Ozone Variability and Tendencies in the Upper Troposphere and Lower Stratosphere Based on Aura MLS an Sonde Data
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Froidevaux, Lucien↗
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Cluster-based Characterization of Multi-dimensional Tropospheric Ozone Variability in Coastal Regions: An Analysis of Lidar Measurements and Model Results
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Claudia Bernier↗
Variability in Ozone in the Tropical Upper Troposphere-Lower Stratosphere from the 1998-2000 SHADOZ (Southern Hemisphere Additional Ozonesondes) Data
The first view of lower stratospheric and upper tropospheric structure from sondes is provided by a 3-year, 10-site record from the Southern Hemisphere ADditional OZonesondes (SHADOZ) network: . Observations covering 1998-2000 were made over Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Taking the UT/LS (upper troposphere- lower stratosphere) as the region between 12 and 17 km, we examine ozone variability in this region on a week-to-week and seasonal basis. The tropopause is lower in September-October-November than in March-April-May, when ozone is a minimum at most SHADOZ stations. A zonal wave-one pattern (referring to ozone mixing ratios greater over the Atlantic and adjacent continents than over the Pacific and eastern Indian Ocean), persists all year. The wave, predominantly in the troposphere and with variable magnitude, appears to be due to general circulation - with subsidence over the Atlantic and frequent deep convection over the Pacific and Indian Ocean. The variability of deep convection most prominent at Java, Fiji, Samoa and Natal - is explored in time-vs-altitude ozone curtains. Stratospheric incursions into the troposphere are most prominent in soundings at Irene and Reunion Island.
Thompson, A. M.↗
Variability in total ozone associated with baroclinic waves
One-point regression maps of total ozone formed by regressing the time series of bandpass-filtered geopotential height data have been analyzed against Total Ozone Mapping Spectrometer data. Results obtained reveal a strong signature of baroclinic waves in the ozone variability. The regressed patterns are found to be similar in extent and behavior to the relative vorticity patterns reported by Lim and Wallace (1991).
Mote, Philip W.↗
The temporal behavior of upper stratospheric ozone at low latitudes - Evidence from Nimbus 4 BUV data for short-term responses to solar ultraviolet variability
Ozone mixing ratios at pressure levels near 2 mbar are analyzed for the purpose of estimating the average response of the upper stratospheric ozone to solar UV variability on the time scale of the solar rotation period. The data were obtained from observations made with the Nimbus 4 backscattering UV radiometer in 13 latitude zones between 65 degrees N and 65 degrees S. The anaysis showed that temporal variations are negatively correlated with changes in zonally averaged equivalent temperature measured simultaneously by Nimbus 4 radiometer. A linear regression analysis is performed in order to obtain estimates of the average percent change of ozone at low latitudes, on the considered time scale for given changes in 10.7-cm flux, and in the UV flux model developed by Lean et al. (1982). Reproductions of the ozone profiles are provided.
Hood, L. L.↗
The Contribution of Dynamic Interannual Variability to Ozone Trends
At middle latitudes the total column ozone and the lower stratospheric ozone mixing ratio exhibit natural variability. Models and statistical analyses of observations such as SAGE ozone profiles and TOMS column measurements show that seasonal cycle, solar cycle, and interannual dynamical variability and dynamical phenomena such as the quasi- biennial oscillation all contribute to ozone variability. These must be accounted for when deriving ozone trends. Systematic or random changes in the atmospheric circulation may also contribute to ozone trends. It is presently unclear how much of the ozone trend derived from observations is due to changes in the chemical composition of the stratosphere and how much is due to changes in the atmospheric circulation. We are attempting to resolve this issue by comparing a twenty-five year simulation of ozone with fixed source gas boundary conditions with an identical simulation with time dependent source gas boundary conditions. Both simulations are driven with output from a general circulation model that produces realistic interannual variability in dynamical forcing. The model trend in ozone due to changes in composition is determined from the difference in these simulations. We compare these trends with trends determined from observations and model output using the same analysis techniques. Initial results emphasize the complications to attribution of observed ozone trends to dynamical and photochemical effects that are due to interrelationships between trends in transport, temperature, and photochemical effects. It may not be possible to describe the ozone trend as a superposition of dynamical and photochemical contributions.
Douglass, Anne↗
Variability of ozone near the tropopause from GASP data
The first 22 months of ozone data from the Global Atmospheric Sampling Program are summarized. Variations in space and time were examined at nearly all scales permitted by the data. Case studies in the tropics suggest that local ozone maxima may be found in or near clouds. Preliminary seasonal mean maps of ozone during spring are presented for the Northern Hemisphere. In the troposphere over the United States during summer there is a distinct midcontinental ozone maximum. There is a diurnal variation in ozone in the upper troposphere and the daily range is about 5 ppbv. Correlations between ozone and other variables are given for the synoptic-scale and on a hemispheric scale. The possible bearing of these results on ozone transport computations is discussed.
Nastrom, G. D.↗
Stratospheric Impact on the Northern Hemisphere Winter and Spring Ozone Interannual Variability in the Troposphere
In this study we use ozone and stratospheric ozone tracer simulations from the high-resolution (0.5°x0.5°) Goddard Earth Observing System, Version 5 (GEOS-5) in a replay mode to study the impact of stratospheric ozone on tropospheric ozone interannual variability (IAV). We use these simulations in conjunction with ozone sonde measurements from 1990 to 2016 during the winter and spring seasons. The simulations include a stratospheric ozone tracer (StratO3) to aid 15in the evaluation of the impact of stratospheric ozone IAV on the IAV of tropospheric ozone at different altitudes and location. The model is in good agreement with the observed interannual variation of tropospheric ozone, except for the post-Pinatubo period(1992-1994)over the region of North America. Ozone sonde data show a negative ozone anomaly in 1992-1994 following the Pinatubo eruption, with recovery thereafter. The simulated anomaly is only half the magnitude of that observed. Our analysis suggests that the simulated Stratosphere-troposphere exchange (STE)flux deduced from the analysis 20might be too strong over the North American (50°N-70°N) region after the Mt. Pinatubo eruption in the early 1990s,maskingthe impact of lower stratospheric ozone concentration on tropospheric ozone. European ozone sonde measurements show a similar but weaker ozone depletion after the Mt. Pinatubo eruption, which is fully reproduced by the model. Analysis based on the stratospheric ozone tracer (StratO3) identifies differences in strength and vertical extent of stratospheric ozone impact on the tropospheric ozone interannual variation (IAV)between North America and Europe. Over NorthAmerica25stations, the StratO3IAV has a significant impact on tropospheric ozone from the upper to lower troposphere and explains about 60% and 66% of the simulated ozone IAV at 400 hPa, and ~11% and 34% at 700 hPa in winter and spring respectively. Over European stations, the influence is limited to the middle to upper troposphere, and becomes much smaller at 700 hPa. The Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2)assimilated fields exhibit strong longitudinal variations over northern hemisphere (NH) mid-high latitudes, with lower tropopause height and 30lower geopotential height over North America than Europe. These variations associated with the relevant variations in the location of tropospheric jet flows are responsible for the longitudinal differences in the stratospheric ozone impact, with stronger effects over North America than over Europe
tropospheric ozone IAV, Model, ozonesonde, stratos↗
Interannual Variability of Ozone and Ultraviolet Exposure
Annual zonal averages of ozone amounts from Nimbus-7/TOMS (Total Ozone Mapping Spectrometer) (1979 to 1992) are used to estimate the interannual variability of ozone and UVB (290 - 315 nm) irradiance between plus or minus 60 deg. latitude. Clear-sky interannual ozone and UVB changes are mainly caused by the Quasi Biennial Oscillation (QBO) of stratospheric winds, and can amount to plus or minus 15% at 300 nm and plus or minus 5% at 310 nm (or erythemal irradiance) at the equator and at middle latitudes. Near the equator, the interannual variability of ozone amounts and UV irradiance caused by the combination of the 2.3 year QBO and annual cycles implies that there is about a 5-year periodicity in UVB variability. At higher latitudes, the appearance of the interannual UVB maximum is predicted by the QBO, but without the regular periodicity. The 5-year periodic QBO effects on UVB irradiance are larger than the currently evaluated long-term changes caused by the decrease in ozone amounts.
Herman, J. R.↗
Analysis and interpretation of variabilities in ozone and temperature fields
The temporal and spatial variabilities were studied of short and long term fluctuations in stratospheric ozone and temperature at various pressure levels using several years of ozone, temperature, and solar flux data from Nimbus 4, Nimbus 7, and SME satellites. Some results are as follows: (1) the solar UV flux and various indices of solar activity indicate a strong period at about 5 months; (2) satellite total ozone observations were analyzed using 17 years of data from the Nimbus 4 BUV and the Nimbus 7 SBUV experiments, which show very similar seasonal variations and quasibiennial oscillation (QBO) with some indication of a 4 year component; and (3) the zonal characteristics of both the ozone and temperature trends were derived from ten years of total ozone and 50 mb temperature based on the Nimbus 7 TOMS measurements and the NMC analyses respectively.
Chandra, S.↗
Capturing tropospheric ozone time variability : a study using TES Nadir Retrievals
We perform nadir retrievals of ozone using simulated radiances from ozone-sondes over Bermuda from April 14 to May 25, 1993. Using a novel two-step retrieval strategy, we characterize the sensitivity of TES nadir retrievals to time variations of ozone. 02000 Optical Society of America.
atmospheric ozone retrievals↗
Equatorial ozone profiles from the ground to 52 km during the Southern Hemisphere autumn
The results of an ozone measurement campaign conducted at Natal, Brazil from March 25 to April 15, 1985 are reported. Complete profiles of ozone, pressure, and temperature were obtained from the ground to 52 km, and all of the profiles correspond with site overpasses by ozone instruments on NASA and NOAA satellites. The profiles from this measurement series show reasonable agreement with established satellite climatologies. Stratospheric ozone variability was 2 percent or less during the 3 weeks of the measurement campaign, with stratospheric temperature and pressure variabilities half that amount. Low variability at a single location for this period implies comparable uniformity for ozone profiles over a large area around the measurement site. The auxiliary pressure and temperature profiles presented here allow the use of this data set as a transfer standard between satellite instruments with different fundamental ozone measurements. Finally, the low ozone variability in the stratosphere at Natal during this measurement series should provide an opportunity for high-quality intercomparisons of measured and modeled ozone concentrations in the equatorial stratosphere and lower mesosphere as well as a consistency check among satellite ozone measurements.
Barnes, Robert A.↗
Variability of ozone loss during Arctic winter (1991 to 2000) estimated from UARS Microwave Limb Sounder measurement
A comprehensive analysis of version 5 Upper Atmosphere Research Satellite (UARS) Microwave Limb Sounder (MLS) ozone data using a Lagrangian Transport (LT) model provides estimates of chemical ozone depletion for the 1991-1992 through 1997-1998 Arctic winters. These new estimates give a consistent, three-dimensional picture of ozone loss during seven Arctic winters; previous Arctic ozone loss estimates from MLS were based on various earlier data versions and were done only for late winter and only for a subset of the years observed by MLS. We find large interannual variability in the amount, timing, and patterns of ozone depletion and in the degree to which chemical loss is masked by dynamical processes.
Arctic ozone loss↗
Interannual Variability of Ozone in the Polar Vortex during the Fall Season
Previous analysis has shown that the distribution of O3 at high northern latitudes in the lower-to-middle stratosphere at the beginning of the winter season has a characteristic distribution, which is consistent between in situ and satellite measurements. Initial O3 profiles in the vortex are similar to each other and are quite different from outside the vortex at the same latitude and also from a zonal mean climatology. In the vortex, O3 is nearly constant from 500 to above 800 K with a value near 3 ppmv. Values outside the vortex are up to a factor of 2 higher and increase significantly with potential temperature. Model analysis indicates that the characteristic vortex O3 profiles arise from a combination of seasonally accelerated photochemical loss at high latitudes and minimal transport of air from lower latitudes. Analysis of the relatively high-resolution POAM data shows that these characteristic O3 distributions are consistent from year to year and between the hemispheres. Here we emphasize analysis of the 24-year time series of O3 data from SBUV in the lower-to-middle stratosphere at high latitudes in the fall vortex. We find that the variability of O3 from SBUV is relatively small in this regime and no significant trend is detectable. The implications of the findings for stratospheric O3 chemistry and transport will be explored.
Bhartia, P. K.↗
Satellite Soil Moisture Data Assimilation Impacts on Modeling Weather Variables and Ozone in the Southeastern US – Part 2: Sensitivity to Dry-Deposition Parameterizations
Ozone (O3) dry deposition is a major O3 sink. As a follow-up study of Huang et al. (2021), we quantify the impact of satellite soil moisture (SM) on model representations of this process when different dry-deposition parameterizations are implemented, based on which the implications for interpreting O3 air pollution levels and assessing the O3 impacts on human and ecosystem health are provided. The SM data from NASA's Soil Moisture Active Passive mission are assimilated into the Noah-Multiparameterization (Noah-MP) land surface model within the NASA Land Information System framework, semicoupled with Weather Research and Forecasting model with online Chemistry (WRF-Chem) regional-scale simulations covering the southeastern US. Major changes in the modeling system used include enabling the dynamic vegetation option, adding the irrigation process, and updating the scheme for the surface exchange coefficient. Two dry-deposition schemes are implemented, i.e., the Wesely scheme and a “dynamic” scheme, in the latter of which dry-deposition parameterization is coupled with photosynthesis and vegetation dynamics. It is demonstrated that, when the dynamic scheme is applied, the simulated O3 dry-deposition velocities vd and their stomatal and cuticular portions, as well as the total O3 fluxes Ft, are larger overall; vd and Ft are 2–3 times more sensitive to the SM changes due to the data assimilation (DA). Further, through case studies at two forested sites with different soil types and hydrological regimes, we highlight that, applying the Community Land Model type of SM factor controlling stomatal resistance (i.e., β factor) scheme in replacement of the Noah-type β factor scheme reduced the v(d) sensitivity to SM changes by ∼75 % at one site, while it doubled this sensitivity at the other site. Referring to multiple evaluation datasets, which may be associated with variable extents of uncertainty, the model performance of vegetation, surface fluxes, weather, and surface O3 concentrations shows mixed responses to the DA, some of which display land cover dependency. Finally, using model-derived concentration- and flux-based policy-relevant O3 metrics as well as their matching exposure–response functions, the relative biomass/crop yield losses for several types of vegetation/crops are estimated to be within a wide range of 1 %–17 %. Their sensitivities to the model's dry-deposition scheme and the implementation of SM DA are discussed.
Min Huang↗
Solar variability and ozone
Stratospheric temperature and concentration of ozone above 26 km, as measured by rocket-borne instruments, showed an increase from 1964 to 1969-70, and a decline between 1970 and 1975, closely following the solar cycle, which peaked in 1969 (+0.89 correlation at both 35 and 50 km). Similar correlations were found between the ozone density and the 10.7 cm solar radio flux (as measured by the Nimbus IV satellite), and between ozone column density and the Lyman-alpha flux, both observations being taken over the same 10 month period. A mechanism is hypothesized which would link solar flux variation with both changes in stratospheric temperature and concentration of ozone (which is produced by the photodissociation of stratospheric oxygen molecules by solar radiation in the ultraviolet wavelength region).
Callis, L. B.↗
Tidal influences on vertical diffusion and diurnal variability of ozone in the mesosphere
Possible dynamical influences on the diurnal behavior of ozone are investigated. A time dependent one-dimensional photochemical model is developed for this purpose; all model calculations are made at 70 deg N during summer. It is shown that the vertical diffusion can vary as much as 1 order of magnitude within a day as a result of large changes in the zonal wind induced by atmospheric thermal tides. It is found that by introducing a dissipation time scale for turbulence produced by breaking gravity waves, the agreement with Poker Flat echo data is improved. Comparisons of results from photochemical model calculations, where the vertical diffusion is a function of height only, with those in which the vertical diffusion coefficient is changing in time show large differences in the diurnal behavior of ozone between 70 and 90 km. By including the dynamical effect, much better agreement with the Solar Mesosphere Explorers data is obtained. The results are, however, sensitive to the background zonally averaged wind. The influence of including time-varying vertical diffusion coefficient on the OH densities is also large, especially between 80 and 90 km. This suggests that dynamical effects are important in determining the diurnal behavior of the airglow emission from the Meinel bands.
Bjarnason, Gudmundur G.↗
Observations of, and sources of the spatial and temporal variability of ozone in the middle atmosphere on climatological time scales (OZMAP) and equatorial dynamics: Seasonal variations of ozone trends
The long term trends (least square linear regression with time) of ozone content at seven European, seven North American, three Japanese and two tropical stations during 21 years (1964 to 1984) are analyzed. In all regions negative trends are observed during the 1970s, but are partly compensated by limited periods of positive trends during the late 1960s and late 1970s. Solely the North American ozone data show negative trends in all 10 year periods. When the long term ozone trends are evaluated for each month of the year separately, a seasonal variation is revealed, which in Europe and North America has largest negative trends in late winter and spring. While in Europe the negative trends in winter/spring are partly compensated by positive trends in summer, in North America the summer values reach only zero, retaining the significant negative trend in annual mean values. In contrast to the antarctic ozone hole, the spring reduction of ozone in Europe and in North America is associated with stratospheric temperatures increasing in the analyzed period and therefore is consistent with the major natural ozone production and loss processes.
Entzian, G.↗