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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Encapsulation of Ba in InSb Framework Introduces Chirality in Clathrate-Like BaIn 4 Sb 4

The discovery of Zintl compounds remains a powerful strategy for identifying materials with tunable electronic and thermal transport properties. During a concerted search for new inorganic clathrates with In–Sb frameworks, we discovered BaIn 4 Sb 4 . The composition of this phase deviates from that expected for a type-I clathrate with tetrahedral coordination of all In and Sb atoms (Ba 8 In 31 Sb 15 ). Instead, in the chiral structure of BaIn 4 Sb 4 (space group P 3 1 21, No. 152), a part of the In atoms have a trigonal planar coordination of 1In + 2Sb, forming Sb 2 –In–In–Sb 2 nonplanar fragments isostructural to diborane(4) B 2 H 4 with D 2 d symmetry. Ba atoms are located inside 16-vertex In 8 Sb 8 polyhedra, which share vertices and edges to form a chiral framework around the 3 1 screw axes. The title compound is electron-balanced, [Ba 2+ ][In 2+ ] 2 [In 3+ ] 2 [Sb3–] 4 , which was confirmed by characterization of the charge and heat transport properties. BaIn 4 Sb 4 exhibits a low thermal conductivity and high Seebeck coefficient, suggesting its untapped potential for thermoelectric applications. Finally, density functional theory (DFT) calculations indicate that chemical doping may enhance carrier concentration and improve the originally low electrical conductivity, thus enhancing thermoelectric performance.

electrical properties↗
NASA NTRS1969

The use of satellite beacons for meteorological research

The use of microwave beacon transmissions from synchronous and near synchronous satellites is discussed as a means of measuring atmospheric absorption. It is suggested that, with a fixed angle of elevation of a synchronous satellite, complete diurnal coverage of the integrated absorption is available. In addition, with refined interferometric equipment, angle of arrival studies can be made and phase deviations measured.

Aarons, J.↗
NASA NTRS1985

Linearity optimization in a class of analog phase modulators

This paper examines the ultimate modulating linearity attainable with a phase modulation technique based on the linear addition of quadrature phase carrier signals which have been multiplied by precisely defined nonlinear transformations of the modulating signal. Optimum gain coefficients are derived and plotted to permit implementation of analog phase modulators capable of exceptionally good linearity of phase deviations as large as 5 radians.

Hearn, C. P.↗
NASA NTRS1989

Development of a class of antennas for space-based Navstar GPS applications

This paper describes the performance of several unique antenna/ground plane configurations currently being developed for the TOPEX satellite and which may also be used for improved ground station operation. These antennas are designed with the objective of achieving nearly hemispherical coverage with sharp pattern cutoff above the horizon together with uniform phase response over the entire coverage area. The most promising of these designs is a uniform choke ring approximately 2 lambda in diameter. The ground planes, when used with the Dorne-Margolin C246 antenna element, produce smooth pattern cutoff of the order of 0.25 dB per deg over 135 deg, excellent LCP rejection, and rms phase deviation of 5-5.7 deg. Other ground plane designs, including larger choke ring structures, slotted ground planes, and the use of absorber material, proved much less effective.

Tranquilla, J. M.↗
NASA NTRS1992

Miniature X-band GaAs MMIC analog and bi-phase modulators for spaceborne communications applications

The design concepts, analyses, and the development of GaAs monolithic microwave integrated circuit (MMIC) linear-phase and digital modulators for the next generation of spaceborne communications systems are summarized. The design approach uses a very compact lumped-element, quadrature hybrid, and MESFET-varactors to provide low-loss and well-controlled phase performance for deep-space transponder (DST) applications. The measured results of the MESFET-diode show a capacitance range of 2:1 under reverse bias, and a Q of 38 at 10 GHz. Three cascaded sections of hybrid-coupled reflection phase shifters have been modeled and simulations performed to provide an X-band (8415 +/- 50 MHz) DST phase modulator with +/-2.5 radians of peak phase deviation.

Mysoor, Narayan R.↗
NASA NTRS1994

Measuring Frequency Instability Of A Large Antenna

Frequency instability of antenna under test determined from measurement of phase deviation between outputs of two antennas. Fiber-optic system used to minimize spurious component of frequency instability contributed by propagation of signal from reference antenna to Allan-variance-measuring instrument. Intended primarily to reveal contributions of wind and air-temperature effects on antenna and beam-waveguide structures to overall frequency instabilities of received signals. Technique simpler, less expensive, potentially capable of providing instability data in shorter measuring times, and more precise.

Otoshi, Tom Y.↗
NASA NTRS1993

The MRIS feasibility study

The Microwave Reflectometer Ionization Sensor (MRIS) is an instrument being developed for use in detecting and ranging of electron density layers in the reentry plasma of a space transfer vehicle. The rationale for the selection of the Double Sideband Suppressed Carrier (DSBSC) system used in the feasibility study for the MRIS is presented. A 25 GHz single-oscillator system and a 220 GHz double-oscillator system are described. The 25 GHz system was constructed and tested in the laboratory and test results are presented. As developed, the system employs a sideband spacing of 160 MHz. Based on an estimated electromagnetic wave velocity in the plasma, a round-trip phase shift measurement accuracy of +/- 7.6 degrees was required for the desired +/- 1/2 cm distance measurement accuracy. The interaction of parallel ground and reflecting planes produces interference that prevents the basic DSBSC system from meeting the accuracy goal so a frequency modulation was added to the system to allow averaging of the measured phase deviation. With an FM deviation of +/- 1 GHz, laboratory measurements were made for distances from 5 to 61 cm tip free space. Accounting for the plasma velocity factor, 82 percent of the data were equal to or better than the desired accuracy. Based on this measured result a sideband spacing to 250 MHz could be expected to yield data approximately 96 percent within the accuracy goal.

Neece, Robert T.↗
NASA NTRS1993

The 24 GHz measurements of 2.2 lambda conical horn antennas illuminating a conducting sheet

Monostatic reflection-coefficient magnitude, absolute value of Gamma, measurements occurring between a radiating horn and a metal reflecting plate are presented for a family of three 2.2 lambda diameter conical horn antennas. The three horns have different aperture phase deviations: 6 deg, 22.5 deg, and 125 deg. Measurements of the magnitude of absolute value of Gamma as a function of horn-plate separation (d) extend from an effective antenna aperture short (d = O) to beyond the far-field boundary (d = 2D(sup 2)/lambda, where D is the antenna diameter). Measurement data are presented with various physical environments for each of the horns. Measured scalar data are compared with theoretical data from two models, a numerical model for a circular waveguide aperture in a ground plane and a scalar diffraction theory model. This work was conducted in support of the development effort for a spaceborne multifrequency microwave reflectometer designed to accurately determine the distance from a space vehicle's surface to a reflecting plasma boundary. The metal reflecting plate was used to simulate the RF reflectivity of a critically dense plasma. The resulting configuration, a ground plane mounted aperture facing a reflecting plane in close proximity, produces a strong interaction between the ground plane and the reflecting plate, especially at integral half-wavelength separations. The transition coefficient is characterized by large amplitude variations.

Cross, A. E.↗
NASA NTRS2018

Radio Science System Design and Measurement Results for the NASA Deep Space Network (DSN)

Radio science measurements have been performed using the NASA Deep Space Network (DSN) with many different spacecraft over several decades. Radio science has been used for the study of planetary atmospheres, the solar corona and the search for gravity waves, among other things. The majority of these measurements are made using the X and Ka-band deep space bands. Although the primary mission for the DSN is tracking, telemetry and command (TT&C) for NASA’s many deep-space spacecraft, radio science measurements continue to be an important secondary mission. The science requirements for these measurements have resulted in stringent performance requirements for both the spacecraft and ground system equipment. In particular, the requirements for amplitude stability, phase stability (Allen deviation) and phase noise are very demanding. The system Allen deviation requirement at Ka-band is < 2.4 E-15 over 1000 seconds, while the phase noise requirement is < -50 dBc/Hz for a 1 Hz offset. Various design techniques have been used for the DSN radio frequency (RF) electronics, high power transmitters and antenna structures to meet the stringent requirements for all 3 of these parameters. Some details for the design techniques will be described in the paper. Another important consideration for a radio science system is the verification approach for components, as well as for individual subsystems and then the overall system. Phase-locked oscillators (PLOs) are one of the key component types that determine overall phase noise and Allen deviation system performance. Measurement techniques used for PLOs, as well as for the overall ground system, will be discussed. Measurement results for the 2 new DSN antennas, recently built under the DSN Aperture Enhancement Project (DAEP) will also be shown. In addition, some recent radio science measurements from the Cassini and JUNO missions, using the new antennas, will be presented.

LaBelle, Remi C.↗
DOE OSTI2023

Large Angle Deviation in Grid-Following IBRs Upon Grid Voltage Dip

In the 2021 Texas Odessa large-scale solar PV tripping events, phase-locked-loop (PLL) loss of synchronism is identified as a major cause of solar PV tripping. When solar PVs detected a large phase angle deviation (e.g., 10 degrees), tripping commands were initiated. Here, the large phase angle deviation was triggered by a transmission line fault 200 miles away, which in turn led to approximately 30% voltage drop in the 345-kV system. This paper offers a plausible reason why grid-following inverter-based resources (IBRs) may experience a large angle deviation upon grid voltage dip. Critical operating conditions contributing to such phenomena are identified via analysis and their effects are demonstrated using electromagnetic transient (EMT) simulation. Furthermore, the effect of converter control, e.g., grid-following control vs. grid-forming control, is examined. It is found from EMT simulation results that frequency and voltage control are helpful in mitigating angle deviation. Furthermore, linear block diagrams are derived to examine why frequency control can effectively suppress large angle deviation.

14 SOLAR ENERGY↗
NASA NTRS1995

Digital signal processing in the radio science stability analyzer

The Telecommunications Division has built a stability analyzer for testing Deep Space Network installations during flight radio science experiments. The low-frequency part of the analyzer operates by digitizing wave signals with bandwidths between 80 Hz and 45 kHz. Processed outputs include spectra of signal, phase, amplitude, and differential phase; time series of the same quantities; and Allan deviation of phase and differential phase. This article documents the digital signal-processing methods programmed into the analyzer.

Greenhall, C. A.↗
NASA NTRS2004

An exact solution for the steady state phase distribution in an array of oscillators coupled on a hexagonal lattice

When electronic oscillators are coupled to nearest neighbors to form an array on a hexagonal lattice, the planar phase distributions desired for excitation of a phased array antenna are not steady state solutions of the governing non-linear equations describing the system. Thus the steady state phase distribution deviates from planar. It is shown to be possible to obtain an exact solution for the steady state phase distribution and thus determine the deviation from the desired planar distribution as a function of beam steering angle.

injection locking↗
DOE OSTI2021

Ethane and methane at high pressures: Structure and stability

We have performed a combined experimental and theoretical study of ethane and methane at high pressures of up to 120 GPa at 300 K using x-ray diffraction and Raman spectroscopies and the USPEX ab initio evolutionary structural search algorithm, respectively. For ethane, we have determined the crystallization point, for room temperature, at 2.7 GPa and also the low pressure crystal structure (phase A). This crystal structure is orientationally disordered (plastic phase) and deviates from the known crystal structures for ethane at low temperatures. Moreover, a pressure induced phase transition has been identified, for the first time, at 13.6 GPa to a monoclinic phase B, the structure of which is solved based on good agreement with the experimental results and theoretical predictions. For methane, our x-ray diffraction measurements are in agreement with the previously reported high-pressure structures and equation of state (EOS). Finally, we have determined the EOSs of ethane and methane, which provides a solid basis for the discussion of their relative stability at high pressures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1996

Evaluation of Two Computational Techniques of Calculating Multipath Using Global Positioning System Carrier Phase Measurements

Two computational techniques are used to calculate differential phase errors on Global Positioning System (GPS) carrier war phase measurements due to certain multipath-producing objects. The two computational techniques are a rigorous computati electromagnetics technique called Geometric Theory of Diffraction (GTD) and the other is a simple ray tracing method. The GTD technique has been used successfully to predict microwave propagation characteristics by taking into account the dominant multipath components due to reflections and diffractions from scattering structures. The ray tracing technique only solves for reflected signals. The results from the two techniques are compared to GPS differential carrier phase ns taken on the ground using a GPS receiver in the presence of typical International Space Station (ISS) interference structures. The calculations produced using the GTD code compared to the measured results better than the ray tracing technique. The agreement was good, demonstrating that the phase errors due to multipath can be modeled and characterized using the GTD technique and characterized to a lesser fidelity using the DECAT technique. However, some discrepancies were observed. Most of the discrepancies occurred at lower devations and were either due to phase center deviations of the antenna, the background multipath environment, or the receiver itself. Selected measured and predicted differential carrier phase error results are presented and compared. Results indicate that reflections and diffractions caused by the multipath producers, located near the GPS antennas, can produce phase shifts of greater than 10 mm, and as high as 95 mm. It should be noted tl the field test configuration was meant to simulate typical ISS structures, but the two environments are not identical. The GZ and DECAT techniques have been used to calculate phase errors due to multipath o the ISS configuration to quantify the expected attitude determination errors.

Gomez, Susan F.↗
DOE OSTI2021

Effects of interaction strength of associating groups on linear and star polymer dynamics

A small number of associating groups incorporated onto a polymer backbone have dramatic effects on the mobility and viscoelastic response of the macromolecules in melts. These associating groups assemble, driving the formation of clusters, whose lifetime affects the properties of the polymers. In this study, we probe the effects of the interaction strength on the structure and dynamics of two topologies, linear and star polymer melts, and further investigate blends of associative and non-associating polymers using molecular dynamics simulations. Polymer chains of approximately one entanglement length are described by a bead–spring model, and the associating groups are incorporated in the form of interacting beads with an interaction strength between them that is varied from 1 to 20 k B T. We find that, for all melts and blends, interaction of a few k B T between the associating groups drives cluster formation, where the size of the clusters increases with increasing interaction strength. These clusters act as physical crosslinkers, which slow the chain mobility. Blends of chains with and without associating groups macroscopically phase separate for interaction strength between the associating groups of a few k B T and above. For weakly interacting associating groups, the static structure function S(q) is well fit by functional form predicted by the random phase approximation where a clear deviation occurs as phase segregation takes place, providing a quantitative assessment of phase segregation.

36 MATERIALS SCIENCE↗
NASA NTRS1985

Maser cavity servo-tuning system

Two collocated, weakly coupled probes, one loop and one dipole, detect the magnetic and electric fields inside a maser cavity. Signals from the probes are compared in phase, and the signal output from the phase detector is applied to a varactor, the reactance of which is coupled into the cavity by a microwave coupler. Alternatively, the varactor may be placed inside the cavity. Any deviation of phase from 90 deg as detected by the phase detector will then produce an error signal that will change the reactance coupled into the resonant cavity to change its reactance, and thus correct its resonance frequency. An alternative to using two probes is to use a single disk probe oriented to detect both the magnetic and electric fields, and thus provide the error signal directly.

Sydnor, R. L.↗