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NASA NTRS2006

Pressure Effects on Oxygen Concentration Flammability Thresholds of Materials for Aerospace Applications

Spacecraft materials selection is based on an upward flammability test conducted in a quiescent environment in the highest-expected oxygen-concentration environment. However, NASA s advanced space exploration program is anticipating using various habitable environments. Because limited data is available to support current program requirements, a different test logic is suggested to address these expanded atmospheric environments through the determination of materials self-extinguishment limits. This paper provides additional pressure effects data on oxygen concentration and partial pressure self-extinguishment limits under quiescent conditions. For the range of total pressures tested, the oxygen concentration and oxygen partial pressure flammability thresholds show a near linear function of total pressure. The oxygen concentration/oxygen partial pressure flammability thresholds depend on the total pressure and appear to increase with increasing oxygen concentration (and oxygen partial pressure). For the Constellation Program, the flammability threshold information will allow NASA to identify materials with increased flammability risk because of oxygen concentration and total pressure changes, minimize potential impacts, and allow for development of sound requirements for new spacecraft and extraterrestrial landers and habitats.

Hirsch, David↗

NASA NTRS1990

Lower solar chromosphere-corona transition region. II - Wave pressure effects for a specific form of the heating function

Lower transition region models with a balance between mechanical heating and radiative losses are expanded to include wave pressure effects. The models are used to study the simple damping length form of the heating function. The results are compared to the results obtained by Woods et al. (1990) for solutions in the lower transition region. The results suggest that a mixture of fast-mode and slow-mode waves may provide the appropriate heating mechanism in the lower transition region, with the decline in effective vertical wave speed caused by the refraction and eventual total reflection of the fast-mode wave resulting from the decreasing atmospheric density.

Woods, D. Tod↗

NASA NTRS1993

Temperature and pressure effects on capacitance probe cryogenic liquid level measurement accuracy

The inaccuracies of liquid nitrogen and liquid hydrogen level measurements by use of a coaxial capacitance probe were investigated as a function of fluid temperatures and pressures. Significant liquid level measurement errors were found to occur due to the changes in the fluids dielectric constants which develop over the operating temperature and pressure ranges of the cryogenic storage tanks. The level measurement inaccuracies can be reduced by using fluid dielectric correction factors based on measured fluid temperatures and pressures. The errors in the corrected liquid level measurements were estimated based on the reported calibration errors of the temperature and pressure measurement systems. Experimental liquid nitrogen (LN2) and liquid hydrogen (LH2) level measurements were obtained using the calibrated capacitance probe equations and also by the dielectric constant correction factor method. The liquid levels obtained by the capacitance probe for the two methods were compared with the liquid level estimated from the fluid temperature profiles. Results show that the dielectric constant corrected liquid levels agreed within 0.5 percent of the temperature profile estimated liquid level. The uncorrected dielectric constant capacitance liquid level measurements deviated from the temperature profile level by more than 5 percent. This paper identifies the magnitude of liquid level measurement error that can occur for LN2 and LH2 fluids due to temperature and pressure effects on the dielectric constants over the tank storage conditions from 5 to 40 psia. A method of reducing the level measurement errors by using dielectric constant correction factors based on fluid temperature and pressure measurements is derived. The improved accuracy by use of the correction factors is experimentally verified by comparing liquid levels derived from fluid temperature profiles.

Edwards, Lawrence G.↗

NASA NTRS1985

Vacuum chamber pressure effects on thrust measurements of low Reynolds number nozzles

Tests were conducted to investigate the effect of vacuum facility pressure on the performance of small thruster nozzles. Thrust measurements of two converging-diverging nozzles with an area ratio of 140 and an orifice plate flowing unheated nitrogen and hydrogen were taken over a wide range of vacuum facility pressures and nozzle throat Reynolds numbers. In the Reynolds number range of 2200 to 12 000 there was no discernable viscous effect on thrust below an ambient to total pressure ratio of 1000. In nearly all cases, flow separation occurred at a pressure ratio of about 1000. This was the upper limit for obtaining an accurate thrust measurement for a conical nozzle with an area ratio of 140.

Sovey, J. S.↗

NASA NTRS1985

Vacuum chamber pressure effects on thrust measurements

Tests were conducted to investigate the effect of vacuum facility pressure on the performance of small thruster nozzles. Thrust measurements of two converging-diverging nozzles with an area ratio of 140 and an orifice plate flowing unheated nitrogen and hydrogen were taken over a wide range of vacuum facility pressures and nozzle throat Reynolds numbers. In the Reynolds number range of 2200 to 12,000 there was no discernable viscous effect on thrust below an ambient to total pressure ratio of 1000. In nearly all cases, flow separation occurred at a pressure ratio of about 1000. This was the upper limit for obtaining an accurate thrust measurement for a conical nozzle with an area ratio of 140.

Sovey, J. S.↗

NASA NTRS1986

Vacuum chamber pressure effects on thrust measurements of low Reynolds number nozzles

Tests were conducted to investigate the effect of vacuum facility pressure on the performance of small thruster nozzles. Thrust measurements of two converging-diverging nozzles with an area ratio of 140 and an orifice plate flowing unheated nitrogen and hydrogen were taken over a wide range of vacuum facility pressures and nozzle throat Reynolds numbers. In the Reynolds number range of 2200 to 12,000 there was no discernable viscous effect on thrust below an ambient to total pressure ratio of 1000. In nearly all cases, flow separation occurred at a pressure ratio of about 1000. This was the upper limit for obtaining an accurate thrust measurement for a conical nozzle with an area ratio of 140.

Sovey, J. S.↗

NASA NTRS1999

Pressure Effect in ZnO Films Using Off-Axis Sputtering Deposition

ZnO films are deposited on (0001) sapphire, (001) Si and quartz substrates using the off-axis reactive magnetron sputtering deposition. Based on film thickness measurements, three transport regions of sputtered particles are observed when films are deposited in the pressure regions of 5 mtorr - 150 mtorr. X-ray diffraction, scanning probes microscopy, and electrical measurements are also used to characterize these films. The full width at half maximum of theta rocking curves for epitaxial films is less than 0.5 deg. In textured films, it rises to several degrees. The epitaxial films deposited at high pressure reveal a flat surface with some hexagonal facets. The density of hexagonal facets decreases when the growth pressure is reduced. The resistivity of these epitaxial films also depends on the growth pressures. A relationship between the pressure effects and film properties are discussed.

Zhu, Shen↗

NASA NTRS2012

Pressure Effects on the Temperature Sensitivity of Fiber Bragg Gratings

A 3-dimensional physical model was developed to relate the wavelength shifts resulting from temperature changes of fiber Bragg gratings (FBGs) to the thermal expansion coefficients, Young s moduli of optical fibers, and thicknesses of coating polymers. Using this model the Bragg wavelength shifts were calculated and compared with the measured wavelength shifts of FBGs with various coating thickness for a finite temperature range. There was a discrepancy between the calculated and measured wavelength shifts. This was attributed to the refractive index change of the fiber core by the thermally induced radial pressure. To further investigate the pressure effects, a small diametric load was applied to a FBG and Bragg wavelength shifts were measured over a temperature range of 4.2 to 300K.

Wu, Meng-Chou↗

NASA NTRS2016

Probabilistic Modeling of Intracranial Pressure Effects on Optic Nerve Biomechanics

Altered intracranial pressure (ICP) is involved/implicated in several ocular conditions: papilledema, glaucoma and Visual Impairment and Intracranial Pressure (VIIP) syndrome. The biomechanical effects of altered ICP on optic nerve head (ONH) tissues in these conditions are uncertain but likely important. We have quantified ICP-induced deformations of ONH tissues, using finite element (FE) and probabilistic modeling (Latin Hypercube Simulations (LHS)) to consider a range of tissue properties and relevant pressures.

biomechanics↗

NASA NTRS1975

Uranian methane abundance, rotational temperature, and effective pressure from the 6800 A band

Measurements of the methane absorption features at 6800 A in two spectrograms of Uranus have been analyzed on the working hypothesis that the features are the R branch of the 5 mu(3) rotation-vibration overtone. Internal and external consistencies in temperature calculations from the measurements give increased confidence that the band identification and rotational-quantum-number assignments to band members are correct. Parametric fitting of synthetic reflecting-layer and homogeneous scattering-layer spectra to the spectrograms is attempted. The best-fit methane abundances, taken with recent estimates of the molecular hydrogen abundance, correspond to an average C:H ratio between 1.5 and 25 times larger than the solar ratio. Even greater enrichment of the C:H ratio may occur below the visible cloud boundary. High spectroscopic resolution of the present data permits direct measurement of the methane line halfwidth in Uranus's spectrum. The halfwidth corresponds to an effective pressure greater than 3 atm, depending on the mixture of atmospheric gases. Pressure in this range, at the methane rotational temperature of between 93 and 100 K, is inconsistent with current Uranus atmosphere models having solar elemental-abundance ratios. It is consistent with models which are considerably enriched in 'heavier' constituents.

Bergstralh, J. T.↗

NASA NTRS1976

Solar radiation pressure effects on the Helios spacecraft

A mathematical model of the solar radiation force and torques, developed for the Mariner 10 Venus/Mercury spacecraft mission, was used for a detailed analysis of the effects of solar light pressure on the Helios spacecraft. Due to the fact that the main body of the Helios spacecraft is a surface of enclosure, inside of which most of the reradiated thermal energy is lost, expressions for the portion of the solar radiation force, produced by the thermal reradiation, had to be given a different form. Hence the need for the derivation of a somewhat different theoretical model for the force acting on the main body of the spacecraft.

Georgevic, R. M.↗

NASA NTRS1980

Feasibility study of using a two-plate model to approximate the TDRSS solar pressure effects

An investigation was performed to determine the feasibility of using a two plate model to approximate the Tracking and Data Relay Satellite (TDRS) in orbit propagation, taking into account the effects of solar radiation pressure. The two plate model comprises one plate which always points to the Earth, and the other which is hinged to an axis normal to the orbital plane and is always rotated so that its normal makes a minimum angle with the direction of the sun. The results indicate that it is sufficient to take three parameters, the areas of the two plates and the reflectivity of the Earth pointing plate, to achieve an accuracy of one meter during a 24 hour orbit propagation.

Chan, F. K.↗

DOE OSTI2025

Pressure effects on lithium anode/nickel-manganese-cobalt oxide cathode pouch cells through fixture design

Applying external pressure to a pouch cell results in improved performance, implicating systems-level design of batteries. Here, different formats and amounts of external pressure to Li-Li x Ni 0.8 Mn 0.1 Co 0.1 O 2 (Li-NMC811) pouch cells were studied under lean electrolyte conditions. Due to the more uniform lithium plating/stripping, a constant gap fixture that retains the distance of the frame during cycling performed greater than a constant pressure fixture that retains applied pressure to the cell. In addition, the use of flexible foam in a constant gap fixture revealed enhanced cycle life at 10 psi; however, at 30 psi, the use of a rigid plate extended cycle life to over 250 cycles, while the foam severely shortened cycle life. This discrepancy with pressure was proven to be driven by stress distribution on cell components. The failure mechanisms and the effects of pressure fixture design on cell components were unveiled, shedding light on improving high-energy battery performance through at-scale fixture design.

25 - ENERGY STORAGE↗

DOE OSTI2023

Pressure effects on reactivity and extinction of n -dodecane diffusion cool flame

Low-temperature combustion at high pressure has gained increasing interest owing to the growing demand for clean and efficient propulsion and energy systems. In particular, cool flame structure, extinction limits, and fuel reactivities at high pressure are critical in affecting the engine performance at near-limit conditions. Here, this paper investigates the effects of pressure on the cool flame extinction limit, structure, radical index, reactivity, and oxygen concentration dependence by experiments, analysis, and modeling. A large n-alkane, namely n-dodecane (n C 12 H 26 ), is selected to study its diffusion cool flame dynamics and reactivity in a high-pressure counterflow burner up to 10 atm. The experimental results show that higher pressure increases the cool flame extinction strain rates, and that the pressure-weighted extinction strain rate (aP) is proportional to the square of pressure, P 2 . A scaling analysis explains the relationship between the dependence of flame structure, heat release rate, and pressure-weighted cool flame strain rate on pressure. Furthermore, radical indexes at different pressures are measured by isolating the thermal and transport effects from the chemical contribution to diffusion cool flame extinction. The radical index clearly shows that the low-temperature reactivity increases with pressure. In addition, due to the critical role of multiple oxygen addition reactions in low-temperature chemistry, the relationship between the cool flame extinction limit and the oxygen concentration is explored. It is found that the cool flame extinction limits are proportional to the n th power of the oxygen concentration, [O 2 ] n , and increasing pressure leads to stronger extinction limit dependence (larger n) on the oxygen concentration. The present experiment and detailed kinetic analysis show clearly that increasing pressure promotes the low-temperature chemistry including the oxygen addition reactions, while the scaling analysis explains well the experimental results.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2021

Pressure Effects on the Relaxation of an Excited Ethane Molecule in High-Pressure Bath Gases

Here, we use molecular dynamics to calculate the rotational and vibrational energy relaxation of C 2 H 6 in Ar, Kr, and Xe bath gases over a pressure range of 10 to 400 atm and at temperatures of 300 K and 800 K. The C 2 H 6 is instantaneously excited by 80 kcal/mol randomly distributed into both vibrational and rotational modes. The computed relaxation rates show little sensitivity to the identity of the noble gas in the bath. Vibrational relaxation rates show a non-linear pressure dependence at 300 K. At 800 K the reduced range of bath gas densities covered by the range of pressures do not yet show any non-linearity in the pressure dependence. Rotational relaxation is characterized with two relaxation rates. The slower rate is comparable to the vibrational relaxation rate. The faster rate has a linear pressure dependence at 300 K but an irregular, nonlinear pressure dependence at 800 K. To understand this, a model was developed based on approximating the periodic box used in the molecular dynamics simulations by an equal-volume collection of cubes where each cube is sized to allow only single occupancy by the noble gas or the molecule. Combinatorial statistics then leads to a pressure and temperature dependent analytic distribution of the bath gas species the molecule encounters in a collision. This distribution, the dissociation energy of molecule/bath gas complexes and bath gas clusters, and the computed energy release per collision combine to show that only at 300 K is the energy release sufficient to dissociate likely complexes and clusters. This suggests that persistent and pressure-dependent clusters and complexes at 800 K may be responsible for the non-linear pressure dependence of rotational relaxation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1986

Pressure effects on the thermal stability of SiC fibers

Commercially available polymer derived SiC fibers were treated at temperatures from 1000 to 2200 C in vacuum and argon gas pressure of 1 and 1360 atm. Effects of gas pressure on the thermal stability of the fibers were determined through property comparison between the pressure treated fibers and vacuum treated fibers. Investigation of the thermal stability included studies of the fiber microstructure, weight loss, grain growth, and tensile strength. The 1360 atm argon gas treatment was found to shift the onset of fiber weight loss from 1200 to above 1500 C. Grain growth and tensile strength degradation were correlated with weight loss and were thus also inhibited by high pressure treatments. Additional heat treatment in 1 atm argon of the fibers initially treated at 1360 atm argon caused further weight loss and tensile strength degradation, thus indicating that high pressure inert gas conditions would be effective only in delaying fiber strength degradation. However, if the high gas pressure could be maintained throughout composite fabrication, then the composites could be processed at higher temperatures.

Jaskowiak, Martha H.↗

NASA NTRS1989

Pressure effects on the thermal stability of silicon carbide fibers

Jaskowiak, Martha H.↗

DOE OSTI2020

Pressure Effects on the Electronic and Optical Properties in Low-Dimensional Metal Halide Perovskites

Metal halide perovskites have shown enormous potential in perovskite solar cells and light-emitting diodes and made unprecedented progress in the past decade. Additionally, pressure engineering as an effective technique can systematically modify the electronic structures and physical properties of functional materials. Low-dimensional metal halide perovskites (0D, 1D, and 2D) with a variety of compositions have soft lattices that allow pressure to drastically modulate their structures and properties. High-pressure investigations have obtained a comprehensive understanding of their structure–property relationships. Simultaneously, discoveries of novel pressure-driven properties, such as metallization and partially retained band gap narrowing have contributed significantly to the further development of such materials. In this work, we mainly highlight the effect of pressure on the properties and structures of low-dimensional metal halide perovskites, which is essential for designing new perovskite materials and advancing applications.

36 MATERIALS SCIENCE↗