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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

The effect of polymer grafting on the mechanical properties of PEG-grafted cellulose nanocrystals in poly(lactic acid)

Poly(lactic acid) (PLA) is a commercially available bio-based polymer that is a potential alternative to many commodity petrochemical-based polymers. However, PLA's thermomechanical properties limit its use in many applications. Incorporating polymer-grafted cellulose nanocrystals (CNCs) is one potential route to improving these mechanical properties. One key challenge in using these polymer-grafted nanoparticles is to understand which variables associated with polymer grafting are most important for improving composite properties. In this work, poly(ethylene glycol)-grafted CNCs are used to study the effects of polymer grafting density and molecular weight on the properties of PLA composites. All CNC nanofillers are found to reinforce PLA above the glass transition temperature, but non-grafted CNCs and CNCs grafted with short PEG chains (<2 kg mol –1 ) are found to cause significant embrittlement, generally resulting in less than 3% elongation-at-break. By grafting higher molecular weight PEG (10 kg mol –1 ) onto the CNCs at a grafting density where the polymer chains are predicted to be in the semi-dilute polymer brush conformation (~0.1 chains nm –2 ), embrittlement can be avoided.

36 MATERIALS SCIENCE↗
DOE OSTI2020

A coarse-grain force field based on quantum mechanics (CGq FF) for molecular dynamics simulation of poly(ethylene glycol)- block -poly(ε-caprolactone) (PEG- b -PCL) micelles

In order to provide the means to predict from molecular dynamics (MD) simulations the structures of copolymer-based micelles in solution, we developed coarse grain force field (CGq FF) parameters for poly(ethylene glycol) (PEG) and for poly(ε-caprolactone) (PCL). A key advance here is the use of quantum mechanics to train the parameters describing the non-bonded (NB) interactions between the CG beads. The functional forms are the same as the MARTINI CG FF so standard MD codes can be used. Our CGq FF describes well the experimentally observed properties for the polymer–air and polymer–water interfaces, indicating the accuracy of the NB interactions. Additionally, the structural properties (density, radius of gyration ( R g ), and end-to-end distance ( h )) match both experiment and all atom (AA) simulations. We illustrate the application of this CGq FF by following the formation of a spherical micelle from 250 chains of PEG 23 - b -PCL 9 diblock copolymer, each block with molecular weight of 1000 Daltons (10 500 beads, corresponding to 123 250 atoms), in a water box with 119 139 water beads (426 553 water molecules).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1977

Two measures of performance in a peg-in-hole manipulation task with force feedback

The results are described from two manipulators on a peg-in-hole task, which is part of a continued effort to develop models for human performance with remote manipulators. Task difficulty is varied by changing the diameter of the peg to be inserted in a 50 mm diameter hole. An automatic measuring system records the distance between the tool being held by the manipulator and the receptacle into which it is to be inserted. The data from repeated insertions are processed by computer to determine task times, accumulated distances, and trajectories. Experiments with both the MA-11 cable-connected master-slave manipulator common to hot cell work and the MA-23 servo-controlled manipulator (with and without force feedback) are described. Comparison of these results with previous results of the Ames Manipulator shows that force feedback provides a consistent advantage.

Hill, J. W.↗
NASA NTRS1986

Rotational modulation and flares on RS CVn and BY Dra-type stars. I - Photometry and spot models for BY Dra, AU Mic, AR Lac, II Peg and V 711 Tau (= HR 1099)

Multicolor wide-band photometry of five active stars is presented. The observations were carried out at several places before, during and after the period of IUE observations for the purpose of determining the location, sizes, and evolution of photospheric spots at the time when chromospheric, transition region, and coronal activity data were obtained from UV and radio observations. II Peg, BY Dra, and AU Mic show fairly stable quasi-sinusoidal light curves, while AR Lac and V 711 Tau show double-peaked light curves. For V 711 Tau, a remarkable evolution of the spotted area extent and/or longitude distribution is found. Small, but definite color variations that are consistent with the cool spot hypothesis have also been detected for BY Dra, II Peg and V 711 Tau.

Rodono, M.↗
NASA NTRS1987

Rotational modulation and flares on RS CVn and BY Dra stars. III - IUE observations of V711 Tau (= HR 1099), II Peg, and AR Lac

Observations of three RS CVn stars, which were obtained over the stellar rotation cycles with the IUE satellite, are presented. Emission lines from high-temperature transition regions and chromospheres analogous to those observed in the solar spectrum were observed. The only visible component of II Peg and both components of V711 Tau and AR Lac appear to be chromospherically active. For the latter systems, the Mg II line surface flux from the G-type star is higher than that from the K subgiant, which dominates the observed UV line flux. Moreover, evidence of long-term ultraviolet variability is presented for AR Lac. The emission line fluxes for II Peg and, marginally, for the other two systems were observed to vary in antiphase with the optical variations at the time of the IUE observations. By comparing the results of Rodono et al. (1986) for two-spot models with the variation of UV line flux, evidence of a close spatial correlation between spot and plagelike features is found.

Rodono, M.↗
NASA NTRS2003

Development of a nanostructured DNA delivery scaffold via electrospinning of PLGA and PLA-PEG block copolymers

The present work utilizes electrospinning to fabricate synthetic polymer/DNA composite scaffolds for therapeutic application in gene delivery for tissue engineering. The scaffolds are non-woven, nano-fibered, membranous structures composed predominantly of poly(lactide-co-glycolide) (PLGA) random copolymer and a poly(D,L-lactide)-poly(ethylene glycol) (PLA-PEG) block copolymer. Release of plasmid DNA from the scaffolds was sustained over a 20-day study period, with maximum release occurring at approximately 2 h. Cumulative release profiles indicated amounts released were approximately 68-80% of the initially loaded DNA. Variations in the PLGA to PLA-PEG block copolymer ratio vastly affected the overall structural morphology, as well as both the rate and efficiency of DNA release. Results indicated that DNA released directly from these electrospun scaffolds was indeed intact, capable of cellular transfection, and successfully encoded the protein beta-galactosidase. When tested under tensile loads, the electrospun polymer/DNA composite scaffolds exhibited tensile moduli of approximately 35 MPa, with approximately 45% strain initially. These values approximate those of skin and cartilage. Taken together, this work represents the first successful demonstration of plasmid DNA incorporation into a polymer scaffold using electrospinning.

Non-NASA Center↗
NASA NTRS2016

LO Peg: Surface Differential Rotation, Flares, and Spot-Topographic Evolution

Using the wealth of ∼24 yr multiband data, we present an in-depth study of the star-spot cycles, surface differential rotations (SDR), optical flares, evolution of star-spot distributions, and coronal activities on the surface of young, single, main-sequence, ultrafast rotator LO Peg. From the long-term V-band photometry, we derive rotational period of LO Peg to be 0.4231 +/- 0.0001 d. Using the seasonal variations on the rotational period, the SDR pattern is investigated, and shows a solar-like pattern of SDR. A cyclic pattern with period of ∼2.7 yr appears to be present in rotational period variation. During the observations, 20 optical flares are detected with a flare frequency of ∼1 flare per two days and with flare energy of ∼10(exp 31-34) erg. The surface coverage of cool spots is found to be in the range of ∼9-26 per cent. It appears that the high- and low-latitude spots are interchanging their positions. Quasi-simultaneous observations in X-ray, UV, and optical photometric bands show a signature of an excess of X-ray and UV activities in spotted regions.

Karmakar, Subhajeet↗
DOE OSTI2020

Transcriptome Analysis of Drought-Resistant and Drought-Sensitive Sorghum ( Sorghum bicolor ) Genotypes in Response to PEG-Induced Drought Stress

Drought is a major limiting factor of crop yields. In response to drought, plants reprogram their gene expression, which ultimately regulates a multitude of biochemical and physiological processes. The timing of this reprogramming and the nature of the drought-regulated genes in different genotypes are thought to confer differential tolerance to drought stress. Sorghum is a highly drought-tolerant crop and has been increasingly used as a model cereal to identify genes that confer tolerance. Also, there is considerable natural variation in resistance to drought in different sorghum genotypes. Here, we evaluated drought resistance in four genotypes to polyethylene glycol (PEG)-induced drought stress at the seedling stage and performed transcriptome analysis in seedlings of sorghum genotypes that are either drought-resistant or drought-sensitive to identify drought-regulated changes in gene expression that are unique to drought-resistant genotypes of sorghum. Our analysis revealed that about 180 genes are differentially regulated in response to drought stress only in drought-resistant genotypes and most of these (over 70%) are up-regulated in response to drought. Among these, about 70 genes are novel with no known function and the remaining are transcription factors, signaling and stress-related proteins implicated in drought tolerance in other crops. This study revealed a set of drought-regulated genes, including many genes encoding uncharacterized proteins that are associated with drought tolerance at the seedling stage.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1996

The X-ray Evidence that the 51 Peg Companion is a Planet

51 Pegasi is a nearby G2-3 V star, which is similar to the Sun. Observers have recently detected and confirmed that 51 Pegasi has sinusoidal radial velocity variations with a period of 4.2 days and amplitude of 59 m/s. The radial velocity, if due to orbital motion around the system center-of-mass, implies a minimum companion mass of 0.47 Jupiter masses, which results from the assumption that the inclination angle of ths system is 90(sup 0) from the line of sight. We argue that the X-ray luminosity on the 51 Peg system implies that the unseen companion is a planet, independent of any assumption about the inclination angle.

51 pegasi 51 peg G2-3 V star↗
DOE OSTI2023

Carbonic Anhydrase Enhanced UV-Crosslinked PEG-DA/PEO Extruded Hydrogel Flexible Filaments and Durable Grids for CO 2 Capture

In this study, poly (ethylene glycol) diacrylate/poly (ethylene oxide) (PEG-DA/PEO) interpenetrating polymer network hydrogels (IPNH) were extruded into 1D filaments and 2D grids. The suitability of this system for enzyme immobilization and CO 2 capture application was validated. IPNH chemical composition was verified spectroscopically using FTIR. The extruded filament had an average tensile strength of 6.5 MPa and elongation at break of 80%. IPNH filament can be twisted and bent and therefore is suitable for further processing using conventional textile fabrication methods. Initial activity recovery of the entrapped carbonic anhydrase (CA) calculated from esterase activity, showed a decrease with an increase in enzyme dose, while activity retention of high enzyme dose samples was over 87% after 150 days of repeated washing and testing. IPNH 2D grids that were assembled into spiral roll structured packings exhibited increased CO 2 capture efficiency with increasing enzyme dose. Long-term CO 2 capture performance of the CA immobilized IPNH structured packing was tested in a continuous solvent recirculation experiment for 1032 h, where 52% of the initial CO 2 capture performance and 34% of the enzyme contribution were retained. These results demonstrate the feasibility of using rapid UV-crosslinking to form enzyme-immobilized hydrogels by a geometrically-controllable extrusion process that uses analogous linear polymers for both viscosity enhancement and chain entanglement purposes, and achieves high activity retention and performance stability of the immobilized CA. Potential uses for this system extend to 3D printing inks and enzyme immobilization matrices for such diverse applications as biocatalytic reactors and biosensor fabrication.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1982

Ultraviolet and X-ray detection of the 56 Peg system (KO 2p + WD)

Both IUE short and long wavelength exposures of the 56 Peg system are discussed. This mild barium star has an X-ray luminosity of 3 x 10 to the 31st power ergs/1, comparable to the rapidly rotating RS CVn binary systems, yet lies in a region of the HR diagram where stellar X-rays are generally not observed. This cool, bright giant is not a rapid rotator and the key to understanding its emission lies in the recent discovery of its white dwarf companion. Accretion onto the white dwarf of approximately 0.1% of the stellar wind of the primary is sufficient to power an X-ray source of the observed luminosity. Reprocessing of the X-rays in the cool dense stellar wind explains the origin of the UV emission line spectrum, and may explain the time varying asymmetry of the Mg 2 kappa line profile that is observed. Graphs which show observed fluxes and wavelengths are discussed.

Schindler, M.↗
NASA NTRS1987

Rotational modulation and flares on RS CVn and BY Dra stars. VI - Physical parameters of the chromospheres/transition regions of V 711 Tau (HR 1099), II Peg and AR Lac during October 1981

Ground-based optical and IUE satellite-ultraviolet observations of three RS CVn stars are combined with density sensitive line ratios and differential emission measure curves to describe the physical conditions in their outer atmospheres. Solar-like densities are found to be representative of average conditions on two of the stars, V 711 Tau and AR Lac. The total radiative losses from these two stars are estimated and found to be larger than the sun by at least two orders of magnitude. Consideration of the volume emitting in two of the principal transition region lines suggests a possible relation between the disk 'filling factor' for these two lines and the dynamo-related Rossby number. Only one hemisphere of the star II Peg, the one showing least evidence of starspots, is similar. On the opposite hemisphere the presence of a discrete emitting region is deduced which is almost coincident in phase with the passage of the dominant optical spot group across the visible disk. The dimensions of this region, and an illustrative interpretation in terms of a large emitting magnetic loop, are discussed. It is compared to large active region loops on the sun.

Byrne, P. B.↗
NASA NTRS1990

Stereo advantage for a peg-in-hole task using a force-feedback manipulator

An improved assessment methodology has been implemented at NOSC and tested using an instrumented peg-in-hole (PiH) taskboard. Several aspects of the methodology are discussed in light of their implications for future studies of manipulator performance. Using a simple (but high-fidelity) force-feedback manipulator, a group of 9 trained operators showed a consistent advantage for stereoscopic TV viewing over monoscopic TV viewing when performing the PiH task. To introduce a controlled element of spatial uncertainty into the testing procedure, taskboard orientation relative to the manipulator and remote video camera head was changed in a randomized order on a trial-by-trial basis. The stereoscopic advantage demonstrated by this study can reasonably be expected to be even more pronounced as the quality of the stereo TV interface is improved and force-feedback provided through the manipulator system is diminished and/or distorted.

Spain, Edward H.↗
NASA NTRS2018

Cloud Atlas: Rotational Modulations in the L/T Transition Brown Dwarf Companion HN Peg B

Time-resolved observations of brown dwarfs' rotational modulations provide powerful insights into the properties of condensate clouds in ultra-cool atmospheres. Multi-wavelength light curves reveal cloud vertical structures, condensate particle sizes, and cloud morphology, which directly constrain condensate cloud and atmospheric circulation models. We report results from Hubble Space Telescope/Wide Field Camera 3 (WFC3) near-infrared G141 taken in six consecutive orbits observations of HNPeg B, an L/T transition brown dwarf companion to a G0V type star. The best-fit sine wave to the 1.1 to 1.7 micron broadband light curve has the amplitude of and period of hour. The modulation amplitude has no detectable wavelength dependence except in the 1.4 micron water absorption band, indicating that the characteristic condensate particle sizes are large (greater than 1 micron). We detect significantly (4.4 sigma) lower modulation amplitude in the 1.4 micron water absorption band, and find that HN Peg B's spectral modulation resembles those of early T type brown dwarfs. We also describe a new empirical interpolation method to remove spectral contamination from the bright host star. This method may be applied in other high-contrast time-resolved observations with WFC3.

brown dwarf↗
NASA NTRS2018

VLTI-GRAVITY Measurements of Cool Evolved Stars I. Variable Photosphere and Extended Atmosphere of the Mira Star R Peg

Context. Dynamic model atmospheres of Mira stars predict variabilities in the photospheric radius and in atmospheric molecular layers which are not yet strongly constrained by observations. Aim. Here we measure the variability of the oxygen-rich Mira star R Peg in near-continuum and molecular bands. Methods. We used near-infrared K-band spectro-interferometry with a spectral resolution of about 4000 obtained at four epochs between post-maximum and minimum visual phases employing the newly available GRAVITY beam combiner at the Very Large Telescope Interferometer (VLTI). Results. Our observations show a continuum radius that is anti-correlated with the visual lightcurve. Uniform disc (UD) angular diameters at a near-continuum wavelength of 2.24 m are steadily increasing with values of 8.7 0.1 mas, 9.4 0.1 mas, 9.8 0.1 mas, and 9.9 0.1 mas at visual phases of 0.15, 0.36, 0.45, 0.53, respectively. UD diameters at a bandpass around 2.05 m, dominated by water vapour, follow the near-continuum variability at larger UD diameters between 10.7 mas and 11.7 mas. UD diameters at the CO 2-0 bandhead, instead, are correlated with the visual lightcurve and anti-correlated with the near-continuum UD diameters, with values between 12.3 mas and 11.7 mas. Conclusions. The observed anti-correlation between continuum radius and visual lightcurve is consistent with an earlier study of the oxygen-rich Mira S Lac, and with recent 1D CODEX dynamic model atmosphere predictions. The amplitude of the variation is comparable to the earlier observations of S Lac, and smaller than predicted by CODEX models. The wavelength-dependent visibility variations at our epochs can be reproduced by a set of CODEX models at model phases between 0.3 and 0.6. The anti-correlation of water vapour and CO contributions at our epochs suggests that these molecules undergo different processes in the extended atmosphere along the stellar cycle. The newly available GRAVITY instrument is suited to conducting longer time series observations, which are needed to provide strong constraints on the model-predicted intra- and inter-cycle variability.

photospheric radius↗