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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2

Computing of Fluidic Forces in Rotating Cylinders with Application to Active Magnetic Bearing Control

Oak Ridge National Laboratory (ORNL) has been engaged to develop molten salt technologies. Molten salts are chemically aggressive liquids that operate at high temperatures. As part of this activity, ORNL designed a molten salt pump for molten salt that has no seals and that operates immersed in the salt. To minimize wear on rotating components, the pump uses active magnetic bearings (AMBs) to support the shaft and rotor. The pump is centrifugal and is oriented horizontally (A. Melin, 2013).

42 ENGINEERING↗

Stem CO2 Efflux measurements from Manaus, Brazil, 2017

This data was collected in order to test the effects of temperatures on the autotrophic respiratory process in the tropics. This data package contains raw real-time stem CO2 efflux files during the night and day from 3 different species near the K34 in Manaus during the day and the night. Raw and derived data files are included in the format of .csv and .xlsx and information about the canopy trees and temperatures recorded can be found in the field event log using microsoft excel. The data was collected from three canopy dominant trees in the central Amazon near the K34 tower. Real-time stem CO2 efflux was determined using a Li7000 gas analyzer configured in differential mode and connected to a dynamic stem chamber secured to the stem at breast height using straps to generate a reasonable seal. Ambient air was continuously pumped into the stem chamber and CO2 concentrations of the air entering and exiting the chamber were continuously monitored. CO2 efflux was calculated based on the CO2 concentration difference between ambient and stem chambers, the flow rate of air through the chamber, and the area of the enclosed stem. Additional auxiliary data, including sap flow and crown temperature were also measured. No data processing or QA/QC was done on the raw data packages.

54 ENVIRONMENTAL SCIENCES↗

Gradient Amine Sorbents for Low Vacuum Swing CO 2 Capture at Ambient Temperature

The growing concerns over CO 2 emissions have led to the development of various methods for CO 2 capture. CO 2 capture by amine-based sorbents has been achieved by temperature (thermal) swing adsorption (TSA) process, pressure swing adsorption (PSA) process, and temperature pressure or vacuuming swing adsorption (TPSA or TVSA) process for CO 2 capture. Amine sorbents for energy-efficient TSA, PSA, VSA, TPSA or TVSA CO 2 capture should possess a capability which allow adsorbed CO 2 to desorb and amine sorbent to be regenerated at low temperatures or low vacuums. Development of such amine sorbents would significantly decrease energy consumption and sorbent degradation during the regeneration step. The objective of this project is to develop a low vacuum swing adsorption (VSA) process for the capture of CO 2 from air. The focus is on the development of amine sorbent which allows CO 2 to adsorb in the form of weakly adsorbed CO 2 . The weakly adsorbed CO 2 species can be collected from the sorbent by applying a low vacuum at ambient temperature. Specifically, no heating (i.e., thermal energy) is needed for regeneration of amine sorbents. This novel sorbent allows VSA to be operated at ambient temperature without a significant energy demand. This process eliminates the energy-intensive heating and cooling process in temperature swing adsorption (TSA) process. Ambient temperature operation could prolong the lifetime of sorbent and minimize the maintenance cost. Extensive sorbent studies with in-situ infrared spectroscopy have revealed the modifications of conventional amine sorbents with additives can increase the fraction of weakly adsorbed CO 2 . The amine sorbents with loaded CO 2 can be regenerated in part by the following approaches: (i) mild heating to temperatures below 70 °C, (ii) flowing purging gas over modified amine sorbents at temperatures below 40 °C, (iii) vacuuming at pressure below 0.2 atm and temperatures below 40 °C. The performance of these modified amine sorbents has been tested in a 60 grams VSA unit at ambient temperatures. The results show that weakly adsorbed CO 2 which can be desorbed from modified amine sorbents with purging gas at 100 cc/min can also be evacuated at a vacuum of 1 psia at room temperature. A preliminary techno- economic analysis indicates the major cost of the VSA process with modified amine sorbents stems from the operation of vacuum pumps. Thus, developing an excellent sealing with minimum leakage for the VSA unit is the most critical task for further the development of this VSA technology.

36 MATERIALS SCIENCE↗

Size Up or Size Down? National Analysis of Heat Pump Sizing and Impacts

Electrification of on-site fossil fuel combustion in buildings is recognized as a key component of achieving global greenhouse gas emissions targets. Air-source heat pumps are an efficient approach for space heating electrification. However, a major barrier to heat pump adoption is the high installation cost relative to furnaces and air conditioners. Because the installation cost of heat pumps - especially cold climate models - is dependent on their size, it is important to understand the distribution of heat pump sizes using different sizing methods and factors that impact heat pump sizing. In this study, we use sub-hourly physics simulations of 550,000 statistically representative dwelling units to analyze the distribution of heat pump size in the U.S. for three different efficiency levels of heat pumps, with and without building insulation and air sealing upgrades. We will present results from the national analysis of different factors affecting heat pump sizing along with the impact of sizing decisions on upgrade costs and operating costs.

electrification↗

PARTICULATE STUDY OF NEG PUMPS IRRADIATED IN THE CEBAF TUNNEL

Non-evaporable getter (NEG) pumps are being used to maintain ultra-high vacuum in the beamline of superconducting radio-frequency (SRF) accelerators, such as the Continuous Electron Beam Accelerator Facility (CEBAF) at Jefferson Lab. Because of the sensitivity of the performance of SRF cavities to particulate contamination, it is important to evaluate the integrity of the NEG material after exposure to high radiation during beam operation. The particulate from two NEG pumps based on ZAO® getter alloy was measured with a particle counter in a clean-room. The pumps were assembled onto a hermetically sealed setup which was placed in the CEBAF tunnel. The setup was exposed to 24 h beam operation for ~ 230 days. The total gamma-rays dose measured on the test setup was ~ 1.6 Mrad. The total neutron dose measured at ~ 75 cm of the test setup was ~ 11 krad. The particulate count from the two pumps was measured again in the clean-room after irradiation. Whereas an increase of particulate counts was measured, compared to before irradiation, subsequent measurements indicate the absence of systematically loose particulate. The pumping speed of one of the irradiated pumps was also measured to be consistent with that of a non-irradiated one, corroborating the absence of significant damage to the ZAO® NEG material due to irradiation.

Ciovati, G. [Thomas Jefferson National Accelerator↗

PARTICULATE STUDY OF NEG PUMPS IRRADIATED IN THE CEBAF TUNNEL

Non-evaporable getter (NEG) pumps are being used to maintain ultra-high vacuum in the beamline of superconducting radio-frequency (SRF) accelerators, such as the Continuous Electron Beam Accelerator Facility (CEBAF) at Jefferson Lab. Because of the sensitivity of the performance of SRF cavities to particulate contamination, it is important to evaluate the integrity of the NEG material after exposure to high radiation during beam operation. The particulate from two NEG pumps based on ZAO® getter alloy was measured with a particle counter in a clean-room. The pumps were assembled onto a hermetically sealed setup which was placed in the CEBAF tunnel. The setup was exposed to 24 h beam operation for ~ 230 days. The total gamma-rays dose measured on the test setup was ~ 1.6 Mrad. The total neutron dose measured at ~ 75 cm of the test setup was ~ 11 krad. The particulate count from the two pumps was measured again in the clean-room after irradiation. Whereas an increase of particulate counts was measured, compared to before irradiation, subsequent measurements indicate the absence of systematically loose particulate. The pumping speed of one of the irradiated pumps was also measured to be consistent with that of a non-irradiated one, corroborating the absence of significant damage to the ZAO® NEG material due to irradiation.

Ciovati, Gianluigi [Thomas Jefferson National Acce↗

Characterization of the Insoluble Solids of the 241-17F and 241-49H Pump house Water Sample

Six different water samples from 241-17F and 241-49H pump house were analyzed for chemical and physical characteristics as part of efforts to understand recent mechanical seal failures associated with four new cooling water pumps. A focus of this work was characterization of any “as found” insoluble solids. The insoluble material found in the FCRW (F-Area caustic water treated with sodium chromate at 241-17F) sample are mostly magnetite (Fe3O4 or possibly equipment rust) and silica. It was found that 26% of measured FCRW particles have at least one dimension larger than 15 microns. The insoluble particles found in the source water, domestic water (FDW), are mostly kaolin (aluminosilicate) and some iron oxide. All found FDW particles were larger than 15 microns. The insoluble particles of the other source water, FArea well water (FWW), were mostly iron oxide with some trapped cations like calcium. Only 8% of found FWW particles were bigger than 15 microns.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Demonstration of an All-Refractory Corrosion-Resistant Molten Salt Pumping and Storage Infrastructure Up to 950 degrees C

Concentrating solar power (CSP) with thermal energy storage (TES) has an estimated cost similar to solar photovoltaics (PV) with lithium-ion batteries (LIB), but CSP + TES has the potential for significantly reduced cost by operating above 700 degrees C. However, this requires a TES medium and containment infrastructure which are chemically compatible and do not degrade above 700 degrees C. MgCl2-KCl-NaCl (MKN) salt is a promising medium, but when MKN salt has small amounts of water and oxygen dissolved in it, it excessively corrodes conventional commercial alloys. Here, we consider refractory materials including graphite, carbon-carbon composite (C/C), and molybdenum because they maintain high mechanical strength at elevated temperatures and are expected to resist corrosion by MKN salt. While selection of refractory materials is often constrained by the need to remain chemically stable in air, this work uses an enclosure filled with inert gas to allow the use of materials like graphite and molybdenum. Notably, graphite components can seal against liquids unlike many brittle refractory materials. We demonstrate a centrifugal pump and mechanical seals made of refractory materials in a laboratory-scale circulation loop, which successfully operated continuously for more than 49 h at temperatures ranging from 750 degrees C to 950 degrees C with no mechanical failures or chemical degradation of the refractory materials. To the best of our knowledge, this is the highest temperature molten salt circulation loop that has been successfully developed, and this refractory infrastructure allows for operation at even much higher temperatures (<1600 degrees C) if a storage medium with a lower vapor pressure is used. The principles of this architecture are relevant to other applications with high temperature flowing metals and salts including Generation IV nuclear fission reactors for power production and molten salt electrolysis reactors for metallurgical processing.

14 SOLAR ENERGY↗

Undulating transducer for energy harnessing and propulsion apparatuses, methods and systems

Embodiments disclosed may serve the function of a pump, a generator, or a propulsion system. Two flexible fins are coupled via their longitudinal inner edges to fin coupling modules. An external fluid flow causes traveling fin undulations. The angle of the fins relative to each other changes as undulations travel along the fins which can be translated through the fin coupling modules into mechanical work, powered by the external fluid flow. The mechanical work of the fin coupling modules may be the cyclical extension and contraction of pistons or bellows incorporated into the fin coupling modules, which may draw ambient fluid during their extension cycles and compress fluid during their contraction cycles to create a pump. The pistons or bellows may also be sealed from ambient fluid but connected through conduits through which contained fluid is exchanged in a continuous circulation of fluid to power a pump or a turbine.

Filardo, Benjamin Pietro↗

Metastability exchange optical pumping of 3 He at low pressure and high magnetic field

We report systematic studies on metastability exchange optical pumping of 3 He nuclei have been performed at Jefferson Lab using a 1-torr sealed cell at magnetic fields from 2 to 4 T. The effects of the discharge intensity, pump laser power and pumping transition schemes on achievable nuclear polarization and pumping rate have been investigated. A maximum steady-state nuclear polarization of about 75% has been obtained. This work provides a baseline for the development of the novel polarized 3 He target for CLAS12 at Jefferson Lab.

47 OTHER INSTRUMENTATION↗

High Temperature Ternary Chloride Molten Salt Pump

A ternary chloride (MgCl2-NaCl-KCl) molten salt pump has been developed to operate up to 720°C. The design is the result of a thermal, structural and material study of critical components. The vertical overhung pump incorporates first of a kind salt-wetted hydrodynamic bearings. Several bearing material pairings were tested which include: colmonoy grades, stellite grades, and a novel NiWC-based alloy (i.e. HybrimetTM NiWC3b) used as a High Velocity Oxygen Fuel (HVOF) coating. The coating withstands the corrosion effects of the molten salt, and is also used to protect a 316L stainless steel pump reservoir. The pump bowl assembly components are made of Inconel 625. A Nitrogen flushed carbon ring seal is used to keep salt vapors from interacting with external ambient air. Preliminary testing shows a promising pump design for use in the Concentrating Solar Power Gen 3 systems and sets the ground for further development of the HybrimetTM NiWC3b as a competitive alternative to available superalloys.

Handy-Cardenas, Lewis (ORCID:0009000744006972)↗

High Temperature Ternary Chloride Molten Salt Pump

This work investigates the design criteria considering thermal, structural, and material selection of a ternary chloride (MgCl2-NaCl-KCl) molten salt pump that is capable of running at temperatures above 720 °C. In this work, preliminary testing of salt-wetted hydrodynamic bearings was done to investigate different material pairings including Colmonoy grades, Stellite grades, and a novel Nickel Tungsten Carbide alloy (HybrimetTM NiWC3b) used as a High Velocity Oxygen Fuel (HVOF) coating. The coating has shown to withstand the corrosive nature of the molten salt. The pump wetted components are made of Inconel 625 and features a carbon ring seal (CIRPAC Seal) flooded with a N2 gas flow on the overhead to keep salt vapors from interacting with the external ambient air. A comprehensive pump test program has been completed. Over 90 hours run time pumping hot chloride salts at temperatures up to 720 °C in which enough data was captured to produce performance curves at 3 different operating speeds. This research showcases a promising design for use in the Concentrated Solar Power (CSP) Gen 3 liquid-pathway and sets the ground for further development and use of the HybrimetTM NiWC3b as a competitive alternative to available superalloys.

14 SOLAR ENERGY↗

MAGNETICALLY SUSPENDED CANNED ROTOR PUMPS FOR THE INTEGRAL MOLTEN SALT REACTOR

This project developed a molten salt pump design for small modular reactors, concentrated solar, and Gen IV nuclear reactors with a magnetically levitated rotor that can operate at temperatures of up to 700 °C. This eliminates the need for rotating seals and roller element bearings which require maintenance and are prone to failure. The pump design is also more compact than existing molten salt pump designs which require long shafts to thermally isolate the electric motor. The aims of the project are to: 1) design and test the molten salt pump, 2) develop and test a high temperature position sensor needed for magnetic bearing control, and 3) develop and test high temperature coil fabrication methods for electric motor and magnetic bearing fabrication. To develop the high temperature coils, conductor materials were analyzed for oxidation, diffusion, cladding, and resistivity. Of the candidate conductor materials that met the requirements, silver was chosen. The long-term impact of radiation on silver resistivity was analyzed by developing a model of a generic molten salt fast reactor to model the conductor irradiation in worst case scenarios. The analysis showed that increased resistivity due to transmutation of silver decreases exponentially with the reactor reflector thickness. Different electrical insulation materials were tested and the final high temperature coils developed were able to withstand conductor to ground voltages up to 1800 V before insulation breakdown. Magnetic bearings require high-precision high-speed measurements of the rotor position to operate. Current commercial position sensors can only operate up to 550 °C so a novel position sensor was developed that can operate up to 800 °C. These sensors were also designed to measure the position of the metallic rotor through a thin metallic corrosion barrier that protects that coils, insulation, and magnetic cores so that the salt containment barrier does not have any penetrations. The high-temperature sensor was tested and had comparable performance to commercially available inductive position sensors. The sensor design and signal processing has led to several invention disclosures. The magnetically levitated molten salt pump design was completed and analyzed. The chloride salt test loop at Oak Ridge National Laboratory was chosen to test the pump and the pump hydraulics and power were designed for the test loop flow and pressure requirements. Classes of motor designs that do not utilize permanent magnetic were considered for the high-temperature motor. After extensive analysis of their performance, a synchronous reluctance motor was chosen for the pump. The design was refined and analyzed to optimize performance. The magnetic bearings were designed to meet the force and frequency requirements necessary to levitate the rotor and reject disturbances from rotor imbalance, motor forces, and hydraulic forces. Compliant mounts for the position sensors were designed that would not damage the ceramic sensor components and maintain sensor alignment over a wide temperature range. A thermal hydraulic analysis of the molten salt coolant flow used to cool the rotor and stator was performed to ensure that the maximum temperature in the rotor and stator will not exceed 725 °C. The corrosion barrier and casing were designed to maintain the salt fluid boundary by using compliant features to absorb large expansion mismatches due to different coefficients of thermal expansion (CTE). Finally, the salt drain and fill systems were designed along with the pump support structure, integration with the test loop, and thermal insulation and heating. Corrosion barrier fabrication experiments were performed to assess using laser cladding to apply a sub-millimeter corrosion barrier to the surface of a Fe-Co-V magnetic core material. The cladding method showed minimal mixing between materials at their interface and withstood temperature cycling without damage to the cladding. The technology commercialization is focused on the high-temperature position sensors and there has been significant interest from the nuclear industry in utilizing these sensors along with some interest from the aerospace industry. The project also led to a research collaboration with a fusion energy industrial partner to study barriers to scaling the pump design from the kW size to the MW size. This research collaboration will also study methods to create high-temperature coils that have conductor to ground breakdown voltages above 5 kV. The successful development of high-temperature electromagnetic coils and high-temperature position sensors greatly increases the temperature limits for electromagnetic devices that don’t rely on permanent magnets. This includes electric motors, magnetic bearings, linear actuators, rotary position and velocity sensing, actuated valves, and generators to name a few. This will fill a current need in molten salt reactors, concentrated solar, and fusion energy for these critical peripheral devices needed for practical reactor designs that do not currently have commercial solutions.

Hines, J Wesley↗

High Temperature Ternary Chloride Molten Salt Pump

This work investigates the design criteria considering thermal, structural, and mate-rial selection of a ternary chloride (MgCl2-NaCl-KCl) molten salt pump that is capable of running at temperatures above 720 °C. In this work, preliminary testing of salt-wetted hydrodynamic bearings was done to investigate different material pairings including colmonoy grades, stellite grades, and a novel NiWC-based alloy (i.e. HybrimetTM NiWC3b) used as a High Velocity Ox-ygen Fuel (HVOF) coating. The coating has shown to withstand the corrosive nature of the salt, and is additionally used to protect a 316L stainless steel pump reservoir. The pump wetted components are made of Inconel 625, and it features a carbon ring seal developed by Flows-erve flooded with a N2 gas flow on the overhead to keep salt vapors from interacting with the external ambient air. This research showcases a promising design for use in the CSP Gen 3 liquid-pathway and sets the ground for further development and use of the HybrimetTM NiWC3b as a competitive alternative to available superalloys. Further work will further characterize the pump by performance & cycle testing in molten salt at higher temperatures.

14 SOLAR ENERGY↗

ResStock Measure Documentation: Residential Two-Stage Geothermal Heat Pump (4.0 COP, 20.5 EER) With Light Envelope Improvements

This report is part of series describing a variety of different ResStock(TM) measures. "Measures" refers to energy efficiency retrofits that can be applied to buildings during modeling. This documentation covers the "Residential Two-Stage Geothermal Heat Pump (4.0 COP, 20.5 EER) With Light Envelope Improvements" measure upgrade methodology and briefly discusses key results. All results can be accessed on the ResStock Open Energy Data Initiative "End-Use Load Profiles for the U.S. Building Stock" data lake and on the data viewer at resstock.nlr.gov.

15 GEOTHERMAL ENERGY↗

ResStock Measure Documentation: Residential Variable-Speed Geothermal Heat Pump (4.4 COP, 30.9 EER) With Light Envelope Improvements

This report is part of series describing a variety of different ResStock™ measures. "Measures" refers to energy efficiency retrofits that can be applied to buildings during modeling. This documentation covers the "Residential Variable-Speed Geothermal Heat Pump (4.4 COP, 30.9 EER) with Light Envelope Improvements" measure upgrade methodology and briefly discusses key results. All results can be accessed on the ResStock Open Energy Data Initiative "End-Use Load Profiles for the U.S. Building Stock" data lake and on the data viewer at resstock.nlr.gov.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Simulating Fracture Sealing by Granular LCM Particles in Geothermal Drilling

Lost circulation occurs when the returned fluid is less than what is pumped into the well due to loss of fluid to pores or fractures. A lost-circulation event is a common occurrence in a geothermal well. Typical geothermal reservoirs are often under-pressured and have larger fracture apertures. A severe lost-circulation event is costly and may lead to stuck pipe, well instability, and well abandonment. One typical treatment is adding lost-circulation materials (LCMs) to seal fractures. Conventional LCMs fail to properly seal fractures because their mechanical limit is exceeded at elevated temperatures. In this paper, parametric studies in numerical simulations are conducted to better understand different thermal effects on the sealing mechanisms of LCMs. The computational fluid dynamics (CFDs) and the discrete element method (DEM) are coupled to accurately capture the true physics of sealing by granular materials. Due to computational limits, the traditional Eulerian–Eulerian approach treats solid particles as a group of continuum matter. With the advance of modern computational power, particle bridging is achievable with DEM to track individual particles by modeling their interactive forces between each other. Particle–fluid interactions can be modeled by coupling CFD algorithms. Fracture sealing capability is investigated by studying the effect of four individual properties including fluid viscosity, particle size, friction coefficient, and Young’s modulus. It is found that thermally degraded properties lead to inefficient fracture sealing.

15 GEOTHERMAL ENERGY↗

DOE Zero Energy Ready Home Case Study HIA 2021: Insight Homes, The Brenner, Felton, DE

Case study of a DOE 2021 Housing Innovation Award winning custom home in a mixed-humid climate that got a HERS 51 without PV, with 1,940 square feet, MERV 13 filters and low-emission paints, adhesives, and carpeting; plus a sealed, conditioned crawl space, and a high-efficiency gas furnace and heat pump.

Building America, residential construction, home b↗