifically targeted at fine spatial and mass resolution in the CGM (Δx ≲ 1 kpc h –1 and M ≃ 200M ⊙ ). We develop a new analysis framework that calculates the forces provided by thermal pressure gradients, turbulent pressure gradients, ram pressure gradients of large-scale radial bulk flows, centrifugal rotation, and gravity acting on the gas in the CGM. Thermal and turbulent pressure gradients vary strongly on scales of ≲5 kpc throughout the CGM. Thermal pressure gradients provide the main supporting force only beyond ~0.25R 200 , or ~50 kpc at z = 0. Within ~0.25R 200 , turbulent pressure gradients and rotational support provide stronger forces than thermal pressure. More generally, we find that global equilibrium models are neither appropriate nor predictive for the small scales probed by absorption line observations of the CGM. Local conditions generally cannot be derived by assuming a global equilibrium, but an emergent global equilibrium balancing radially inward and outward forces is obtained when averaging over the nonequilibrium local conditions on large scales in space and time. Approximate hydrostatic equilibrium holds only at large distances from galaxies, even when averaging out small-scale variations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Republished: Colossal density-driven resistance response in the negative charge transfer insulator MnS 2

The Mn chalcogenides show a remarkable variation in structural and physical properties with density. In MnS 2 we observe a pronounced difference with the effects of varying hydrostaticity with pressure inducing a structural transition at 300 K. Within the pyrite phase, a colossal electrical resistance drop of 10 8 Ohms is observed by 12 GPa of nonhydrostatic compression at 300 K. DFT simulations reveal the metallization to be unexpectedly driven by previously unoccupied S$^{2-}_2$ σ$^*_{3p}$ antibonding states crossing the Fermi level. This is a seldom seen variant of the charge transfer insulator to metal transition for negative charge transfer insulators which have anions with an unsaturated valence. Finally, by 36 GPa of nonhydrostatic compression, the single presence of the low-spin insulating arsenopyrite (P2 1 /c) phase is confirmed, and the bulk metallicity is broken with the system returning to an insulative electronic state.

36 MATERIALS SCIENCE↗
NASA NTRS1980

The mechanism of growth of quartz crystals into fused silica

It is proposed that the growth of quartz crystals into fused silica is effected by a mechanism involving the breaking of an Si-O bond and its association with an OH group, followed by cooperative motion of the nonbridging oxygen and the hydroxyl group which results in the crystallization of a row of several molecules along a crystalline-amorphous interfacial ledge. This mechanism explains, at least qualitatively, all the results of the earlier experimental study of the dependence of quartz crystal growth upon applied pressure: large negative activation volume; single activation enthalpy below Si-O bond energy; growth velocity constant in time, proportional to the hydroxyl and chlorine content, decreasing with increasing degree of reduction, and enhanced by nonhydrostatic stresses; lower pre-exponential for the synthetic than for the natural silica.

Fratello, V. J.↗
NASA NTRS2000

Evaluation of Bogus Vortex Techniques with Four-Dimensional Variational Data Assimilation

The effectiveness of techniques for creating "bogus" vortices in numerical simulations of hurricanes is examined by using the Penn State/NCAR nonhydrostatic mesoscale model (MM5) and its adjoint system. A series of four-dimensional variational data assimilation (4-D VAR) experiments is conducted to generate an initial vortex for Hurricane Georges (1998) in the Atlantic Ocean by assimilating bogus sea-level pressure and surface wind information into the mesoscale numerical model. Several different strategies are tested for improving the vortex representation. The initial vortices produced by the 4-D VAR technique are able to reproduce many of the structural features of mature hurricanes. The vortices also result in significant improvements to the hurricane forecasts in terms of both intensity and track. In particular, with assimilation of only bogus sea-level pressure information, the response in the wind field is contained largely within the divergent component, with strong convergence leading to strong upward motion near the center. Although the intensity of the initial vortex seems to be well represented, a dramatic spin down of the storm occurs within the first 6 h of the forecast. With assimilation of bogus surface wind data only, an expected dominance of the rotational component of the wind field is generated, but the minimum pressure is adjusted inadequately compared to the actual hurricane minimum pressure. Only when both the bogus surface pressure and wind information are assimilated together does the model produce a vortex that represents the actual intensity of the hurricane and results in significant improvements to forecasts of both hurricane intensity and track.

Pu, Zhao-Xia↗
DOE OSTI2021

Theoretical and experimental studies of compression and shear deformation behavior of Osmium to 280 GPa

Abstract The compression behavior of osmium metal was investigated up to 280 GPa (volume compression V/V o = 0.725) under nonhydrostatic conditions at ambient temperature using angle dispersive axial x-ray diffraction (A-XRD) with a diamond anvil cell (DAC). In addition, shear strength of osmium was measured to 170 GPa using radial x-ray diffraction (R-XRD) technique in DAC. Both diffraction techniques in DAC employed platinum as an internal pressure standard. Density functional theory (DFT) calculations were also performed, and the computed lattice parameters and volumes under compression are in good agreement with the experiments. DFT predicts a monotonous increase in axial ratio ( c/a ) with pressure and the structural anomalies of less than 1% in ( c/a ) ratio reported below 150 GPa were not reproduced in theoretical calculations and hydrostatic measurements. The measured value of shear strength of osmium ( τ ) approaches a limiting value of 6 GPa above a pressure of 50 GPa in contrast to theoretical predictions of 24 GPa and is likely due to imperfections in polycrystalline samples. DFT calculations also enable the studies of shear and tensile deformations. The theoretical ideal shear stress is found along the (001)[1–10] shear direction with the maximal shear stress ∼24 GPa at critical strain ∼0.13.

Lin, Chia-Min↗
NASA NTRS2000

An Interconnected Network of Core-Forming Melts Produced by Shear Deformation

The formation mechanism of terrestrial planetary is still poorly understood, and has been the subject of numerous experimental studies. Several mechanisms have been proposed by which metal-mainly iron with some nickel-could have been extracted from a silicate mantle to form the core. Most recent models involve gravitational sinking of molten metal or metal sulphide through a partially or fully molten mantle that is often referred to as a'magma ocean. Alternative models invoke percolation of molten metal along an interconnected network (that is, porous flow) through a solid silicate matrix. But experimental studies performed at high pressures have shown that, under hydrostatic conditions, these melts do not form an interconnected network, leading to the widespread assumption that formation of metallic cores requires a magma ocean. In contrast, here we present experiments which demonstrate that shear deformation to large strains can interconnect a significant fraction of initially isolated pockets of metal and metal sulphide melts in a solid matrix of polycrystalline olivine. Therefore, in a dynamic (nonhydrostatic) environment, percolation remains a viable mechanism for the segregation and migration of core-forming melts in a solid silicate mantle.

Bruhn, D.↗
NASA NTRS1985

Application of radiative boundary conditions to nonhydrostatic primitive equation models

A procedure is presented for applying a radiative boundary condition to the lateral boundary of a limited domain model. The model considered, the Terminal Area Simulation System (TASS), has nonhydrostatic compressible and unsteady governing equations. The primary applications to date have been studies of downbursts, wind shear, thunderstorms and mass fires. A time-splitting integration is used with TASS, with the acoustic terms being integrated separately with a smaller time step. A first-order closure approximation is employed to ensure subgrid turbulence closure. TASS applications for two-dimensional axisymmetric and three-dimensional simulations are described. The radiative boundary conditions were applied in the two-dimensional case to the temperature, pressure and non-normal velocity components. Solutions in both cases avoided runaway circulations and experienced minimal domain-wide mass loss. Also, distorsion was minimized at the boundaries.

Proctor, F. H.↗
NASA NTRS2006

Internal Structure of Rhea

We model the interior of Rhea on the basis of observational constraints and the results from geodynamical models available in the literature. Ten main types of models are defined, depending on the presence or absence of a high-pressure ice layer (ice II), and the extent of separation of the rock component from the volatiles. The degree-two gravity coefficients are computed for each of these models in order to assess which properties of the interior are likely to be inferred from Cassini radio science measurements scheduled on 26 November 2005. C22 greater than 2.5 x 10(exp -4) indicates that the satellite is undifferentiated, except for a slight increase in density with depth resulting from material self-compression. C22 between 1.67 x 10(exp -4)(lower bound) and 1.90 x 10(exp -4) indicates the presence of a rocky core, whose radius can be determined from the satellite's mass and ices densities, for a given temperature profile. For other values, most of the ten models cannot be distinguished from each other. However, assumptions on the density of the rock phase, presence or absence of ice II, and the degree of differentiation could allow a unique model to be determined in many cases. While the calculation presented in this work assumes that Rhea is in hydrostatic equilibrium, it is likely that Rhea' gravity field is partly affected by nonhydrostatic anomalies.

gravity science↗