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At least 37 records · Page 2

Solar Wind Change Exchange from the Magnetosheath

We report the results of a long (approximately 100 ks) XMM-Newton observation designed to observe solar wind charge exchange emission (SWCX) from Earth's magnetosheath. By luck, the observation took place during a period of minimal solar wind flux so the SWCX emission was also minimal. Never-the-less, there is a significant if not stunning correlation between the observed O VIII count rate and our model for magnetosheath emission. We also report on the observed O VII and O VII emission.

Snowden, Steve↗

Hydrolysis of Small Oxo/Hydroxo Molecules Containing High Oxidation State Actinides (Th, Pa, U, Np, Pu): A Computational Study

The energetics of hydrolysis reactions for high oxidation states of oxo/hydroxo monomeric actinide species (Th IV O 2 , Pa IV O 2 , U IV O 2 , Pa V O 2 (OH), U V O 2 (OH), U VI O 3 , Np VI O 3 , Np VII O 3 (OH), and Pu VII O 3 (OH)) were calculated at the CCSD(T) level. The first step is the formation of a Lewis acid/base adduct with H 2 O (hydration), followed by a proton transfer to form a dihydroxide molecule (hydrolysis); this process is repeated until all oxo groups are hydrolyzed. The physisorption (hydration) for each H 2 O addition was predicted to be exothermic, ca. -20 kcal/mol. The hydrolysis products are preferred energetically over the hydration products for the +IV and +V oxidation states. The compounds with An VI are a turning point in terms of favoring hydration over hydrolysis. For An VII O 3 (OH), hydration products are preferred, and only two waters can bind; the complete hydrolysis process is now endothermic, and the oxidation state for the An in An(OH) 7 is +VI with two OH groups each having one-half an electron. The natural bond order charges and the reaction energies provide insights into the nature of the hydrolysis/hydration processes. The actinide charges and bond ionicity generally decrease across the period. Here, the ionic character decreases as the oxidation state and coordination number increase so that covalency increases moving to the right in the actinide period.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Prediction of Redox Potentials for Different Oxidation States of U, Np, Pu, and Am in Alkaline Aqueous Solution

The redox potentials for U, Np, Pu, and Am for oxidation states +III up to +VIII in alkaline aqueous solutions were predicted using density functional theory (DFT) and small-core pseudopotentials and their basis sets, with a hybrid explicit/implicit solvent model using SHE = 4.28 V. For each oxidation state, various oxo/hydroxo complexes were evaluated resulting in a variety of one-electron redox pathways. For An(VIII/VII) couples, the predicted redox potentials for the [An(VIII)O 5 (OH)] -3 /[An(VII)O 4 (OH) 2 ] -3 , or [An(VIII)O 4 (OH) 2 ] -2 /[An(VII)O 4 (OH) 2 ] -3 couples are in good agreement with existing estimates. For An(VII/VI) redox couples, all couples, particularly [An(VII)O 4 (OH) 2 ] -3 /[An(VI)O 2 (OH) 4 ] -2 , were in agreement with experimental values for U, Np, and Pu, but the results for Am showed larger differences from the estimated potentials. The An(VI/V) couples were consistent with experiment for dioxo/tetrahydroxo couples, and the An(V/IV) couples showed acceptable agreement based on actinide-specific couples, with neutral hydroxides often favored in the +IV state. The An(IV/III) couples were consistent with literature values when modeled as soluble neutral hydroxides. The use of our approach yielded calculated redox potentials that were within ±0.2 V from experimental or estimated values consistent with our prior calculations on redox potentials of actinides from Ac to Am in acidic aqueous solutions. Finally, as a result, this supports the robustness of our DFT-based methodology for predicting actinide redox potentials, offering valuable insights for actinide chemistry in aqueous solutions.

Actinides↗

XMM-Newton Observations of MBM 12: More Constraints on the Solar Wind Charge Exchange and Local Bubble Emissions

We present the first analysis of an XMM-Newton observation of the nearby molecular cloud MBM 12. We find that in the direction of MBM 12 the total O VII (0.57 keV) triplet emission is 1.8(+0.5/-0.6) photons/sq cm/s/sr (or Line Units - LU) while for the O VIII (0.65 keV) line emission we find a 3(sigma) upper limit of <1 LU. We also use a heliospheric model to calculate the O VII and O VIII emission generated by Solar Wind Charge-eXchange (SWCX) which we compare to the XMM-Newton observations. This comparison provides new constraints on the relative heliospheric and Local Bubble contributions to the local diffuse X-ray background. The heliospheric SWCX model predicts 0.82 LU for O VII, which accounts for approx. 46+/-15% of the observed value, and 0.33 LU for the O VIII line emission consistent with the XMM-Newton observed value. We discuss our results in combination with previous observations of the MBM 12 with CHANDRA and Suzaku.

Koutroumpa, Dimitra↗

Dinuclear Complexes of Uranyl, Neptunyl, and Plutonyl: Structures and Oxidation States Revealed by Experiment and Theory

Dinuclear perchlorate complexes of uranium, neptunium, and plutonium were characterized by reactivity and DFT, with results revealing structures containing pentavalent, hexavalent, and heptavalent actinyls, and actinyl-actinyl interactions (AAIs). Electrospray ionization produced native complexes [(AnO 2 ) 2 (ClO 4 ) 3 ] - for An:An = U:U, Np:Np, Pu:Pu, and Np:Pu, which are intuitively formulated as actinyl(V) perchlorates. However, DFT identified lower-energy structures [(AnO 2 )(AnO 3 )(ClO 4 ) 2 (ClO 3 )] - comprising a perchlorate fragmented to ClO 3 , actinyl(VI) cation An VI O 2 2+ , and neutral AnO 3 . For U:U and Np:Np, and Np in Np:Pu, the coordinated AnO 3 is calculated as actinyl(VI) with an equatorial oxo, [O yl =An VI =O yl ][=O eq ], whereas for Pu:Pu, it is plutonyl(V) oxyl, [O yl =Pu V =O yl ][-O eq • ]. The implied lower stability of Pu VI versus Np VI indicates weaker Pu=O eq versus Np=O eq bonding. Adsorption of O 2 by the U:U complex suggests oxidation of U V to U VI , corroborating the assignment of perchlorate [(An V O 2 ) 2 (ClO 4 ) 3 ] - . DFT predicts the O 2 adducts are [(An VI O 2 )(O 2 )(An VI O 2 )(ClO 4 ) 3 ] - with actinyls oxidized from +V to +VI by bridging peroxide, O 2 2- . In accordance with reactivity, O 2- addition is computed as substantially exothermic for U:U and least favorable for Pu:Pu. Collision-induced dissociation of native complexes eliminated ClO 2 to yield [(AnO 2 )(O) 2 (AnO 2 )(ClO 4 ) 2 ] - , in which fragmented O atoms bridge as oxyl O -• and oxo O 2- to yield uranyl(VI) and plutonyl(VI), or as oxos O 2- to yield neptunyl(VII), [O yl =Np VII =O yl ] 3+ .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

X-ray spectra of the Puppis A and the Vela supernova remnants

Low-energy X-ray spectra are presented for the entire Vela supernova remnant (SNR), the two most intense subregions of the Vela SNR, and the Puppis A SNR. Acceptable chi-squared fits are obtained from the model of a high-temperature low-density plasma with Allen cosmic abundances when thermal bremsstrahlung, radiative recombination, line emission, and interstellar absorption are included. A suggested increase of 45-fold in the Si abundance for the entire Vela SNR is found unacceptable by chi-squared tests of the present spectra. The two enhanced regions of Vela are found to have different temperatures. A deficiency of at least a factor of 3 is seen in the O VII and O VIII emission from the entire Vela SNR. Because ultraviolet observations indicate a normal abundance of oxygen, this is interpreted as evidence for the existence of nonequilibrium conditions in the emitting plasma.

Moore, W. E.↗

Carbon and oxygen X-ray line emission from the interstellar medium

A soft X-ray, 0.3-1.0 keV spectrum from a 1 sr region which includes a portion of the North Polar Spur, obtained by three rocketborne lithium-drifted silicon detectors, shows the C V, C VI, O VII and O VIII emission lines. The spectrum is well fitted by a two-component, modified Kato (1976) model, where the coronal emission is in collisional equilibrium, with interstellar medium and North Polar Spur temperatures of 1.1 and 3.8 million K, respectively.

Schnopper, H. W.↗

On the possibility of detecting very hot gas through absorption-line studies

The possibility of detecting hot (T greater than or approximately equal to 10 to the 6th K) diffuse interstellar and intergalactic gas through absorption-line studies is assessed. Optical studies of semiforbidden lines are shown to be just beyond feasibility. X-ray absorption-line studies are concluded to be within the capability of future soft X-ray spectrographs, however. In particular, it is shown that the Bragg crystal spectrometer aboard Einstein could possibly have been used to detect O VII and O VIII lines against the Crab if they are present at plausible levels. Improvement of instrument parameters by only a small factor could make this the most important method available for studying hot interstellar, galactic halo and possibly even intergalactic gas.

York, D. G.↗

Accretion disk corona line emission from X0614+091

The low-mass X-ray binary X0614+091 was observed on 3 days in 1979 with the Einstein Observatory solid state spectrometer and the monitor proportional counter. During the observation with the highest measured flux, corresponding to an X-ray luminosity of 8 x 10(exp 36) erg/s (in the 0.5-20 keV band for an assumed distance of 5 kpc), significant low-energy emission was detected, centered at 0.77 keV, possibly due to line emission for O VII-O VIII and Fe XVII-Fe XIX. The other observations, which were at fluxes lower by a factor of 2, are consistent with the presence of the emission feature. The equivalent width of the feature, 37 +/- 6 eV, is of the same order as equivalent widths previously reported for more luminous low-mass X-ray binaries using grating spectrometer data. The soft X-ray lines could be emitted by gas expected to arise in an accretion disk corona excited by the central source. But to explain the observed feature, most of the corona needs to contribute, or other sources of emission are required.

Christian, D. J.↗

Soft X-ray spectral features in the Seyfert 1 Galaxy NGC4051

We report ASCA observations of NGC 4051 during the PV phase. The time averaged X-ray spectrum is not well fit by a simple power law with an iron K-emission line and shows significant absorption-edge features most probably due to O VII and O VIII and a strong soft excess. This is the first direct measurement of edges in the spectrum of this object and confirms that the X-ray spectrum of NGC 4051 is modified by a 'warm' absorbing gas. The best fit underlying power law index in the 0.4-10 keV band is 1.88. A power law modified by a warm absorber model can partly explain the apparent soft excess and qualitatively fit the SIS spectrum. However, the addition of a black body of kT approx. = 0.1 keV improves the fit considerably. The 90% upper limit on the width of the iron line is 460 eV full width at half maximum (FWHM). Applying the fluorescent iron line model from an accretion disk gives an upper limit of 20 deg for the inclination of the disk.

Mihara, Tatehiro↗

The X-ray and ultraviolet absorbing outflow in 3C 351

3C 351 (z = 0.371), and X-ray-'quiet' quasar, is one of the few quasars showing signs of a 'warm absorber' in its X-ray spectrum; i.e., partially ionized absorbing material in the line of sight whose opacity depends on its ionization structure. The main feature in the X-ray spectrum is a K-edge due to O VII or O VIII. 3C 351 also shows unusually strong, blueshifted, associated, absorption lines in the ultraviolet (Bahcall et al. 1993) including O VI (lambda lambda 1031, 1037). This high ionization state strongly suggests an identification with the X-ray absorber and a site within the active nucleus. In this paper we demonstrate that the X-ray and UV absorption is due to the same material. This is the first confirmed UV/X-ray absorber. Physical conditions of the absorber are determined through the combination of constraints derived from both the X-ray and UV analysis. This highly ionized, outflowing, low-density, high-column density absorber situated outside the broad emission line region (BELR) is a previously unknown component of nuclear material. We rule out the identification of the absorber with a BELR cloud as the physical conditions in the two regions are inconsistent with one another. The effect of the X-ray quietness and IR upturn in the 3C 351 continuum on the BELR is also investigated. The strengths of the high-ionization lines of C IV lambda-1549 and O VI lambda-1034 with respect to Lyman-alpha are systematically lower (up to a factor of 10) in the material ionized by the 3C 351 continuum as compared to those produced by the 'standard' quasar continuum, the strongest effect being on the strength of O VI lambda-1034. We find that for a 3C 351-like continuum, C III) lambda-1909 ceases to be a density indicator.

Mathur, Smita↗

NE VIII lambda 774 and time variable associated absorption in the QSO UM 675

We discuss measurements of Ne VIII lambda 774 absorption and the time variability of other lines in the z(sub a) approximately equal z(sub e) absorption system of the z(sub e) = 2.15 QSO UM 675 (0150-203). The C IV lambda 1549 and N V 1240 doublets at z(sub a) = 2.1340 (shifted approximately 1500 km/s from z(sub e) strengthened by a factor of approximately 3 between observations by Sargent, Boksenberg and Steidel (1981 November) and our earliest measurements (1990 November and December). We have no information on changes in other z(sub a) approximately equal z(sub e) absorption lines. Continued monitoring since 1990 November shows no clear changes in any of the absorptions between approximately 1100 and 1640 A rest. The short timescale of the variability (less than or approximately equal to 2.9 yr rest) strongly suggests that the clouds are dense, compact, close to the QSO, and photoionized by the QSO continuum. If the line variability is caused by changes in the ionization, the timescale requires densities greater than approximately 4000/cu cm. Photoionization calculations place the absorbing clouds within approximately 200 pc of the continuum source. The full range of line ionizations (from Ne VIII lambda 774 to C III lambda 977) in optically thin gas (no Lyman limit) implies that the absorbing regions span a factor of more than approximately 10 in distance or approximately 100 in density. Across these regions, the total hydrogen (H I + H II) column ranges from a few times 10(exp 18)/sq cm in the low-ionization gas to approximately 10(exp 20)/sq cm where the Ne VIII doublet forms. The metallicity is roughly solar or higher, with nitrogen possibly more enhanced by factors of a few. The clouds might contribute significant line emission if they nearly envelop the QSO. The presence of highly ionized Ne VIII lambda 774 absorption near the QSO supports recent studies that link z(sub a) approximately equal to z(sub e) systems with X-ray 'wamr absorbers. We show that the Ne VIII absorbing gas would itself produce measurable warm absorption -- characterized by bound-free O VII or O VIII edegs near 0.8 keV -- if the column densities were N(sub H) greater than or approximately equal to 10(exp 21)/sq cm (for solar abundances).

Hamann, Fred↗

The Ionization and Metallicity of the Intervening O VI Absorber at z=0.1212 in the Spectrum of H1821+643

We use high-resolution UV (ultraviolet) spectra of the radio-quiet QSO (quasi-stellar object) H1821+643 (z(sub em) = 0.297), obtained with the Space Telescope Imaging Spectrograph (STIS) and the Far Ultraviolet Spectroscopic Explorer (FUSE), to study the ionization and metallicity of an intervening O VI absorption line system at z(sub abs) = 0.1212. This absorber has the following notable properties: (1) Several galaxies are close to the sight line at the absorber redshift, including an actively star-forming galaxy at a projected distance of 144 h(sub 75)(exp -1) kpc. (2) There is a complex cluster of H I Ly(alpha) absorption lines near the O VI redshift, including at least five components spread over a velocity range of approximately 700 km s(exp -1). (3) The strongest Ly(alpha) line in the cluster appears to be composed of a mildly saturated component with a typical b-value blended with a remarkably broad component with b approximately equals 85 km s(exp -1). (4) The O VI absorption is not aligned with the strongest (saturated) H I absorption, but instead is well-aligned with the very broad component. (5) The only detected species (at the 4(sigma) level) are O VI and H I despite coverage of strong transitions of abundant elements (e.g., C II, C III, and C IV). Based on these constraints, we find that the absorption line properties can be produced in collisionally ionized gas with 10(exp 5.3) is equal to or less than T is equal to or less than 10(exp 5.6) K and -1.8 is equal to or less than [O/H] is equal to or less than -0.6. However, we find that photoionization is also viable if the pathlength l through the absorbing gas is long enough; simple photoionization models require 85 is equal to or less than l is equal to or less than 1900 kpc and -1.1 is equal to or less than [O/H] is equal to or less than -0.3. We briefly discuss how observations of X-ray absorption lines due to O VII and O VIII could be used, in principle, to break the ionization mechanism degeneracy, and we conclude with some comments regarding the nature of O VI absorbers.

Tripp, Todd M.↗

Probing the Reverse Shock in an Oxygen-Rich Supernova Remnant

The aim of this proposal was to examine the O VI emission at three positions around the X-ray bright ring of the remnant in order to investigate the relation between the O VI emission, the X-ray O VII and O VIII emission, and the optical [O III] emission, and how these vary around the rim of the remnant. So far, only one Far Ultraviolet Spectroscopic Explorer (FUSE) pointing at the remnant has been performed, together with the background pointing needed to subtract the diffuse scattered light from nearby O stars. The data were recalibrated using the CalFUSE calibration pipeline, but the emission is faint enough that hand processing will be needed for this pointing to optimize the extraction. Rereduction of the data is underway. A postdoctoral fellow has also been hired, and in part she will assist with the analysis.

Sonneborn, George↗

Simultaneous UV and X-ray Spectroscopy of the Seyfert 1 Galaxy NGC 5548. I: Physical Conditions in the UV Absorbers

We present new UV spectra of the nucleus of the Seyfert 1 galaxy NGC 5548, which we obtained with the Space Telescope Imaging Spectrograph at high spectral resolution, in conjunction with simultaneous Chandra X-ray Observatory spectra. Taking advantage of the low UV continuum and broad emission-line fluxes, we have determined that the deepest UV absorption component covers at least a portion of the inner, high-ionization narrow-line region (NLR). We find nonunity covering factors in the cores of several kinematic components, which increase the column density measurements of N V and C IV by factors of 1.2 to 1.9 over the full-covering case; however, the revised columns have only a minor effect on the parameters derived from our photoionization models. For the first time, we have simultaneous N V and C IV columns for component 1 (at -1040 km/s), and find that this component cannot be an X-ray warm absorber, contrary to our previous claim based on nonsimultaneous observations. We find that models of the absorbers based on solar abundances severely overpredict the O VI columns previously obtained with the Far Ultraviolet Spectrograph, and present arguments that this is not likely due to variability. However, models that include either enhanced nitrogen (twice solar) or dust, with strong depletion of carbon in either case, are successful in matching all of the observed ionic columns. These models result in substantially lower ionization parameters and total column densities compared to dust-free solar-abundance models, and produce little O VII or O VIII, indicating that none of the UV absorbers are X-ray warm absorbers.

Crenshaw, D. M.↗

RGS Spectroscopy of the Cygnus Loop XA Knot

The observations were performed at the end of April 2002, and the data were received in July 2002. Unfortunately, the observations were badly compromised by high levels of background radiation; one the three observations lost entirely. Two replacement observations were scheduled for November 2002, and were only made available in January of 2003. Consequently, we have had little time to grapple with the unusual data analysis challenges. The search for a postdoctoral fellow has been successfully concluded, and Manami Sasaki began working for us in January 2003. She will be supported in part by these funds, and will be working to help understand these data. Examination of the RGS 'Orders' images indicate the presence of broad emission lines (as expected for the diffuse XA knot). However, examination of the 'Spatial' dispersion/cross-dispersion images indicate that the emission is also broad in the cross-dispersion direction. (As a crosscheck, some of the 'Lockman Hole' datasets were also examined as representative 'sky background' datasets; in these, both types of images are relatively flat (outside the calibration source regions). The quicklook plots of the spectra show the expected O VII and O VIII lines, in addition to a complex around 35 Angstroms; the approx. 35 Angstrom line is likely the C V He-beta line at 34.97 Angstrom, but identifying the additional line(s) will require a more careful reduction of the data. Consequently, there is valuable information to be extracted from these data, but it is complicated by diffuse nature of the emission. Because the angular scale is large, we will have to make use of sky background datasets in order to do the background fitting. A color composite image of OM data in the three UV bands was presented at the 'How does the Galaxy Work?' meeting, and compared to optical and X-ray imaging data. Quantitative analysis will require obtaining the effective bandpasses of the UV filters so that the predominant line and continuum contributions can be identified using plasma shock emission models. In view of the facts that the data were only obtained relatively recently, and the complexity of the data analysis, we request a one year no-cost extension on the grant.

Gaetz, Terrance J.↗

Simultaneous FUSE, HST, and Chandra Observations or Intrinsic Absorbers in NGC 7469 and MRK 279

We obtained FUSE observations of NGC 7469 on 2002 Dec 13 & 14. The two exposures totaled only 7 ks. The observations only have good data in one channel, LiF1, due to channel alignment problems. These observations were obtained simultaneously with high-quality HST/STIS and Chandra HETG spectra. The previously known O VI absorption lines in the FUSE spectrum are detected at good signal to noise ratio, and a wide array of other intrinsic absorption lines are visible in the X-ray spectrum and in the STIS spectrum. Compared to prior FUSE observations, the continuum flux for this observation was 50% lower. We see the effects of this in the lowest-velocity O VI absorber, which we associate with the X-ray absorbing gas also detected in this object. This O VI absorber has only a 50% covering fraction, consistent with its covering only the continuum in this source, and its strength and inferred column density increased as the continuum flux of NGC 7469 decreased. This is consistent with the recombination expected from photoionization models of the highly ionized gas. We obtained FUSE observations of Mrk 279 on 2002 May 18. As for NGC 7469, channel alignment problems led to good data being present only in LiFl. While we obtained a much longer integration on the target than planned (47.4 ks vs. 31 ks requested), the UV flux was down a factor of 10 or more from previous HST and FUSE observations, and our wavelength coverage was restricted due to the channel alignment problems. These data still cover the important O VI emission line and absorption lines in Mrk 279. The FUSE flux also agrees well with the simultaneous HST STIS data, which have good signal to noise. We have also analyzed FUSE observations made at three earlier epochs. We detect the Fe K-alpha emission line in the Chandra spectrum, and its flux is consistent with the low X-ray continuum flux level of Mrk 279 at the time of the observation. Because of low signal-to-noise ratios (S/N) in the Chandra spectrum, no O VII or O VIII absorption features are observable in the Chandra data, but the UV spectra reveal strong and complex absorption from H I and high-ionization species such as O VI, N V, and C IV, as well as from low-ionization species such as C III, N III, C II, and N II in some velocity components. The far-UV spectral coverage of the FUSE data provides information on high-order Lyman series absorption, which we use to calculate the optical depths and line and continuum covering fractions in the intrinsic H I absorbing gas in a self-consistent fashion. Based on the velocities, profile shapes, covering fractions and variability of the UV absorption, we conclude that some of the absorption components, particularly those showing prominent low-ionization lines, are likely associated with the host galaxy of Mrk 279, and possibly with its interaction with a close companion galaxy, while the remainder arises in a nuclear outflow.

Sonneborn, George↗

K-shell Photoabsorption of Oxygen Ions

The high spectral resolutions of the Chandra and XMM-Newton X-ray observatories have unveiled the useful diagnostic possibilities of oxygen K absorption. To mention a few, strong O VII and O VIII edges are almost ubiquitous in the spectra of Seyfert 1 galaxies which have been used by Lee et al. (2001) to predict of a warm dust absorber along the line of sight; although this conclusion has been criticized in the light of a data reanalysis (SA0 et al. 2003), Steenbrugge et al. (2003) have detected inner-shell transitions of O III-O VI in the spectrum of NGC 5548 that point to a warm absorber that spans three orders of magnitude in ionization parameter. Moreover, Behar et al. (2003) have stressed that, in the case of both Seyfert 1 and Seyfert 2 galaxies, a broad range of oxygen charge states are usually observed along the line of sight that must be fitted simultaneously, and may imply strong density gradients of 2-4 orders of magnitude over short distances.

Garcia, J.↗